• Title/Summary/Keyword: $NH_3-NH_4^+$

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Pollution Characteristics of PM2.5 Observed during Winter and Summer in Baengryeongdo and Seoul (겨울 및 여름철 백령도와 서울에서 측정한 PM2.5 오염 특성)

  • Yu, Geun-Hye;Park, Seung-Shik;Park, Jong Sung;Park, Seung Myeong;Song, In Ho;Oh, Jun;Shin, Hye Jung;Lee, Min Do;Lim, Hyung Bae;Kim, Hyun Woong;Choi, Jin Young
    • Journal of Korean Society for Atmospheric Environment
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    • v.34 no.1
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    • pp.38-55
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    • 2018
  • Hourly measurements of $PM_{2.5}$ mass, organic and elemental carbon (OC and EC), and water-soluble ionic species were made at the air quality intensive monitoring stations in Baengryeongdo (BR) and Seoul (SL) during the winter (December 01~31, 2013) and summer (July 10~23, 2014) periods, to investigate the increase of $PM_{2.5}$ and secondary ionic species and the reasons leading to their increase during the two seasons. During winter, $PM_{2.5}$ and its major chemical species concentrations were higher at SL than at BR. Contribution of organic mass to $PM_{2.5}$ was approximately 1.7 times higher at BR than at SL, but the $NO_3{^-}$ contribution was two times higher at SL. Total concentration of secondary ionic species ($SO{_4}^{2-}$, $NO_3{^-}$, and $NH_4{^+}$) at BR and SL sites accounted for 29.1 and 40.1% of $PM_{2.5}$, respectively. However, during summer, no significant difference in chemical composition of $PM_{2.5}$ was found between the two sites with the exception of $SO{_4}^{2-}$. Total concentration of the secondary ionic species constituted on average 43.9% of $PM_{2.5}$ at BR and 53.0% at SL. A noticeable difference in chemical composition between the two sites during summer was attributed to $SO{_4}^{2-}$, with approximately twofold concentration and 10% higher contribution in SL. Low wind speed and high relative humidity were important factors in secondary formation of water-soluble ionic species during winter at SL, resulting in $PM_{2.5}$ increase. While the secondary formation during summer was attributed to strong photochemical processes in daytime and high relative humidity in nighttime hours. The increase of $PM_{2.5}$ and its secondary ionic species during the winter haze pollution period at SL was mainly caused either by long-range transport (LTP) from the eastern Chinese regions, or by local pollution. However, the increased $SO{_4}^{2-}$ and $NO_3{^-}$ during summer at SL were mainly caused by LTP, photochemical processes in daytime hours, and heterogeneous processes in nighttime hours.

Changes in Chemical Components of Stagnant Water, Germination Rate and Seedling Elongation of Rice Varieties under Different Amount of Barley Straw Mulching (보리짚 피복량에 따른 논물의 화학성분 변화와 벼 발아율 및 유묘신장의 품종간 차이)

  • Cheong, Jin-Il;Kim, Bo-Kyeong;Ha, Ki-Yong;Lee, Jae-Kil;Shin, Hyun-Tak
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.41 no.5
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    • pp.505-513
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    • 1996
  • This study was conducted to investigate the variation of chemical components in stagnant water under different mulching amount of barley straw after combine harvesting and the effect of stagnent water on the germinatidn and seedling elongation at early growth stage in rice. pH was lower in barley straw mulching than non-mulching and decreased with increasing of mulched barley straw but was not different among treatments in stagnant water at 15 days after flooding. Dissolved oxygen decreased with the increasing of mulched barley straw and increased with the passing of time, while saline content increased with the increasing of mulched barley straw, showing significant difference among treatments, was peaked at 15 days after flooding and thereafter, decreased. NH4-N was higher 5 days after flooding with thicker barley straw mulching but was not different at 10 days. N $O_3$-N increased up to 10 to 15 days after flooding and increased with thicker barley straw mulching. Water soluble phosphorus and cation content ( $K^{+}$, $Ca^{2+}$, $Mg^{2+}$)were higher in thicker barley straw mulching and peaked at 10 and 15 days after flooding. Germination rate was decreased by thicker straw mulching and was high in order of medium late, medium and early maturing rice variety. Keumobyeo, Gancheokbyeo, Ilpumbyeo, Dongjinbyeo and Gyehwabyeo showed higher germination rate. Seedling elongation at early growth stage was poorer with increasing of barley. straw mulching. Ilpumbyeo had good seedling elongation in one time amount of barley straw mulching and Shinunbongbyeo, Unjangbyeo, Nonganbyeo and Dongjinbyeo had poorer, in two times.mes.

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Development of Mixed Pesticides Containing Herbicide and Topdressing Fertilizer for Paddy Rice (벼 제초제(除草劑)와 분약비(分蘖肥) 혼합약제(混合藥劑)의 개발(開發))

  • Park, Yang-Ho;Lee, Byung-Moo;Park, Seung-Soon;Lee, In-Yong;Kim, Young-Koo;Park, Young-Sun
    • Korean Journal of Environmental Agriculture
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    • v.13 no.3
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    • pp.279-287
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    • 1994
  • To develop mixed pesticides of herbicide and topdressing fertilizer for paddy rice, twelve mixtures were formulated with combination of urea coated with different level of acrylic acid wax(AAW) and four herbicides, which were thiobencarb, pretilachlor, mefenacet + bensulfuron-methyl and mefenacet + bensulfuron-methyl + dymron, and effects of the mixtures for weed control, phytotoxicity and rice tillering were investigated in the laboratory and the field experiments. Release rates of active ingredient of herbicides in the distilled water were over 90% during 24 hours same as that of the reference herbicides. The release rates of nitrogen showed different patterns according to coated level of granular urea with acrylic acid wax. Optimum release rate of nitrogen as $NH_4-N$ was obtained by 5.5% AAW coating on urea for thiobencarb or pretilachlor mixture, and by 4.0% AAW coating on urea for mefenacet + bensulfuron-methyl or mefenacet + bensulfuron-methyl + dymron mixture. The pesticide active ingredients of the mixtures were stable, which showed $3.7{\sim}8.0%$ of degradation rate after 90 days of storage under $50^{\circ}C$. Effects on weed control of mixtures were acceptable for both annual and perennial weeds, while ACRI-M9213 mixture showed considerable phytotoxicity at double dose of standard. When treated the mixed pesticides to paddy rice, rice growth status including culm length, ear length, panicle number and polished rice yield exhibited no significant differences compared with the conventional treatment.

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Synecological Study of the Naturalized Plant Communities in Old-Andong City (구 안동시역에 분포하는 귀화식물군락의 생태학적 연구)

  • 송종석;안상흥
    • The Korean Journal of Ecology
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    • v.22 no.3
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    • pp.169-179
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    • 1999
  • The present study was undertaken to classify and describe the spring naturalized plant communities in old-Andong city by the methodology of the ZM school of phytosociology. As a result, the vegetation was classified into the six communities and two subcommunities: A. Bromus tectorum community A-a. Bromus japonicus subcommunity, A-b. Melica onoei subcommunity; B. Poa pratensis community; C. Rumex crispus community; D. Oenothera lamarckiana community; E. Ambrosia artemisiifolia var. eiatior community; F. Rumex conglomeratus community. The total taxa of the naturalized plant communities consisted of 31 families, 86 genera, 114 species and 13 varieties. Of which the taxa of the naturalized plant species consisted of 8 families, 21 genera, 25 species and 1 variety. The result of Bray-Curtis ordination revealed that the plots suveyed were arranged according largely to the vegetation units of' the communities. Also the interspecific affinity was examined by an analysis of interspecific association and the main component species in the communities were divided into two groups. The naturalized rate was higher in the communitise affected by strong human impacts, while was lower in the communities affected relatively less by human impacts. On the other hand the seasonal changes of the communities and the naturalized rate between the spring and the autumn were investigated. Many naturalized communities present in Spring were replaced by the other native ruderal communitues in the Autumn. The naturalized rate based on the dominance was largely decreased over from the spring to the Autumn.

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Effects of Dietary Effective Microorganism (EM) on Growth Performance, Microflora Population and Noxious Gas Emission in Broiler (유용 미생물 첨가가 육계 생산성, 맹장 내 균총 및 유해가스 발생량에 미치는 영향)

  • Kang, Hwan Ku;Kim, Chan Ho;Bang, Han Tae;Kim, Ji Hyuk;Kim, Min Ji;Kim, Dong Woon;Na, Jae Cheon;Hwangbo, Jong;Yang, Young Rok;Choi, Hee Cheol;Moon, Hong Kil
    • Korean Journal of Poultry Science
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    • v.41 no.4
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    • pp.227-233
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    • 2014
  • This study investigated the effects of dietary supplementation with the effective microorganism (EM) on the growth performance, blood parameter, small intestinal microflora, and noxious gas emission of broilers. A total 720 1-d old ROSS 308 was randomly assigned to 6 dietary treatment groups: control, virginiamycin (6 mg/kg), 0.1% PB 0.1% EM, 0.5% EM, and 1.0% EM. Each treatment was fed to 4 replicates of 30 birds per diet for d 35. Two-phase feeding program with a starter diet from 0 to 3 wk, and a finisher diet from 4 to 5 wk was used in the experiment. Within each phase, a diet was formulated to meet or exceed NRC requirements of broilers for macro- and micronutrients. The diet and water were available ad libitum. Result indicated that during overall periods of the experiment, final weight, body weight gain, and feed intake were not different among dietary treatments. Feed conversion ratio was less (P<0.05) for EM treatments than control, antibiotics, and PB. Total cholesterol (TC), triglyceride (TRG), glucose (GLU), total protein (TP), calcium (CA), aspartate aminotransferase (AST) and alanine aminotransferase (ALT) were not different among dietary treatments. White blood cell (WBC), hemoglobin (Hb), heterophils (HE), lymphocyte (LY), monocytes (MO), and eosinophils (EO) were not different among dietary treatments. HE:LY was less (P<0.05) for EM0.5 treatments than control, antibiotics, and PB. Lactobacillus was greater (P<0.05) for EM treatments than control and antibiotics. E. coli and Salmonella were not different among dietary treatments. $NH_3$ and $CO_2$ wereless (P<0.05) for EM treatments than control. These results indicated that EM treatments were effective feed conversion ratio, noxious gas emission and micro flora population on the cecum in broilers.

Characteristics on De-CH4/NOx according to Ceramic and Metal Substrates of SCR Catalysts for CNG Buses (CNG 버스용 SCR 촉매의 세라믹과 메탈 담체에 따른 De-CH4/NOx 특성)

  • Seo, Choong-Kil
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.1
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    • pp.18-24
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    • 2018
  • The policy-making and technological development of eco-friendly automobiles designed to increase their supply is ongoing, but the internal combustion engine still accounts for about 95% of the automobiles in use. Also, in order to meet the stricter emission regulations of internal combustion engines based on fossil fuels, the proportion of after-treatments for vehicles and (ocean going) vessels is gradually increasing. Natural gas is a clean fuel that emits few air pollutants and has been used mainly as a fuel for city buses. In the long term, we intend to develop a new NGOC/LNT+NGCO/SCR combined system that simultaneously reduces the toxic gases, $CH_4$ and NOx, emitted from CNG buses. The objective of this study is to investigate the characteristics of $de-CH_4/NOx$ according to the ceramic and metal substrates of the SCR (Selective Catalytic Reduction) catalysts mounted downstream of the combined system. The V and Cu-SCR catalysts did not affect the $CH_4$ oxidation reaction, the two NGOC/SCR catalysts each coated with two layers began to oxidize $CH_4$ at $400^{\circ}C$, and the amount of $CH_4$ emitted was reduced to about 20% of its initial value at about $550^{\circ}C$. The two NGOC/SCR catalysts each coated with two layers showed a negative (-) NOx conversion rate above $350^{\circ}C$. The ceramic-based combined system reached LOT50 at $500^{\circ}C$, which was about 20% higher in terms of the $CH_4$ conversion rate than the metal-based combined system, showing that the combined system of NGOC/LNT+Cu-SCR is a suitable combination.

Biogeochemical Fluxes Through the Cheju Strait (제주해협을 통과하는 화학물질 플럭스)

  • Chung, Chang-Soo;Hong, Gi-Hoon;Kim, Suk-Hyun;Park, Jun-Kun;Kim, Yong-Il;Moon, Duk-Soo;Chang, Kyung-Il;Nam, Su-Yong;Park, Yong-Chul
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.5 no.3
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    • pp.208-215
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    • 2000
  • The estimated total material transports through the Cheju Strait using all data which investigated in 1997 and 1999 are as follows; A large amount of suspended sediments and dissovted inorganic nutrients are carried tothe South Sea through the Cheju Strait by a persistent eastward flow (Cheju Current) from the Y311ow Sea andthe East China Sea. The annual material Oanspous by the Cheju Current are as follows; 22.9${\times}$10$^6$ ton yr$^{-1}$(SS), 0.52${\times}$10$^{10}$ mol yr$^{-1}$ (NH$_4\;^+$), 6.05${\times}$10$^{10}$ mol yr$^{-1}$ (NO$_3\;^-$), 0.36${\times}$10$^{10}$ mol yr$^{-1}$ (PO$_4\;^{3-}$), 10.27${\times}$10$^{10}$ mol yr$^{-1}$ (Si(OH)$_4$). The annual suspended sediment flux per water transport in the Cheju Strait (44.48${\times}$10$^6$ ton yr$^{-1}$ Sv$^{-1}$) is about 1.7 larger than that in the Korean Strait (26.08${\times}$10$^6$ ton yr$^{-1}$ Sv$^{-1}$). The annual nitrate flux per water transport (11.60${\times}$10$^{10}$ mol yr$^{-1}$ Sv$^{-1}$) is about 1.2 larger than that in the Korean Strait (9.72${\times}$10$^{10}$ mol yr$^{-1}$ Sv$^{-1}$) and 2/3 of that by Kuroshio in the East China Sea (18.55${\times}$10$^{10}$ ton yr$^{-1}$ Sv$^{-1}$). It suggests that chemical rich Cheju Current will play a significant role in the biogeochemical processes in the South Sea where the huge land-based waste are introduced.

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ICT-Based Ginseng Process Ginseng Plant Composition Analysis (ICT 기반의 인삼 공정 육묘 시 인삼 식물체 분석)

  • Kim, D.H.;Kim, Y.B.;Koo, H.J.;Baek, H.J.;Lee, S.B.;Hong, E.K.;Kim, S.K.;Chang, K.J.
    • Journal of Practical Agriculture & Fisheries Research
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    • v.23 no.2
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    • pp.63-70
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    • 2021
  • In order to compare and investigate the growth rates of each of the various soils, the soil mixing ratios were varied to four soils (Pitmos, Pearlite, Masato, General Soil, and Cocopeat). Ten were selected for each soil ratio and the average length and weight were compared. As a result, in the ratio of No. 1 pitmos 6.5: Perlite 2: Masato 1.5, it was measured as 16.36cm, 0.60g. In the ratio of No. 2 pitmos 10, 13.74cm, 0.41g. In the ratio of No. 3 general clay 10, it was measured as 12.43cm, 0.26g. 4 general clay 8, 0.39g. The growth rate of each soil was measured to be superior to that of other soil growth environments in the ratio of pitmos 6.5: pearlite 2: masato 1.5 soil. For ginseng plant analysis, 30 ginseng plants grown in the average length and weight of each soil at a ratio of 6.5: pearlite 2: masato 1.5 and relatively low-result general soil were selected and analyzed. As a result, 1,040ppm of nitrite nitrogen(NO3-N) was higher in ginseng plants grown in general soil. There was no significant difference in phosphoric acid(P), potassium(K), and magnesium(Mg). Ginseng is characterized by poor growth when it exceeds 300ppm by combining ammonia tae (NH4-N) and nitrate tae (NO3-N) nitrogen. In addition, nitric acid produced in a part of this nitrite makes the pH reaction of the soil acidic, and the nitrite remaining in the soil evaporates into gas.

Change of Blooming Pattern and Population Dynamics of Phytoplankton in Masan Bay, Korea (마산만 식물플랑크톤의 대발생 양상의 변화와 군집 동태)

  • Lee, Ju-Yun;Han, Myung-Soo
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.12 no.3
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    • pp.147-158
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    • 2007
  • To clarify the bloom pattern and species succession in phytoplankton community, the population dynamics with the determination of physico-chemical factors have been studies in Masan Bay, the south sea of Korea, for the periods November 2003-October 2004. Concentration of $NH_4-N$ was always higher than that of $NO_3-N$, which was similar level as compared to other costal areas. $PO_4-P$ concentration was lower than those in other coastal areas but similar to oligotrophic environments. Thus, phosphate seems the limiting nutrient rather than nitrogen. $SiO_2-Si$ concentration was also low as compared to other costal areas. Si:P ratio was low from autumn to winter, suggesting silicate and/or phosphate limitation during this period. The cell density of phytoplankton was high in winter 2003 and early autumn 2004. The carbon biomass was high in winter 2003 and summer 2004. And chlorophyll-a concentration was high in late autumn 2003 and summer 2004. Among 78 species of phytoplankton found in the bay during the investigated period, dominant species were two diatoms of Cylindrotheca closterium, Skeletonema costatum, and three dinoflagellates of Heterocapsa triquetra, Prorocentrum minimum, P. triestinum, and one raphidophyte of Heterosigma akashiwo. P. minimum dominated from late autumn to winter, but it was replaced by H. triquetra in late winter. P. triestinum dominated from late spring to early summer. Simultaneously, H. akashiwo cell density steadily increased, and it became dominant with C. closterium in late summer. With decreasing of H. akashiwo and C. closterium, S. costatum became the most dominant species in autumn. The canonical analyses showed that total phytoplankton cell density related to diatom cell density and it was affected by temperature, and concentrations of $NO_3-N\;and\;PO_4-P$. The carbon bio-mass and $chlorophyll-{\alpha}$ concentration related to diatom- and dinoflagellate cell densities and these were affected by flagellate cell density, salinity, and concentrations of $SiO_2-Si\;and\;PO_4-P$. Last six years monitoring data in Masan city obtained from Korean Meteorological Agency indicates gradual increase in air temperature. And the precipitation decreased especially in spring season. The winter bloom found in 2003 may be caused by the increase in the temperature and this bloom subsequently induced the nutrients depletion, which continued until next spring probably due to no precipitation. Therefore, the spring bloom, which had been usually observed in the bay, might disappear in 2004.

Seasonal Distribution of Water Masses and Spatio-temporal Characteristics of Nutrients in the Coastal Areas of Gangwon Province of the Korean East Sea in 2009 (2009년 강원 연안의 계절별 수괴 분포 및 영양염의 시공간적 특성)

  • Choi, Mi-Yeon;Moon, Deok-Soo;Jung, Dong-Ho;Kim, Hyeon-Ju
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.15 no.2
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    • pp.76-88
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    • 2012
  • In order to investigate the distribution of water masses and spatio-temporal variation of nutrients in the coastal areas of Gangwon province of the Korean East Sea, a survey of the physico-chemical parameters (temperature and salinity) and nutrients ($NO_2$-N, $NO_3$-N, $NH_4$-N, $PO_4$-P, and $SiO_2$-Si) was carried out at 5 locations (Goseong, Sokcho, Yangyang, Gangneung, and Donghae) in February, May, August, and November 2009. The water masses included in the study area were divided into 4 groups; 1) Tsushima Surface Water (TSW), 2) Tsushima Middle Water (TMW), 3) North Korean Cold Water (NKCW), and 4) East Sea Proper Water (ESPW). The distribution of water masses was affected by the change of season. In February, surface water was derived from the TMW. The TSW was not observed in May, but only observed in August. In November, as the influence of the TSW weakened, that of the NKCW strengthened. Considering the vertical profiles of nutrients, the concentrations in all the seasons were very low within the surface water, but increased rapidly near the thermocline. Most of nutrient concentrations, except for dissolved silicate, remained constant below the depth of 200 m. However, the dissolved silicate concentration increased with depth, suggesting that silicate has a delayed regenerative pattern. The ESPW had the highest nutrient concentration, followed by the NKCW, TMW, and TSW. In February, May, and November, the N/P ratio in most of the water masses was similar to or larger than the Redfield ratio, indicating that nitrogenous nutrients did not act as a limiting factor for phytoplankton growth. However, in August, the N/P ratio in the TSW was less than the Redfield ratio, and the concentration of $NO_2$-N+$NO_3$-N was 0.86 ${\mu}m$, indicating that nitrogenous nutrients did act as a limiting factor for phytoplankton growth in the study area.