• Title/Summary/Keyword: $NO_2$ gas

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An Experimental Study on Variations of Exhaust Gas Temperature and Concentration with Synthetic Gas Combustion in Exhaust Manifold (배기관에서의 합성가스 연소에 따른 배기가스 온도 및 농도 변화에 관한 실험적 연구)

  • Cho, Yong-Seok;Lee, Seang-Wock;Yang, Seung-Il;Song, Chun-Sub;Park, Young-Joon
    • Transactions of the Korean Society of Automotive Engineers
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    • v.16 no.4
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    • pp.56-62
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    • 2008
  • A synthetic gas reformed from hydrocarbon-based fuels consists of $H_2$, CO and $N_2$. Hydrogen contained in the synthetic gas is a very useful species in chemical processes, due to its wide flammability range and fast burning speed. The ESGI (Exhaust Synthetic Gas Injection) technology is developed to shorten the light-off time of three way catalysts through combustion of the synthetic gas in the exhaust manifold during the cold start period of SI engines. Before the ESGI technology is applied to the test engine, the authors set a test rig that consists of gas temperature and composition controllers, an exhaust pulse generator and an exhaust manifold with a visualization window, in order to optimize the point and conditions of injection of the synthetic gas. Through measuring burned gas temperatures and taking photographs of synthetic gas combustion at the outlet of the exhaust manifold, the authors tried to find the optimal injection point and conditions. Analysis of burned gas composition has been performed for various $O_2$ concentrations. As a result, when the synthetic gas is injected at the port outlet of the cylinder No. 4 and $O_2$ concentration exceeds 4%, combustion of the synthetic gas is strong and effective in the exhaust manifold.

Gas sensor based on hydrogenated multilayer graphene

  • Park, Seong-Jin;Park, Min-Ji;Yu, Gyeong-Hwa
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.273.1-273.1
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    • 2016
  • Graphene exhibits a number of unique properties that make it an intriguing candidate for use in sensor. Here, we report graphene-based gas sensor. Graphene was grown using CVD. Then, the sensor was made using standard lithography techniques. The sensor conductance increased upon exposure to NH3, whereas it decreased upon NO2, suggesting that NH3 and NO2 might be discriminated using the graphene-based sensor. To improve the sensitivity, graphene was treated with hydrogen plasma. After hydrogen treatment, the electrical properties of graphene changed from ambipolar to p-type semiconductors. In addition, the sensor performance was improved probably due to an opening of bandgap.

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Design of Improved Detection Instrumentation for the Annulus Gas System for Wolsong 2

  • Kim, Seog-Nam;Koo, Jun-Mo;Chang, Ik-Ho;Jung, Ho-Chang;Han, Sang-Joon
    • Nuclear Engineering and Technology
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    • v.28 no.4
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    • pp.423-430
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    • 1996
  • The improved and advanced Annulus Gas System(AGS) has been developed for Wolsong 2 to satisfy the requirements of the regulatory body. The Atomic Energy Control Board(AECB) required a shorter detection time following a small leak from a pressure tube and/or calandria tube. This paper describes licensing requirements, functional requirements and detail design description for the AGS. The Wolsong unit No. 1 AGS was designed to operate as a stagnant system normally requiring only pressure regulation and having provisions for purging. no improved AGS involves the adoption of gas recirculation in AGS, duplication of dew point indicators with additional instrumentation and sampling provisions to prompt operator action. The improved system operates in the recirculation mode with continuous dew point measurement for leak detection. An AGS with improved detection instrumentation is provided.

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A Study of The NO$_2$Gas Detect Properties of N-docosyl pyridinium(TCNQ) LB Film (N-docosyl pyridinium(TCNQ) LB막의 NO$_2$가스탐지 특성에 관한 연구)

  • 유병호;조형근;김형석;이창희;김정수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1994.05a
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    • pp.75-78
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    • 1994
  • Organic ultra thin films about 500${\AA}$ in thickness are fabricated by LB(Langmuir-Blodgett) technique and their gas detect properties are investigated. The LB films deposited are made of the specimen named as N-docosyl pyridinium(TCNQ) and the deposition is verified by capacitance conductivity measurement. From the study of gas detect properties with I-V characteristics and UV spectrum we have found that their conductivities were increased about 3 times of magnitude and peaks of UV spectrum were decreased.

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Bidirectional pulse generator for removal of flue gas (배기가스 처리용 양방향 펄스 전원)

  • 박정호;고광철;강형부
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.11a
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    • pp.233-236
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    • 1997
  • An investigation has been made of the various plasma chemistry reactions that occur in the corona discharge of an electrostatic precipitator operating in a typical flue gas. As the results of investigation, sulphur dioxide is removed principally by reactions with OH radicals to produce sulphuric acid, while nitrogen oxides are removed principally by reduction via the N radical to molecular nitrogen. If electrostatic precipitator\ulcorner used for flue gases are operated with positive voltages instead of negative dc voltages, there are significant reductions in the emission of the undesirable gases SO$_2$, NO, and NO$_2$. Thus, in this paper we design the bidirectional pulse generator for removal of flue gas, where the pulse width is more than 50[nsec] and the maximum output voltage is more than 100[kVl.

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Air Pollution Protection onboard by Seawater and Electrolyte

  • An Suk-Heon
    • Journal of Advanced Marine Engineering and Technology
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    • v.30 no.1
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    • pp.93-101
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    • 2006
  • This research makes a new attempt to apply the activated seawater by electrolysis in the development of two-stage wet scrubber system to control the exhaust gas of large marine diesel engines. First, with using only seawater that is naturally alkaline (pH typically around 8.1). the $SO_2\;and\;SO_3$ are absorbed by relatively high solubility compared to other components of exhaust pollutants, and PM (Particulate Matter) is removed through direct contact with sprayed seawater droplets. Besides, the electrolyzed alkaline seawater by electrolysis, which contains mainly NaOH together with alkali metal ions $(i.e.\;Na^+,\;Mg^{2+},\;Ca^{2+})$, is used as the absorption medium of NOx and $CO_2$. Especially, to increase NOx absorption rate into the alkaline seawater. nitric oxide (NO) is adequately oxidized to nitrogen dioxide $(NO_2)$ in the acidic seawater, which means both volume fractions are adjusted to identical proportion. The results found that the strong acidic seawater was a valid oxidizer from NO to $NO_2$ and the strong alkaline seawater was effective in $CO_2$ absorption In the scrubber test, the SOx reduction of nearly $100\%$ could be achieved and also led to a sufficientPM reduction. Hence, the author believes that applying seawater and its electrolyte would bring the marine air pollution control system to an economical measure. Additionally it is well known that NOx and SOx concentration has a considerable influence on the $N_2O$ emission of green house gas. Although the $N_2O$ concentration exhausted from diesel engines is not as high, the green house gas effect is around 300 times greater than an equivalent volume of $CO_2$. Therefore, we investigated the $N_2O$ removal efficiency with using the electrolyzed seawater too. Finally this research would also plan to treat the effluent by applying electro-dialysis and electro-flotation technique s in the future.

Ga doped ZnO Thin Films for Gas Sensor Application (Ga이 첨가된 ZnO 박막의 가스센서로의 응용 연구)

  • Hwang, Hyun-Suk;Yeo, Dong-Hun;Kim, Jong-Hee;Song, Joon-Tae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.6
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    • pp.499-502
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    • 2008
  • In this work, Ga-doped ZnO (GZO) thin films for gas sensor application were deposited on low temperature co-fired ceramics (LTCC) substrates, by RF magnetron sputtering method. The LTCC substrate is one of promising materials for this application since it has many advantages (e.g., low cost production, high manufacturing yields and easy realizing 3D structure etc.). The LTCC substrates with thickness of $400\;{\mu}m$ were fabricated by laminating 12 green tapes which consist of alumina and glass particle in an organic binder. The structural properties of the fabricated GZO thin film with thickness of 50 nm is analyzed by X-ray diffraction method (XRD) and field emission scanning electron microscope (FESEM). The film shows good adhesion to the substrate. The GZO gas sensors are tested by gas measurement system and show fast response and recovery characteristics to $NO_x$ gas that is 27.2 and 27.9 sec, recpectively.

Faint Dwarf Galaxies along the Leo Large Scale HI Gas Ring

  • Park, Hyuk;Chung, Ae-Ree
    • The Bulletin of The Korean Astronomical Society
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    • v.36 no.2
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    • pp.113.1-113.1
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    • 2011
  • The Leo ring in the M96 group is unique in its morphology and size among the intergalactic gas features found in nearby universe. Its ring-like structure of 200 kpc on diameter appears to be orbiting around the M105-NGC 3384 pair with $1.67{\times}109\;M{\odot}$ of HI gas. While the origin of the ring - whether it is primordial or tidally stripped - is yet unclear, the optical and gas properties of dwarf galaxies associated with the gas ring help us to understand the formation process of this large scale intergalactic HI cloud. At the first step, we present the optical catalog of dwarf galaxy candidates in the Leo ring using deep optical images with MegaCam on the CFHT. Image convolution method is used in order to detect very faint dwarf galaxies. Comparing the ALFALFA HI data from the literature, we have identified that 4 dwarf candidates coexist with HI clumps. There are also 27 HI dwarfs with no optical counterpart and 12 optical dwarfs with no HI clump. In this work, we probe the optical and global gas properties of these dwarfs.

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Gas trasport and Gas hydrate distribution characteristics of Southern Hydrate Ridge: Results from ODP Leg 204

  • Lee, Young-Joo;Ryu, Byong-Jae;Kim, Ji-Hoon;Lee, Sang-Il
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.06a
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    • pp.407-409
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    • 2006
  • Geochemical analyses carried out on samples collected from cores on and near the southern smit of Hydrate Ridge have advanced understanding by providing a clear contrast of the two major modes of marine gas hydrate occurrence. High concentrations (15%-40% of pore space) of gas hydrate occurring at shallow depths (0-40 mbsf) on and near the southern summit are fed by gas migrating from depths of as much as 2km within the accretionary prism. This gas carries a characteristic minor component of C2-C5 thermogenic hydrocarbons that enable tracing of migration pathways and may stabilize the occurrence of some structure II gas hydrate. A structure II wet gas hydrate that is stable to greater depths and temperatures than structure I methane hydrate may account for the deeper, faint second bottom simulating reflection (BSR2) that occurs on the seaward side of the ridge. The wet gas is migrating In an ash/turbidite layer that intersects the base of gas hydrate stability on the seaward side of and directly beneath the southern summit of Hydrate Ridge. The high gas saturation (>65%) of the pore space within this layer could create a two-phase (gas + solid) system that would enable free gas to move vertically upward through the gas hydrate stability zone. Away from the summit of the ridge there is no apparent influx of the gas seeping from depth and sediments are characterized by the normal sequence of early diagenetic processes involving anaerobic oxidation of sedimentary organic matter, initially linked to the reduction of sulfate and later continued by means of carbonate reduction leading to the formation of microbial methane.

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A Study on Characteristic of NO Reduction by High Level O2Gas in Selective Non-Catalystic Reaction (High Level O2배가스중 NO 저감에 대한 선택적비촉매환원 반응특성에 관한 연구)

  • 이강우;정종현;오광중
    • Journal of Environmental Science International
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    • v.11 no.6
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    • pp.577-582
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    • 2002
  • Selective catalytic reduction and selective non-catalytic reduction processes are mainly used to treat nitrogen oxidants generated from fossil-fuel combustion. Especially, the selective non-catalytic reduction process can be operated more economical and designed more simply than the selective catalytic reduction. For this reason, many researchers carried out to increase the removal efficiency of nitrogen oxidants in the condition of low oxygen concentration by using the selective non-catalytic reduction process. However, this study was flue gas contained high oxygen concentration of 20(v/v%) with ammonia as a reducing agent. Moreover, it carried out experiment with many factors that are reaction temperature, retention time, initial NO concentration, NSR(normalized stoichiometric ratio). It was determined optimal operating conditions to improve NO removal efficiency with SNCR process. The De-NOx efficiency was increased with NSR, initial NO concentration and retention time increasement. This study has NO removal efficiency over 80% in the high oxygen concentration as well as low oxygen concentration. The injection of reducing agent may be considered for SNCR process and facility operation in 850$\^{C}$ of optimal condition.