• 한국수소및신에너지학회논문집
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• 제23권1호
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• pp.83-92
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• 2012

Syngas combustion characteristics of mass produced oxygen carrier particle (OCN706-1100) were investigated in a pressurized fluidized bed reactor using simulated syngas and air as reactants for reduction and oxidation, respectively. The oxygen carrier showed high fuel conversion, high $CO_2$ selectivity, and low CO concentration at reduction conditions and no NO emission at oxidation conditions. Moreover, OCN706-1100 particle showed good regeneration ability during successive reduction-oxidation cyclic tests up to the 10th cycle. Fuel conversion and $CO_2$ selectivity decreased and CO emission increased as temperature increased. These results can be explained by trend of calculated equilibrium CO concentration with temperature. However, fuel conversion and $CO_2$ selectivity increased and CO emission decreased as pressure and gas residence time increased.

• 한국환경과학회지
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• 제20권12호
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• pp.1647-1661
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• 2011

The Government had devised legislation of Special Act and drew up guidelines for improving air quality in Seoul Metropolitan area. In 2007 local government of Seoul, Incheon and Gyeonggi conducted the results of application policy by reduced air pollutants emission for the first time. Although there was reduction of air pollutant emission in each local government, it was ineffective as expected using air pollution monitoring database. Therefore we worked out a way to prepare modeling input data using the results of enforcement plan. And we simulated surface $NO_2$ and PM10 before and after decrease in air pollutants emission and examine reduction effects of air pollution according to enforcement regulation except other influence, by using MM5-SMOKE-CMAQ system. Each local government calculated the amount of emission reduction under application policy, and we developed to prepare input data so as to apply to SMOKE system using emission reduction of enforcement plan. Distribution factor of emission reduction were classified into detailed source and fuel codes using code mapping method in order to allocate the decreased emission. The code mapping method also included a way to allocate spatial distribution by CAPSS distribution. According to predicted result using the reduction of NOx emission, $NO_2$ concentration was decreased from 19.1 ppb to 18.0 ppb in Seoul. In Gyeonggi and Incheon $NO^2$ concentrations were down to 0.65 ppb and 0.68 ppb after application of enforcement plan. PM10 concentration was reduced from 18.2 ${\mu}g/m^3$ to 17.5 ${\mu}g/m^3$ in Seoul. In Gyeonggi PM10 concentration was down to 0.51 ${\mu}g/m^3$ and in Incheon PM10 concentration was decreased about 0.47 ${\mu}g/m^3$ which was the lower concentration than any other cities.

• 대한기계학회논문집B
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• 제29권9호
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• pp.979-987
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• 2005

Numerical simulations were performed at atmospheric pressure in order to understand the effect of additives on flame speed, flame temperature, radical concentrations, $NO_x$ formation, and heat flux in freely propagating $CH_4-Air$ flames. The additives were both carbon dioxide and hydrogen chloride which had a combination of physical and chemical behavior on hydrocarbon flame. In the flame established with the same mole of methane and additive, hydrogen chloride significantly contributed toward the reduction of flame speed, flame temperature, $NO_x$ formation and heat flux by the chemical effect, whereas carbon dioxide mainly did so by the physical effect. The impact of hydrogen chloride on the decrease of the radical concentration was about $1.4\~3.0$ times as large as that of carbon dioxide. Hydrogen chloride had higher effect on the reduction of $EI_{NO}$ than carbon dioxide because of the chemical effect of hydrogen chloride. The reaction, $OH+HCl{\rightarrow}Cl+H_2O$, played an important role in the heat flux from flames added by hydrogen chloride instead of the reaction, $OH+H_2{\rightarrow}H+H_2O$ which was an important reaction in hydrocarbon flames.

• 대한환경공학회지
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• 제28권2호
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• pp.191-196
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• 2006

유전체장벽방전에 의해 발생된 오존을 배기가스에 주입하면 질소산화물의 주성분인 NO가 빠르게 $NO_2$로 산화된다. 일단 NO가 $NO_2$로 산화되면 다음 단계에서 황화나트륨이나 아황산나트륨과 같은 환원제에 의해 쉽게 $N_2$로 환원될 수 있다. 본 연구에 사용된 환원제들은 $SO_2$도 효과적으로 제거시킬 수 있으므로 $NO_x$와 $SO_2$를 동시에 처리하는 것이 가능하다. 오존처리실과 흡수환원반응기로 구성된 본 연구의 2단계 공정은 모사 배기가스에 포함된 $NO_x$를 95%, $SO_2$를 100% 제거시킬 수 있었다. 환원제인 황화나트륨으로부터 발생되는 황화수소는 강염기인 수산화나트륨을 환원제와 함께 사용함으로써 방지할 수 있었다. $NO_x$와 $SO_2$를 동시에 처리하기 위한 환원제로 $Na_2SO_3$보다 $Na_2S$가 더 우수한 성능을 보여주었다.

• 한국분말재료학회지
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• 제21권6호
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• pp.422-428
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• 2014

In this study, the reduction kinetics and behaviors of oxides in the water-atomized iron powder have been evaluated as a function of temperature ranging $850-1000^{\circ}C$ in hydrogen environment, and compared to the reduction behaviors of individual iron oxides including $Fe_2O_3$, $Fe_3O_4$ and FeO. The water-atomized iron powder contained a significant amount of iron oxides, mainly $Fe_3O_4$ and FeO, which were formed as a partially-continuous surface layer and an inner inclusion. During hydrogen reduction, a significant weight loss in the iron powder occurred in the initial stage of 10 min by the reduction of surface oxides, and then further reduction underwent slowly with increasing time. A higher temperature in the hydrogen reduction promoted a high purity of iron powder, but no significant change in the reduction occurred above $950^{\circ}C$. Sequence reduction process by an alternating environment of hydrogen and inert gases effectively removed the oxide scale in the iron powder, which lowered reduction temperature and/or shortened reduction time.

• Nuclear Engineering and Technology
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• 제53권6호
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• pp.1931-1938
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• 2021

Uranium ingot is produced by metallothermic reduction of uranium tetrafluoride using magnesium or calcium as reductant. Presence of oxygen containing compounds viz. uranyl fluoride and uranium oxide in the starting uranium fluoride has a significant effect on the firing time, final temperature of the charge, slag-metal separation and hence the metal recovery. As reported in the literature, the maximum tolerable limit for uranyl fluoride in the UF₄ is 2.5 wt% and limit for uranium oxide content is in the range 2-3 wt%. No theoretical or experimental basis is available till date for these limits. Analyses have been carried out in this study to understand the effect of UO₂F₂ concentration in the starting fluoride on the final temperature of the products and thus the reduction characteristics. UF₄ having uranyl fluoride concentration, less than as well as more than 2.5 wt%, have been investigated. Thermodynamic calculations have been carried out to arrive at a general expression for the final temperature attained by the products during calciothermic reduction of UF₄. Finally, an upper limit for the oxygen containing impurities has been estimated using the CaO-CaF₂ phase diagram.

• 한국조경학회지
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• 제31권3호
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• pp.83-90
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• 2003

This study explored effects of urban greenspace on improving atmospheric environment, which is concerned with $CO_2$, SO$_2$ and NO$_2$ uptake, and with reduction of summer air temperatures. The site of this study was focused on Jung-gu in Seoul. Tree density and cover were 1.1 trees/100 $m^2$ and 12.5% respectively for the study area except forest lands. Atmospheric purification by greenspace was associated with changes in tree cover per unit area of each land use type. The mean $CO_2$ storage by woody plants was 19.4t/ha, and annual uptake averaged 2.2t/ha/yr for $CO_2$, 1.9kg/ha/yr for SO$_2$ and 5.0kg/ha/yr for NO$_2$. Entire tree plantings in the study area played a significant role by annually offsetting $CO_2$ emissions of about 1,830t from fossil fuel consumption by 330 persons, SO$_2$ emissions of 1,620kg by 1,080 persons, and NO$_2$ emissions of 4,230kg by 450 persons. The summer air temperature was 3.6$^{\circ}C$ cooler at a location with 54% cover of woody plants and 4.5$^{\circ}C$ cooler at a forest site with 100% cover, compared to a place with no planting. A 10% increase of woody plant cover was estimated to decrease summer air temperature by approximately 0.6$^{\circ}C$ until a certain level of canopy cover. Analyzing data from the Automatic Weather Stations in Seoul revealed that increasing tree cover decreased mean air temperature for the summer season (Jun~Aug) in a nonlinear function. Woody plant cover was the best predictive variable of summer temperature reduction. The results from this study are expected to be useful in emphasizing the environmental benefits and importance of urban greenspace enlargement, and in urging the necessity for planting and management budgets.

• 대한화학회지
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• 제22권1호
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• pp.37-44
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• 1978

$BH_3$-THF 용액에 염화리튬을 가한 새로운 환원계의 환원특성에 대한 연구가 대표적인 작용기를 가진 유기화합물을 가지고 표준조건($0^{\circ}$, THF)에서 이루어졌다. 조사 연구된 화합물중 벤조페논, 4가지 에스테르 및 시클로헥센은 $BH_3$ 환원과 별 차이를 보이지 않았으나, 2-헵탄온, 아세토페논, 염화벤조일, 프탈산무수물, 그리고 3가지 에폭시화물은 소량의 염화리튬에 의해 빠른 속도로 환원이 완결 되었다. 특히 에폭시화시클로헥센의 환원에 있어서는 소량의 염화리튬 존재하에서는 정량적으로 시클로헥산올을 생성하였으나 염화리튬의 양이 증가하면 2-클로로시클로헥산올이 시클로헥산올과 함께 생성됨을 알았다. 또한, 에폭시화시클로헥센과의 반응에 있어서 질산리튬은 염화리튬과는 달리 별로 효과가 없었다. 따라서 보란-염화리튬용액에 클로로수소화붕소리튬의 생성가능성을 논의하였다.

• Architectural research
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• 제7권2호
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• pp.69-79
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• 2005

There are no formal decision tools or guidelines to assist owners and contractors in choosing delivery systems and project strategies that would allow for a radical reduction in project cycle time - from the preplanning phase through project start up. Therefore, it is important to identify the state-of-practice and the state-of-art on methods of achieving radical reduction defined as a reduction of 25% or more in overall project cycle time. A comprehensive literature review, three questionnaire surveys, and the seven case studies were conducted and the data obtained from them were analyzed to establish the state-of-practice and state-of-art for project cycle time reduction techniques.

• 대한화학회지
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• 제21권2호
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• pp.149-151
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• 1977