• Title/Summary/Keyword: $NO_2$ gas

Search Result 2,411, Processing Time 0.04 seconds

A Simultaneous Reduction of Smoke and $NO_X$ with Biodiesel Fuel in a D. I. Diesel Engine (직접분사식 디젤기관에서 바이오디젤유 적용시 매연과 $NO_X$의 동시저감)

  • Choi, Seung-Hun;Oh, Young-Taig
    • Transactions of the Korean Society of Automotive Engineers
    • /
    • v.13 no.2
    • /
    • pp.65-71
    • /
    • 2005
  • Our environment is faced with serious problems related to the air pollution from automobiles in these days. In particular, the exhaust emissions of diesel engine are recognized main cause which influenced environment strong. In this study, the potential possibility of biodiesel fuel was investigated as an alternative fuel for a naturally aspirated D.I. diesel engine. The smoke emission of biodiesel fuel was reduced remarkably in com parison with diesel fuel, that is, it was reduced approximately 48.5% at 2500rpm, full load. But, power, torque and brake specific energy consumption didn't have no large differences. But, $NO_X$ emission of biodiesel fuel was increased com pared with commercial diesel fuel. Also, the effects of exhaust gas recirculation(EGR) on the characteristics of $NO_X$ emission has been investigated. It was found that simultaneous reduction of smoke and $NO_X$ was achieved with biodiesel fuel(20vol-%) and cooled EGR method($5{\sim}15%$).

A study of decomposition of harmful gases using Composite catalyst by Photocatalytic plasma reactions (복합촉매를 이용한 플라즈마 반응에 의한 유해가스의 제거에 관한 연구)

  • Park, Hwa-Young;Kim, Kwan-Jung;Woo, In-Sung
    • Journal of the Korea Safety Management & Science
    • /
    • v.15 no.1
    • /
    • pp.121-132
    • /
    • 2013
  • The objective of this study is to maintain the same frequency as the electrode material, concentration, duration of decomposition efficiency, power consumption and voltage measurements using a composite catalyst according to the change of process parameters to obtain the optimum state of the process and the maximum decomposition efficiency. In this paper, known as a major cause of air pollution, such as NO, NO2, SO2, frequency, flow rate, concentration, the material of the electrodes, and using TiO2 catalyst reactor with surface discharge caused by discharging the reactor plasma NOx, SOx decompose the harmful gas want to remove.

Simultaneous Removal of $SO_2$ and NOx Using Ozone Generator and Absorption- Reduction Technique (오존발생장치와 흡수환원법을 이용한 배기가스 동시 탈황 탈질 공정)

  • Mok, Young-Sun;Lee, Joo-Hyuck;Shin, Dong-Nam;Koh, Dong-Jun;Kim, Kyong-Tae
    • Journal of Korean Society of Environmental Engineers
    • /
    • v.28 no.2
    • /
    • pp.191-196
    • /
    • 2006
  • The injection of ozone, produced by dielectric barrier discharge, into the exhaust gas gives rise to a rapid oxidation of NO that is the main component of nitrogen oxides($NO_x$) in most practical exhaust gases. Once NO is converted into $NO_2$, it on readily be reduced to $N_2$ in the next step by a reducing agent such as sodium sulfide and sodium sulfite. The reducing agents used ca also remove $SO_2$ effectively, which makes it possible to treat $NO_x\;and\;SO_2$ simultaneously. The present two-step process made up of an ozonizing chamber and an absorber containing a reducing agent solution was able to remove about 95% of the $NO_x$ and 100% of the $SO_2$, initially contained in the simulated exhaust gas. The formation of $H_2S$ from sodium sulfide was prevented by using a strong basic reagent(NaOH) together with the reducing agent. The removal of $NO_x$\;and\;SO_2$ was more effective for $Na_2S$ than $Na_2SO_3$.

NOx Formation Characteristics with Oxygen Enrichment in Nonpremixed Counterflow Flames (비예혼합 대향류화염에서 산소부화에 따른 NOx 생성특성)

  • Lee, Chang-Eon;Hwang, Cheol-Hong;Yoo, Byung-Hun;Han, Ji-Woong
    • Journal of the Korean Institute of Gas
    • /
    • v.11 no.4
    • /
    • pp.17-22
    • /
    • 2007
  • The NOx emission characteristics with oxygen enrichment in non-premixed counterflow flames were investigated numerically. To consider systematically the situation of inevitable $N_2$ contamination by air infiltration in the process of pure-oxygen combustion, the volume ratio of $O_2$ in an oxidizer was changed from 21% to 100%. As a result the NO emission index $(EI_{NO})$ has the highest value under condition of 75% oxygen enrichment. This result can be explained by the change of $N_2$ destruction rate with oxygen enrichment rather than flame temperature, flame thickness and residence time. In particular, it was found that the reaction of N+NO=$N_2+O$ has the largest contribution on NOx production in oxygen-enrichment flames.

  • PDF

EFFECT OF ETHENE $(C_2 H_4)$ ON THE PLASMA $DeNO_X$ PROCESS FROM DIESEL ENGINE EXHAUST

  • Park, Kwang-Seo;Kim, Dong-Inn;Lee, Hyeong-Sang;Chun, Bae-Hyeock;Yoon, Woong-Sup;Chun, Kwang-Min
    • International Journal of Automotive Technology
    • /
    • v.2 no.2
    • /
    • pp.77-83
    • /
    • 2001
  • Effect of ethene on the $DeNO_X$ conversion process in a simulated diesel engine operating conditions was investigated experimentally and theoretically. With the addition of even a small amount of ethene the NO to $NO_2$ conversion enhances greatly. The energy required to convert one NO molecule is 27 eV with 250 ppm ethene added, while 137 eV without ethene at 473 K. The effect of energy density, temperature, and the initial concentrations of ethene and oxygen are also discussed and the results show that the increase of the mentioned parameters lead to the promotion of NO oxidation. A kinetic model used in this study shows good agreement with the experimental result. Byproducts like formaldehyde ($CH_2$ 0) and methyl nitrite ($CH_3$ ONO) predicted by model calculation are broken up into CO and $H_2O$ eventually when high energy is delivered to the gas mixture. Sensitivity analysis shows that the main reactions of NO oxidation when ethene is added we: $HO_2+ NO \arrow NO_2 + OH, RO_2 + NO \arrow NO_2 + RO$, where R is a hydrocarbon radical. Also the direct oxidizing reaction of NO with O cannot be neglected.

  • PDF

Day and Night Distribution of Gas and Particle Phases Polycyclic Aromatic Hydrocarbons (PAHs) Concentrations in the Atmosphere of Seoul (서울 대기 중 기체 및 입자상 다환방향족탄화수소 (PAHs)의 낮·밤 분포 특성)

  • Lim, Hyung Bae;Kim, Yong Pyo;Lee, Ji Yi
    • Journal of Korean Society for Atmospheric Environment
    • /
    • v.32 no.4
    • /
    • pp.408-421
    • /
    • 2016
  • Day and night sampling for gas and particle phases PAHs were carried out in Seoul to characterize gas and particle phases PAHs concentrations in day and night times. There was no significant difference between day and night time for particle phase PAHs concentrations and phase distribution of PAHs, while, gas phase PAHs concentrations in daytime were about 1/2 of nighttime concentrations in both summer and winter due to photochemical reaction of gas phase PAHs during daytime. A high fraction of cancer risk for PAHs was attributed to particle phase PAHs and the excess cancer risk in winter was higher than in summer. The excess cancer risk level of total(gas+particle) PAHs in summer was partially observed when both gas and particle phase PAHs concentrations were considered as risk assessment. Based on the diagnostic ratios and factor analysis of PAHs concentrations, combustion(coal and natural gas) and vehicular emission might be the most significant contributors of PAHs and major factors for determining of PAHs concentration were different between day and night times.

A method of human error management in chemical process industries (화학공정산업의 인적오류 제어 방법)

  • Jo Young-Do;Park Kyo-Shik;Park Heui-Joon
    • Journal of the Korean Institute of Gas
    • /
    • v.7 no.2 s.19
    • /
    • pp.42-47
    • /
    • 2003
  • To prevent major accident from toxic gas release, explosion, or fire in chemical processes, it needs dynamic control of human error with mechanical failure. Although most of major accidents occur with a coupling of human error and mechanical failure, numbers of researches have studied human error and mechanical reliability independently, but no where cross each other, to reduce the risk in the process. This work focuses on the coincidence of human error and mechanical failure for management of human error, and on some important performance shaping factors to propose a method for improving safety effectively of the process industries.

  • PDF

A Performance Simulation for Spark Ignition Wankel Rotary Engine (불꽃점화 반켈 로터리 기관의 성능 시뮬레이션)

  • 채재우;이상만;전영남;김규정;정영식
    • Transactions of the Korean Society of Automotive Engineers
    • /
    • v.1 no.1
    • /
    • pp.80-89
    • /
    • 1993
  • Performance simulation for a Spark Ignition Wankel rotary Engine is presented in this paper. The volume of chamber at each eccentric shaft angle is evaluated by using geometric models of housing and rotor. A thermodynamic model which includes the first law of thermodynamics, combustion and convective heat transfer from chamber contents to surroundings is imployed. A thermochemical equilibrium model which considers 10 species(CO, $CO_2$, $O_2$, $H_2$, $H_2O$, OH, O, NO, $N_2$) in the burned gas region, is also employed. Four processes of gas exchange, compression, combustion and expansion are considered and the pressure, temperature and composition of chamber gas at each eccentric shaft angle in each process are computed in this performance simulation. This performance simulation must be useful for optimal design of Spark Ignition Wankel Rotray Engine with parametric study for various design parameters and operating conditions.

  • PDF

A Study on the Assessment of Safety Performance for Complex Installation System of Stationary Fuel Cell and Boiler (건물용 연료전지-보일러 복합설치 안전성능 평가에 관한 연구)

  • Kim, Min-Woo;Lee, Eun-Kyung;Oh, Gun-Woo;Lee, Jung-Woon;Lee, Seung-Kuk
    • Korean Journal of Hazardous Materials
    • /
    • v.6 no.2
    • /
    • pp.77-86
    • /
    • 2018
  • Interest in renewable energy is increasing for eco-friendly use of energy, and fuel cells are being used in various ways such as houses and buildings as power generation methods that have low emissions such as $NO_X$ and $CO_2$. As the supply of fuel cells expands, more and more boilers are installed in the existing buildings, but safety management is not being performed properly. Therefore, in this study, a prior study was conducted on the status of fuel cell-boiler complex installation and related criteria, and the risk factors were analyzed according to the installation environment and structure. Based on these standards, the safety performance of the fuel cell-boiler combined installation is assessed by conducting a demonstration using the starting product of the simulated operation to derive the installation criteria (proposal) for the fuel cell-boiler combined installation. The installation criteria (proposal) include the construction and connection method of the piping according to the fuel cell-boiler complex installation.