• Title/Summary/Keyword: $NH_3$ 슬립

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Effect of $NH_3$/NOx ratio and Catalyst Temperature on DeNOx Performance in the $NH_3$-SCR reactor ($NH_3$-SCR 반응기 내에서의 $NH_3$/NOx 및 SCR 촉매 온도가 DeNOx 성능에 미치는 영향)

  • Hong, Kil-Hwa;Gong, Ho-Jeong;Hwang, In-Goo;Park, Sim-Soo
    • Proceedings of the KSME Conference
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    • 2008.11b
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    • pp.3096-3101
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    • 2008
  • Selective Catalytic Reduction (SCR) technology is well-known to be effective for the reduction of NOx emission. So car manufacturers has adopted Ures-SCR system to be satisfied with emission regulation. This paper discusses the effective of $NH_3/NOx$ ratio and SCR catalyst temperature in the $NH_3$-SCR reactor on DeNOx performance. So it is shown the characteristic of NOx conversion and ammonia slip using the $NH_3$ instead of Urea-Solution. From the result of this study, it is found to optimize $NH_3/NOx$ ratio to have the best case of high NOx conversion and low ammonia slip at variable SCR catalyst temperatures. Lastly, it is also found the characteristics of NOx conversion and ammonia slip with compared with Urea.

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Experimental Verification of Adsorption Rate Feedback Control Strategy for Automotive Urea-SCR DeNOX System (실차 실험을 통한 승용 디젤엔진의 Urea-SCR을 위한 암모니아 흡장률 피드백 제어 분사전략 검증)

  • Shin, Byeonguk;Park, Jooyoung;Lee, Seang Wock;Kang, Yeonsik
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.41 no.6
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    • pp.397-407
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    • 2017
  • In this study, a SCR system is employed to selectively reduce $NO_X$, which is a major cause of environmental pollution and issues in diesel engines. In particular, this paper focuses on the combination of feedforward injection strategies, depending on the NO/$NO_X$ ratio, and feedback injection control, using $NH_3$ coverage ratio, based on a SCR model. A 2.2 L passenger diesel engine, which is equipped with a diesel oxidation catalyst (DOC) and a diesel particle filter (DPF), was used in the experiments. The developed control algorithm is implemented on a real-time computer with injection control algorithm. By analyzing the $NO_X$ emission measurement, the performance of the proposed injection control algorithm is verified.

A Study of NH3 Adsorption/Desorption Characteristics and Model Based Control in the Urea-SCR System (Urea-SCR 시스템의 NH3 흡·탈착 특성 및 모델기반 제어 연구)

  • Ham, Yunyoung;Park, Suyeol
    • Transactions of the Korean Society of Automotive Engineers
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    • v.24 no.3
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    • pp.302-309
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    • 2016
  • Urea-SCR system is currently regarded as promising NOx reduction technology for diesel engines. SCR system has to achieve maximal NOx conversion in combination with minimal $NH_3$ slip. In this study, model based open loop control for urea injection was developed and assessed in the European Transient Cycle (ETC) for heavy duty diesel engine. On the basis of the transient modeling, the kinetic parameters of the $NH_3$ adsorption and desorption are calibrated with the experimental results performed over the zeolite based catalyst. $NH_3$ storage or surface coverage of SCR catalyst can not be measured directly and has to be calculated, which is taken into account as a control parameter in this model. In order to reduce $NH_3$ slip while maintaining NOx reduction, $NH_3$ storage control algorithm was applied to correct the basic urea quantity. If the actual $NH_3$ surface coverage is higher than the maximal $NH_3$ surface coverage, the urea injection quantity is significantly reduced in the ETC cycle. By applying this logic, the resulting $NH_3$ slip peak can be avoided effectively. With optimizing the kinetic parameters based on standard SCR reaction, it suggests that a simplified, less accurate model can be effective to evaluate the capability of model based control in the ETC cycle.

Control of SCR System for NOx Reduction in a Refuse Incineration Plant Using Repetitive Control Method (반복제어법을 이용한 소각장 NOx 저감용 SCR 시스템의 제어)

  • 김인규;여태경;김환성;김상봉
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.24 no.11
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    • pp.2762-2770
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    • 2000
  • The refuse incineration plant has an important role in saving the combustion energy for local heating system. But harmful combustion gas(NOx etc.) leads to some serious environmental problem. To reduce the gas, a SCR(Selective Catalytic Reduction)system is installed and it is controlled by adjusting the flow of ammonia gas(NH3) . In this paper, we apply a repetitive control method to reduce NOx by adjusting the flow of ammonia gas for SCR system in a refuse incineration plant which is located in Haeundae, Pusan, Firstly, we analyze the inlet NOx period by FFt method, and verify its periodic variations. Secondly, we design a repetitive control system by using state space model method. Lastly, the effectiveness of repetitive control system is shown by comparing to a conventional PID control in simulation and experimental results.

Development of Map based Open Loop Control Algorithm for Urea - SCR System (Urea-SCR 시스템의 Map 기반 Open Loop 제어알고리즘 개발)

  • Ham, Yun-Young;Park, Yong-Sung
    • Transactions of the Korean Society of Automotive Engineers
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    • v.19 no.2
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    • pp.50-56
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    • 2011
  • To meet the NOx limit without a penalty of fuel consumption, Urea-SCR system is currently regarded as promising NOx reduction technology for diesel engines. SCR system has to achieve maximal NOx conversion in combination with minimal $NH_3$ slip. In this study, map based open loop control for urea injection was developed and assessed in the European Transient Cycle (ETC) for heavy duty diesel engine. The basic urea quantity set-value which was calculated using the look up tables of engine out NOx, exhaust flow rate and optimum NSR resulted in NOx reduction of 80% and the average $NH_3$ slip of 24 ppm and maximum of 79 ppm. In order to reduce $NH_3$ slip, $NH_3$ storage control algorithm was applied to correct the basic urea quantity and reduced $NH_3$ slip levels to the average 15 ppm and maximum 49 ppm while keeping NOx reduction of 76%. With high and increasing SCR temperature, the $NH_3$ storage capacity decreases, which leads to $NH_3$ slip. The resulting $NH_3$ slip peak can be avoided by stopping or significantly reducing the urea injection during the SCR temperature gradient is over $30^{\circ}C/min$.

The Development and Implementation of Model-based Control Algorithm of Urea-SCR Dosing System for Improving De-NOx Performance and Reducing NH3-slip (Urea-SCR 분사시스템의 DeNOx 저감 성능 향상과 NH3 슬립저감을 위한 모델 기반 제어알고리즘 개발 및 구현)

  • Jeong, Soo-Jin;Kim, Woo-Seung;Park, Jung-Kwon;Lee, Ho-Kil;Oh, Se-Doo
    • Transactions of the Korean Society of Automotive Engineers
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    • v.20 no.1
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    • pp.95-105
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    • 2012
  • The selective catalytic reduction (SCR) system is a highly-effective aftertreatment device for NOx reduction of diesel engines. Generally, the ammonia ($NH_3$) was generated from reaction mechanism of SCR in the SCR system using the liquid urea as the reluctant. Therefore, the precise urea dosing control is a very important key for NOx and $NH_3$ slip reduction in the SCR system. This paper investigated NOx and $NH_3$ emission characteristics of urea-SCR dosing system based on model-based control algorithm in order to reduce NOx. In the map-based control algorithm, target amount of urea solution was determined by mass flow rate of exhaust gas obtained from engine rpm, torque and $O_2$ for feed-back control NOx concentration should be measured by NOx sensor. Moreover, this algorithm can not estimate $NH_3$ absorbed on the catalyst. Hence, the urea injection can be too rich or too lean. In this study, the model-based control algorithm was developed and evaluated on the numerical model describing physical and chemical phenomena in SCR system. One channel thermo-fluid model coupled with finely tuned chemical reaction model was applied to this control algorithm. The vehicle test was carried out by using map-based and model-based control algorithms in the NEDC mode in order to evaluate the performance of the model based control algorithm.

Study on the Performance Characteristics of Urea-SCR System in the ETC Test (ETC 모드에서 Urea-SCR 시스템의 성능 특성 연구)

  • Ham, Yun-Young;Choi, Dong-Seok;Park, Yong-Sung
    • Transactions of the Korean Society of Automotive Engineers
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    • v.18 no.2
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    • pp.122-128
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    • 2010
  • To meet the NOx limit without a penalty of fuel consumption, urea-SCR system is currently regarded as promising NOx reduction technology for diesel engines. SCR system has to achieve maximal NOx conversion in combination with minimal $NH_3$ slip. In this study, the performance characteristics of urea-SCR system with open loop control were assessed in the European Transient Cycle(ETC) for heavy duty diesel engine. The SCR inlet temperaure varied in the range of 200 to $340^{\circ}C$ in the ETC cycle. Open loop control calculated the urea flow rate based on the NOx and NSR map which gave for each combination of SCR inlet temperature and space velocity the normalized $NH_3$ to NOx stoichiometric ratio which resulted in a steady-state $NH_3$ slip of 20ppm. During the ETC cycle, the open loop control with the optimized NSR offset achieved NOx reduction of 80% while keeping the average $NH_3$ slip below 10ppm and maximum 20ppm. It was also found that NOx sensor was cross-sensitive to $NH_3$ and a control strategy for cross-sensitivity compensation was required in order to use a NOx sensor as feedback device.

A Study on Effect of Urea-SCR Aftertreatment System upon Exhaust Emissions in a LPG Steam Boiler (LPG 증기보일러의 배기 배출물에 미치는 요소-SCR 후처리 시스템의 영향에 관한 연구)

  • Bae, Myung-Whan;Song, Byung-Ho
    • Transactions of the Korean Society of Automotive Engineers
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    • v.22 no.3
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    • pp.1-11
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    • 2014
  • The aim of this study is to investigate the effect of SCR reactor on the exhaust emissions characteristics in order to develop a urea-SCR aftertreatment system for reducing $NO_x$ emissions. The experiments are conducted by using a flue tube LPG steam boiler with the urea-SCR aftertreatment system. The urea-SCR aftertreatment system utilizes the ammonia converted from 17% aqueous urea solution injected in front of SCR catalyst as a reducing agent for reducing $NO_x$ emissions. The equivalence ratio, urea injection amount, ammonia slip and $NO_x$ conversion efficiency relative to boiler load are applied to discuss the experimental results. In this experiment, the average equivalence ratio is calculated by changing only the fuel consumption rate while the intake air amount is constantly fixed at $25,957.11cm^3/sec$. The average equivalence ratios are 1.38, 1.11, 0.81 and 0.57 when boiler loads are 100, 80, 60 and 40%. The $NO_x$ conversion efficiency is raised with increasing urea injection amount, and $NH_3$ slip is also boosted at the same time. Consequently, the $NO_x$ conversion efficiency relative to boiler load should be examined in combination with urea injection amount and $NH_3$ slip. The results are calculated by 89, 85, 77 and 79% for the boiler loads of 100, 80, 60 and 40%. The appropriate amount of urea injection for the respective boiler load can be not discussed by only $NO_x$ emissions, and should be determined by considering the $NO_x$ conversion efficiency, $NH_3$ slip and reactive activation temperature simultaneously. In this study, the urea amounts of 230, 235, 233 and 231 mg/min are injected at the boiler loads of 100, 80, 60 and 40%, and the final $NH_3$ slips are measured by 8.48, 5.58, 11.97 and 11.34 ppm at the same conditions. THC emission is affected by the SCR reactor under other experimental conditions except 100% engine load, and CO emission at only 40% engine load. The rest of exhaust emissions are not affected by the SCR reactor under all experimental conditions.

A Parameters Estimation of Five-phase Induction Motor (5상 유도전동기의 파라미터 추정)

  • Kim, Nam-Hun;Baik, Won-Sik;Kim, Min-Huei;Jung, Hyung-Woo;Kim, Dong-Hee
    • Proceedings of the KIPE Conference
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    • 2010.07a
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    • pp.55-56
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    • 2010
  • 다상 유도 전동기(Multi phase induction motor)의 고성능 제어를 수행하기 위해서는 정확한 파라미터 계산이 필수적이다. 특히 전동기의 벡터제어(FOC, Field oriented control)나 직접토크제어(DTC, Direct torque control)와 같은 고성능 제어 시스템의 경우, 슬립 계산이나 자속관측기 그리고 PI 제어기 게인 추정에서 전동기 상수들이 필수적으로 사용된다. 본 논문에서는 실험용으로 집중권(Concentrated winding) 구조를 가지는 2kW, 5상 유도전동기를 제작하였으며, 5상 유도전동기 파라미터 추정에 대한 방법을 제시하였다. 일반적으로 다상 유도전동기의 경우 1차 공간 고조파(1st space harmonic) 성분에 대한 파라미터만을 추정하여 제어에 사용하지만, 본 논문에서는 1차 공간 고조파 성분과 3차 공간 고조파(3rd space harmonic) 성분에 대한 파라미터 추정 방법을 제시한다. 결과적으로 제안된 파라미터 추정 방법의 타당성을 확인하기 위해서 설계값과 실험값을 비교하였다.

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Numerical Study on the Injector Shape and Location of Urea-SCR System of Heavy-duty Diesel Engine for Preventing $NH_3$ Slip (대형 디젤엔진용 SCR 시스템의 암모니아 슬립 억제를 위한 인젝터의 형상 및 위치에 관한 수치적 연구)

  • Jeong Soo-Jin;Lee Sang Jin;Kim Woo-Seung;Lee Chun Beom
    • Transactions of the Korean Society of Automotive Engineers
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    • v.14 no.1
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    • pp.68-78
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    • 2006
  • In the past few years, considerable efforts have been directed towards the further development of Urea-SCR(selective catalytic reduction) technique for diesel-driven vehicle. Although urea possesses considerable advantages over Ammonia$(NH_3)$ in terms of toxicity and handling, its necessary decomposition into Ammonia and carbon dioxide complicates the DeNOx process. Moreover, a mobile SCR system has only a short distance between engine exhaust and the catalyst entrance. Hence, this leads to not enough residence times of urea, and therefore evaporation and thermolysis cannot be completed at the catalyst entrance. This may cause high secondary emissions of Ammonia and isocyanic acid from the reducing agent and also leads to the fact that a considerable section of the catalyst may be misused for the purely thermal steps of water evaporation and thermolysis of urea. Hence the key factor to implementation of SCR technology on automobile is fast thermolysis, good mixing of Ammonia and gas, and reducing Ammonia slip. In this context, this study performs three-dimensional numerical simulation of urea injection of heavy-duty diesel engine under various injection pressure, injector locations and number of injector hole. This study employs Eulerian-Lagrangian approach to consider break-up, evaporation and heat and mass-transfer between droplet and exhaust gas with considering thermolysis and the turbulence dispersion effect of droplet. The SCR-monolith brick has been treated as porous medium. The effect of location and number of hole of urea injector on the uniformity of Ammonia concentration distribution and the amount of water at the entrance of SCR-monolith has been examined in detail under various injection pressures. The present results show useful guidelines for the optimum design of urea injector for reducing Ammonia slip and improving DeNOx performance.