• Title/Summary/Keyword: $NO_2$ Sensor

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Fabrication and Performances of Amperometric Gas Sensors (전류검출형 가스센서의 구성 및 성능평가에 관한 연구)

  • 김귀열;박용필;이준웅;서장수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.1073-1075
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    • 2001
  • The nitrogen oxides, NO and NO2, abbreviated usually as NOx, emitted from combustion facilities such as power plants and automobiles are the typical air-pollutants causing acid rain and photochemical smog. In order to solve the NOx-related pollution problems effectively, we need efficient techniques to monitor NOx in the combustion exhausts and in environments. Development of solid-state electrochemical devices for detecting NOx is demonstrated based on various combination of solid electrolytes and auxiliary sensing materials. The object of this research is to develop various sensor performance for solid state amperometric sensor, and to test gas sensor performance manufactured. So we try to present a guidance for developing amperometric gas sensor. We concentrated on development of manufacturing process and performance test.

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Failure Case Studies of Sensors for Electronic Controlled Engine in LPG Vehicle (LPG 자동차에서 전자제어엔진용 센서의 고장사례에 관한 연구)

  • Kim, Chung-Kyun;Lee, Il-Kwon
    • Journal of the Korean Institute of Gas
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    • v.14 no.4
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    • pp.56-62
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    • 2010
  • The purpose of this paper analyzes and investigates the failure case studies of electronic control sensors for a LP gas engine. The malfunction of crank angle sensor, which controls a fuel injection volume of LP gas, displays an irregular and non-uniform pulse wave form. The pulse form, which is related to the noise of the crank angle sensor, displays at the rectangular peak with a saw-toothed shape and is intermittently generated with a level of 2.46V noise signal. The malfunction of No. 1 TDC sensor in which is caused from the internal disorder affects to the reduction of engine power and engine stop suddenly. If the malfunction of oxygen sensor is occurred due to a wiring problem of a sensor connector, the LP gas vehicle may produce a shaking and disharmony of an engine because of no signal supply from the oxygen sensor. The air cleaner replica produces the clogging of continuous supply of fresh air. This may cause the retardation of vehicle acceleration and engine disharmony intermittently.

A QCM-based Sensor System for Detecting NO2 and SO2 (QCM기반 NO2와 SO2 감지용 센서시스템)

  • Hwang, Min-Jin;Shim, Wang Geun;Moon, Hee
    • Korean Chemical Engineering Research
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    • v.51 no.2
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    • pp.285-291
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    • 2013
  • The effects of sensing materials, coating methods, diluent gases, and temperature have been studied in detail to make a quartz crystal microbalance based adsorption sensor system for detecting gases. In particular, sensor elements for detecting $NO_2$ and $SO_2$, that are known as major air pollutants, have been prepared by coating two different polymers, polypyrrole and poly(3,4-ethylenedioxythiophene). The sensor elements prepared in this work have high sensitivity and selectivity for $NO_2$ and $SO_2$ at ppm level concentrations. It was proven that the sensing characteristics and response rate of the sensing elements are highly dependent on the coating method and the loading mass of sensing materials.

Sensing Characterization of Metal Oxide Semiconductor-Based Sensor Arrays for Gas Mixtures in Air

  • Jung-Sik Kim
    • Korean Journal of Materials Research
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    • v.33 no.5
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    • pp.195-204
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    • 2023
  • Micro-electronic gas sensor devices were developed for the detection of carbon monoxide (CO), nitrogen oxides (NOx), ammonia (NH3), and formaldehyde (HCHO), as well as binary mixed-gas systems. Four gas sensing materials for different target gases, Pd-SnO2 for CO, In2O3 for NOx, Ru-WO3 for NH3, and SnO2-ZnO for HCHO, were synthesized using a sol-gel method, and sensor devices were then fabricated using a micro sensor platform. The gas sensing behavior and sensor response to the gas mixture were examined for six mixed gas systems using the experimental data in MEMS gas sensor arrays in sole gases and their mixtures. The gas sensing behavior with the mixed gas system suggests that specific adsorption and selective activation of the adsorption sites might occur in gas mixtures, and allow selectivity for the adsorption of a particular gas. The careful pattern recognition of sensing data obtained by the sensor array made it possible to distinguish a gas species from a gas mixture and to measure its concentration.

$NO_2$ gas sensing properties of $SnO_2$ thin films dopped with Pd and CNT (Pd 및 CNT 첨가에 따른 $SnO_2$ 박막의 이산화질소 감지특성)

  • Kim, H.K.;Lee, R.Y.
    • Journal of the Microelectronics and Packaging Society
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    • v.15 no.4
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    • pp.101-106
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    • 2008
  • The $SnO_2$ thin films doped with Pd and CNT as $NO_2$ gas sensor were prepared by spin coating and then the $NO_2$ gas response of these films were evaluated under $1ppm{\sim}5ppm\;NO_2$ concentration and operating temperature of $200^{\circ}C$. It was found that the sensor resistance was increased with $NO_2$ exposure and $NO_2$ concentration. The 3wt% Pd doped sample showed a sensitivity of 26.5 which was 10 times higher than that of pure $SnO_2$. And also the sensitivity of CNT doped sample increased with CNT content and it had 72 when 0.225 wt% of CNT was added under 5ppm $NO_2$ concentration.

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The highly sensitive NO2 gas sensor using ZnO nanorods grown by the sol-gel method (졸-겔법으로 증착된 ZnO 나노막대를 이용한 고감도 이산화질소 가스 센서 제작 및 특성 연구)

  • Park, S.J.;Kwak, J.H.;Park, J.;Lee, H.Y.;Moon, S.E.;Park, K.H.;Kim, J.;Kim, G.T.
    • Journal of Sensor Science and Technology
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    • v.17 no.2
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    • pp.147-150
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    • 2008
  • Multiple ZnO nanorod device detecting $NO_2$ gas was fabricated by sol-gel growth method and gas response characteristics were measured as a chemical gas sensor. The device is mainly composed of sensing electrode and sensing nano material. To acquire high sensitivity of the device for $NO_2$ gas it was heated by a heat chuck up to $400^{\circ}C$ The sensing part was easily made using the CMOS compatible process, for example, the large area and low temperature nano material growth process, etc. The sensors were successfully demonstrated and showed high sensitive response for $NO_2$ gas sensing.

Improved Sensitivity of an NO Gas Sensor by Chemical Activation of Electrospun Carbon Fibers

  • Kang, Seok-Chang;Im, Ji-Sun;Lee, Young-Seak
    • Carbon letters
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    • v.12 no.1
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    • pp.21-25
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    • 2011
  • A novel electrode for an NO gas sensor was fabricated from electrospun polyacrylonitrile fibers by thermal treatment to obtain carbon fibers followed by chemical activation to enhance the activity of gas adsorption sites. The activation process improved the porous structure, increasing the specific surface area and allowing for efficient gas adsorption. The gas sensing ability and response time were improved by the increased surface area and micropore fraction. High performance gas sensing was then demonstrated by following a proposed mechanism based on the activation effects. Initially, the pore structure developed by activation significantly increased the amount of adsorbed gas, as shown by the high sensitivity of the gas sensor. Additionally, the increased micropore fraction enabled a rapid sensor response time due to improve the adsorption speed. Overall, the sensitivity for NO gas was improved approximately six-fold, and the response time was reduced by approximately 83% due to the effects of chemical activation.

Quantitative Analysis of SO2 and NO2 Adsorption and Desorption on Quartz Crystal Microbalance Coated with Cobalt Gallate Metal-Organic Framework

  • Junhyuck Ahn;Taewook Kim;Sunghwan Park;Young-Sei Lee;Changyong Yim
    • Journal of Sensor Science and Technology
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    • v.32 no.3
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    • pp.147-153
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    • 2023
  • Metal-organic frameworks (MOFs) of cobalt gallate were synthesized and deposited on gold electrodes using self-assembly monolayers (SAMs) and hydrothermal processing. These MOF films exhibit strong adsorption capabilities for gaseous particulates, and the use of SAMs allows the synthesis and deposition processes to be completed in a single step. When cobalt gallate is mixed with SAMs, a coordination bond is formed between the cobalt ion and the carboxylate or hydroxyl groups of the SAMs, particularly under hydrothermal conditions. Additionally, the quartz crystal microbalance (QCM) gas sensor accurately measures the number of particulates adsorbed on the MOF films in real-time. Thus, the QCM gas sensor is a valuable tool for quantitatively measuring gases, such as SO2, NO2, and CO2. Furthermore, the QCM MOF film gas sensor was more effective for gas adsorption than the MOF particles alone and allowed the accurate modeling of gas adsorption. Moreover, the QCM MOF films accurately detect the adsorption-desorption mechanisms of SO2 and NO2, which exist as gaseous particulate matter, at specific gas concentrations.

Sensing Characteristics of $SnO_{2}$ type CO sensors for combustion exhaust gases monitoring (연소배가스 모니터링을 위한 $SnO_{2}$계 CO센서의 검지특성)

  • Kim, I.J.;Han, S.D.;Lim, H.J.;Son, Y.M.
    • Journal of Sensor Science and Technology
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    • v.6 no.5
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    • pp.369-375
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    • 1997
  • $V_{2}O_{5}/ThO_{2}/Pd$-doped $SnO_{2}$ sensor has a good selectivity and stability to CO at high sensor temperature of about $500^{\circ}C$, and shows rapid response. In particular, many kinds of interference gases, such as $NO_{x}$, $C_{3}H_{8}$, $CH_{4}$ and $SO_{2}$ have been found to give only a slight influence on the sensor selectivity to CO gas sensitivity by doped $V_{2}O_{5}$ (3.0 wt.%). For the sensor we used well-known thick film technological route with $V_{2}O_{5}$(3.0 wt.%), Pd(1.0 wt.%) and $ThO_{2}$(l.5 wt.%) as catalytic materials. In the case of mixed $NO_{x}$-CO gases, as combustion exhaust gas, only CO detection by $SnO_{2}$ type semiconductor sensor is generally very difficult because of $NO_{x}$ interference. The developed sensors can use to measure the exhausting gas of the automobile or the boiler for the Air-to-Fuel ratio control.

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