• Title/Summary/Keyword: $NO_2$ gas

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Catalistic effect of sludge on $NO_x$ removal in cylinder type reactor (원통형 플라즈마 반응기에서 $NO_x$ 제거에 미치는 슬러지의 촉매효과)

  • Park, Jae-Yoon;Lee, Kyung-Ho;Park, Sang-Hyun;Kim, Hyung-Man;Kim, Jong-Suk;Ha, Hyun-Jin
    • Proceedings of the KIEE Conference
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    • 2001.07c
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    • pp.1777-1779
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    • 2001
  • In this experiment, an attempt to use the sludge pellets as catalyst for NO removal from simulated gas is experimentally investigated by using cylinder type reactor. An experimental investigation has been conducted for NO concentration of 50[ppm], 100[ppm], 200[ppm] balanced with air. a gas flow rate of 5[1/min]. Cylinder type reactor is at upstream of system for corona discharge and packed bed type reactor filled with sludge pellets ate put at downstream of Cylinder type reactor for catalystic effect. And AC voltage to discharge the gases was supplied. In the result, NO removal with magnetic field is higher than that without magnetic field, when packed-bed reactor with sludge pellet is installed at downstream of cylinder reactor NO, $NO_2$ removal rate increased and $O_3$ is not generated.

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Fabrication of Stack-Structured Gas Sensor of LaCrxCo1-xO3/Li1.3Al0.3Ti1.7(PO4)3 and Its NOx Sensing Properties (LaCrxCo1-xO3/Li1.3Al0.3Ti1.7(PO4)3의 적층구조를 가지는 가스센서 제조와 그의 NOx 검지특성)

  • Lee, Young-Sung;Shimizu, Y.;Song, Jeong-Hwan
    • Korean Journal of Materials Research
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    • v.25 no.8
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    • pp.423-428
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    • 2015
  • Impedancemetric $NO_x$ (NO and $NO_2$) gas sensors were designed with a stacked-layer structure and fabricated using $LaCr_xCo_{1-x}O_3$ (x = 0, 0.2, 0.5, 0.8 and 1) as the receptor material and $Li_{1.3}Al_{0.3}Ti_{1.7}(PO_4)_3$ plates as the solid-electrolyte transducer material. The $LaCr_xCo_{1-x}O_3$ layers were prepared with a polymeric precursor method that used ethylene glycol as the solvent, acetyl acetone as the chelating agent, and polyvinylpyrrolidone as the polymer additive. The effects of the Co concentration on the structural, morphological, and $NO_x$ sensing properties of the $LaCr_xCo_{1-x}O_3$ powders were investigated with powder X-ray diffraction, field emission scanning electron microscopy, and its response to 20~250 ppm of $NO_x$ at $400^{\circ}C$ (for 1 kHz and 0.5 V), respectively. When the as-prepared precursors were calcined at $700^{\circ}C$, only a single phase was detected, which corresponded to a perovskite-type structure. The XRD results showed that as the Co concentration of the $LaCr_xCo_{1-x}O_3$powders increased, the crystal structure was transformed from an orthorhombic phase to a rhombohedral phase. Moreover, the $LaCr_xCo_{1-x}O_3$ powders with $0{\leq}x<0.8$ had a rhombohedral symmetry. The size of the particles in the $LaCr_xCo_{1-x}O_3$powders increased from 0.1 to $0.5{\mu}m$ as the Co concentration increased. The sensing performance of the stack-structured $LaCr_xCo_{1-x}O_3/Li_{1.3}Al_{0.3}Ti_{1.7}(PO_4)_3$ sensors was found to divide the impedance component between the resistance and capacitance. The response of these sensors to NO gas was more sensitive than that to $NO_2$ gas. Compared to other impedancemetric sensors, the $LaCr_{0.8}Co_{0.2}O_3/Li_{1.3}Al_{0.3}Ti_{1.7}(PO_4)_3$ sensor exhibited good reversibility and reliable sensingresponse properties for $NO_x$ gases.

A study on power improvement emission characteristics of marine diesel engine with response power 200HP turbocharger (대응출력 200마력 과급기에 의한 디젤기관의 출력향상 및 배출특성에 관한 연구)

  • Lee, Chi-Woo
    • Journal of Advanced Marine Engineering and Technology
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    • v.38 no.1
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    • pp.23-30
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    • 2014
  • To improve efficiency of diesel engine which requests high output recently and is used all kinds of industrial areas, this thesis experimented dynamic characteristics and exhaust gas characteristics of diesel engine installed by supercharger of correspondent output 200HP and natural inhalation diesel engine through the dynamometer and exhaust gas analyzer in same condition. As the result of experiment with natural inhalation diesel engine and diesel engine installed by supercharger, there were a few differences of output, but dynamic characteristics at high speed showed increased output and efficiency of the engine installed by supercharger. On the contrary, in exhaust gas characteristics, the model installed by supercharger showed increased exhaust gas such as $NO_X$, $O_2$, etc, but added value of exhaust gas is low if considering $CO_2$ reduction and efficiency of dynamic characteristic's increase. Based on the results, diesel engine installed by supercharger is expected to show higher economic feasibility than natural inhalation diesel than natural inhalation engine from an angle of efficiency. Keywords: 200hp class Turbocharger, Exhaust Gas, Engine Performance, Marine Diesel Engine.

Effect of Nitrogen Volume in Ar-N2 Shielding Gas on Microstructure and Hardness of GTA Welded Pure Ti (순 Ti GTA 용접부의 미세조직과 경도에 미치는 Ar-N2 보호가스 중 질소량의 영향)

  • An, Hyun-Jun;Jeon, Ae-Jeong;Hong, Jae-Keun;Jeong, Bo-Young;Lee, Jong-Sub;Kang, Chung-Yun
    • Journal of Welding and Joining
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    • v.30 no.2
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    • pp.70-75
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    • 2012
  • In this study, effect of nitrogen volume in the shielding gas of Ar-$N_2$ mixing gas on the bead shape, hardness and microstructure of GTA welds of 3mm thick Commercial Pure Ti was investigated. As the nitrogen volume increased, the welding current for full penetration was reduced and hardness in the fusion zone significantly increased compared with that of the base metal, but there is no difference in the hardness of HAZ. Microstructure in the fusion zone with pure Ar gas changed from equiaxed alpha of the base metal to serrated alpha. On the other hand, microstructure using Ar-$N_2$ mixing gas changed to acicular alpha. With the increasing of nitrogen content, the amount of acicular alpha increased and the size of that was fine.

Development of Direct DME Synthesis Process (DME 직접 합성공정 기술개발)

  • Mo, Yong-Gi;Cho, Won-Jun;Baek, Young-Soon
    • Journal of the Korean Institute of Gas
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    • v.14 no.3
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    • pp.41-45
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    • 2010
  • The physical properties of DME(Dimethyl Ether) are very similar to LPG and well-mixed. As cetane number of DME is similar to diesel fuel that can replace diesel fuel and alternative energy. DME is a clean energy source that can be manufactured from various raw materials such as natural gas, CBM(Coal Bed Methane) and biomass. DME has no carbon-carbon bond in its molecular structure and its combustion essentially generates no soot as well as no SOx. The development of DME process in KOGAS have 4 section. First, syngas section can be manufactured various syngas ratio. This completes the tri-reforming process for the synthesis gas ratio of approximately 4.0 to 1.0 range can be adjusted. Second, $CO_2$ is removed from the $CO_2$ removal section of about 92~99%, so the maximum concentration of $CO_2$ entering the DME synthesis reactor should not exceed 8%. Third, in the DME synthesis section, if the temperature of DME reactor increases, the activity of DME catalyst increased. but for the long-term activity is desirable to maintain the proper temperature. Finally, the purity of DME in the DME purification section is over 99.6%.

Quality Changes of Strawberry by Slow-released ClO2 Gas Gel-pack during Storage (서방형 이산화염소 가스 젤팩을 이용한 딸기의 저장 중 품질 변화)

  • Lee, Kyung-Haeng;Bong, So-Jung;Yoon, Ye-Ji;Lee, Bom;Kwak, Il-Hwan;Min, Kyung-Hoon;Kim, Hong-Gil
    • The Korean Journal of Food And Nutrition
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    • v.30 no.3
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    • pp.591-598
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    • 2017
  • To prolong the shelf-life of strawberry, samples were treated with gel packs containing slow-released chlorine dioxide($ClO_2$) gas at 3~7 ppm for 6 days at room temperature. The weight loss and decay ratio as well as changes in pH, color and texture properties of the treated samples were investigated. The weight of the control and $ClO_2$ gas treated samples decreased slightly, but the weight of the control changed faster than those of the $ClO_2$ gas treated samples during the storage period. The decay ratio of control was higher than those of the $ClO_2$ gas treatments since 4 days of storage. The pH and acidity in the control and in the $ClO_2$ gas treated samples were no differences during storage period. The lightness of strawberry decreased during storage, but there was no difference in lightness among the treatments even when storage time was extended. The redness and yellowness of the control showed higher change than those of the $ClO_2$ gas treatments during 6 days. The firmness of the control changed more rapidly than those of the $ClO_2$ gas treatments during 6 days. Especially, the samples treated 3 and 5 ppm $ClO_2$ gas were the least changed. And the scores for appearance, firmness and overall acceptance control and 7 ppm $ClO_2$ gas treatment decreased more rapidly than those of 3 and 5 ppm treatment.

Structural and Electrical Properties of WOx Thin Films Deposited by Direct Current Reactive Sputtering for NOx Gas Sensor

  • Yoon, Young-Soo;Kim, Tae-Song;Park, Won-Kook
    • Journal of the Korean Ceramic Society
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    • v.41 no.2
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    • pp.97-101
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    • 2004
  • W $O_{x}$-based semiconductor type thin film gas sensor was fabricated for the detection of N $O_{x}$ by reactive d.c. sputtering method. The relative oxidation state of the deposited W $O_{x}$ films was approximately compared by the calculation of the difference of the binding energy between Ols to W4 $f_{7}$2/ core level XPS spectra in the standard W $O_3$ powder of known composition. As the annealing temperature increased from 500 to 80$0^{\circ}C$, relative oxygen contents and grain size of the sputtered films were gradually increased. As the results of sensitivity ( $R_{gas}$/ $R_{air}$) measurements for the 5 ppm N $O_2$ gas, the sensitivity was 110 and the sensor showed recovery time as fast as 200 s. The other sensor properties were examined in terms of surface microstructure, annealing temperature, and relative oxygen contents. These results indicated that the W $O_3$ thin film with well controlled structure is a good candidate for monitoring and controlling of automobile exhaust.haust.t.t.t.

A Theoretical Analysis on Hydrogen Gas Fueled Turbine Engine with No Emissiom Gas (배기가스가 없는 수소가스용 터빈엔진에 대한 이론적 해석)

  • Oh, Byeong-Soo
    • Transactions of the Korean hydrogen and new energy society
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    • v.5 no.1
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    • pp.25-31
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    • 1994
  • It is very important factor to reduce air pollution from any engines. Some exhaust gases, as $CO_2$, $NO_X$ and $SO_X$, are the products by combustion of hydrocarbon fuel and air. Hydrogen is clean energy to keep our environment out of air pollution. In this study a turbine engine system is theoretically developed which produces pure water only with no exhaust gas by combustion of hydrogen and stoichiometric oxygen. The thermal efficiency of the whole system can be calculated by calculation of each part.

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Diode-Laser Absorption Sensors for measurement of combustion Gas (연소배기 가스의 계측을 위한 다이오드 레이저 센서)

  • Shin, Myung-Chul;Kim, Se-Won;Kim, Dong-Hyuck
    • Journal of the Korean Society of Combustion
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    • v.11 no.3
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    • pp.26-35
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    • 2006
  • This work forcus on the development of gas sensor that measure the concentrations of exhaust gas using diode laser, Each diode laser for exhaust gas measurement is set to work at near-IR using both DA and WMS methods. Also use of fiber-coupled optical elements makes such a sensor rugged and easy to align. The results showed that gas concentrations of $O_2$, CO, $CO_2$, NO are accurately measured within ${\pm}2%$ error. The application of WMS method increased the beam intensity 2-3 times higher than DA method. It were experimentally compared WMS (Wavelength Modulation Spectroscopy) with DA (Direct Absorption) for the accuracy.

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Spatial Distribution of Electron Number Density in an Inductively Coupled Plasma (유도결합 플라스마 공간내의 전자밀도 분포)

  • Beom Suk Choi
    • Journal of the Korean Chemical Society
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    • v.30 no.3
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    • pp.327-332
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    • 1986
  • Spatial (radial and height) distribution of electron number density is measured for an inductively coupled plasma under five operating conditions: (1) no carrier gas, (2) carrier gas without aerosel, (3) carrier gas with aerosol, (4) carrier gas with desolvated aerosol, and (5) carrier gas with aerosol and excess lithium. A complete RF power mapping of electron density is obtained. The plasma electrons for a typical analytical torch are observed to be hollow at the radial center in the region close to the induction coil, but diffuse rapidly toward the center in the higher region of the plasma. The presence of excess Li makes no significant change in the electron density profiles. The increases in the RF power levels increase the values of electron density uniformly across the radial coordinate.

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