• Title/Summary/Keyword: $NH_4$

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Effects of Seed Size and Several Factors on Ultra-drying and Germination of Ultra-dried Seeds in Soybean

  • Lee, Yeong-Ho;Chang, Ching-huan
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.45 no.5
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    • pp.305-309
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    • 2000
  • Ultra-drying [<5.0% seed moisture content (SMC)] storage technique is a cost-effective storage method for oily seeds. To decide proper ultra-drying condition for soybean seeds, drying rate was compared three silica gel to seed ratios, two seed sizes with varietal difference, two kinds of container, and three seed amounts per container under :t 23$\pm$1$^{\circ}C$. When the relative humidity (RH) was reduced at the rate of less than 0.1 % a day, silica gel was replaced with dry one by 47 days. Higher silica gel to seed ratios (3:1 and 2:1) dried faster than lower ratio (1:1) until 28 days, but not after 43 days of drying. Also, large seeded variety was dried faster than small seeded variety. Kinds of container and seed amounts per container didn't show differences in drying of soybean seeds. After completion of ultra-drying, percentage germination by standard germination test (SGT) was not different among silica gel to seed ratios, kinds of container, and seed amounts per container, except among seed sizes (varieties). Before SGT, soybean seeds were premoistened using saturated ${CaCl}_2$ for 48 hours and ${NH}_4$Cl for 24 hours in desiccators. To compare germinability between ordinary-dried seeds and ultra-dried seeds, the seeds of seven soybean varieties, which were varying in size from 8.1 to 34.9 g per 100 seeds, were dried using same amount of silica gel under 23$\pm$1$^{\circ}C$. After completion of 76 days of drying, SMCs were reduced to 3.13-3.45% from 7.86-8.82%. SMC after completion of drying was not correlated with 100-seed weight (r=0.556). Before germination tests, soybean seeds were premoistened using saturated salt solutions. Percentage germination was higher with ultra-dried seeds than ordinary-dried seeds in SGT and higher with ordinary-dried seeds than ultra-dried seeds in AAT at the beginning of storage and after 6 months storage, but general trend of percentage germination was not observed among varieties classified by 100-seed weight. From these results, we concluded that further studies are needed to improve ultra-drying storage method for soybean seeds.

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Nitrogen Removal Characteristics in DynaFlow Biofilter System Using Sewage Wastewater of Low C/N Ratio (낮은 C/N비에서 운영되는 유로변경식 생물여과 공정의 질소 제거 특성)

  • Kim, Jin-Sik;Kim, Kyu-Ri;Kang, Han-Sol;Won, In-Seop;Kim, Keum-Yong;Lee, Sang-Ill
    • Journal of Korean Society of Environmental Engineers
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    • v.34 no.3
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    • pp.189-194
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    • 2012
  • In this study, a 3-stage biological aerated filter (BAF) system was proposed to enhance nitrogen removal in the treatment of low carbon to nitrogen ratio (C/N ratio) municipal wastewater. Laboratory experiments were conducted to evaluate the effects of dynamic-flow at the HRT of 6 h. Results of the long-term operation of 3-stage BAF systems showed that the dynamic-flow enabled the total nitrogen removal (T-N) removal efficiency of the system to be about 7 % higher than that of non-dynamic-flow system in treating domestic wastewater due to the more efficient use of organic substrates. The overall $NH_4$-N removal performance was stable during the operational period due to the unique system configuration where independent nitrification occurred. It was concluded that the 3-stage BAF system proposed in this study provided excellent performance in the removal of nitrogen by employing dynamic-flow and three columns functioning as sorption, denitrification and nitrification, respectively.

A Study on the Optimum Operating Conditions and Effects of Wastewater Characteristics in Electrochemical Nitrogen Removal Process (질소 제거를 위한 전기화학적 처리 공정의 최적 운전조건 및 폐수 성상에 따른 영향에 관한 연구)

  • Sim, Joo-Hyun;Kang, Se-Han;Seo, Hyung-Joon;Song, Su-Sung
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.1
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    • pp.29-34
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    • 2009
  • This study was performed under four operational conditions for nitrogen removal in metal finishing wastewater. The conditions include electrode gap, reducing agent, the recycling of treated wastewater in 1st step and the simultaneous treatment of nitrate and other materials. Result showed that the removal efficiency of $NO_3{^-}-N$ was highest at the electrode gap of 10 mm. As the electrode gap was shorter than 10 mm, the removal efficiency of $NO_3{^-}-N$ decreased due to increasing in concentration polarization on electrode. And, in case that the electrode gap was longer than 10 mm, the removal efficiency of $NO_3{^-}-N$ increased with an increase in energy consumption. Because hydrogen ions are consumed when nitrate is reduced, reducing reaction of nitrate was effected more in acid solution. As 1.2 excess amount of zinc was injected, the removal efficiency of $NO_3{^-}-N$ increased due to increasing in amount of reaction with nitrate. As the effluent from 1st step in the reactor was recycled into the 1st step, the removal efficiency of $NO_3{^-}-N$ increased. Because the zinc were detached from the cathode and concentration-polarization was decreased due to formation of turbulence in the reactor. The presence of $NH_4{^+}-N$ did not affect the removal efficiency of $NO_3{^-}-N$ but the addition of heavy metal decreased the removal efficiency of $NO_3{^-}-N$. As chlorine is enough in wastewater, the simultaneous treatment of nitrate and ammonia nitrogen may be possible. The problem that heavy metal decrease the removal efficiency of $NO_3{^-}-N$ may be solved by increasing current density or using front step of electrochemical process for heavy metal removal.

Control of $NH_4-N$ in Wastewater Treatment Effluent According to Simplified ASM No. 1 (간략화된 활성슬러지 모델(ASM No. 1)을 이용한 유출수 중 암모니아성 질소의 제어에 관한 연구)

  • Kim, Shin-Geol;Choi, In-Su;Koo, Ja-Yong
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.5
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    • pp.548-555
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    • 2007
  • The control of wastewater treatment has two merits; one is to regulate water quality of effluent and the other is to reduce the cost of wastewater treatment. The purpose of this study was to control the ammonium nitrogen in effluent that is known to cause eutrophication. The control was based on simplified ASM No. 1 which had 3 component materials and 8 coefficients, and the control method was as following. Firstly the ammonium concentration of inflow was measured and the optimal aeration time in effluent was determined according to simplified ASM No. 1 to be 1.0 mg/L. If ammonium concentration of effluent was not equal to 1.0 mg/L, the influent ammonium was corrected by adaptive control. These processes above were repeatedly performed. The SBR running aerobic-anoxic phase had been controlled for 1 month with this method. As a result, the ammonium concentration of the effluent showed in the range of $0.22\sim3.1$ mg/L with an average concentration of 1.1 mg/L. The adaptive control method used in this study was found very useful to control and predict the effluent concentration of ammonium.

As 조성비에 따른 InAsSb alloy 유전함수와 전이점 연구

  • Hwang, Sun-Yong;Yun, Jae-Jin;Kim, Tae-Jung;Aspnes, D.E.;Kim, Yeong-Dong;Kim, Hye-Jeong;Chang, Y.C.;Song, Jin-Dong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.161-161
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    • 2010
  • InAsSb alloy system 은 HgCdTe 를 대체하는 적외선 광소자 및 검출기 등에 응용이 가능한 유망한 물질이지만 정확한 유전함수 및 전이점의 연구는 미흡한 실정이다. 본 연구에서는 타원 편광 분석법을 이용하여 1.5 ~ 6 eV 의 분광 영역에서 As 조성비를 각기 (x = 0, 0.127, 0.337, 0.491, 0.726 및 1.00) 다르게 한 $InAs_xSb_{1-x}$ alloy의 유전함수를 측정하였다. 또한 표면에 자연산화막을 제거하기 위하여 Methanol 과 DI Water 로 표면을 세척 한 후 $NH_4OH$, Br in Methanol, HCl 등으로 적절한 화학적 에칭을 하여 산화막을 제거함으로서 순수한 InAsSb 의 유전함수를 측정할 수 있었다. 측정된 InAsSb 유전함수를 Standard analytic critical point line shape 방법으로 As 조성비에 따른 에너지 전이점을 얻을 수 있었다. 또한 얻어진 에너지 전이점 값을 이용하여 linear augmented Slater-type orbital 방법으로 전자 밴드 구조 계산을 하였고, 이를 바탕으로 $E_0$, $E_1$, $E_2$ 전이점 지역의 여러 전이점 ($E_1$, $E_1+\Delta_1$, $E_0'$, $E_0'+\Delta_0'$, $E_2$, $E_2+\Delta_2$, $E_2'$, $E_2'+\Delta_2$, $E_1'$) 의 특성을 정확히 정의할 수 있었다. 또한 As 조성비가 증가하면서 $E_2$, $E_2+\Delta_2$, $E_2'$, $E_2'+\Delta_2$ 전이점들이 서로 교차 되는 것을 발견하였고, 저온에서만 관측이 가능하였던 InSb 의 두 saddle-point (${\Delta_5}^{cu}-{\Delta_5}^{vu}$, ${\Delta_5}^{cl}-{\Delta_5}^{vu}$)를 상온에서 찾아내었다. 타원 편광 분석법을 이용한 전이점 연구 및 물성 분석은 InAsSb alloy 의 광학적 데이터베이스를 확보하는 성과와 더불어 새로운 디바이스기술 및 광통신 산업에도 유용한 정보가 될 것이다.

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Development and Application of Water Quality Level Model (WQLM) for the Small Streams of Rural Watersheds with Discriminant Analysis (판별분석을 통한 농촌유역 소하천의 수질등급모형(WQLM) 개발 및 적용)

  • Kim, Jin-Ho;Choi, Chul-Mann;Ryu, Jong-Soo;Jung, Goo-Bok;Shin, Joung-Du;Han, Kuk-Heon;Lee, Jung-Taek;Kwun, Soon-Kuk
    • Journal of Korean Society on Water Environment
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    • v.23 no.2
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    • pp.260-265
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    • 2007
  • This study was carried out to complement water quality standards and to establish new concept for water quality standards reflecting current state of water quality in small streams. By this purpose, discriminant analysis was performed and Water Quality Level Model (WQLM) was developed using the data such as EC, BOD, $COD_{Mn}$, SS, T-N, T-P, $NH_3-N$ in 224 agricultural streams. To give water quality level for water quality parameters, it divided into 20% respectively in the order of excellent water quality. On the basis of the lowest water quality level, water quality level of small streams is granted. As a result of it, number of stream corresponding to Level I was no, Level II was 2 streams, Level III was 22 streams, Level IV was 70 streams, and Level V was 130 streams. Average of water quality in each level was the highest in Level V. EC, SS, and T-N of 7 parameters were selected in variance concerned water quality level. By standardized canonical discriminant function coefficient, EC of three variances was the highest in 0.625 at the discriminant power. The next was T-N (0.509), SS (0.414). By discriminant function for water quality level, Level II was equal to $-2.973+19.376{\times}(EC)+0.647{\times}(T-N)+0.009{\times}(SS)$, Level III was equal to $-3.288+19.190{\times}(EC)+0.733{\times}(T-N)+0.041{\times}(SS)$, Level IV was equal to $-4.462+27.097{\times}(EC)+0.792{\times}(T-N)+0.053{\times}(SS)$, and Level V was equal to $-9.117+40.040{\times}(EC)+1.305{\times}(T-N)+0.111{\times}(SS)$. As a result of test at real agricultural watershed of Jeongan and Euidang in Gongju city, the fitness of WQLM was high to 88.78%. But, to get accomplished water quality assessment more exactly in agricultural streams, we had to concentrate and get vast data, and WQLM was modified and complemented continually.

Operation of CROM System and its Effects of on the Removal of Seston in a Eutrophic Reservoir Using a Native Freshwater Bivalve (Anodonta woodiana) in Korea. (담수산 이매패 펄조개를 이용한 흐름형 유기물 제어(CROM) 운영 - 퇴적물의 영향)

  • Kim, Baik-Ho;Baik, Soon-Ki;Hwang, Su-Ok;Hwang, Soon-Jin
    • Korean Journal of Ecology and Environment
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    • v.42 no.2
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    • pp.161-171
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    • 2009
  • A 'continuous removal of organic matters (CROM) system' using a native freshwater bivalve in Korea Anodonta woordiana, was developed to determine its potential of controlling various sestons in eutrophic lake system, and to evaluate its effect on water quality improvement under consideration of sediment addition as habitat. We designed CROM experiments with four treatments: no mussels and no sediment (W, negative control), no mussels and sediment (WS, positive control), mussels and no sediment (WM), and mussels and sediment (WMS). The experiments were performed at the condition of 18${\sim}$25 L $h^{-1}$ of inflow, mussel density of 486.1 indiv. $m^{-2}$, and temperatures between 15 and $22^{\circ}C$ for 13 consecutive days. Physicochemical and biological parameters were measured at daily (10:00 am) intervals after the mussel addition. Results indicated that mussel stockings without addition of sediment effectively removed sestons (suspended solids and chlorophyll-a) at nearly same level over 80 percentage of the control during the study, while there were no differences in removal activities of sestons between with and without sediment (P>0.5). Therefore, it clearly suggests that CROM system using A. woordiana has a strong potential to control the seston in surface water of eutrophic lake.

Odor Emission Reduction from Enclosed Growing-Finishing Pig House Using Different Biofilter Media (무창 육성$\cdot$비육돈사에서의 Biofilter에 의한 악취제어 효과)

  • Song J. I;Kim T. I.;Choi H. C.;Yoo Y. H.;Jeong J. W.;Yeon K. Y.;Barroga Antonio;Yang C. B.;Kim D. H.;Lee J. W.
    • Journal of Animal Environmental Science
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    • v.11 no.1
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    • pp.55-60
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    • 2005
  • This study was conducted to determine the odor reduction efficiency of a biofilter desist using different filter materials. The summary of results are as follows; 1. The airflow penetration rate of the different filter materials namely; rice straw, woodchips, rice hulls and sawdust were 0.72 m/s, 0.64 m/s, 0.48 m/s and 0.17 m/s, respectively. 2. The elimination of $NH_3$ gas was fastest in the rice hull at a rate of 4 mg/${\iota}$ followed by sawdust, woodchips and rice straw at 3 mg/${\iota}$, 3 mg/${\iota}$ and 7 mg/${\iota}$, respectively. 3. The filter material made of wood chips was able to eliminate the offensive gas known as $H_2S$ at a rate of 2.2 mg/${\iota}$ on the 7th day, 17.6 mg/${\iota}$ on the 21st day but decreased to 10.7 mg/${\iota}$ on the 36th day. In contrast, the filter material composed of sawdust had a continuous increase in the reduction of $H_2S$ at a rate of 12.3 mg/${\iota}$ on the 7th day, 18.3 mg/${\iota}$ on the 21st day and 20.1 mg/${\iota}$ on the 36th day. The above findings indicated that among the filter materials, sawdust was the most effective in absorbing $H_2S$. Airflow penetration rate can be related to $H_2S$ odor elimination efficiency as shown by the slowest airflow rate of sawdust which is only 0.17 m/s.

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Odor Removal Efficiency of Biofilter Ducting Systems in Indoor Pig House (바이오 필터를 이용한 비육돈사 배기덕트 시설의 악취저감 효과)

  • Song, J.I.;Choi, H.L.;Choi, H.C.;Kwon, D.J.;Yoo, Y.H.;Jeon, J.H.
    • Journal of Animal Environmental Science
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    • v.13 no.3
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    • pp.195-200
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    • 2007
  • Management of odors is essential to swine industry in the Republic of Korea. This study was conducted to evaluate the odor removal efficiency of biofilter ducting systems. Rice straw and auto clave concrete(ALC) were used as filter medium. The ventilation fans(5 units, diameter: 500 mm) at the side wall of a growing pig housing were connected to a biofilter using a duct. The size of a biofilter is $2.5{\times}2{\times}1.2(W{\times}L{\times}H)$. The air velocities at the 300 mm above rice straw and ALC were 0.77 and 0.56 m/s, respectively. Ammonia concentration at the outlet of rice straw and ALC media were 2 and 3 ppm, respectively. Dust concentrations were also measured. The dust concentrations of rice straw and ALC were 93, $32\;mg/m^3$, respectively. There was no significant difference between filter mediums in terms of carbon dioxide concentrations(rice straw: 320, ALC: 270 mg/l). The concentration of hydrogen sulfide was stable over the experimentation. The actual concentrations of hydrogen sulfide were 4, 3 and 3 ppm at the days of 7, 21 and 36, respectively. These results suggest that biofilter ducting systems may remove odors from pig house effectively.

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Assessment on Nitrous oxide (N2O) Emissions of Korea Agricultural Soils in 2009 (2009년 우리나라 농경지 토양에서의 N2O 배출량 평가)

  • Jeong, Hyun-Cheol;Kim, Gun-Yeob;Lee, Deog-Bae;Shim, Kyo-Moon;Lee, Seul-Bi;Kang, Kee-Kyung
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.6
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    • pp.1207-1213
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    • 2011
  • This study was conducted to assess $N_2O$ emissions in agricultural soils of Korea. According to 1996 and 2006 IPCC (Intergovernmental Panel on Climate Change) methodology, $N_2O$ emission was calculated the sum of direct emission ($N_2O_{DIRECT}$) and indirect emission ($N_2O_{INDIRECT}$). To calculate $N_2O$ emissions, emission factor was used default of IPCC and activity data was used the food, agricultural, forestry and fisheries statistical yearbook of MIFAFF (Ministry for Food, Agriculture, Forestry and Fisheries). It was emitted 8,608 $N_2O$ Mg resulted from direct emission by application of chemical fertilizer and animal manure, input in n-fixation crops and input of crop residues and emissions converted $N_2O$ into $CO_2$ equivalent was 2,668 $CO_2$-eq Gg. Indirect emission as $N_2O_{(G)}$ (atmospheric deposition of $NH_3$ and $NO_X$) and $N_2O_{(L)}$ (leaching and runoffs) were 4,567 and 6,013 $N_2O$ Mg and emissions converted $N_2O$ into $CO_2$ equivalent were 1,416 and 1,864 $CO_2$-eq Gg, respectively. Total $N_2O$ emission in Korea agricultural soil in 2009 was 5,948 $CO_2$-eq Gg.