• Title/Summary/Keyword: $NO_2/NO_x$ ratio

검색결과 545건 처리시간 0.028초

디메틸술폭시드용매중에서 Thorium (IV)-Crown Ether 착물의 산화-환원 반응메카니즘 (Redox Reaction Mechanisms of Thorium (IV) Complexes with Crown Ethers in Dimethylsulfoxide)

  • 정학진;정오진;서혁춘
    • 대한화학회지
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    • 제31권3호
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    • pp.250-257
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    • 1987
  • DMSO와 $H_2O$용매 중에서 결합구조가 밝혀진 동공의 크기를 달리한 토륨(IV) 착물들의 전기전도도를 측정하여 해리현상과 전해질의 행동을 알아 보고 DMSO용매중에서 polarography와 cyclic voltammography적 거동을 조사하여 합성착물의 산화환원반응 메카니즘, 가역성을 알아 보고 환원과정에 관여하는 전자수 및 착물의 확산계수를 계산하였다. 그 결과 반양성자성 용매에서 모든 착물들은 1:1전해질로, 물에서는 1:4전해질로 각각 행동하고, DMSO용매중에서 각 착물의 환원반응은 1전자 1단계의 환원반응으로 가역적이며 확산계수는 착물종에 따라 $5.831{\times}10^{-6}{\sim}6.900{\times}10^{-6}$이었다. 그리고 모든 착물의 물분자는 -1.8V(대조전극, SCE)이상에서 분해를 일으켜 수소기체를 발생한다.

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우리 나라 청정지역에서의 황과 질소 농도 비의 특성 (Characteristics of Concentration Ratio of Sulfur and Nitrogen at Background Areas in Korea)

  • 이종훈;김용표;문길주;김희강
    • 한국대기환경학회:학술대회논문집
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    • 한국대기환경학회 1999년도 추계학술대회 논문집
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    • pp.139-140
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    • 1999
  • 우리 나라, 일본, 중국, 대만, 홍콩 등을 포함하는 동북아시아지역은 전세계 인구의 1/3 이상이 살고있으며, 급속한 경제성장을 보이고 있다. 이에 따른 주민의 생활수준 향상과 생산활동의 증가에 따라 오염물질의 배출량도 급격한 증가추세를 보이고 있어, 이 지역 환경에 큰 영향을 미치고 있다. 동북아시아지역의 대기오염과 관련하여 주목할 것은 이 지역에서 $SO_2$$NO_x$ 같은 인위적인 산성오염 물질의 배출량이 급증하고 있는 것이다.(중략)

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다단 생물반응기에 의한 질소제거 (Nitrogen Removal from Wastewater by a Multi-stage Bio-reactor)

  • 최규철;정일현
    • 환경위생공학
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    • 제13권1호
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    • pp.91-103
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    • 1998
  • Design data for COD and nitrogen removal from wastewater were collected from Pilot's Multi-stage Bio-reactor. Hyraulic conditions and pollutant loadings were varied in order to optimize the biological and operational parameters. Pilot's experimental results summarize as followings. 1. T-N removal efficiency in the organic volumetric loading 0.2 kgCOD/m$^{3}$·d was obtained as maxium of 85% at internal recycle ratio 2.5 and in more ratio than this it was decreased. Organic removal efficiency was about 91% under the overall experimental conditions and not influenced by recycle ratio.. 2. Nitrification reaction was shown as maxium in the SCOD$_{cr}$/NH$^{+}$-N ratio of 6.5 and in more ratio than this it was decreased. Denitrification rate was the maxium as 85% in more than 7.5 of SCOD$_{cr}$/NO$_{x}$-N ratio and in the ratio over this ratio it becomes constant. 3. By utilizing an applied new model of Stover-Kincannon from Monod's kinetic model, concentration of T-N in the effluent according to flow quanity in the influent was estimated as 8.74 and -67.5 respectively. The formula for estimating T-N concentration of effluent was obtained like this: N$_e$=N$_0$(1- $\frac{8.74}{(QN$_0$/A)-67.05}$)

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규폐증에서 Gallium-67 신티그라피의 정량적인 분석: 흉부 X-선과 폐기능검사와의 비교 (Quantitative Ga-67 Scintigraphy in patients with Silicosis: Comparison with Chest X-ray and Pulmonary Function)

  • 신광현;손형선;정용안
    • 대한핵의학회지
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    • 제33권4호
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    • pp.381-387
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    • 1999
  • 목적: 직업성 질병은 원인 규명과 함께 병의 진행정도를 정확히 평가하는 것이 중요하여 ILO에서 흉부 X-선 소견을 기준으로 국제표준화를 시행하여 왔으나 사진의 질에 영향을 받을 수 있고, 초기 병변을 발견하기에는 어려움이 많다. 본 연구자들은 Ga-67의 섭취정도를 규폐증의 진행 정도를 나타내는 지표로 이용하기 위하여 폐기능검사 및 흉부 X-선 소견에 의한 임상적 병기 분류와의 상관관계를 보고자하였다. 대상 및 방법: 25명의 규폐증 환자를 대상으로 Ga-67 신티그라피를 분석하였으며 10명의 정상인을 대조군으로 하였다. 검사방법은 Ga-67 citrate, 5 mCi를 정맥 주사한 후 48시간 후 전신 스캔 및 흉부, 복부 스캔 영상을 얻어 후면상에서 간과 폐병변의 최대 섭취 부위의 관심영역을 설정하여 픽셀당 방사능 섭취 정도의 비를 구하여 임상적 병기 분류와의 상관관계를 비교 분석하였다. 결과: L/L Ratio 값은 정상군 0형(n=10): $0.3948{\pm}.0692$0, 1형(n=10): $0.5763{\pm}$0.1837, 2형(n= 11): $0.6849{\pm}0.1459$, 3형(n=4): $0.9913{\pm}0.0712$였으며 흉부 X-선의 분류형과 서로 유의한 상관관계를 보였다(r=0.618, p<0.05). 그러나 L/L Ratio 값과 폐기능검사 지표와는 통계적으로 유의하지 않았다. 결론: 저자들의 연구에 따르면 규폐증의 진행과정을 평가하여 환자의 병기를 결정하는 데 Ga-67 신티그라피의 정량적인 분석이 도움을 주었다. 그러나 폐기능과는 상관관계가 없어 폐기능을 평가하는 지표가 되지 못하였다.

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알루미늄이 첨가된 Li(Ni1/3Co1/3Mn1/3-xAlx)O2 양극활물질의 전기화학적 특성 (Electrochemical Properties of Al Doped Li(Ni1/3Co1/3Mn1/3-xAlx)O2, Cathode Materials)

  • 김선혜;심광보;김창삼
    • 전기화학회지
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    • 제9권2호
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    • pp.64-69
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    • 2006
  • 초음파분무열분해법과 한 단계의 후열처리로 이차상이 없는 Al이 첨가된 $Li(Ni_{1/3}Co_{1/3}Mn_{1/3-x}Al_x)O_2$ (x=0.0, 0.005, 0.01. 0.05) 리튬이차전지용 양극활물질을 합성하였다. 합성된 분말은 Al의 첨가량이 많아짐에 따라서 $I_{003}/I_{104}$ 비는 감소하고 입자가 커지는 경향을 보였다. 상온에서 전류밀도 1C의 rate로 $3.0\sim4.5V$ 범위에서 충방전 시험한 결과, Al 치환량이 0.5와 1.0 at%에서는 초기용량이 180과 $184mAhg^{-1}$으로 치환하지 않았을 때의 $182mAhg^{-1}$과 차이가 없었으며, 싸이클 특성도 치환하지 않은 것과 0.5, 1.0 at% 치환한 조성에서 각각 81, 77, 81%의 방전용량이 유지되었다. 그러나 $3.0\sim4.6V$에서는 치환효과가 확실하게 나타나서, 50 싸이클 후의 치환하지 않은 것의 방전용량은 초기용량의 30%가지 감소한데 비하여 Al을 0.5 at% 치환한 것은 70%를 유지하였다. 치환에 의한 싸이클 특성 향상은 XPS 분석 결과 Al 치환이 $Mn^{3+}$의 양을 감소시켰기 때문인 것으로 사료되었다.

가시광선중합화에 따른 충전용 Glass Ionomer Cement의 물리적 성질에 관한 연구 (A STUDY ON THE PHYSICAL PROPERTIES OF GLASS IONOMER CEMENT FOR RESTORATIVE FILLING USING VISIBLE LIGHT POLYMERIZATION)

  • 신동훈;권혁춘
    • Restorative Dentistry and Endodontics
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    • 제17권2호
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    • pp.307-330
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    • 1992
  • The aim of this study was to investigate the physical properties of visible light curing Glass Ionomer cement for restorative esthetic filling. The control group was the autopolymerizing GC Fuji II Glass Ionomer cement (2.2: 1 P/L ratio) and the experimental groups were made by following procedure. To induce the polymerization by visible light, the powder of GC Fuji II GI cement and the liquid of Vitrabond for base & liner were mixed in an amalgam capsule with 2.5:1, 3.0:1, 3.5:1 P/L ratio (% wt/wt). After fabrication of specimens, compressive strength, fracture toughness ($K_{IC}$) Scanning Electron Microscope and X-ray Diffraction, water-leachable content, marginal leakage and surface roughness were studied. The results were as follows: 1. Only experimental No. 1 group (visible light curing) showed less compressive strength than control group 1 hour after curing. Strength was increased with aging in all groups, so the compressive strength of light curing groups was no less than that of autopolymerizing group after 3 weeks. 2. Experimental No.3 group (visible light curing) was inferior to No.2 group (visible light curing) in fracture resistance but light curing groups were more resistant to fracture than autopolymerizing group and showed ductile fracture pattern as compared with the brittle fracture pattern of autopolymerizing group. 3. From scanning electron microscopic image, various sized unreacted powder particles, surrounded by silica gel, were embedded in polysalt matrix. Light curing groups showed little crack and more dense unreacted particles than autopolymerizing group. 4. From X-ray diffraction analysis, GC Fuji II Glass Ionomer cement powder and all groups showed glassy appearance but light curing groups seemed to be more intensive in crystaline than autopolymerizing group. S. The most significant dissolution was shown in early setting period in all group. Light curing groups were dissolved less than autopolymerizing group. 6. Marginal leakage was not different significantly in case of cavity margin composed of same tooth structure (ex. only enamel margin, only dentin margin) but much more leakage was shown in dentin/cementum margin than enamel margin. In only case of only enamel margin, light curing groups were superior to autopolymerizing group. 7. All groups showed relatively smooth surface, which irregularity was less than $1{\mu}m$. Light curing groups were smoother than autopolymerizing group.

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천궁의 현탁배양에서 탄소원과 질소원이 체세포배 형성에 미치는 영향 (Effect of Carbon and Nitrogen Source on Somatic Embryogenesis in Suspension Culture of Ligusticum chuanxiang Hort.)

  • 채영암;박상언
    • 한국약용작물학회지
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    • 제2권1호
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    • pp.44-50
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    • 1994
  • 1. 2.4-D 0.5mg/1에서 배발생캘러스 생장과 발생빈도가 가장 양호하였다. 2. 배지 중에서 MS배지가 체세포배 형성과 생육에 좋았으며, 1X MS배지 보다 1/2X MS배지가 배형성에 더 효과적이었다. 3. 탄소원으로는 sucrose가 효과적이었다. 농도는 1%처리가 가장 양호하였으며 농도가 높아짐에 따라 체세포배 형성이 억제되었다. 4. Sucrose 대신 sugar 처리에서도 체세포배 형성이 앙호하였다. 5. 질소원으로는 $KNO_3\;825mg\;/\;l$$NH_{4}NO_3$ 238mg /l 처리가 배발생에 가장 효과적이었다.

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흙의 물리적 성질이 다짐에 미치는 영향 (A Study on the Effect of Some Physical Properties of Soil on the Compaction)

  • 김성교;김문기
    • 한국농공학회지
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    • 제18권3호
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    • pp.4171-4183
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    • 1976
  • This study is to investigate the effect of some physical properties of soil on the compaction. The compaction effect depends upon various factors such as soil type, moisture content, gradation and compaction energy. In this study, with steady compaction energy, the relationships between maximum dry density and moisture content, gradation and consistency were analyzed by soil types. Some results obtained in this study are summarized as follows 1. Generally, the coarser the grain size, the bigger is the maximum dry density and the smaller is the optimum moisture content and its moisture-dry denisty curve is relatively steep. The finner the grain size, the smaller is the max. dry density and the bigger is the opt. moisture content and its moisture-dry density curve is less steep. 2. The relationship between max. dry density (${\gamma}$dmax) and opt. moisture content, void ratio, clay content, percent passing of No. 200 sieve, liquid limit and plastic limit can be represented by the equation ${\gamma}$dmax =ao+a1X(a0>0, a1<0) 3. The relationship between opt. moisture content (Wopt) and clay content, percent passing of No. 200 sieve, liquid limit and plastic limit can be represented by the equation Wopt=a0+a1X(a0>0, al>0). 4. The fact that maximum dry density of the compacted soil is decreased with the increase of the optimum moisture content in any types of soil tested, and the fact that optimum moisture content can be positively correlated with clay content, percent passing of No. 200 sieve, liquid limit and plastic limit of the soil, lead to the conclusion that clay content, percent passing of No. 200 sieve, liquid limit and plastic limit of the soil are direct factors in reduction of the maximum dry density of engineering soil.

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일부 제조업 남성근로자의 요통경험 및 관련요인 (Low Back Pain and Related Factors in Men Workers for Manufacturing Industry)

  • 이승주;김기열;차상은;박상래;임원식
    • The Journal of Korean Physical Therapy
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    • 제12권2호
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    • pp.7-15
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    • 2000
  • Objectives: The purpose of this study w8s to investigate the experience rate and point prevalence and factors related with Low Back Pain(LBP) in men workers for the manufacturing industry. Methods: Questionnaires were completed by 97 men workers for 1 vehicle company in Taegu city in September 6-26, 2000. The information was used to estimate odds ratio and $95\%$ confidence intervals fur the LBP related factors association. Results: The experience rate for LBP was $67.0\%$. point prevalence was $14.4\%$. Variables significantly associated with LBP were weight(p=0.052) and smoking(p=0.010). $57\%$ for patients with LBP was higher than 50.095 far without in normal weight. whereas $43.0\%$ for patients with LBP was smaller than $50.0\%$ for without in overweight. $73.8\%$ for patients with smoking increased than $46.9\%$ for smokers without in smoking. The experience for LBP increased as weight increased(Odds ratio=2.923). As subjects are getting older. experience increased(Odds ratio= 1.393). The higher subjects had experienced stress, the higher experience for LBP was(Odds ratio= 1.328), however all three variables had no significant relationship. Conclusions: Results from this study indicated that a statistically significant association between LBP and weight. smoking in X2-test. In logistic regression test, there were no related variables.

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FT반응 Off-gas를 이용한 고압축비 전기점화 엔진의 연소 및 배기가스 특성에 관한 연구 (Combustion and Emission Characteristics in a High Compression Ratio Spark Ignition Engine using Off-gas from FT reaction)

  • 정탄;이준순;이용규;김창업;오승묵
    • 한국분무공학회지
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    • 제23권3호
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    • pp.114-121
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    • 2018
  • FT process is a technology of chemical reactions that converts a mixture of carbon monoxide and hydrogen into liquid hydrocarbons. During the FT process unreacted gas, known as Off-gas which has low-calorie, is discharged. In this study, we developed an engine that utilize simulated Off-gas, and studied the characteristics of the engine. The off-gas composition is assumed to be $H_2$ 70%, CO 15%, $CO_2$ 15% respectively. Under stoichiometric air-fuel ratio, the experiment was conducted at WOT and IMEP 0.3 Mpa changing compression ratio. Ignition timing was applied with MBT timing. Maximum indicated thermal efficiency 37% was achieved at compression ratio 15 under WOT. CO, $CO_2$ and $NO_x$ were influenced by changing compression ratio, and CO emission was satisfied with the US Tier 4 standard for nonroad engine over the entire experimental conditions.