• Title/Summary/Keyword: $NO_2$ gas

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Thermohydraulic Characteristics of Two-Phase Flow in a Submerged Gas Injection System (잠겨진 가스분사장치에서의 2상유동의 열수력학적 특성)

  • Choi, Choeng Ryul;Kim, Chang Nyung
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.23 no.10
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    • pp.1327-1339
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    • 1999
  • Characteristics of two-phase flow and heat transfer were numerically investigated in a submerged gas Injection system. Effects of both the gas flow rate and bubble size were investigated. In addition, heat transfer characteristic and effects of heat transfer were investigated when temperature of the injected gas was different from that of the liquid. The Eulerian approach was used for the formulation of both the continuous and the dispersed phases. The turbulence in the liquid phase was modeled by the use of the standard $k-{\varepsilon}$ turbulence model. The interphase friction and heat transfer coefficient were calculated by means of correlations available in the literature. The turbulent dispersion of the phases was modeled by introducing a "dispersion Prandtl number". The plume region and the axial velocities are increased with increases in the gas flow rate and with decreases in the bubble diameter. The turbulent flow field grows stronger with the increases in the gas flow rate and with the decreases in the bubble diameter. In case that the heat transfer between the liquid and the gas is considered, the axial and the radial velocities are decreased in comparison with the case that there is no temperature difference between the liquid and the gas when the temperature of the injected gas is higher than the mean liquid temperature. The results in the present research are of interest in the design and the operation of a wide variety of material and chemical processes.

Investigation of NO Formation Characteristics in Multi Staged Air Combustor (공기 다단 연소기 화염의 NO 발생특성에 관한 연구)

  • Kim, Han-Seok;An, Guk-Yeong;Baek, Seung-Uk;Yu, Myeong-Jong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.25 no.11
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    • pp.1594-1605
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    • 2001
  • In this study, a numerical simulation was developed which was capable of predicting the characteristics of NO formation in pilot scale combustor adopting the air-staged burner flame. The numerical calculation was constructed by means of establishing the mathematical models fur turbulence, turbulent combustion, radiation and turbulent nitric oxide chemistry. Turbulence was solved with standard k-$\xi$ model and the turbulent combustion model was incorporated using a two step reaction scheme together with an eddy dissipation model. The radiative transfer equation was calculated by means of the discrete ordinates method with the weighted sum of gray gases model for CO$_2$and H$_2$O. In the NO chemistry model, the chemical reaction rates for thermal and prompt NO were statistically averaged using the $\beta$ probability density function. The results were validated by comparison with measurements. For the experiment, a 0.2 MW pilot multi-air staged burner has been designed and fabricated. Only when the radiation was taken into account, the predicted gas temperature was in good agreement with the experimental one, which meant that the inclusion of radiation was indispensable for modeling multi-air staged gas flame. This was also true of the prediction of the NO formation, since it heavily depended on temperature. Subsequently, it was found that the multi-air staged combustion technique might be used as a practical tool in reducing the NO formation by controlling the peak flame temperature.

$DeNO_{x}$ Performance of Activated Carbon Catalysts Regenerated by Surfactant Solution (계면활성제 수용액에 의해 재생된 활성탄 촉매의 탈질 성능)

  • Park, Hye-Min;Park, Young-Kwon;Jeon, Jong-Ki
    • Korean Chemical Engineering Research
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    • v.49 no.6
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    • pp.739-744
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    • 2011
  • Activated carbon SCR(CSCR) catalyst that is used to remove $NO_x$ in exhaust gas including boron discharged from the production process of liquid crystal display(LCD) shows deactivation when boron is deposited to block the pores within the catalyst or to cover its active sites. The spent carbon catalyst is regenerated by washing with various surfactants, drying and calcination. For comparison of the physical and chemical properties before and after the regeneration with the variables, type of surfactants and calcination condition, element analysis by ICP, $N_{2}$ adsorption were conducted. $DeNO_{x}$ in SCR with $NH_3$ was carried out in a fixed bed reactor at $120^{\circ}C$. The activated carbon catalyst regenerated through washing with a non-ionic surfactant in $H_{2}O$ at $90^{\circ}C$ and calcination under $N_{2}$ gas at $550^{\circ}C$ shows similar level of surface area and $NO_x$ removal efficiency with those of fresh catalyst.

Numerical Study to Develop Low-NOx Multi-nozzle Burner in Rotary Kiln (로터리 킬른용 Low-NOx 다공노즐버너 개발을 위한 수치해석적 연구)

  • Ahn, Seok-Gi;Kim, Jin-Ho;Hwang, Min-Young;Kim, Gyu-Bo;Jeon, Chung-Hwan
    • Journal of Energy Engineering
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    • v.23 no.4
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    • pp.130-140
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    • 2014
  • Rotary kiln burner has been developed continuously to improve process efficiency and exhaust emission. In this study, the characteristics of the flame and exhaust emission were numerically analyzed according to the diameter of primary air nozzle, equivalent ratio of burner, and equivalent ratio at center and side nozzle for development of multi-nozzle burner in the COG(Coke Oven Gas) rotary kiln for sintering iron ore. The results indicated that the flame length and $NO_x$ emission increase, as the diameter of primary air nozzle and equivalent ratio of burner increase. And according to the change of equivalent ratio at the center and the side of the nozzle, the flame length and average temperature in the kiln show very little change but the $NO_x$ emission shows obvious difference. In conclusion, the best design conditions which have satisfying flame length, average temperature and $NO_x$ emission are as follows: $D_2/D_1$ is 1.33, equivalent ratio of burner is 1.25 and center nozzle conditions are Rich.

Molecular gas and star formation in early-type galaxies

  • Bureau, Martin
    • The Bulletin of The Korean Astronomical Society
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    • v.36 no.2
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    • pp.65-65
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    • 2011
  • Early-type galaxies represent the end point of galaxy evolution and, despite pervasive residual star formation, are generally considered "red and dead", that is composed exclusively of old stars with no star formation. Here, their molecular gas content is constrained and discussed in relation to their evolution, supporting the continuing importance of minor mergers and/or cold gas accretion. First, as part of the Atlas3D survey, the first complete, large, volume-limited survey of CO in normal early-type galaxies is presented. At least of 23% of local early-types possess a substantial amount of molecular gas, the necessary ingredient for star formation, independent of mass and environment but dependent on the specific stellar angular momentum. Second, using CO synthesis imaging, the extent of the molecular gas is constrained and a variety of morphologies is revealed. The kinematics of the molecular gas and stars are often misaligned, implying an external gas origin in over a third of all systems, more than half in the field, while external gas accretion must be shot down in clusters. Third, many objects appear to be in the process of forming regular kpc-size decoupled disks, and a star formation sequence can be sketched by piecing together multi-wavelength information on the molecular gas, current star formation, and young stars. Fourth, early-type galaxies do not seem to systematically obey all our usual prejudices regarding star formation (e.g. Schmidt-Kennicutt law, far infrared-radio continuum correlation), suggesting a greater diversity in star formation processes than observed in disk galaxies and the possibility of "morphological quenching". Lastly, a first step toward constraining the physical properties of the molecular gas is taken, by modeling the line ratios of density- and opacity-sensitive molecules in a few objects. Taken together, these observations argue for the continuing importance of (minor) mergers and cold gas accretion in local early-types, and they provide a much greater understanding of the gas cycle in the galaxies harbouring most of the stellar mass. In the future, better dust masses and dust-to-gas mass ratios from Herschel should allow to place entirely independent constraints on the gas supply, while spatially-resolved high-density molecular gas tracers observed with ALMA will probe the interstellar medium and star formation laws locally in a regime entirely different from that normally probed in spiral galaxies.

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Performance and Emission Characteristics of a CNG Engine Under Different Natural Gas Compositions (천연가스 조성 변화에 따른 CNG 엔진 성능 및 배기가스 특성)

  • Ha, Young-Cheol;Lee, Seong-Min;Kim, Bong-Gyu;Lee, Chang-Jun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.35 no.7
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    • pp.749-755
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    • 2011
  • The performance and emission characteristics of a CNG (compressed natural gas) engine were experimentally investigated under different natural gas compositions. The engine specifications were as follows: 6606 cc, turbo, lean-burn-type; its ignition timing was fixed for the fuel gas with a HHV (higher heating value) of 10454 kcal/$Nm^3$. The experimental results showed that when the HHV of the fuel gas was changed from 10454 kcal/$Nm^3$ to 9811 kcal/$Nm^3$ and 9523 kcal/$Nm^3$, the average power reductions were 3.2 % and 3.4 % (1.5 % and 2.1 %, respectively, with A/F control switched off), respectively, and the average thermal-efficiency reductions were 1.1 % and 1.5 % (1.5 % and 2.1%, respectively, with A/F control switched off), respectively. The emissions of $CO_2$, CO, and $NO_x$ decreased as the HHV of the fuel gas was lowered. On the other hand, the emissions of THC (total hydrocarbon) were not consistent, and the extent of change in their emissions was small.

The influence of $O_2$ concentration on the generation of $NO_2$ by using the wire-plate reactor (선대 평판형 반응기에서 $NO_2$ 생성에 미치는 $O_2$의 영향)

  • Park, Jae-Youn;Kim, Sung-Jin;Kim, Jong-Dal;Lee, Sun-Jae;Ha, Sang-Tae;Han, Sang-Bo;Lee, Dong-Hoon
    • Proceedings of the KIEE Conference
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    • 2000.07c
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    • pp.2050-2052
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    • 2000
  • In this paper, the effect of $O_2$ concentration on NO removal and $NO_2$ generation by corona discharge from simulated flue gas was measured and estimated for the wire-plate reactor. $NO_2$ removal rate was 0$\sim$30[%] under about 3.4[%] of oxygen concentration, however, it was difficult to remove NOx over 3.4[%] of oxygen concentration. It may be due to generate $NO_2$ from $N_2$ and $O_2$ molecules and converse NO to $NO_2$ by 0 and $O_3$. Magnetic field applied to electric field in plasma was very effective for NOx removal under 2[%] of $O_2$ concentration.

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Magnetic Properties and Microstructure of Co Thin Films by RF-diode Sputtering Method (RF-diode Sputtering법으로 제작한 Co박막의 자기특성과 미세구조)

  • Han, Chang-Suk;Kim, Sang-Wook
    • Korean Journal of Materials Research
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    • v.28 no.3
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    • pp.159-165
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    • 2018
  • In order to increase the efficiency of the sputtering method widely used in thin film fabrication, a dc sputtering apparatus which supplies both high frequency and magnetic field from the outside was fabricated, and cobalt thin film was fabricated using this apparatus. The apparatus can independently control the applied voltage, the target-substrate distance, and the target current, which are important parameters in the sputtering method, so that a stable glow discharge is obtained even at a low gas pressure of $10^{-3}$ Torr. The fabrication conditions using the sputtering method were mainly performed in $Ar+O_2$ mixed gas containing about 0.6 % oxygen gas under various Ar gas pressures of 1 to 30 mTorr. The microstructure of Co thin films deposited using this apparatus was examined by electron diffraction pattern and X-ray techniques. The magnetic properties were investigated by measuring the magnetization curves. The microstructure and magnetic properties of Co thin films depend on the discharge gas pressure. The thin film fabricated at high gas pressure showed a columnar structure containing a large amount of the third phase in the boundary region and the thin film formed at low gas pressure showed little or no columnar structure. The coercivity in the plane was slightly larger than that in the latter case.

A Study on Combustion Characteristics of Pre-mixed $CH_4$-air by Flame Trap (플레임트랩에 의한 메탄-공기 예혼합기의 연소특성에 관한 연구)

  • Kim, Deok-Ho;Lee, Jai-Hyo;Choi, Su-Jin;Cho, Gyu-Back;Jeong, Dong-Soo
    • Transactions of the Korean Society of Automotive Engineers
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    • v.13 no.2
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    • pp.22-28
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    • 2005
  • Exhaust gas emissions from internal combustion engines are one of the major sources of air pollution. And, it is extremely difficult to increase gasoline engine efficiency and to reduce $NO_X$ and PM(particulate matter) simultaneously in diesel combustion. This paper offers some basic concepts to overcome the above problems. To solve the problems, a recommended technique is CAI(controlled auto-ignition) combustion. In this paper, a flame trap was used to simulate internal EGR(exhaust gas recirculation) effect. An experimental study was carried out to find combustion characteristics using homogeneous premixed gas mixture in the constant volume combustion chamber(CVCC). Flame propagation photos and pressure signals were acquired to verify the flame trap effect. The flame trap creates high speed burned gas jet. It achieves higher flame propagation speed and more stable combustion due to the effect of geometry and burned gas jet.