• Title/Summary/Keyword: $NH_3-NH_4^+$

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Investigation on the Effects of Hydrogen Charging on Oxidation Behavior of Ultrahigh-Strength Automotive Steels (초고강도 자동차용 강의 환원정전류인가에 따른 산화 거동 변화 연구)

  • Ha, Heon-Young;Kim, Hye-Jin;Moon, Joonoh;Lee, Tae-Ho;Jo, Hyo-Haeng;Lee, Chang-Geun;Yoo, Byung-Kil;Yang, Won-Seog
    • Corrosion Science and Technology
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    • v.16 no.6
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    • pp.317-327
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    • 2017
  • The change in the oxidation behavior of three types of B-added ultrahigh strength martensitic steels containing Ti and Nb induced by applying constant cathodic current was investigated. In a 3% NaCl+0.3% $NH_4SCN$ solution, the overall polarization behavior of the three alloys was similar, and degradation of the oxide film was observed in the three alloys after applying constant cathodic current. A significant increase in the anodic current density was observed in the Nb-added alloy, while it was diminished in the Ti-added alloy. Both Ti and Nb alloying decreased the hydrogen overpotential by forming NbC and TiC particles. In addition, the thickest oxide film was formed on the Ti-added alloy, but the addition of Nb decreased the film thickness. Therefore, it was concluded that the remarkable increase in the anodic current density of Nb-added alloy induced by applying constant cathodic current density was attributed to the formation of the thinnest oxide film less protective to hydrogen absorption, and the addition of Ti effectively blocked the hydrogen absorption by forming TiC particles and a relatively thick oxide film.

Fabrication of TiO2 Nanotube Arrays by Anodic Oxidation Method and its Photoelectrochemical Properties (양극산화법에 의한 TiO2 나노튜브 어레이의 제조 및 광전기화학적 특성에 관한 연구)

  • Kim, Seon-Min;Cho, Kwon-Koo;Choe, Yeong-Jin;Kim, Ki-Won;Ryu, Kwang-Sun
    • Journal of Powder Materials
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    • v.17 no.3
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    • pp.216-222
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    • 2010
  • Self-standing $TiO_2$ nanotube arrays were fabricated by potentiostatic anodic oxidation method using pure Ti foil as a working electrode and ethylene glycol solution as electrolytes with small addition of $NH_4F$ and $H_2O$. The influences of anodization temperature and time on the morphology and formation of $TiO_2$ nanotube arrays were investigated. The fabricated $TiO_2$ nanotube arrays were applied as a photoelectrode to dye-sensitized solar cells. Regardless of anodizing temperature and time, the average diameter and wall thickness of $TiO_2$ nanotube show a similar value, whereas the thickness show a different trend with reaction temperature. The thickness of $TiO_2$ nanotube arrays anodized at $20^{\circ}C$ and $30^{\circ}C$ was time-dependent, but on the other hand its at $10^{\circ}C$ are independent of anodization time. The conversion efficiency is low, which is due to a morphology breaking of the $TiO_2$ nanotube arrays in manufacturing process of photoelectrode.

RANKL expression is mediated by p38 MAPK in rat periodontal ligament cells (백서 치주인대세포의 RANKL 발현에 대한 p38 MAPK의 역할)

  • Kim, Chong-Cheol;Kim, Young-Joon;Chung, Hyun-Ju;Kim, Ok-Su
    • Journal of Periodontal and Implant Science
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    • v.34 no.3
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    • pp.489-498
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    • 2004
  • Recent studies have demonstrated that human periodontal ligament cells express receptor activation of nuclear factor ${\kappa}B$ ligand (RANKL) which enhances the bone resorbing activity of osteoclasts differentiated from hematopoietic preosteoclasts. The purpose of this study is to determine the effects of p38 MAPK and JNK kinase upon regulating RANKL and OPG in response to $IL-1{\beta}$(l ng/ml) in rat periodontal ligament cells. Soluble RANKL was measured by immunoassay. The effects of p38 MAPK on RANKL and OPG expression was determined by RT-PCR. The results were as follows: 1. Periodontal ligament cells which stimulated by $IL-1{\beta}$ increased soluble RANKL synthesis by dose-dependent pattern. 2. p38 MAP kinase inhibitor (SB203580) showed regulation of soluble RANKL expression by dose-dependent manners. 3. p38 MAP kinase inhibitor (SB203580) regulated the expression of RANKL, but it dose regulate the expresseion of OPG. 4. JNK (c-jun $NH_2-terminal$ kinase) inhibitor (PD98059) did not regulate mRANKL and mOPG. These results suggested that p38 MAPK play a significant role in RANKL gene expression.

The Quality of Yakju be brewed from many kind of Nuruk (누룩에 따른 약주의 품질 평가)

  • 이미경;이성우;배상면
    • Journal of the East Asian Society of Dietary Life
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    • v.1 no.1
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    • pp.99-111
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    • 1991
  • In each nuruk using today, effect of pH on glucoamylase activity and viable cell count of yeast and bacteria was measured. Common components during fermentation, alcohol, acetaldehyde and acetone, amino acid composition, and total sugars and mineral content were determined in yakju(korean wine) brewed from different ingredients and by different methods. Results are summarized as follows ; 1. The lower the pH, the lower the glucoamylase activity in JK, BK, JK-S BK-S and JN. But the higher the glucoamylase activity ratio in Koji and KN. 2. Yeast and bacteria cell count could not determined in nuruk inoculated of seed. In JK, BK and JN, yeast cell count was 50${\times}$104∼80${\times}$104, bacteria cell count was 5${\times}$106∼24${\times}$106. 3. In yakju during fermentation, pH was higher in RU, total acidity content was higher in ST-N, ST-K, RU and ST-RUPO and alcohol content was lower in RUPO and ST-RUPO. 4. Ethanol and acetaldehyde content were highest in dukyunju. Trace amount of acetone was determined only in ST-K, RUPO and ST-RUPO . n-Propyl alcohol content was higher in ST-K, ST-RUPO and ST-N, iso-butyl alcohol content was higher in L-RUPO, Dukyunju and Songyupju and iso-amyl alcohol content was higher in Songyupju, RU, L-RUPO and Dukyunju. 5. In amino acids composition of each yakju, Pro, Ala and Val content was higher than other amino acids. Total amino acids content was the highest in Dukyunju and second highest in ST-N, NH3 was higher in ST-N, Dukyunju, RUPO than other samples. 6. Total sugars content was the highest in ST-N and second highest in RU. 7. P, K and Mg content were higher in Dukyunju and ST-N than in other samples. In Dukyunju, Ca and P ratio was 0.075 because of low Ca content and high P content.

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THE PROCESSING OF CLUMPY MOLECULAR GAS AND STAR FORMATION IN THE GALACTIC CENTER

  • LIU, HAUYU BAOBAB;MINH, YOUNG CHOL;MILLS, ELISABETH
    • Publications of The Korean Astronomical Society
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    • v.30 no.2
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    • pp.133-137
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    • 2015
  • The Galactic center uniquely provides opportunities to resolve how star clusters form in neutral gas overdensities engulfed in a large-scale accretion flow. We have performed sensitive Green Bank 100m Telescope (GBT), Karl G. Jansky Very Large Array (JVLA), and Submillimeter Array (SMA) mapping observations of molecular gas and thermal dust emission surrounding the Galaxy's supermassive black hole (SMBH) Sgr $A^{\ast}$. We resolved several molecular gas streams orbiting the center on ${\gtrsim}10$ pc scales. Some of these gas streams appear connected to the well-known 2-4 pc scale molecular circumnuclear disk (CND). The CND may be the tidally trapped inner part of the large-scale accretion flow, which incorporates inflow via exterior gas filaments/arms, and ultimately feeds gas toward Sgr $A^{\ast}$. Our high resolution GBT+JVLA $NH_3$ images and SMA+JCMT 0.86 mm dust continuum image consistently reveal abundant dense molecular clumps in this region. These gas clumps are characterized by ${\gtrsim}100$ times higher virial masses than the derived molecular gas masses based on 0.86 mm dust continuum emission. In addition, Class I $CH_3OH$ masers and some $H_2O$ masers are observed to be well associated with the dense clumps. We propose that the resolved gas clumps may be pressurized gas reservoirs for feeding the formation of 1-10 solar-mass stars. These sources may be the most promising candidates for ALMA to probe the process of high-mass star-formation in the Galactic center.

Comparison of analytical methods for quantifying total chromium in soil using Atomic Absorption Spectrometer (AAS) and Inductively Coupled Plasma-Atomic Emission Spectrometry (ICP-AES) (토양 시료 중 Atomic Absorption Spectrometry (AAS) 및 Inductively Coupled Plasma-Atomic Emission Spectrometry (ICP-AES)를 이용한 총 크롬 분석방법 비교)

  • Lee, Hong-gil;Kim, Ji-in;Byun, Yoonjoo;Kim, Hyunkoo;Yoon, Jeong Ki
    • Journal of Soil and Groundwater Environment
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    • v.22 no.6
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    • pp.22-28
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    • 2017
  • The accuracy of analytical results in response to the use of different additives ($NH_4Cl$, KCl, $LaCl_3$) and oxidant gases was evaluated and compared by using Atomic Absorption Spectrometry (AAS). Identification of spectroscopic interferences and possible improvements in Inductively Coupled Plasma-Atomic Emission Spectrometry (ICP-AES) analysis were also discussed. The average accuracies of total chromium using Certified Reference Materials (CRMs) were found to be 72.1~94.2% in air/acetylene flame condition by AAS, and they were improved to 100.5~110.5% when the oxidants was changed to nitrous oxide rather than adding the additives. The field samples showed similar trends to CRMs, but chromium concentrations were highly variable depending on analytical conditions. The average accuracies using CRMs were estimated to be 89.3~166.1% by ICP-AES, and improved to below 121.7% after eliminating iron interference. Field samples with low chromium and high iron concentration were measured to be > 30% lower in total chromium concentrations by ICP-AES than AAS in nitrous oxide/acetylene flame. Total chromium concentrations in soil could be analyzed with better accuracy under nitrous oxide/acetylene flame by AAS because it was more effective to increase the temperature of the flame than to eliminate the chemical interference for maximizing atomization of chromium. When using ICP-AES, interference substances, total chromium levels, and analytical conditions should be also considered.

Experiments of Rice Cultivation for Establishment of Total Nitrogen(T-N) Item of Agricultural Water Standards (농업용수 수질기준 T-N 항목 설정을 위한 벼생육 실험)

  • Choi, Sun-Hwa;Kim, Ho-il;Yoon, Kyung-Seup;Choi, I-Song;Oh, Jong-Min
    • Journal of Korean Society on Water Environment
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    • v.20 no.3
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    • pp.301-306
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    • 2004
  • The present water quality standards for agricultural were established without considering the effects of water quality on the safety, growth, yield and quality of crops. This study was carried out to investigate the effects of irrigation water quality on the growth, yield, and grain quality of rice, and to acquire basic knowledges to set up water quality standards for irrigation. The field and pot experiments were conducted with irrigation water that was previously adjusted four concentrations (control, 5, 10, 20 mg/L) and six concentrations (control, 5, 10, 15, 20, 30 mg/L) by $NH_4NO_3$ solution and replicated three and four times with randomized block design, respectively. The results of this study showed that the inorganic nutrient of rice plant, rice protein contents and number of panicle tended to increase as the T-N concentration in irrigation water was increased. In addition, grain yield at T-N 10 mg/L and 20mg/L were significantly higher than the control at the field experiment. From the pot experiment at T-N 30 mg/L, the percentage of head rice was slightly lower due to the increase of green kernel and white belly/core kernel.

A Study on the Treatment of Swine Wastewater by Using Intermittently Aerated Activated Sludge Process (간헐폭기법에 의한 돈사 폐수 처리에 관한 연구)

  • Yang, Tae-Du;Lee, Mi-Kyung;Chung, Yoon-Jin
    • Journal of Korean Society of Water and Wastewater
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    • v.12 no.4
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    • pp.86-96
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    • 1998
  • In this study, an intermittently aerated activated sludge process, modified process from conventional activated sludge process, was developed to treat high strength swine wastewater, which has been blamed as major pollutant for stream pollution. Therefore, the optimum cycle for oxic and anoxic period, SRT, and OLR were studied as design parameters. The effects of different time interval for oxic and anoxic period on nitrification and denitrification were examined by operating two reactors with 60/60min and 60/90min as oxic/anoxic period. Although the reactor with 60/60min showed complete denitrification of $NO_x-N$ generated during oxic period, the reactor with 60/90min showed incomplete nitrification due to the inactivity of nitrifier by accumulated $NH_3-N$ toxicity during anoxic period. Therefore, it is recommended to operate same interval for oxic and anoxic period. In order to determine the optimum cycle for oxic/anoxic period, four different reactors with 30/30, 60/60, 90/90 and 120/120min were examined. The reactor operation with 90/90min was optimum to get the most stable results in this study. However, the optimum cycle for oxic and anoxic period should be changed with characteristics of influent wastewater and operating conditions. According to lie operation results of three reactors with SRT of 15, 20 and 30days. The reactor with 2Odays SRT showed best removal efficiency of T-N. The optimum OLR would be $2.5Kg\;COD/m^3/day$ which showed the most stable nitrification and denitrification. Since characteristics of influent wastewater in the real system has a severe fluctuation, so it is very difficult to determine each interval for oxic and anoxic period. Therefore, ORP curves, describing the change of oxidation/reduction potential in reactor, can be used as a control parameter for automatic control of oxic and anoxic period. In other words, bending point (Nitrate Knee) of ORP curve during anoxic period could be used as a starting point of oxic period.

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Influences of Bulking Materials on Sustainable Livestock Mortality Composting (부자재 종류가 친환경적 사축퇴비화에 미치는 영향)

  • Won, Seung Gun;Park, Ji Young;Cho, Won Sil;Kwag, Jung Hoon;Choi, Dong Yoon;Ahn, Hee Kwon;Ra, Chang Six
    • Journal of Animal Science and Technology
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    • v.55 no.5
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    • pp.483-488
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    • 2013
  • To develop a sustainable composting method for livestock mortality, a natural aeration-composting process was designed and the influences of bulking materials on the mortality composting process were studied. Bulking materials (e.g., compost, swine manure, sawdust, and rice husks), easily supplied at the scene of an animal mortality outbreak, were tested in this research. A lab-scale composting system (W34 ${\times}$ L60 ${\times}$ H26 cm) was made using 100 mm styrofoam, and natural aeration was achieved through pipes installed on the bottom of the system. Four treatments were designed (compost, compost + swine feces, sawdust, and rice husks treatment groups) and all experiments were done in triplicates. During composting for 40 days, no leachate was observed in compost and sawdust treatment groups, whereas 18 and 8.2 ml leachate/kg-mortality was emitted from the compost + feces and rice husks treatment groups, respectively. Dimethyl disulfide (DMDS) emission during the composting was very low in all treatment groups, possibly due to the bio-filtering function of the compost cover layer on the pile. The mortality degradability in compost, compost + feces, sawdust, and rice husks groups was 25.3, 25.8, 13.5, and 14.5%, respectively, showing significantly higher levels in compost and compost + feces groups (p<0.05). Also, only the compost + feces group produced enough heat (over $55^{\circ}C$) and lasted for 7 days, indicating that bio-security cannot be guaranteed without feces supplementation.

Assessment of an Optimum Biochar Application Rate for Tomato(Solanum lycopersicum L.) Cultivation (토마토 재배를 위한 바이오차 최적시용 비율 평가)

  • Park, Do-Gyun;Hong, Seung-Gil;Jang, Eunsuk;Shin, Joung-Du
    • Journal of the Korea Organic Resources Recycling Association
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    • v.27 no.1
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    • pp.39-48
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    • 2019
  • Objective of this study was to evaluate an optimum biochar application rate and estimate the carbon sequestration based on the soil chemical properties and growth responses for biochar application during tomatoes cultivation. The treatments consisted of control as recommended application rates of fertilizers, 0.01%, 0.03%, 0.05%, and 0.07% of biochar application(w/w, biochar:soil). For effects of soil chemical properties, the $NO_3-N$contents in the soil were peaked at 9 days after transplanting. But there was not significant difference(p>0.05) among the treatments during cultivation periods. However, $NH_4-N$ contents in the biochar treatment were lower than the control until 14 days of transplanting. $P_2O_5$ contents in the biochar treatments were lower than that of the control until 19 days after transplanting except 0.01% of biochar application plot. $K_2O$ contents in soils treated with 0.01% and 0.03% of biochar were higher until 6 days after transplanting than that in the control. For N use efficiency of biochar application, it was observed that the 0.05% biochar application plot was highest among the treatments. The highest carbon sequestration was estimated at $2.83mg\;kg^{-1}$ for 0.03% of biochar application. However, it is considered that the optimum biochar application rate was 0.05% for tomato cultivation, considering the growth characteristics and yield components.