• Title/Summary/Keyword: $NO_2$ gas

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Effects of $CO_2$ and $H_2O$ Additions on Partially Premixed Counterflow Flame by Considering Nongray Gas Radiation (비회색 가스 복사를 고려한 층류대향류 부분예혼합 화염에서의 $CO_2$$H_2O$ 첨가에 따른 영향 연구)

  • Jo, Bum-Jin;Kim, Tae-Kuk
    • Journal of the Korean Society of Combustion
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    • v.10 no.3
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    • pp.10-16
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    • 2005
  • Detailed flame structures of the counterflow flames of $CH_4/Air$ formed with $CO_2$ and $H_2O$ addition are studied numerically. The detailed chemical reactions are modeled by using the OPPDIF and CHEMKIN-II code. Only the $CO_2$ and $H_2O$ are assumed to participate in radiative heat transfer while all other gases are assumed to be transparent. The discrete ordinates method(DOM) and the narrow band based WSGGM with a gray gas regrouping technique(WSGGM-RG) are applied for modeling the radiative transfer through non-homogeneous and non-isothermal combustion gas mixtures generated by the counter flow flames. The results compared with the SNB model show that the WSGGM-RG is successful in modeling the counterflow flames with non-gray gas mixture. The numerical results show that the addition of $CO_2$ and $H_2O$ to the oxidant nozzle lowers the peak temperature and the NO concentration in flame.

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Effect of Air Velocity on Combustion Characteristics in Small-Scale Burner

  • Laryea, Gabriel Nii;No, Soo-Young
    • Journal of the Korean Society of Combustion
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    • v.10 no.1
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    • pp.1-6
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    • 2005
  • This paper presents the combustion characteristics of hydrocarbon fuel from a conventional pressure-swirl nozzle of a small-scale burner. The nozzle has orifice diameters of 0.256 mm and liquid flow rates ranging from 50 to 64 mL/min were selected for the experiments. The furnace temperature distribution along the axial distance, the gas emission such as CO, $CO_2$, NOx, $SO_2$, flue gas temperature, and combustion efficiency were studied. The local furnace and flue gas temperatures decreased with an increase in air velocity. At injection pressures of 1.1 and 1.3 MPa the maximum furnace temperatures occurred closer to the burner exit, at an axial distance of 242 mm from the diffuser tip. The CO and $CO_2$concentrations decreased with an increase in air velocity, but they increased with an increase in injection pressure. The effect of air velocity on NOx was not clearly seen at low injection pressures, but at injection pressure of 1.3 MPa it decreased with an increase in air velocity. The effect of air velocity on $SO_2$ concentration level is not well understood. The combustion efficiency decreased with an increase in air velocity but it increased with an increase in injection pressure. It is recommended that injection pressure less than 0.9 MPa with air velocity not above 8.0 m/s would be suitable for this burner.

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Effect of Air Velocity on Combustion Characteristics Scale Burner

  • Laryea, Gabriel Nii;No, Soo-Young
    • Proceedings of the Korean Society for Agricultural Machinery Conference
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    • v.10 no.1
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    • pp.76-82
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    • 2005
  • This paper presents the combustion characteristics of hydrocarbon fuel from a conventional pressureswirl nozzle of a small-scale burner. The nozzle has orifice diameters of 0.256 mm and liquid flow rates raging from 50 to 64 mL/min were selected for the experiments. The furnace temperature distribution along the axial distance, the gas emission such as CO, $CO_2,\;NOx,\;S0_2,$ flue gas temperature, and combustion efficiency were studied. The local furnace and flue gas temperatures decreased with an increase in air velocity. At injection pressures of 1.1 and 1.3 MPa the maximum furnace temperatures occurred closer to the burner exit, at an axial distance of 242 mm from the diffuser tip. The CO and $CO_2$ concentrations decreased with an increase in air velocity, but they increased with an increase in injection pressure. The effect of air velocity on NOx was not clearly seen at low injection pressures, but at injection pressure of 1.3 MPa it decreased with an increase in air velocity. The effect of air velocity $SO_2$ concentration level is not well understood. The combustion efficiency decreased with an increase in air velocity but it increased with an increase in injection pressure. It is recommended that injection pressure less than 0.9 MPa with air velocity not above 8.0 m/s would be suitable for this burner.

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Coal Gasification using Catalyst in a Fluidized Bed Reactor (유동층 반응기에서 촉매를 이용한 석탄 가스화반응 특성)

  • 이운재;김상돈
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 1995.05a
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    • pp.129-132
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    • 1995
  • 상압의 유동층반응기 (0.1 m-i.d x 1.6 m-high) 에서 호주탄을 수증기와 공기를 사용하여 가스화 하였다. 또한 반응기에서 촉매효과를 고찰하기 위해 $K_2$SO$_4$+Ni(NO$_3$)$_2$ 촉매를 호주탄에 담지하여 가스화반응을 수행하였다. 생성가스조성, 생성가스량, 탄소전환율, cold gas efficiency 및 발열량 등에 대한 유동화속도 (2~5U$_{mf}$), 반응온도 (750~90$0^{\circ}C$), 공기/석탄 비 (1.6~3.2), 수증기/석탄 비 (0.63~l.26)의 영향을 조사하였다. 탄소전환율, 생성 가스량, 생성가스 발열량 및 cold gas efficiency 는 유동화속도와 반응온도의 증가에 따라 증가하였다. 공기/석탄 비가 증가함에 따라 탄소전환율과 생성가스량 및 cold gas efficiency 는 증가하지만 생성가스 발열량은 감소하였다. 수증기/석탄 비의 증가에 따라 발열량, cold gas efficiency 및 생성가스량은 증가하였으며, 탄소 전환율은 거의 일정하였다. 촉매 가스화반응에서 유동화속도, 반응온도, 공기/석탄 비 및 수증기/석탄 비의 증가에 따라 탄소 전환 율, 생성가스량, 생성가스 발열량 및 cold gas efficiency 는 크게 향상됨을 알 수 있었다.

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The Pre-service Teacher's Conceptions of 'the Color of Gases': Focusing on the Survey from Freshmen at a National University of Education ('기체의 색깔'에 대한 초등 예비교사들의 인식 조사: 교육대학교 1학년 학생들을 대상으로)

  • Kim, Han-Je;Jang, Myoung-Duk;Joung, Yong Jae
    • Journal of Korean Elementary Science Education
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    • v.31 no.2
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    • pp.253-268
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    • 2012
  • The purpose of this study is to investigate the elementary pre-service teachers' conceptions of 'color of gases' focusing on the survey from freshmen at a National University of Education. For the study, the views about 'color of gases' were surveyed from the pre-service teachers. And the responses were analyzed based on the patterns. The results from the study are as follows: First, the conceptions about 'color of gases' were divided into 2 top-level, 5 mid-level and 7 sub-level categories. Second, the number of students who answered 'certain gas has color' was significantly greater than those who answered 'every gas has no color'. However, only a small number of students who answered former understand the scientific meaning of color and the color of gases correctly. Third, out of 5 misconception categories, greater number of students answered with 'inaccurate scientific knowledge (Ma1)', so the category was classified again into five detailed sub-categories. Fourth, most of the students, who answered 'every gas has no color', stated "they have not seen any color gases through their lives" based on their own experience. Fifth, the distribution percentage for scientific conceptions vs misconceptions was not related with the students' gender but highly related with students' academic area and their science courses taken at high school. Sixth, the pre-service teachers have various types of misconceptions regarding the 'color of gases' and when they have to explain visibility of gases to other people they tend to pass on their misconceptions. Based on the results from the study, some educational guidelines were suggested.

Exhaust Emissions Characteristics on the SI Engine according to the Air-Fuel Mixture with Ozone (혼합기 오존 첨가에 따른 SI기관의 배기배출물 특성)

  • Lee, B.H.;Yi, C.S.;Lee, Y.H.;Lee, C.K.;Jeong, H.M.;Chung, H.S.
    • Journal of Power System Engineering
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    • v.10 no.3
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    • pp.5-10
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    • 2006
  • In a conventional and lean operating engine, the state of mixture is very important in the combustion and emission characteristics. Lean operation is known to decrease the formation while maintaining a good fuel economy, but the unstable operation due to misfire and erratic combustion prevents engines from being operated at very lean mixtures, so both combustion rates and exhaust emission formation need to be satisfied comparably. In this study, it is designed and experimented the modified engine, and analyzed the combustion and exhaust emission according to the change of engine speed and with adding ozone. The conclusions were drawn out and enumerated as follows. 1. At the experimental result of automobile diesel engine, it has been verified that the formation of particulate matter(PM) gas is able to be lower with the addition of optimum quantities of ozone. 2. Carbon monoxide(CO) was formed by the lack of oxygen and the thermal dissociation in the combustion process. Therefore, with the change of swirl valve's position and addition of oxygen and ozone, CO formation was decreased by the increasing of excessive O2, but it was increased by the temperature of combustion gas growing higher. As a result of the two effects, CO formation was decreased in this study. 3. Hydrocarbon(HC) was formed by the lack of O2, and the flow of mixture in cylinder. According to opening of the swirl valve and adding the oxygen and ozone, hydrocarbon gas was decreased by 20%, 9%, and 27.5%, respectively. 4. Nitric oxides($NO_x$) was strongly affected by the combustion gas temperature. As a result of respectively experimental conditions, $NO_x$ formation was increased about 20% due to (be the) high(er) combustion gas temperature.

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The removal characteristics of No, SOx for plasma reactor separated flue gas duct from discharge domain (연소가스관로와 방전영역 분리형 플라즈마 반응기에서 Nox, SOx 제거특성)

  • Park, J.Y.;Koh, Y.S.;Lee, J.D.;Song, W.S.;Park, S.H.;Lee, D.C.
    • Proceedings of the KIEE Conference
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    • 1999.07e
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    • pp.2007-2009
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    • 1999
  • In this paper, discharge domain of wire-cylindrical plasma reactor was separated from a gas flow duct to avoid unstable discharge by aerosol particle deposited on discharge electrode and grounded electrode. The NOx, SOx removal was experimentally investigated by a reaction induced to ammonium nitrate, ammonium sulfate using a low price of aqueous NaOH solution and a small quantity of ammonia. Volume percentage of aqueous NaOH solution used was 20% and $N_2$ flow rate was 2.5[$\ell$/min] for bubbling aqueous NaOH solution. Ammonia gas(14.82%) balanced by argon was diluted by air and was introduced to a main simulated flue gas duct through $NH_3$ injection system which was in downstream of reactor. The $NH_3$ molecular ratio[MR] was determined based on $NH_3$ to [NO+$SO_2$]. MR is 1.5. The NOx removal rates increased in the order of DC, AC and pulse, but SOx removal rates was not significantly effected by source of electricity. The NOx removal rate slightly decreased with increasing initial concentration but SOx removal rate was not significantly effect by initial concentration, and NOx, SOx removal rates decreased with increasing gas flow rate.

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Analysis of A Gas Explosion-Related State Compensation Case (가스폭발 사고와 관련된 국가배상 사례의 분석)

  • Lee, Euipyeong
    • Journal of the Society of Disaster Information
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    • v.16 no.1
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    • pp.44-59
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    • 2020
  • This study analyzed a gas explosion accident. A gas smell from a underground coffee shop in the two-story building was reported to 119. A fire brigade was turned out, turned off the main valve of LPG gas cylinder on the roof, and checked the turning off of middle valve in the coffee shop. The fire brigade required a gas supplier and gas installer who arrived at the spot to take safety actions. Gas explosion occurred seven minutes after the fire brigade was withdrawn and two people died and 21 people were injured. A court decided that because the causes for gas explosion were not found, compensation responsibility could not be charged with the gas supplier, the gas installer, or Korea Gas Safety Corporation. In this reason, the court judged that only the fire brigade who was withdrawn without taking safety actions shall compensate victims or bereaved families. Therefore, fire brigades who turn out after a 119 report of a gas leak should take safety actions such as escaping people or preventing people's access and ventilating and be withdrawn when there is no possibility of fire or explosion.

DeNOx by Hydrocarbon-Selective Catalytic Reduction on Ag-V/γ-Al2O3 Catalyst (Ag-V/γ-Al2O3 촉매상에서 탄화수소-Selective Catalytic Reduction에 의한 질소산화물 저감)

  • Kim, Moon-Chan;Lee, Cheal-Gyu
    • Applied Chemistry for Engineering
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    • v.16 no.3
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    • pp.328-336
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    • 2005
  • In order to remove the NO contained in exhaust gas by the non-selective catalyst reduction method, the catalysts were prepared by varing the loading amount of Ag and V into ${\gamma}-Al_2O_3$. The conversion of $NO_x$ using the prepared catalysts was studied by varying the temperatures, $O_2$ concentrations and $SO_2$ concentrations using. The influence of the catalyst structure on $NO_x$ conversion was studied through the analysis of the physical properties of the prepared catalysts. In the case of $AgV/{\gamma}-Al_2O_3$ catalyst, the $NO_x$ conversion was lower than that of $Ag/{\gamma}-Al_2O_3$ at higher temperatures but higher than that of $Ag/{\gamma}-Al_2O_3$ at lower temperatures. Even though $SO_2$ was contained in the reaction gas, the $NO_x$ conversion did not decrease. Based on the analysis including XRD, XPS, TPR, and UV-Vis DRS before and after the experiments, the experimental results were examined. The results indicated that, $NO_x$ conversion decreased at higher temperatures since Ag oxide could not be maintained well due to the addition of V, whereas it increased at temperatures lower than $300^{\circ}C$ due to the catalytic action of V.

Systemic search for gas outflows in AGNs and star-forming galaxies

  • Woo, Jong-Hak;Son, Donghoon;Bae, Hyun-Jin
    • The Bulletin of The Korean Astronomical Society
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    • v.41 no.1
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    • pp.35.2-35.2
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    • 2016
  • We present a census of AGN-driven gas outflows based on the kinematics of ionized gas and stars, using a large sample of ~11,000 emission line galaxies at z < 0.3, selected from SDSS. First, a broad correlation between gas and stellar velocity dispersions indicates that the bulge gravitational potential plays a main role in determining the ionized gas kinematics. However, the velocity dispersion of the [OIII] emission line is larger than stellar velocity dispersion by a factor of 1.3-1.4, suggesting that the non-gravitational (non-virial) component, i.e., outflows, is almost comparable to the gravitational component. Second, gas-to-stellar velocity dispersion ratio increases with both AGN luminosity and Eddington ratio, suggesting that non-gravitational kinematics are clearly linked to AGN accretion. The distribution in the [OIII] velocity - velocity dispersion diagram dramatically expands toward large values with increasing AGN luminosity, implying that the launching velocity of gas outflows increases with AGN luminosity. Third, the fraction of AGNs with a signature of the non-gravitational kinematics, steeply increases with AGN luminosity and Eddington ratio, while the majority of luminous AGNs presents the non-gravitational kinematics in the [OIII] profile. These results suggest that ionized gas outflows are prevalent among type 2 AGNs. On the other hand, we find no strong trend of the [OIII] kinematics with radio luminosity, once we remove the effect of the bulge gravitational potential, indicating that ionized gas outflows are not directly related to radio activity for the majority of type 2 AGNs. We will discuss the implication of these results for AGN feedback in the local universe.

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