• Title/Summary/Keyword: $NO_2$ gas

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The Influence of Support on Gas Mask Cobalt Catalysts for Low Temperature CO Oxidation (방독마스크용 코발트 촉매의 저온 일산화탄소 산화반응에서 지지체의 영향)

  • Kim, Deog-Ki;Kim, Bok-Ie;Shin, Chae-Ho;Shin, Chang-Sub
    • Journal of the Korean Society of Safety
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    • v.21 no.2 s.74
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    • pp.35-45
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    • 2006
  • Cobalt catalysts for gas mask loaded on various supports such as $Al_{2}O_{3},\;TiO_{2}$, AC(activated carbon) and $SiO_{2}$ were used to examine influences of calcination temperatures and reaction temperatures for CO oxidation. $Co(NO_{3})_2{\cdot}6H_{2}O$ was used as cobalt precursor and the catalysts were prepared by incipient wetness impregnation. The catalysts were characterized using XRD, TGA/DTA, TEM, $N_{2}$ sorption, and XPS. For the catalytic activity, support was in the order of ${\gamma}-Al_{2}O_{3}>TiO_{2}>SiO_{2}>AC\;and\;Al_{2}O_{3}$. The catalytic activity at lower temperature than $80^{\circ}C$ showed that with the increase of reaction temperature, cobalt catalysts on ${\gamma}-Al_{2}O_{3},\;TiO_{2},\;AC\$ has the negative activation energy but that of $SiO_{2}$ was positive.

Hot gas halo in early type galaxies and their environments

  • Kim, Eun-Bin;Choi, Yun-Young;Kim, Sung-Soo S.;Park, Chang-Bum
    • The Bulletin of The Korean Astronomical Society
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    • v.37 no.1
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    • pp.49.2-49.2
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    • 2012
  • We present an investigation of X-ray hot gas halo in 12 isolated early-type galaxies from cross-matched sample of XMM-Newton and SDSS DR 7(0.025 < z < 0.08588 and Mr <-19.5). Isolated galaxies that the separation between galaxy and the closest neighbor is farther than its virial radius are not affected by environments, and their X-ray hot gas halo can be studied without contribution of intragalactic medium in all circumstances. We find that isolated galaxies in low density have correlation of $L_X-L_R$ and those in high density have no trend. This suggests that internal process is much effective in low density and environmental effects play important role of this relationship in high density. We also find the galaxies affected by environments in the large scale structure. In this paper, we report preliminary results for the study.

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EVELOPMENT OF AXISYMMETRIC MULTI-SPECIES GH EQUATION FOR HYPERSONIC RAREFIED FLOW ANALYSES (극초음속 희박유동 해석을 위한 축대칭 다화학종 GH 방정식의 개발)

  • Ahn, J.W.;Kim, C.
    • 한국전산유체공학회:학술대회논문집
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    • 2008.03a
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    • pp.84-91
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    • 2008
  • Generalized hydrodynamic (GH) theory for multi-species gas and the computational models are developed for the numerical simulation of hypersonic rarefied gas flow on the basis of Eu's GH theory. The rotational non-equilibrium effect of diatomic molecules is taken into account by introducing excess normal stress associated with the bulk viscosity. The numerical model for the diatomic GH theory is developed and tested. Moreover, with the experience of developing the dia-tomic GH computational model, the GH theory is extended to a multi-species gas including 5 species; O$_2$, N$_2$, NO, O, N. The multi-species GH model includes diffusion relation due to the molecular collision and thermal phenomena. Two kinds of GH models are developed for an axisymmetric flow solver. By compar-ing the computed results of diatomic and multi-species GH theories with those of the Navier-Stokes equations and the DSMC results, the accuracy and physical consistency of the GH computational models are examined.

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EVELOPMENT OF AXISYMMETRIC MULTI-SPECIES GH EQUATION FOR HYPERSONIC RAREFIED FLOW ANALYSES (극초음속 희박유동 해석을 위한 축대칭 다화학종 GH 방정식의 개발)

  • Ahn, J.W.;Kim, C.
    • 한국전산유체공학회:학술대회논문집
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    • 2008.10a
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    • pp.84-91
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    • 2008
  • Generalized hydrodynamic (GH) theory for multi-species gas and the computational models are developed for the numerical simulation of hypersonic rarefied gas flow on the basis of Eu's GH theory. The rotational non-equilibrium effect of diatomic molecules is taken into account by introducing excess normal stress associated with the bulk viscosity. The numerical model for the diatomic GH theory is developed and tested. Moreover, with the experience of developing the dia-tomic GH computational model, the GH theory is extended to a multi-species gas including 5 species; $O_2,\;N_2$, NO, O, N. The multi-species GH model includes diffusion relation due to the molecular collision and thermal phenomena. Two kinds of GH models are developed for an axisymmetric flow solver. By compar-ing the computed results of diatomic and multi-species GH theories with those of the Navier-Stokes equations and the DSMC results, the accuracy and physical consistency of the GH computational models are examined.

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A Study on an Ion Wind Created by a Wire Electrode and Parallel Plates Assembly (와이어 전극과 평행판에서 발생되는 이온풍 특성 연구)

  • 안영철;황필재;이재근
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.16 no.4
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    • pp.318-323
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    • 2004
  • When a strong electric field is applied between a sharply curved electrode and a blunt surface, the corona may result in a gas movement in the electrode gap which is directed toward the blunt surface. That is called the corona wind. It enhances heat and mass transfer between the surface and the surrounding gas. Moreover such enhancement causes no noise or vibration, which can be applied in complex, isolated geometries, and allows simple control of surface temperatures. This paper examines the relationship between the corona wind and the relative humidity. The facility consists of high voltage power supply thin tungsten wire, plate electrode, multimeter, microammeter and flow meter. Gas velocity is a linear function of voltage, relative humidity and is proportional to the square root of the current. The maximum velocities for the positive and negative corona discharge are 1.9 m/s (2.74 CMM/m), 1.5 m/s(2.15 CMM/m), respectively.

Porometric Study on the Gas Diffusion Layer in PEMFCs Using Method of Standard Porosimetry (MSP 기법을 적용한 고분자 전해질 연료전지 가스확산층의 포로시메트리 연구)

  • Lee, Yongtaek
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.25 no.2
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    • pp.64-69
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    • 2013
  • The structure of pore network of gas diffusion layers (GDLs) in PEMFCs plays a critical role in determining the transport phenomena of reaction gas as well as generated water. In addition, the interactive characteristics between water and surface of pore are no less important than the structural characteristics of pore network. In this study, porometric investigation is conducted for two kinds of GDL using method of standard porosimetry which enable to distinguish hydrophobic pores from hydrophilic pores of GDLs. The porosity of TGPH-120 decreases by 6% by adding 30 wt.% of PTFE, but the porosity of hydrophilic pores decreases by 12%. The relation of $p_c-S_{nw}$ varies with the addition of PTFE, especially at low $p_c$.

Effects of a Simplified Mixture Nozzle Geometry on the Acoustic Field in an Aero Gas Turbine Combustor (항공용 가스터빈 연소기에서의 혼합기 노즐 형상의 단순화가 음향장 해석 결과에 미치는 영향)

  • Pyo, Yeongmin;Hong, Sumin;Kim, Daesik
    • Journal of ILASS-Korea
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    • v.24 no.2
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    • pp.58-65
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    • 2019
  • A 3D FEM (Finite Element Method) based Helmholtz solver has been commonly used to characterize fundamental acoustic behavior and investigate dynamic instability features in many combustion systems. In this approach, a geometrical simplification of the target system has been generally made in order to reduce computational time and cost because a real combustor and fuel nozzle have a very complicated flow passage. The feasibility of these simplifications is quantitatively investigated in a small aero gas turbine nozzle in term of acoustic characteristics. It is found that the simplification in a nozzle geometry during the 3D FEM analysis process has no great influence on the acoustic modeling results, while the calculation complexity can be improved for a similar modeling accuracy.

The Oxidation Behavior of Pitch based Carbon Fibers in ${CO}_2$ Gas and Air (${CO}_2$ gas및 공기중에서 피치계 탄소섬유의 산화거동)

  • No, Jae-Seung;Seo, Dong-Su
    • Korean Journal of Materials Research
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    • v.7 no.2
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    • pp.121-128
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    • 1997
  • Two-types of carbon fiber, anisotropic- and isotropic- pitch based, were expose to isothermal oxidation in air and $CO_{2}$ gas and the weight change rates was measured by TGA apparatus. Thc oxidation rate was laster in air than in $CO_{2}$ gas, and the oxidation rare of isotropic T- 101s liher was over 23 9 times faster than that of anisotropic HM-60 filler at $600^{\circ}C$ in air. The activation energy was 36-56 Kcal/mole at lower temperature range and 6- 13 Kcal/molc at higher temperature range. It was higher that the transition temperalure 01 reaction zone(zone 1. 2, :i) of 11M-GO fiber than that of T-101s fiber, and it was higher in $CO_{2}$ gas than in air. From SEM observation, it Lvas found that the oxidation of carbon fibers was progressed through the imperfection.

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Seasonal Characteristics of PM2.5 Water Content at Seoul and Gosan, Korea (서울과 고산의 PM2.5 수분함량 계절 특성)

  • Lee, Hyung-Min;Kim, Yong-Pyo
    • Journal of Korean Society for Atmospheric Environment
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    • v.26 no.1
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    • pp.94-102
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    • 2010
  • Water content of $PM_{2.5}$ (particles in the atmosphere with a diameter of less than or equal to a nominal $2.5{\mu}m$) was estimated by using a gas/aerosol equilibrium model, SCAPE2, for the particles collected at Seoul and Gosan, Korea. From measured and analyzed characteristics of the particles, the largest difference between Seoul and Gosan is the proportions of total ammonia (t-$NH_3$=gas phase $NH_3$+particle phase ${NH_4}^+$), total nitric acid (t-$HNO_3$=gas phase $HNO_3$+particle phase ${NO_3}^-$) and sulfuric acid ($H_2SO_4$). Even though both sites have sufficient t-$NH_3$ to neutralize acidic species such as $H_2SO_4$, t-$HNO_3$, and t-HCl (total chloric acid=gas phase HCl+particle phase $Cl^-$), equivalent fraction of t-$NH_3$ and t-$HNO_3$ are higher at Seoul and $H_2SO_4$ is higher at Gosan. Based on the modeling result, it is identified that the $PM_{2.5}$ at Seoul is more hygroscopic than Gosan if the meteorological conditions are the same. To reduce water content of $PM_{2.5}$, and thus, mass concentration, control measures for ammonia and nitrate reduction are needed for Seoul, and inter-governmental cooperation is required for Gosan.

GIS based Effective Methodology for GAS Accident Management (GIS를 이용한 효율적인 가스사고관리 방법에 관한 연구)

  • 김태일;김계현;전방진;곽태식
    • Spatial Information Research
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    • v.12 no.1
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    • pp.89-100
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    • 2004
  • Nowadays, the gas utilities have been increasing constantly due to the expansion of the urban areas. Using computerized information database, the gas companies have developed a gas management system in order to maintain the current status. However, this system can only give basic functions of the maintenance and management of the gas facilities and it has no proper utilities to provide information against accidents from gas leaks. Therefore, a gas accident management system has been developed in this study. Through primary and secondary pipe searching algorithm realtime based management system was devised against gas leaks to propose proper actions. In addition, supporting decision making has been enabled providing estimated maximum amount of gas leaks. Furthermore, all the residential units could be identified thereby minimizing damages through early warning. This system can be expected to contribute to enhance the efficiency of the gas management not to mention of protecting human lives and properties of the nation.

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