• Title/Summary/Keyword: $MgO-P_2O_5$

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Medium Temperature and Lower Pressure Metamorphism and Tectonic Setting of the Pyeongan Supergroup in the Munkyeong Area (문경지역에 분포하는 평안누층군의 중온-저압 변성작용과 지구조 환경 해석)

  • Kim, Hyeong Soo;Seo, Bongkyun;Yi, Keewook
    • The Journal of the Petrological Society of Korea
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    • v.23 no.4
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    • pp.311-324
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    • 2014
  • The Hongjeom formation of the Pyeongan Supergroup in the Munkyeong coalfield mainly consists of metapsammite and metapelites. Metampelites occur as slate preserving chloritoid+chlorite+muscovite and andalusite+biotite+chlorite+muscovite mineral assemblages. Chloritoid and andalusite occur as porphyroblast, and the matrix composed of fine-grained micas. Metamorphic P-T conditions for these mineral assemblages are $510-520^{\circ}C$ and 3.0-3.5kbar based on P-T pseudosection in $MnO-K_2O-FeO-MgO-Al_2O_3-SiO_2-H_2O(MnKFMASH)$ system and isopleth intersections of Fe/(Fe+Mg) ratios in chloritoid and chlorite. The medium temperature and low pressure metamorphism resulted from a higher geothermal gradient ($40-45^{\circ}C/km$) condition than that of burial metamorphism. The youngest (SHRIMP U-Pb age; ca. 327-310 Ma) detrital zircon grains from the Hongjeom formation display oscillatory zoning and relatively high Th/U ratio (0.60-1.12). Based on the previous sedimentary, paleontological, and geochronological studies in the Taebaeksan basin together with results of this study, we suggest that (1) initial deposition of the Hongjeom formation was contemporaneous with a magmatic activity in the provenance, (2) the Pyeongan Supergroup was deposited in an arc-related basin at an active continental margin during the Carboniferous to Permain, and (3) magmatic activities occurred repetitively in relatively short interval in the active continental margin had continuously supplied sediments to the basin.

Effect of Fly ash Application on the Yield of Rice and Silicate Availability in Paddy Soil (Fly ash 시용(施用)이 수도(水稻)의 수량(收量)과 논 토양(土壤)의 유효규산(有效珪酸) 함량(含量)에 미치는 영향(影響))

  • Kim, Yong-Woong;Yun, Chong-Hee;Kim, Kwang-Sik
    • Korean Journal of Soil Science and Fertilizer
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    • v.27 no.4
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    • pp.275-283
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    • 1994
  • The effects of anthracite and bituminous fly ash application on rice yield were investigated and the available silicate in paddy soil with ash application was analyzed. The obtained results are as follow : The yield of rice gradually decreased as the amount of anthracite ash increased. On the contrary, the rice yield gradually increased as the amount of bituminous ash increased. At harvesting stage the chemical properties in soil such as pH, organic content, and inorganic content($P_2O_5$, K. Ca, Mg and available $SiO_2$) were higher in bituminous ash treated soil than in anthracite treated soil. The amount of inorganic components in rice plant such as T-N, $P_2O_5$, $K_2O$, CaO, and MgO gradually decreased with the growing stage of rice. However, the amount of available silicate increased with the growing stage of rice. The silicate content in soil was determined by two different methods ; 1N-NaOAc extracted method and submerging setting method. In bituminous ash treated soil, the correlation between the silicate content in plant and in soil was found when the silicate content in soil was determined by the soil submerging method. In anthracite ash treated soil, however no correlation was found between the silicate content in plant and in soil determined by either method.

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Production of $PGE_2$ and $H_2O_2$ from Alveolar Macrophage Stimulated by Silica (유리규산에 의하여 자극된 폐포 대식세포의 $H_2O_2$$PGE_2$ 생성)

  • Lee, Seong-Beom;Choi, Moon-Ju;Park, Won-Sang;Lee, Jung-Yong;Chae, Gue-Tae;Kim, Sang-Ho;Kim, Choo-Soung
    • Tuberculosis and Respiratory Diseases
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    • v.41 no.5
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    • pp.513-520
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    • 1994
  • Background: The pathogenesis of silicosis has been focused on the interaction between alveolar macrophages and silica particle. Although fibrosis in silicosis has been studied extensively, the mechanism is still not fully understood. There is increasing evidence that monokines and arachidonic acid metabolites macrophage are involved in pathogenesis of silicosis. Recently, it was reported that prostaglandin E2 produced from macrophage counteracts the stimulatory effects of other monokines on fibroblast proliferation or collagen production. Until now, it was remained uncertain by which mechanism silica particle may activate alveolar macrophage to an enhanced release of prostaglandin E2. Methods: In order to investigate the relationship between the activity of alveolar macrophage and the production of $PGE_2$ from activated alveolar macrophage, the authors measured hydrogen peroxide and $PGE_2$ from alveolar macrophages activated by silica in vitro and from alveolar macrophages in the silicotic nodules from rat. Experimental silicosis was induced by intratracheal infusion of silica($SiO_2$) suspended in saline(50 mg/ml) in Sprague-Dawley rats. Results: produced by 1) The silicotic nodules with fibrosis were seen from the sections of rat lung at 60 days after intratracheal injection with 50 mg aqueous suspension of silica(Fig. 1). 2) In vitro, silica caused the dose dependent increase of hydrogen peroxide(p<0.05, Fig. 2A) and $PGE_2$(p>0.05, Fig. 2B) release from alveolar macrophages. Alveolar macrophages from rat with silicotic nodules released more hydrogen peroxide and $PGE_2$ than those of control group(p<0.05, Fig. 3). Conclusion: These results suggest that silica particle could activate macrophage directly and enhanced the release of $PGE_2$ and hydrogen peroxide from the alveolar macrophage.

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Effects of Green Manure Crops on Growth and Yield of Carrot for Reduction of Continuous Cropping Injury of Carrot through Crop Rotation (당근 연작장해 경감을 위한 녹비작물 재배가 당근 생육 및 수량에 미치는 영향)

  • Kim, Seong-Heon;Seo, Dong-Cheol;Park, Jong-Hwan;Lee, Seong-Tae;Lee, Sang-Won;Kim, Hong-Chul;Cho, Ju-Sik;Heo, Jong-Soo
    • Korean Journal of Environmental Agriculture
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    • v.32 no.4
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    • pp.279-286
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    • 2013
  • BACKGROUND: Soil incorporation of green manure crop(GMC) is one of the methods for reducing continuous cropping injury and increasing yield of carrot. The purpose of this study was to evaluate the effects of green manure crops on growth and yield of carrot for reduction of continuous cropping injury of carrot through crop rotation. METHODS AND RESULTS: To reduce the injury by continuous cropping system(CCS) of carrot cultivation, GMCs such as crotalaria and sudangrass were applied, which GMC was sowed in latter-June and returned to soil in latter-October. Nutrient contributions of N, $P_2O_5$, $K_2O$, CaO, and MgO in crotalaria were 8.3, 7.5, 4.4, 7.8, and 2.1 kg/10a, respectively. Nutrient contributions of N, $P_2O_5$, $K_2O$, CaO, and MgO in sudangrass were 8.4, 8.6, 26.8, 0.3, and 2.7 kg/10a, respectively. After incorporation of GMCs into soil, bulk density in soil with GMCs was lower than that in soil without GMCs(control). In soil after incorporation of GMCs, pH was not different in all treatment conditions, and ranged from 6.37~6.64. EC in soil after incorporation of GMCs was lower than that in soil without GMCs. The OM, T-N, and avail. $P_2O_5$ contents in soil with GMCs were higher than those in soil without GMCs. The growth and yields were increased as 39.2%(6,226 kg/10a) in the rotational cropping system(RCS) as compared to continuous cropping system(control and without NPK) of 4,473 kg/10a. Crotalaria cultivation were the most effective crop for reducing the injury of continuous cropping of carrot. CONCLUSION(S): This study suggest that the RCS using GMCs showed lower disease outbreak density in soil for carrot cultivation as compared to CCS without GMCs. Especially, the GMCs good effect for reduction of continuous cropping injury of carrot.

Experimental study of degradation and biodegradability of oxytetracycline antibiotic in aqueous solution using Fenton process

  • Zouanti, Mustapha;Bezzina, Mohamed;Dhib, Ramdhane
    • Environmental Engineering Research
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    • v.25 no.3
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    • pp.316-323
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    • 2020
  • The degradation of aqueous oxytetracycline (OTC) from an aqueous solution antibiotic using H2O2/Fe2+ process was studied in one 1 L batch chemical reactor. The extent of OTC degradation (20 mg/L) was investigated from a known initial pH solution, temperature and the type of catalyst (Fe2+, Fe3+) and for various initial concentrations of OTC, H2O2 and Fe2+. The degradation efficiency achieved was found to be very important (90.82% and 90.63%) at initial pH solution of 3 and 4, respectively. However, the type of catalyst and the reaction temperature had a slight impact on the final degradation of OTC. The results showed that the OTC removal increased with increasing initial H2O2 concentration in the range of 70 to 150 mg/L and initial Fe2+ concentrations in the range of 2 to 5 mg/L. The highest degradation efficiency obtained at ambient temperature was 90.95% with initial concentration of OTC of 10 mg/L, H2O2 = 150 mg/L and Fe2+ = 5 mg/L. Moreover, biodegradability improved from 0.04 to 0.36 and chemical oxygen demand degradation was 78.35% after 60 min of treatment. This study proved that Fenton process can be used for pretreatment of wastewater contaminated by OTC before a biological treatment.

Corelation between crystalline phase and corrosion resistance of Mg alloy with different PEO conditions. II. Corrosion resistance (Mg 합금의 PEO 공정 조건에 따른 산화피막 결정상과 내부식성에 대한 연구 II. 내부식성)

  • Kim, Bae-Yeon;Kim, Yong-Nam;Jeon, Min-Seok;Ham, Jae-Ho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.28 no.2
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    • pp.80-84
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    • 2018
  • Mg alloys AZ31 and AZ91 were Plasma-Electrolytic-Oxidized in Na-P and Na-Si system electrolyte at various concentration, applied voltage and time. Thickness and surface roughness of PEO coating were examined. Salt spraying test were carried out to compare their corrosion resistances. Generally, corrosion resistances rate were increased as thickness and crystallinity increasing. Size of pore being larger, long term corrosion resistance decreased. It is turned out that $Mg_2SiO_4$ and other crystalline phase rather than MgO might be increase corrosion resistance dramatically.

Medium Optimization for Fibrinolytic Enzyme Production by Bacillus subtilis MG410 Isolated (Bacillus subtilis MG410에 의한 Fibrin 분해효소 생산배지의 최적화)

  • Lee Ju-Youn;Paek Nam-Soo;Kim Young-Man
    • The Korean Journal of Food And Nutrition
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    • v.18 no.1
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    • pp.39-47
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    • 2005
  • Using the bacteria isolated from Chungkookjang, Bacillus sublilis MG410 which is excellent in fibrinolytic enzyme activity was isolated. In increase the high production of fibrinolytic enzyme from Bacillus sublilis MG410, the effect of various carbon sources, nitrogen sources, inorganic sources, the initial pH of medium were investigated. The most effective carbon and nitrogen sources were founded cellobiose 0.5%(w/v) and soybean meal 2%(w/v) respectively. None of inorganic sources examined had any detectable stimulating effect on fibrinolytic enzyme production except Na₂HPO₄·12H₂O. The initial optimum pH for fibrinolytic enzyme production ranged from 5∼6 and agitation speed was effect at 150rpm. In jar fermentor experiments under optimal culture conditions, the activity of fibrinolytic enzyme reached about 5.050 unit after 48hours.

Evaluation of Algal Growth Potential in the Mangyeong River by MBOD method (MBOD법에 의한 만경강 수계의 조류성장잠재력 평가)

  • Kim, Jong Gu;Kim, Jun U
    • Journal of Environmental Science International
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    • v.13 no.9
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    • pp.807-817
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    • 2004
  • The modified biochemical oxygen demand (MBOD) were conducted to evaluate the water quality and fertility in the Mangyeong river from november 2002 to april 2003. MBOD method was used to evaluate algal growth potentials and their limiting factors. MBOD depends on the amount of available inorganic nutrient and organic substrate during 5-day incubation in the dark condition at $20^{\circ}C.$ The MBOD assay depends on inorganic nutrients such as phosphorus and nitrogen as well as reduced carbon as called MBOD, MBOD-P, and MBOD-N, respectively. The concentration of pollutants were in the range of 3.08~48.36 mg/L for COD. The concentration of nutrients were in the range of 0.37~111.62 mg/L for dissolved inorganic nitrogen (DIN) and 0.00~1.03 mg/L for dissolved inorganic phosphorus (DIP). The results of MBOD bioassay showed that the MBOD, MBOD-P and MBOD-N values were 15~173 mg $O_2/L,$ 13~165 mg $O_2/L$ and 66~175 mg $O_2/L$ ranges, respectively. The MBOD values are found to be the highest in Iksan River and the lowest in Hari River throughout the Mangyeong River. The relationships of MBOD, MBOD-P and MBOD-N in MBOD method were generally found in MBOD$\risingdotseq$ MBOD-P$\risingdotseq$MBOD-N. But the result of Gosan was appeared to MBOD$\risingdotseq$MBOD-N > MBOD-P. The MBOD-N value was higher 3 to 5 times than the MBOD-P value in the Gosan station. The algal growth potentials expressed as the concentration of chlorophyll-a were maximum 20 times more than algal biomass in the water column.

Chemical Properties of Rainwater in Suwon and Taean Area during Farming Season (수원 및 태안지역 영농기 강우의 화학적 특성)

  • Lee Jong Sik;Jung Goo Bok;Shin Joung Du;Kim Jin Ho
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.6 no.4
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    • pp.250-255
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    • 2004
  • This study was carried out to investigate the chemical properties of rainwater in the Suwon and Taean areas. Rainwater was collected during the farming seasons of 2002 and 2003. The number of samples collected in Suwon and Taean were 69 and 71, respectively. These were analyzed for chemical composition. The pH of samples collected in April was higher than those collected after June. The most common range of rainwater pH was 5.0-5.6 in Suwon and 4.5-5.0 in Taean during investigation periods. The neutralization capacity of rainwater acidity by $Ca^{2+}$ and N $H_4$$^{+}$ was decreased during the rainy season. The EC of rainwater was lower during the rainy season. Cation concentrations in rainwater were N $H_4$$^{+}$ > $H^{+}$ > $Ca^{2+}$ > $Mg^{2+}$ > $K^{+}$ in Suwon and $Ca^{2+}$ > N $H_4$$^{+}$ > $H^{+}$ > $K^{+}$ > $Mg^{2+}$ in Taean. In the case of anion, the order was sol > N $O_3$$^{[-10]}$ > C $I^{[-10]}$ in Suwon and S $O_4$$^{2-}$ > C $I^{[-10]}$ > N $O_3$$^{[-10]}$ in Taean. The mean values of sulfate in rainwater were 130 $\mu$eq $L^{-1}$ in Suwon and 117 $\mu$eq $L^{-1}$ in Taean. The ratio of non-sea salt sulfate to sulfate (nss-S $O_4$$^{2-}$ > S $O_4$$^{2-}$) was 89% and 88%. This implies that the major origin of sulfate in rainwater might be anthropogenic.ht be anthropogenic..

Effect of Zeolite and Livestock Manure in Composting Materials on Composting of Seafood Processing Wastewater Sludge (수산가공폐수 슬러지의 퇴비화과정중 zeolite 및 가축분첨가 효과)

  • Lee, Hong-Jae;Cho, Ju-Sik;Park, Hyun-Geoun;Heo, Jong-Soo
    • Journal of the Korea Organic Resources Recycling Association
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    • v.9 no.2
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    • pp.93-100
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    • 2001
  • To study the possibility of agricultural utilization of seafood processing wastewater sludges, the change of temperature, decreasing ratio of weight generation quantity of $CO_2$ and $NH_3$, and contents of inorganic elements for composting by adding different rates of zeolite and livestock manure to seafood processing wastewater sludges were investigated. Changes of temperature, decreasing ratio of total weight and generation quantity of $CO_2$ were not little different with increasing addition rates of zeolite for composting. But the less addition quantity of livestock manure is, the higher were temperature and decreasing ratio weight for composting. Ceneration quantity of $NH_3$ in composting materials as adding zeolite ti 5, 10 and 20% and livestock manure to 50, 65 and 80% were 68, 61 and $46mg/kgvs{\cdot}hr$, respectively, for composting periods. So, $NH_3$ generated little quantity as much as possible addition of zeolite and manure. Contents of T-C and T-N little decreased and C/N ratio little increased after composting than before. Content of $P_2O_5$, $K_2O$, CaO also increased a little, that of MgO is not different and that of Mn decreased very sharply in all conditions after composting than before.

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