• 제목/요약/키워드: $NO_2$ gas

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WO$_3$박막을 이용한 SAW 가스 센서 (SAW Gas Sensor using WO$_3$Thin Film)

  • 정영우;허두오;이해민;안형근;한득영
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1995년도 추계학술대회 논문집
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    • pp.187-189
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    • 1995
  • A Surface Acoustic Wave Gas sensor for NO, CO, H$_2$gas detection was designed fabricated, and tested. A delay line device was designed to composite a single mode SAW oscillator which enables to measure a SAW velocity. To reduce the effect of temperature and humidity, dual delay line oscillator circuit was used. And final output was measured by digital frequency counter. NO, CO, H$_2$gas were detected by WO$_3$thin film deposited on the path of the Delay Line.

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전류검출형 가스센서의 구성 및 성능평가에 관한 연구 (Fabrication and Performances of Amperometric Gas Sensors)

  • 김귀열;박용필;이준웅;서장수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 하계학술대회 논문집
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    • pp.1073-1075
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    • 2001
  • The nitrogen oxides, NO and NO2, abbreviated usually as NOx, emitted from combustion facilities such as power plants and automobiles are the typical air-pollutants causing acid rain and photochemical smog. In order to solve the NOx-related pollution problems effectively, we need efficient techniques to monitor NOx in the combustion exhausts and in environments. Development of solid-state electrochemical devices for detecting NOx is demonstrated based on various combination of solid electrolytes and auxiliary sensing materials. The object of this research is to develop various sensor performance for solid state amperometric sensor, and to test gas sensor performance manufactured. So we try to present a guidance for developing amperometric gas sensor. We concentrated on development of manufacturing process and performance test.

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철도차량용 내장 재료의 연소특성을 고려한 유해가스 정량분석 기법연구 (Technical study on quantitative analysis of the toxic gas concerning the combustion property of interior materials of railway car)

  • 박지영;이철규;이덕희;정우성;정회일
    • 한국철도학회:학술대회논문집
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    • 한국철도학회 2008년도 춘계학술대회 논문집
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    • pp.1114-1118
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    • 2008
  • In previous fire accident of railway car, the fatality was relatively high by toxic gas poisoning cause of closed space. So the necessity of quantifying toxic gas in combustion gas was recognized and then, FT-IR spectroscopy was introduced for real-time analysis of mixed gases and stimulated analysis of the concentration of several gases. Thus, in this study, absorption bands using FT-IR were obtained by each component of combustion gases for interior materials of railway car such as flooring materials and moquette seat. And then the sample spectra were compared with the spectra of NO, $NO_2$, $SO_2$ reference gases, we could obtain some identical peaks of them.

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FTIR법에 의한 천연가스자동차 배기의 촉매반응특성 분석 (Analysis of Catalytic Reaction Characteristics of NGV Exhaust Gas by FTIR Spectroscopy)

  • 최병철;김영길;임명택
    • 한국자동차공학회논문집
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    • 제6권6호
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    • pp.218-225
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    • 1998
  • FTIR spectroscopy, useful technology for simultaneous and continuous measurement of the various components of the automotive exhaust gas, is utilized to investigate catalytic reaction charactristics of methane and a few unregulated exhaust emissions of NGV. Major findings are (1) catalytic reaction characteristics of methane measured in unsteady states of varying temperature are similar to those measured in steady states, (2) about 24 % of NO was oxidized to $NO_2$ as soon as they encounter catalysts, (3) study of formaldehyde suffers from difficulties in measurement due to the proximity in wavenumber of formaldehyde and methane, and requires an analyzer of higher resolution and accuracy than used in this study.

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Sol-Coprecipitation 법에 의한 NO 감지용 $WO_3$ 센서 제조시 pH의 영향 (Influence of pH on Sensitivity of $WO_3$ NO gas sensor fabricated by Sol-Coprecipitation method)

  • 김석봉;이대식;이덕동;허증수
    • 센서학회지
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    • 제10권2호
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    • pp.118-124
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    • 2001
  • 입자들이 용액에 녹아있을 때 pH에 따라서 다른 zeta-potential을 가지게 되며, 이것은 입자의 분산상태에 영향을 주게 된다. NO 센서에서 $WO_3$ 입자의 크기는 감도에 큰 영향을 끼치므로 Sol-Coprecipitation법에 의한 $WO_3$ 센서 제조 시에 $WO_3$ precursor 상태에서의 pH의 영향을 알아보았다. 먼저 $WO_3$ precursor의 전기적 포텐셜을 측정하여 pH가 2에서 7로 변함에 따라 mobility가 증가하여 7일 때에 가장 큰 분산도를 가진 것을 알 수 있었고, 이는 powder 제조 후 입도 분석, 감지막의 XRD peak, 표면사진으로부터 확인 할 수 있었다. 결과적으로 감도 특성에도 영향을 끼쳐 pH=7에서 제조한 센서가 다른 pH에서 제조한 센서보다 감도가 우수한 것으로 나타났다.

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CuTBP(Copper-tetra-tert-butylphthalocyanine) 화학 저항 장치의 $NO_2$ 가스 탐지 특성에 관한 연구 (A study on the $NO_2$ gas detection characteristics of the CuTBP(Copper-tetra-tert-butylphthalocyanine) chemiresistor device)

  • 구자룡;이창희;김태완;김정수
    • E2M - 전기 전자와 첨단 소재
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    • 제10권3호
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    • pp.233-238
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    • 1997
  • We have investigated gas-detection characteristics of CuTBP (Copper-tetra-tert-butylphthalocyanine) chemiresistor devices exposed to air/200ppm N $O_{2}$ gases. The CuTBP films were made by Langmuir-Blodgett (LB) techniques. Sensitivity, response time, recovery time, and reproducibility of the devices were measured by current voltage characteristics. Interdigital electrode was used to improve the sensitivity. It was observed that a conductance G increases monotonically as the number of interdigital electrode finger pairs increases. As the number of interdigital electrode finger pairs increases, the sensitivity S( $G_{gas}$/ $G_{air}$) increases more than 50 times and stable. But the response time was delayed. The average recovery time of the CuTBP chemiresistor devices turned out to be about 100 second. We have also investigated applicability of the CuTBP chemiresistor device for a gas sensor.sor.

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디젤엔진의 후처리장치로서 PCD 플라즈마 시스템에 관한 연구 (A Study on the PCD Plasma System as an After Treatment Apparatus in Diesel Engine)

  • 유경현
    • 한국자동차공학회논문집
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    • 제20권2호
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    • pp.70-77
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    • 2012
  • The selective catalytic reduction(SCR) system used to reduce NOx in diesel engines requires an NO/$NO_2$ ratio of about 1 in exhaust emissions to realize the fast SCR mode at temperatures lower than $300^{\circ}C$. This study investigated the characteristics of a plasma system as a pre-active apparatus for the fast SCR reaction mode of an SCR system. Plasma was generated by the pulse corona discharge(PCD) method with a four-channel wire-cylinder reactor. This study showed that plasma was easily generated in the exhaust gas by the PCD system, and the peak voltage of the normal state condition for plasma generation was generally 12 kV. The PCD system easily converted NO into $NO_2$ at lower temperatures and the NO/$NO_2$ conversion ratio increased with the discharge current for plasma generation. But the PCD system could not convert NO into $NO_2$ at higher engine speeds and higher engine loads due to the lack of oxygen in exhaust gas. The PCD system also activated the diesel oxidation catalysts(DOC) system to reduce CO emissions.

용액적하법으로 제조된 WO3 첨가 SnO2 박막의 가스감응 특성 (Gas Sensing Characteristics of WO3-Doped SnO2 Thin Films Prepared by Solution Deposition Method)

  • 최중기;조평석;이종흔
    • 한국재료학회지
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    • 제18권4호
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    • pp.193-198
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    • 2008
  • $WO_3$-doped $SnO_2$ thin films were prepared in a solution-deposition method and their gas-sensing characteristics were investigated. The doping of $WO_3$ to $SnO_2$ increased the response ($R_a/R_g,\;R_a$: resistance in air, $R_g$: resistance in gas) to $H_2$ substantially. Moreover, the $R_a/R_g$ value of 10 ppm CO increased to 5.65, whereas that of $NO_2$ did not change by a significant amount. The enhanced response to $H_2$ and the selective detection of CO in the presence of $NO_2$ were explained in relation to the change in the surface reaction by the addition of $WO_3$. The $WO_3$-doped $SnO_2$ sensor can be used with the application of a $H_2$ sensor for vehicles that utilize fuel cells and as an air quality sensor to detect CO-containing exhaust gases emitted from gasoline engines.

비열플라즈마에 의한 수소발생에 미치는 캐리어가스의 영향 (A study on the hydrogen generation's characteristics via non-thermal plasma and carrier gas)

  • 김종석;박재윤;정장근;김태용;고희석;이현우
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2004년도 하계학술대회 논문집 Vol.5 No.1
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    • pp.215-219
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    • 2004
  • This paper is investigated about the effect of carrier gas and humidity for generating hydrogen gas. In the experimental result of generating hydrogen gas by non-thermal plasma reactor, the rate of generating hydrogen gas is different with what kind of carrier gas is. We used two types of carrier gas, such as $N_2$ and He. $N_2$ as carrier gas is more efficient to generate hydrogen gas than He because $N_2$ is reacted with $O_2$, which is made from water dissociation. In comparison with no humidity and humidity 45[%], the generation of hydrogen gas is decreased with increasing the humidity. That is the result that the energy for water dissociation is reduced on water surface because a part of plasma energy is absorbed at the small particle produced from humidifier.

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플라즈마와 촉매를 이용한 농용 디젤기관 배기가스 중의 NOx 저감에 관한 실험적 연구 (An Experimental Study on NOx Reduction in Exhaust Gas from Agricultural Diesel Engine with Plasma and Catalyst)

  • 이승규;조기현;황의현
    • Journal of Biosystems Engineering
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    • 제24권6호
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    • pp.465-472
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    • 1999
  • To remove nitrogen oxides(NOx) in exhaust gas of diesel engine, three-way catalytic process with plasma discharger has great possibilities. Characteristics of NOx removal depends on NO conversion to NO$_2$and/or HNO$_3$due to high activation energies for NO oxidation and reduction. NOx removal efficiency by using three-way catalytic with plasma discharger indicated about 50% at 40watt power consumption condition.

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