• Title/Summary/Keyword: $Mg_3N_2$

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Improvement of Hydrogen Storage Properties of Mg by Addition of NbF5 via Mechanical Milling under H2

  • Kwak, Young Jun;Song, Jiyoung;Mumm, Daniel R.
    • Korean Journal of Materials Research
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    • v.23 no.10
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    • pp.562-567
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    • 2013
  • A 90 wt% Mg-10 wt% $NbF_5$ sample was prepared by mechanical milling under $H_2$ (reactive mechanical grinding). Its hydriding and dehydriding properties were then examined. Activation of the 90 wt% Mg-10 wt% $NbF_5$ sample was not required. At n=1, the sample absorbed 3.11 wt% H for 2.5 min, 3.55 wt% H for 5 min, 3.86 wt% H for 10 min, and 4.23 wt% H for 30 min at 593K under 12 bar $H_2$. At n=1, the sample desorbed 0.17 wt% H for 5 min, 0.74 wt% H for 10 min, 2.03 wt% H for 30 min, and 2.81 wt% H for 60 min at 593K under 1.0 bar $H_2$. The XRD pattern of the 90 wt% Mg-10 wt% $NbF_5$ after reactive mechanical grinding showed Mg, ${\beta}-MgH_2$ and small amounts of ${\gamma}-MgH_2$, $NbH_2$, $MgF_2$ and $NbF_3$. The XRD pattern of the 90 wt% Mg-10 wt% $NbF_5$ dehydrided at n=3 revealed Mg, ${\beta}-MgH_2$, a small amount of MgO and very small amounts of $MgH_2$ and $NbH_2$. The 90 wt% Mg-10 wt% $NbF_5$ had a higher initial hydriding rate and a larger quantity of hydrogen absorbed for 60 min than the 90 wt% Mg-10 wt% MnO and the 90 wt% Mg-10 wt% $Fe_2O_3$, which were reported to have quite high hydriding rates and/or dehydriding rates. The 90 wt% Mg-10 wt% $NbF_5$ had a higher initial dehydriding rate (after an incubation period) and a larger quantity of hydrogen desorbed for 60 min than the 90 wt% Mg-10 wt% MnO and the 90 wt% Mg-10 wt% $Fe_2O_3$.

Induction of the Diploid Ovum in Chicken (닭에서 2배수성 난자의 생성에 관한 연구)

  • 여정수
    • Korean Journal of Poultry Science
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    • v.15 no.2
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    • pp.67-71
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    • 1988
  • In order to induce the diploid gamete(ovum) under suppression of meiosis in oogenesis for production of polyploid chicken. this experiment checked meiosis time. through regular ovulation and response of inhibitor (Tri-ethylen Melamine) to meiosis. The results obtained was follows; *Meiosis of oogenesis was 2-4 hours before ovulation. *Response of inhibitor to meiosis was effective at 0.3mg triethylen melamine per kg body weight. *Fertility was highly decreased by influence from inhibitor. *66% of fertilized eggs was triploid(3n) through fertilization induced diploid ovum (2n) with normal sperm(n).

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Assessment of Surface Water Quality in Suburban Golf Courses in Korea

  • Park, Jin-Sung;Kim, Ok-Kyung;Chang, Yoon-Jeong;Lee, In-Sook
    • The Korean Journal of Ecology
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    • v.28 no.5
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    • pp.261-264
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    • 2005
  • In the current study, we examined the quality of surface water in ponds at two golf courses, located in southern (Country Club P) and eastern (Country Club B) areas of Korea respectively. Seasonal measurements were made of following physical parameters;pH, dissolved oxygen, biological oxygen demand, chloride, alkalinity, hardness, and nitrogen compounds [$NH_3$-N, $NO_2$-N, $NO_3$-N] and the concentrations of four heavy metals (Cd, Cu, Pb, and Zn) throughout the courses. The pH values were within the alkaline range (7.3 to 9.0), and the biological oxygen demand was generally between 0.5 and 3.1 mg/L. The alkalinity and hardness ranged from 19.1 to 68.5mg/L and 16.1 to 63.6 mg/L, respectively. Nitrogen as ammonium $(NH_3-N)$ was detected in all samples, and the samples had low concentrations of $NO_2-N$ and $NO_3-N$. Cd concentrations were relatively high (to 22.44 mg/L); the highest Cd concentration was observed in the pond in Country Club P. Other metal concentrations were low compared to the Quebec guidelines.

Effect of no-tillage and green manure practices on the nitrous oxide emission from cropland (농경지에서 무경운 및 녹비 투입에 따른 아산화질소 배출특성)

  • Lee, Sun-Il;Kim, Gun-Yeob;Lee, Jong-Sik;Choi, Eun-Jung
    • Korean Journal of Environmental Biology
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    • v.37 no.3
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    • pp.309-316
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    • 2019
  • Cropland is a major source of atmospheric nitrous oxide (N2O) and we need technologies in the field of agriculture that can reduce the presence of N2O. In this study, a field experiment encompassing six treatments was conducted to determine the efflux of N2O in cropland during the growing season. An experimental plot was composed of two main sectors, no-tillage (NT) and conventional tillage (CT), which were subdivided into three plots according to types of nitrogen (N) sources: CF, chemical fertilizer; HV, hairy vetch+chemical fertilizer; and RY, rye+chemical fertilizer. The cumulative N2O emissions were 179.8 mg N2O m-2 for CF-CT, 108.1 mg N2O m-2 for HV-CT, 303.5 mg N2O m-2 for RY-CT, 86.7 mg N2O m-2 for CF-NT, 73.8 mg N2O m-2 for HV-NT, and 122.7 mg N2O m-2 for RY-NT during the fallow season. The CT, HV, and RY of no-tilled soils were reduced by 51.8, 31.7 and 59.6%, respectively (p<0.001). Our results indicate that the use of no-tillage and hairy vetch practice rather than conventional tillage and chemical fertilizer practice can decrease N2O emission.

Characteristics of Non-point source pollutant loads according to Landuse (토지이용에 따른 비점오염부하 특성)

  • Shin, Min-Hwan;Shin, Yong-Chul;Heo, Sung-Gu;Kim, Woong-Gi;Lim, Kyoung-Jae;Choi, Joong-Dae
    • Proceedings of the Korea Water Resources Association Conference
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    • 2007.05a
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    • pp.1824-1828
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    • 2007
  • 본 연구에서는 농촌, 산림 및 도시유역에서 발생하는 비점원오염이 하천 수질에 미치는 영향에 관하여 분석하였다. 연구 유역으로는 농촌유역인 유포리, 산림유역인 학술림 및 도시유역인 공지천 등 3개 유역을 선정하였다. 유포리 유역의 면적은 $1.96\;km^2$으로 토지이용은 밭 7.5%, 논 11%, 과수원 1.95%를 제외한 70%가 임야지역으로 나타났다. 산림유역은 면적이 $3.9\;km^2$으로 임산실습을 위한 제탄소 등 교육 및 연구시설을 제외한 대부분(99%)이 산림으로 잘 보전되어 있다. 춘천시에 위치한 공지천 유역은 구시가지와 산림으로 구성되어 있고, 면적은 $0.19\;km^2$중 불투수면적이 $0.15\;km^2$으로 유역면적의 81.9%를 차지한다. 연구유역별로 강우시에는 5분, 건기시에는 30분 간격으로 수위를 측정한 후 수위-유량 곡선을 이용하여 유량으로 환산하였다. 수질 자료는 강우시에는 1일 3회 이상, 건기시에는 2주일에 1회 채취 하여 T-N과 T-P의 분석항목을 환경부 제정 수질 공정시험법의 제반 규정에 따라 분석하여 유역별 오염부하를 산정하였다. 농촌 및 산림유역의 T-N과 T-P의 평균농도는 8.3 mg/L 및 0.3mg/L, 2.4 mg/L 및 0.1 mg/L로 나타났고 도시유역의 건기시와 강우시의 T-N과 T-P의 평균농도는 28.1 mg/L 및 3.1 mg/L, 20.6 mg/L 및 2.5 mg/L로 나타났다. 농촌, 산림 및 도시유역의 T-N과 T-P의 연오염부하는 각각 270.60 kg/ha 및 8.64 kg/ha, 223.16 kg/ha 및 13.87 kg/ha 그리고 612.37 kg/ha 및 69.14 kg/ha이 발생하였다. 100mm 이상의 강우가 발생한 $6{\sim}9$월의 유포리와 학술림의 T-N과 T-P의 오염부하가 연오염부하의 86% 및 88% 그리고 66% 및 82%로 나타나 강우량이 오염부하에 큰 영향을 미치는 것으로 나타났다. 그러나 도시유역의 오염부하는 강우량이 많은 $6{\sim}8$월보다 강우량이 적은 5월과 12월에 크게 나타났다. 토지이용별 T-N과 T-P의 연오염부하는 도시>농촌>산림유역의 순서로 나타났다. 공장, 가정하수, 생활하수 등의 오염원이 많은 도시유역에서 T-N의 오염부하량은 농촌 및 산림유역보다 $2{\sim}3$배 높게 이상 나타났으며 T-P의 경우는 $5{\sim}9$배 이상 높게 나타나 비점원오염 배출은 하천 주변의 토지이용이 큰 영향을 미치는 것으로 판단된다.

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Development of Process for Village Scale Wastewater Treatment Using Biofilter and Sulfur-limestone (바이오필터와 황-석회석을 이용한 마을하수 처리 공정 개발)

  • Kim, Tae-Kyu
    • Journal of The Korean Society of Agricultural Engineers
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    • v.49 no.2
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    • pp.75-86
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    • 2007
  • This process which has a connection of biofilter and sulfur-limestone has been developed to treat organic substances including BOD, COD and SS etc. and to treat sulfur-limestone is for denitrification.. The whole process consists of chemical reaction tank, sedimentation tank, trickling filter, denitrification tank The trickling filter is equipped with a reactor filled with absorptive filter, and the sulfur denitrification tank is filled with sulfur-limestone mixed media. After setting up practical facilities whose capacity is 60 tons a day, we have observed the removal efficiencies of pollutants through 60 experiments during Summer and Winter seasons. The average concentration of polluted water was BOD for 3.6 mg/L, $COD_{Mn}$ for 11.3 mg/L, SS for 2.8 mg/L, T-N for 8.6 mg/L, and T-P for 0.8 mg/L, and the rate of treatment efficiencies 96.5%, 84.7%, 96.5%, 79.2%, and 80.8%, respectively was found through the experiments. The average treatment efficiency for BOD and $COD_{Mn}$ was 85.0% and 55.7%, respectively and the average removal efficiency for NH4+-N was 84.9% in the trickling filter. The removal efficiency in the denitrification tank is as follows; The removal rate of $NO_3^--N$ was as high as 93.2% within the compass of pH 6.3 to 7.3 through $16.8{\sim}37.0mg/L$ flown into $NO_3^--N$ and $0.1{\sim}8.3mg/L$ outflown. It had observed that this process has implemented highly efficient and advanced treatment without external carbon sources and internal recycle during its process. In conclusion, this process is suitable for a sewerage in a small village due to the merits of low power consumption and easy maintenance.

Role of n-3 long-chain polyunsaturated fatty acids in human nutrition and health: review of recent studies and recommendations

  • Dael, Peter Van
    • Nutrition Research and Practice
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    • v.15 no.2
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    • pp.137-159
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    • 2021
  • Long-chain (LC) n-3 polyunsaturated fatty acids (n-3 PUFAs), in particular docosahexaenoic acid (DHA) and eicosapentaenoic acid (EPA), are nutrients involved in many metabolic and physiological processes, and are referred to as n-3 LCPUFA. They have been extensively studied for their effects in human nutrition and health. This paper provides an overview on metabolism, sources, dietary intake, and status of n-3 LCPUFA. A summary of the dietary recommendations for n-3 LCPUFAs for different age groups as well as specific physiological conditions is provided. Evidence for n-3 LCPUFA in cardiovascular diseases, including new studies, is reviewed. Expert recommendations generally support a beneficial effect of n-3 LCPUFA on cardiovascular health and recommend a daily intake of 500 mg as DHA and EPA, or 1-2 servings of fish per week. The role of n-3 LCPUFA on brain health, in particular neurodegenerative disorders and depression, is reviewed. The evidence for beneficial effects of n-3 LCPUFA on neurodegenerative disorders is non-conclusive despite mechanistic support and observational data. Hence, no definite n-3 LCPUFA expert recommendations are made. Data for the beneficial effect of n-3 LCPUFA on depression are generally compelling. Expert recommendations have been established: 200-300 mg/day for depression; up to 1-2 g/day for major depressive disorder. Recent studies support a beneficial role of n-3 LCPUFAs in reducing the risk for premature birth, with a daily intake of 600-800 mg of DHA during pregnancy. Finally, international experts recently reviewed the scientific evidence on DHA and arachidonic acid (ARA) in infant nutrition and concluded that the totality of data support that infant and follow-on formulas should provide both DHA and ARA at levels similar to those in breast milk. In conclusion, the available scientific data support that dietary recommendations for n-3 LCPUFA should be established for the general population and for subjects with specific physiological conditions.

Sanitary Chemical Conditions of Farmwaters in Choongcheongnam and Kangwon Province According to Spring and Summer (충청남도 및 강원도 목장지역 목장용수의 춘하절간 위생화학적 변화)

  • 이강문;박석기;이용욱
    • Journal of Food Hygiene and Safety
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    • v.9 no.4
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    • pp.229-235
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    • 1994
  • It is very important to investigate the sanitary chemical conditions of farmwaters used for cattle breeding in the dairy farms. For this purpose we examined pH, KMnO4 consumption, total hardness, chloride, sulfate, NH3-N, NO3-N, fluoride, lead, iron, manganese, cadmium, copper, zinc and chrome in the farmwaters sampled 2 times(spring and summer)in Choongcheongnam and Kangwon Province. The pH of farmwaters in Choongcheongnam and Kangwon Province was 6.49$\pm$0.09, 6.70$\pm$0.06, total hardness 90.21$\pm$7.07, 64.53$\pm$6.38 mg/ι, consumption of KMnO4 4.13$\pm$0.62, 4.34$\pm$0.26mg/ι, NO3-N 6.51$\pm$0.55, 3.61$\pm$0.58 mg/ι, chloride ion 20.51$\pm$1.99, 5.41$\pm$1.36 mg/ι and sulfate ion 6.61$\pm$1.02, 7.28$\pm$1.30 mg/ι, respectively. But NH3-N was scarcely detected. Fluoride, iron, lead, cadmium, zinc, manganese and chrome were not detected from the tested farmwaters. There was high significance between each other in total hardness, NO3-N, chloride ion and sulfate ion. There was regional and seasonal significance in only NO3-N but only regional significance in total hardness and chloride ion.

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Structural and Dielectric Properties of $(1-y)Pb(Mg_{(1-x)/3}Zn_{x/3}Zn_{x/3}Nb_{2/3})O_3-yBaTiO_3$Ceramics ($(1-y)Pb(Mg_{(1-x)/3}Zn_{x/3}Zn_{x/3}Nb_{2/3})O_3-yBaTiO_3$ 세라믹스의 구조 및 유전 성질)

  • 홍영식;박휴범;김시중
    • Journal of the Korean Ceramic Society
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    • v.32 no.8
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    • pp.938-944
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    • 1995
  • Dielectric properties and the stabilization of perovskite phase for the (1-y)Pb(Mg(1-x)/3Znx/3Znx/3Nb2/3)O3-yBaTiO3 ((1-y)PM1-xZxN-yBT) ceramics have been investigated as a function of amount of x and y. In the (1-y)PM0.6Z0.4N-yBT ceramics, the amount of pyrochlore phae was decreased by the addition of 2 mol% BT and the dielectric constant was increased. However, the dielectric constant decreased with further addition of BT even though pyrochlore phase was decreased. Dielectric prooperties in (1-y)PM0.6Z0.4N-yBT ceracmis were affected by the character of the BT rather than the amount of pyrochlore phase. The phase transitions were broadened and phase transition temperatures were lowered by the increase of BT contents.

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Properties of Water Quality and Land Use at the Rural Area in the Nakdong River Watershed (낙동강수계 농촌유역의 토지이용 및 수질 특성)

  • Kim, Jin-Ho;Kim, Chan-Yong;Lee, Seong-Tae;Choi, Chul-Mann;Jung, Goo-Bok;Lee, Jong-Sik;Kim, Won-Il
    • Korean Journal of Environmental Agriculture
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    • v.26 no.2
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    • pp.99-106
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    • 2007
  • This study was focused on understanding the agricultural non-point sources pollution in 72 rural catchments of Nakdong river watershed from 2001 to 2005 every two year. Also. Pearson correlations between water quality and basin characteristic were computed. Water quality of this study watershed was better in 2003 than any other period. The water quality of upstream was recorded from 0.040 to 0.510 dS/m in EC, from 3.55 to 22.60 mg/L in DO, from 0.32 to 16.64 mg/L in T-N, from 0.00 to 12.21 mg/L in $NO_3-N$, from 0.000 to 0.860 mg/L in T-P, and from 0.000 to 0.640 mg/L in $PO_4-P$. A the downstream, EC was measured from 0.030 to 0.520 dS/m, DO from 4.13 to 18.36 mg/L, T-N from 0.38 to 26.88 mg/L, $NO_3-N$ from 0.10 to 20.12 mg/L, T-P from 0.002 to 0.820 mg/L, $PO_4-P$ from 0.002 to 0.690 mg/L. But there was no difference between upstream and downstream for the water quality. Based on the correlation analysis between water quality and land use, correlation between BOD and residential was the highest positive correlation of 0.541 (p<0.01), and correlation between $PO_4-P$ and forest was the highest negative correlation of -0.451 (p<0.01). Also, T-N, $NO_3-N$, and pH were not correlated with all basin characteristics and basin was not correlated with all water quality parameter. According to the correlation residential was causative of growing worst for water quality, and forest was causative of improving for water quality.