• Title/Summary/Keyword: $NO_2$ 저감

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Emission Reduction Characteristics of Three-way Catalyst with Engine Operating Condition Change in an Ultra-lean Gasoline Direct Injection Engine (초희박 직접분사식 가솔린 엔진용 삼원촉매의 운전조건에 따른 배기저감 특성)

  • Park, Cheol Woong;Lee, Sun Youp;Yi, Ui Hyung;Lee, Jang Hee
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.39 no.9
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    • pp.727-734
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    • 2015
  • Recently, because of the increased oil prices globally, there have been studies investigating the improvement of fuel-conversion efficiency in internal combustion engines. The improvements realized in thermal efficiency using lean combustion are essential because they enable us to realize higher thermal efficiency in gasoline engines because lean combustion leads to an increase in the heat-capacity ratio and a reduction of the combustion temperature. Gasoline direct injection (GDI) engines enable lean combustion by injecting fuel directly into the cylinder and controlling the combustion parameters precisely. However, the extension of the flammability limit and the stabilization of lean combustion are required for the commercialization of GDI engines. The reduction characteristics of three-way catalysts (TWC) for lean combustion engines are somewhat limited owing to the high excess air ratio and low exhaust gas temperature. Therefore, in the present study, we assess the reaction of exhaust gases and their production in terms of the development of efficient TWCs for lean-burn GDI engines at 2000 rpm / BMEP 2 bar operating conditions, which are frequently used when evaluating the fuel consumption in passenger vehicles. At the lean-combustion operating point, $NO_2$ was produced during combustion and the ratio of $NO_2$ increased, while that of $N_2O$ decreased as the excess air ratio increased.

Computational Fluid Dynamics(CFD) Simulation and in situ Experimental Validation for the Urea-Based Selective Non-Catalytic Reduction(SNCR) Process in a Municipal Incinerator (생활폐기물 소각장 2차 연소로에서 요소용액을 이용한 선택적무촉매환원 공정에 대한 전산유체역학 모사 및 현장 검증)

  • Kang, Tae-Ho;Nguyen, Thanh D.B.;Lim, Young-Il;Kim, Seong-Joon;Eom, Won-Hyeon;Yoo, Kyung-Seun
    • Korean Chemical Engineering Research
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    • v.47 no.5
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    • pp.630-638
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    • 2009
  • A computational fluid dynamics(CFD) model is developed and validated with on-site experiments for a urea-based SNCR(selective non-catalytic reduction) process to reduce the nitrogen oxides($NO_x$) in a municipal incinerator. The three-dimensional turbulent reacting flow CFD model having a seven global reaction mechanism under the condition of low CO concentration and 12% excess air and droplet evaporation is used for fluid dynamics simulation of the SNCR process installed in the incinerator. In this SNCR process, urea solution and atomizing air were injected into the secondary combustor, using one front nozzle and two side nozzles. The exit temperature($980^{\circ}C$) of simulation has the same value as in situ experiment one. The $NO_x$ reduction efficiencies of 57% and 59% are obtained from the experiment and CFD simulation, respectively at NSR=1.8(normalized stoichiometric ratio) for the equal flow rate ratio from the three nozzles. It is observed in the CFD simulations with varying the flowrate ratio of the three nozzles that the injection of a two times larger front nozzle flowrate than the side nozzle flowrate produces 8% higher $NO_x$ reduction efficiency than the injection of the equal ratio flowrate in each nozzle.

Treatment Technology of N2O by using Bunsen Premixed Flame (분젠 예혼합 화염을 활용한 아산화질소 처리기술에 관한 연구)

  • Jin, Si Young;Seo, Jaegeun;Kim, Heejae;Shin, Seung Hwan;Nam, Dong Hyun;Kim, Sung Min;Kim, Daehae;Yoon, Sung Hwan
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.27 no.1
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    • pp.153-160
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    • 2021
  • Nitrous oxide is a global warming substance and is known as the main cause of the destruction of the ozone layer because its global warming effect is 310 times stronger than carbon dioxide, and it takes 120 years to decompose. Therefore, in this study, we investigated the characteristics of NOx emission from N2O reduction by thermal decomposition of N2O. Bunsen premixed flames were adopted as a heat source to form a high-temperature flow field, and the experimental variables were nozzle exit velocity, co-axial velocity, and N2O dilution rate. NO production rates increased with increasing N2O dilution rates, regardless of nozzle exit velocities and co-axial flow rates. For N2O, large quantities were emitted from a stable premixed flame with suppressed combustion instability (Kelvin Helmholtz instability) because the thermal decomposition time is not sufficient with the relatively short residence time of N2O near the flame surface. Thus, to improve the reduction efficiency of N2O, it is considered effective to increase the residence time of N2O by selecting the nozzle exit velocities, where K-H instability is generated and formed a flow structure of toroidal vortex near the flame surface.

An Experimental Study of NO_x$ Reduction Using PPCP (PPCP장치를 이용한 NO_x$ 저감에 대한 실험적 연구)

  • 정태용;허문회
    • Journal of the Korean Society of Safety
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    • v.12 no.2
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    • pp.95-101
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    • 1997
  • The confidence of new technology development for NO_x$ components elimination is obtained as conclusion based 1ike followings ; 1) The technology using PSC spark is a excellent methods for NO_x$ components elimination above 70% without by-product pollutants. 2) Some materials like Oxygen, Vaporized Water and Ammonia, increase the of NO_x$ elimination by staged addition. 3) Environmental conditions like pulse frequency and peak voltage are the important dosing factors for pollutants elimination effects. 4) As the PSC technic is the up-to-date one for pollutions elimination the research and development must be executed continuously for the purpose of theoretical establishment. And the application field must be broaden in future.

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Porous Photocatalytic Concrete Filter Manufacturing and Efficiency Evaluation for NOx Reduction (NOx 저감을 위한 다공성 광촉매 콘크리트 필터 제조 및 효율평가)

  • Kim, Jong Kyu
    • Korean Journal of Materials Research
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    • v.32 no.4
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    • pp.223-229
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    • 2022
  • A porous photocatalyst concrete filter was successfully produced to remove NOx, by mixing TiO2 photocatalyst with lightweight aerated concrete. Ultra Fine Bubbles were used to form continuous pores inside the porous photocatalytic concrete filter, which was mixed via a bubble generation experiment. The optimal mixing condition was determined to be with 4 % of the bubble generation agent B. NO removal specimens were prepared for various photocatalytic loading conditions, and the specimen containing 3 % P-25 removed NO at a concentration of 1.03 µmol in 1 h. The NO removal rate of the porous photocatalytic concrete filter prepared in this study was 10.99 %. This photocatalytic filter performance was more than 9 times the amount of NO removed by a general photocatalytic filter. The porous photocatalyst concrete filter for removing NOx developed in this study can be applied to various construction sites and the air quality can be solved by reducing NOx contributing to the formation of fine particles.

Set up Reduction Goals of Combined Sewer Overflow Pollutant Load Using Long-Term Rainfall-Runoff Model Simulation (장기간 강우-유출 모의를 통한 합류식하수관로시스템의 월류부하량 저감목표 설정 연구)

  • Lee, Gunyoung;Na, Yongun;Ryu, Jaena;Oh, Jeill
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.11
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    • pp.785-794
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    • 2013
  • Combined sewer overflows during rainfall events contain sewer sediments and surface pollutants. This can cause significant chemical, physical and biological problems to receiving watershed. However, there are no method that can commonly apply to decide criteria for controlling the pollutant load. In this study, it sets up the reduction goals of combined sewer overflow through long-term simulation using the rainfall-runoff model. From a review of domestic and foreign management standard of combined sewer overflow for this, it makes decision that 60% (phase 1), 85% (phase 2) of total pollutant load and frequency per year for reduction goals is more proper. Also, the result of analyzing long-term simulation (minimum 10 years) applied to research basin indicates that reduction goals of BOD pollutant load are 1,123 kg (phase 1) and 2,374 kg (phase 2), and overflow volumes for research objective achievement are $11,685m^3$ (phase 1) and $24,701m^3$ (phase 2).

Study on the Feasibility of Utilization of Pine Cone Byproduct as a Natural Deodorizing Agent for Composting Process (퇴비화 시설용 천연 악취저감제로의 잣송이 부산물의 활용 가능성에 관한 연구)

  • Chun, H.S.;Kwag, J.YH.;Ga, C.H.;Park, J.I.;Kim, C.H.;Ra, C.S.
    • Journal of Animal Environmental Science
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    • v.13 no.2
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    • pp.129-138
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    • 2007
  • A natural deodorizing agent (NDA) was made using pine cone byproduct, and its effects on malodor emission and composting were analyzed in this study. NDA was manufactured by mixing pine cone byproduct with three species of microorganisms and water containing mineral nutrients and molasses, and then by incubating for 48 hours at $30^{\circ}C$. Lab scale experiments were done with three treatment groups, T1 (control, sawdust treatment), T2 (microorganisms and sawdust treatment group), and T3 (NDA and sawdust treatment group). During composting, temperatures reached over $55^{\circ}C$, a minimum temperature for the inactivation of pathogenic microorganisms. No differences were found in physicochemical composition of compost among treatments. However, it was observed that over usage of NDA could obstruct temperature increase, since the biodegradation rate of organic matter of NDA was relatively low, Nitrogen loss due to ammonia gas emission, which normally happens during composting, was reduced by using NDA, and hence the nitrogen level of final compost was higher in T3 than in others. During experiment, it was found that ammonia gas emission was entirely lasted through compositing duration, but the $CH_3SH$ and $H_2S$ gases were produced only at early stage of composting. The ammonia concentration trapped in $H_2SO_4$ solution during 31 days of composting in T1, T2 and T3 was 12,660mg/L, 11,598mg/L and 7,367mg/L, respectively, showing distinguishable reduction of ammonia gas emission in T3. The emissions of $CH_3SH$ and $H_2S$ gases were also remarkably reduced in T3. Based on these obtained results, usage of the deodorizing agent made with pine cone byproduct could reduce the emission of malodor during composting, without any deterioration of compost quality.

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Estimation Method of Noise Reducing Devices Installed on the Noise Barrier(2) - Estimation by Sound Pressure Level - (방음벽 상단소음저감장치의 성능평가 방법에 관한 연구(2) - 음압레벨에 의한 평가 -)

  • Kim, Chul-Hwan;Chang, Tae-Sun;Lee, Ki-Jung;Kim, Dong-Joon;Jeong, Tae-Ryang;Chang, Seo-Il;Kim, Bong-Seok
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2007.11a
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    • pp.1125-1128
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    • 2007
  • In order to improve the acoustic performance of a noise barrier without increasing its height, various type of acoustic devices are suggested but, there is no proper method to estimate the performance in Korea. For this, an outdoor test facility was established in Expressway and Transportation Technology Institute(ETTI) of Korea Expressway Corporation for testing the acoustical performance of noise reducing devices installed on the top of a noise barrier. Noise measurements before and after installation of the noise reducing devices were carried out by using sound pressure level for long distance range from the barrier, from 10m to 40m. For considering the directivity effects of noise reducing devices, multivariate regression analysis was attempted.

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Effect of $CO_2$ Addition on Flame Structure and NOx Formation of $CH_4-Air$ Counterflow Diffusion Flames ($CO_2$ 첨가가 $CH_4$-공기 대향류 확산화염의 구조 및 NOx 생성에 미치는 영향)

  • Lee, S.R.;Han, J.W.;Lee, C.E.
    • Journal of the Korean Society of Combustion
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    • v.4 no.2
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    • pp.97-108
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    • 1999
  • This numerical study was to investigate the effect of $CO_2$ addition on the structures and NOx formation characteristics in $CH_4$ counterflow diffusion flame. The importance of radiation effect was identified and $CO_2$ addition effect was investigated in terms of thermal and chemical reaction effect. Also the causes of NOx reduction were clarified by separation method of each formation mechanisms. The results were as follows : The radiation effect was intensified by $CO_2$ addition. Thermal effect mainly contributed to the changes in flame structure and the amount of NO formation but the chemical reaction effect also cannot be neglected. The reduction of thermal NO was dominant with respect to reduction rate, but that of prompt NO was dominant with respect to total amount.

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A Study on Stability of Root Fixing Stone Construction in Breakwater (호안에 설치한 근고사석의 안정성에 관한 연구)

  • Park, Choon-Sik;Kim, Tae-Kyun;Seo, Hyo-Sik
    • Proceedings of the Korean Geotechical Society Conference
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    • 2009.03a
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    • pp.702-706
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    • 2009
  • From the result of analysis the necessity of root fixing stone construction through the result of finite element method, following results were acquired. 1. The consolidation settlement by stone weight is small amount so that it is interpreted there is no stone settlement reducing effect by root fixing stone. 2. It is interpreted that there is no effect existence and nonexistence of the heaving soil to the settlement. 3. There is little settlement reducing effect by root fixing stone but there may be protection of excavation effect. Therefore, for long-term stability, installing the root fixing stone to the section where the typhoon effect directly would be proper.

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