• Title/Summary/Keyword: $NH_3-NH_4^+$

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Water Quality Assessment and Turbidity Prediction Using Multivariate Statistical Techniques: A Case Study of the Cheurfa Dam in Northwestern Algeria

  • ADDOUCHE, Amina;RIGHI, Ali;HAMRI, Mehdi Mohamed;BENGHAREZ, Zohra;ZIZI, Zahia
    • Applied Chemistry for Engineering
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    • v.33 no.6
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    • pp.563-573
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    • 2022
  • This work aimed to develop a new equation for turbidity (Turb) simulation and prediction using statistical methods based on principal component analysis (PCA) and multiple linear regression (MLR). For this purpose, water samples were collected monthly over a five year period from Cheurfa dam, an important reservoir in Northwestern Algeria, and analyzed for 12 parameters, including temperature (T°), pH, electrical conductivity (EC), turbidity (Turb), dissolved oxygen (DO), ammonium (NH4+), nitrate (NO3-), nitrite (NO2-), phosphate (PO43-), total suspended solids (TSS), biochemical oxygen demand (BOD5) and chemical oxygen demand (COD). The results revealed a strong mineralization of the water and low dissolved oxygen (DO) content during the summer period. High levels of TSS and Turb were recorded during rainy periods. In addition, water was charged with phosphate (PO43-) in the whole period of study. The PCA results revealed ten factors, three of which were significant (eigenvalues >1) and explained 75.5% of the total variance. The F1 and F2 factors explained 36.5% and 26.7% of the total variance, respectively and indicated anthropogenic pollution of domestic agricultural and industrial origin. The MLR turbidity simulation model exhibited a high coefficient of determination (R2 = 92.20%), indicating that 92.20% of the data variability can be explained by the model. TSS, DO, EC, NO3-, NO2-, and COD were the most significant contributing parameters (p values << 0.05) in turbidity prediction. The present study can help with decision-making on the management and monitoring of the water quality of the dam, which is the primary source of drinking water in this region.

The Shelf-Life Extension of Low-Salted Myungran-Jeot 1. The Effects of pH Control on the Shelf-life of Low-Salted Myungran-Jeot (저염 명란젓의 Shelf-Life 연장 방안 1. pH 조정에 의한 연장 효과)

  • KIM Sang-Moo;LEE Keun-Tai
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.30 no.3
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    • pp.459-465
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    • 1997
  • In order to extend the shelf-life of the low-salted Myungran-Jeot, before immersing alaska pollack roe, the salt solutions was adjusted to pH 7.0 and 4.7, respectively. pH during ripening was somewhat constant, whereas the content of lactic acid was slightly increased, and especially, that of pH 4.7 Myungran-Jeot was increased rapidly in the begining of fermentation period. $NH_2-N$ content of pH 4.7 Myungran-Jeot was increased with increasing fermentation period, whereas those of control and pH 7.0 decreased except the begining of fermentation period. The contents of TMA, TBA, and VBN of pH 4.7 were lower than those of control and pH 7.0. In addition, the mirrobial growth was significantly inhibited in pH 4.7 Myungran-Jeot. The estimated shelflives of control, pH 7.0, and pH 4.7 Myungran-Jeots were about 12, 12, and 16 days, respectively.

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Comparison of Seasonal Nutrient Variations and Productivity between Rice Fields Conventionally Managed and Recommended Fertilized in Large-Scale Environment-Friendly Agricultural Districts (광역친환경 벼 농업 단지 내 관행구와 추천시비구의 시기별 무기성분과 생산성 비교)

  • Lee, Ju-Ryeong;Choi, Hyun-Sug;Jung, Seok-Kyu
    • Korean Journal of Organic Agriculture
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    • v.27 no.2
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    • pp.173-191
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    • 2019
  • The study was initiated to compare seasonal nutrient variations and rice (Oryza sativa L.) productivity in each of leading rice farm with conventionally managed and recommended fertilized of the large-scale environment-friendly agricultural districts in Jangheung, Suncheon, and Okcheon provinces in 2017. Suncheon rice experimental farm plots included a recommended fertilization plot that had been additionally sown hairy vetch in the fall of previous year, while Okcheon rice farm included a recommended fertilization plot applying half amount of the compost in the conventional plot. A Jangheung rice farm only practiced crop-livestock farming system. Soil pH and EC in all experimental plots were suitable levels for rice growth to cultivate. Seasonal soil pH from March to September was the highest for Suncheon rice farm, and seasonal soil EC was the highest for Jangheung rice farm. Seasonal soil T-N increased in all the plots from March to June in particular for Suncheon rice farm, and Jangheung rice farm had the lowest seasonal soil P. Seasonal soil K decreased in all the plots, with the lowest levels observed for Okcheon farm. Seasonal soil NH4+ mostly increased by up to 90 mg/kg in Jangheung rice farm from March to June. Seasonal plant T-N, P and K concentrations were the highest for Jangheung rice farm. Seasonal plant T-N and P concentrations decreased from June to September, but K leveles were fluctuated between 2.0% and 2.5%. Seasonal SPAD value was the lowest in Suncheon conventional plot. Jangheung rice farm plot produced 6,303 kg of rice per ha, which was approximately two times higher than those of Okcheon recommended plot. The seasonal T-N, P and K balance was the highest in Okcheon conventional plot, with the lowest values observed for Suncheon conventional plot. As a result, Suncheon recommended plot showed relatively low levels of seasonal macro-nutrient balance and the highest rice production, which could be the most environmentally friendly farm practiced conducted in this study.

Geochemical Characteristics and Benthos Distribution in the Three Shellfish Farms in Suncheon Bay, Korea (순천만 패류 양식장 3개소의 지화학적 특성과 저서생물상 분포 -가리맛조개 양식장과 새꼬막 양식장-)

  • Suh, Jinsoo;Kim, Taehoon;Shin, Seyeon;Kahng, Hyung-Yeel;Ahn, Samyoung;Jung, Jae-Sung;Kim, Youngsung;Won, Nam-Il
    • Journal of Environmental Science International
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    • v.26 no.6
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    • pp.691-710
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    • 2017
  • This study was performed to investigate the geochemical and benthic environment of three shellfish farms in Suncheon Bay during the period of September 2014 ~ April 2015. Three sampling stations were selected; St.1 is the shellfish farm of razor clam near Jangsan area. St.2 is the shellfish farm of small ark shell near Hwapo area and St.3 is the shellfish farm of razor clam near Yongdu area. Razor clam was the dominant species at St.1, small ark shell and granulated ark shell were dominant at St.2 and St.3, respectively. Granulated ark shell inhabited St.3, although it is not cultured at that station. This station's exposure to air during the ebb tide and sediment composition likely provides the appropriate habitat for granulated ark shell species. Analysis of the number of different species showed that 8 benthos species were found to be distributed at St.1, 18 species at St.2, and 13 species at St.3. Among three stations, the highest Ignition Loss (IL), Chemical Oxygen Demand (COD) and Acid Volatile Sulfide (AVS) values were obtained from the sediment at St.2. The analysis of pore water from St.2 also showed the highest values of Total Organic Carbon (TOC), ammonia ($NH_4^+$), Dissolved Inorganic Nitrogen (DIN) and phosphate ($PO_4^{3-}$). These results are related to the fact that species dominance and richness is the highest in St.2.

Development of Biofilter for Reducing Offensive Odor from Pig House (돈사 악취 저감을 위한 바이오필터 개발)

  • Lee, Seung-Joo;Lim, Song-Soo;Chang, Dong-Il;Chang, Hong-Hee
    • Korean Journal of Environmental Agriculture
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    • v.24 no.4
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    • pp.386-390
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    • 2005
  • This study was conducted to develop the biofilter fur reducing ammonia $(NH_3)$ and hydrogen sulfide $(H_2S)$ gas emission from a pig house. A biofilter was designed and constructed by a type of squeeze air into the column type of air flow upward. Its column size was ${\Phi}260{\times}360mm$. It was used pressure drop gauge, turbo blower, air temperature, velocity sensor and control program that was programed by LabWindows CVI 5.5. Mixing materials were consisted with composted pine tree bark and perlite with 7:3 ratio (volume). The biofilter media inoculated with ammonia (Rhodococcus equi A3) and hydrogen sulfide (Alcaligenes sp. S5-5.2) oxidizing microorganisms was installed in a commercial pig house to analyzed the effectiveness of biogas removal for 10 days. Removal rates of ammonia and hydrogen sulfide gases were 90.8% and 81.5%, respectively. This result suggests that the pine compost-perlite mixture biofilter is effective and economic for reducing ammonia ana hydrogen sulfide gases.

Purification and Characterization of Degradative Enzyme of Dental Plaque from Streptomyces sp. Y9343 (Streptomyces sp. Y9343이 生産하는 齒面細菌膜 分解酵素의 精製와 特性)

  • Kim, Seong-Joo;Han, Hong-Keun;Yoon, Jeong-Weon
    • Microbiology and Biotechnology Letters
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    • v.24 no.1
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    • pp.9-18
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    • 1996
  • Streptococcus mutans has been implicated as primary causative agents of dental caries by insoluble glucan (IG) in human and experimental animals. An attempt was made to search for the ${\alpha}$-1,3 glucanase that degrades IG produced by S. mutans. ${\alpha}$-1,3 glucanase was detected in the culture supernatant of microorganisms, which are isolated from soils on agar medium containing IG as a sole carbon source. This Streptomyces sp. hydrolysed IG produced by immobilized S. mutans and was named as Y9373. This enzyme required ${\alpha}$-1,3 glucan (IG) as an inducer. The optimum conditions for enzyme production were studied. The enzyme was purified by 30~70% $(NH_4)_2SO_4$ precipitation, anion exchange chroma tography on DEAE-cellulose and gel filtration on Sepadex G-75. The purified enzyme has a specific activity of 7840.0 U/mg protein giving 32.1-fold purification and final yield of 0.53%. The molecular weight was estimated to be about 22.5 kDa by SDS-PAGE. The optimum pH and temperature for enzyme reaction were 6.5 and 37$^{\circ}C$, respectively and the enzyme was relatively stable at the temperature below 60$^{\circ}C$. The activity of purified enzyme was enhanced by adding $Co^{2+},\;Mn^{2+}\;and\;Mg^{2+}$ into the medium, whereas inhibited by adding $Hg^{2+},\;Zn^{2+}$ and SDS. The $K_m\;and\;V_{max}$ value of ${\alpha}$-1,3 glucanase for IG were estimated to be 2.50 mM and 0.0431 mM/min, respectively. The thin layer chromatographic analysis of hydrolysates from IG with ${\alpha}$-1,3 glucanase showed that glucose was the main product of reaction. This enzyme activity was about 14 times higher than marketing dextranase as preventive agent against artificial dental caries by S. mutans in TH medium including 5% sucrose after 30 minutes.

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Effect of Biofilter Made of Composted Pine Tree Bark and Perils on Reducing Odor from Pig House (부숙수피-펄라이트 혼합충전재의 돈사악취 제거 효과)

  • Lee, Seung-Joo;Chang, Dong-Il;Chang, Hong-Hee
    • Korean Journal of Environmental Agriculture
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    • v.25 no.2
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    • pp.118-123
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    • 2006
  • To remove effectively order component ($NH_3\;and\;H_2S$) from pig house, biofilter was made of composted pine tree bark and polite and odor removal efficiency was evaluated in the lab and pilot scales. The columns were designed with ${\Phi}120mm{\times}450mm$ (H) and ${\Phi}850mm{\times}900mm$ (H) in the size in the lab and pilot scale testes, respectively. Single material of composted pine tree bark and polite and the mixture of two materials with 7:3 ratios (vol/vol) were packed in the column, and, herein air flow was controlled upward direction from column bottom. To enhance the efficiency of biofilter, ammonia (Rhodococcus equi A3) and hydrogen sulfide oxidizing bacteria (Alcaligenes sp. S5-5.2) were inoculated in packing materials before the test Removal effect of ammonia and hydrogen sulfide gases were higher in the mixture$[88.7{\sim}98.2%,\;89.5{\sim}97.9%]$ than that in single packing material (composted pine tree haft$[89.4{\sim}98.7%,\;78.7{\sim}85.6%]$ and petite$[65.3{\sim}73.2%,\;88.7{\sim}98.2%]$ by the lab scale biofilter. In the modeled pig house, about 96 and 91% of ammonia and hydrogen sulfide gases were removed by the pilot scale of biofilter, respectively. Conclusively, composted pine tree bark and polite could be a good candidate of biofilter packing materials to remove the odor components.

Effect of Dietary Protein Levels and Addition of Alumincum Sulfate to Litter on Broiler Performance, Ammonia Production and Soluble Phosphorus Content of Litter (동일 축사내에서 Aluminum Sulfate 처리와 단백질 수준에 따른 육계의 생산성과 암모니아 가스 발생 및 깔짚내 수용성 P의 함량에 미치는 영향)

  • 최인학;남기홍
    • Korean Journal of Poultry Science
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    • v.30 no.2
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    • pp.113-118
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    • 2003
  • In this study, broilers were raised up to 6 weeks of age in a single room to determine if different levels of dietary protein or addition of aluminum sulfate[alum, $Al_2$(SO$_4$)$_3$ㆍ14$H_2O$] to the litter affected growth performance, production of ammonia(NH$_3$) and soluble phosphorus(SP) content of the litter.The experimental treatments consisted of six treatments in a 2x3 factorial arrangements: T$_1$=23% protein + 0.2% alum to litter; T$_2$=21% protein + 0.2% alum to litter; T$_3$=19% protein + 0.2% alum to litter; T$_4$=23% protein + no alum; T$_{5}$=21% protein + no alum; T$_{6}$=19% protein + no alum. For broiler performance, there was no effect of alum addition to the litter, but the dietary protein levels significantly affected feed intake from days 22 to 42(P<0.05) and day 0 to 42(P< 0.05), weight gain during all periods(P<0.05 or 0.01), and feed:gain from day 0 to 21(P<0.05) and day 0 to 42(P<0.05). Alum addition to the litter did not affect body weight at 21 and 42 days, but dietary protein levels has a significant effect on it at both 21(P<0.0l) and 42 days(P<0.05). Alum addition only affected ammonia production at weeks 3(P

Research of the Toxic Estimation and Treatment Method of Wastewater Including Nickel (니켈 함유폐수의 독성평가 및 처리방안에 대한 연구)

  • Kim, Man-Soo;Hwang, Hwan-Min;Park, Jong-Woon
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.11
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    • pp.983-988
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    • 2009
  • This study was performed to evaluate the toxicity and seek the control method of the wastewater in which nickel (Ni) was included into an industrial wastewater treatment plant. Nickel concentration of the wastewater, of which samples were taken every hour during 24hours, were various from 0.33 to 116.0 mg/L, with 24.0 mg/L of the average concentration. IC50 values against nitrosomonas and nitorbactor, a toxic level against bacteria which could inhibit 50% of nitrification bacteria in the wastewater, are 5.5 and 4.9 mg/L respectively. Nickel in this industrial wastewater can inhibit the 50% of nitrification bacteria even after diluting this wastewater 5 times. Also, this research, which reduced the nickel concentraion, forming nickel hydroxide compounds by increasing pH of the wastewater, shows that nickel concentraion can be obtained under 1.7 mg/L at pH 11 and 0.6 mg/L at pH 12. Consequently, the result of this study is that the nitrification efficiencies can be obtained from 83.8 to 99.4% with 97.6% of the average in the biological treatment after removing nickel in the wastewater by increasing the pH above 11~12, which is forming the nickel hydroxide compounds.

Identification of PM10 Chemical Characteristics and Sources and Estimation of their Contributions in a Seoul Metropolitan Subway Station (서울시 지하역사에서 PM10의 화학적 특성과 오염원의 확인 및 기여도 추정)

  • Park, Seul-Ba-Sen-Na;Lee, Tae-Jung;Ko, Hyun-Ki;Bae, Sung-Joon;Kim, Shin-Do;Park, Duckshin;Sohn, Jong-Ryeul;Kim, Dong-Sool
    • Journal of Korean Society for Atmospheric Environment
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    • v.29 no.1
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    • pp.74-85
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    • 2013
  • Since the underground transportation system is a closed environment, indoor air quality problems may seriously affect many passengers' health. The purpose of this study was to understand $PM_{10}$ characteristics in the underground air environment and further to quantitatively estimate $PM_{10}$ source contributions in a Seoul Metropolitan subway station. The $PM_{10}$ was intensively collected on various filters with $PM_{10}$ aerosol samplers to obtain sufficient samples for its chemical analysis. Sampling was carried out in the M station on the Line-4 from April 21 to 28, July 13 to 21, and October 11 to 19 in the year of 2010 and January 11 to 17 in the year of 2011. The aerosol filter samples were then analyzed for metals, water soluble ions, and carbon components. The 29 chemical species (OC1, OC2, OC3, OC4, CC, PC, EC, Ag, Al, Ba, Cd, Cr, Cu, Fe, Mn, Ni, Pb, Si, Ti, V, Zn, $Cl^-$, $NO_3{^-}$, $SO_4{^{2-}}$, $Na^+$, $NH_4{^+}$, $K^+$, $Mg^{2+}$, $Ca^{2+}$) were analyzed by using ICP-AES, IC, and TOR after proper pretreatments of each sample filter. Based on the chemical information, positive matrix factorization (PMF) model was applied to identify the $PM_{10}$ sources and then six sources such as biomass burning, outdoor, vehicle, soil and road dust, secondary aerosol, ferrous, and brakewear related source were classified. The contributions rate of their sources in tunnel are 4.0%, 5.8%, 1.6%, 17.9%, 13.8% and 56.9% in order.