• Title/Summary/Keyword: $MgO-P_2O_5$

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Investigation of an Optimum Application Rate of Blended Biochar Pellet as Slow Release Fertilizer during Cabbage Cultivation (배추재배 시 바이오차 펠렛 완효성 비료의 적정 시용량 구명)

  • Kim, HuiSeon;Yun, SeokIn;Jang, Eunsuk;Shin, JoungDu
    • Journal of the Korea Organic Resources Recycling Association
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    • v.27 no.1
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    • pp.49-56
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    • 2019
  • This experiment was conducted to select an optimum application rate of blended biochar pellet as slow release fertilizer during cabbage cultivation. The blended biochar pellet made with a combination(4:6) of biochar and pig manure compost with unloading N, P, K solutions for adjusting about 9% of total nitrogen(TN). The treatments were consisted of the control as recommended application rates for cabbage cultivation in National Institute of Agricultural Sciences, N 40%, N 40% and 0.07M MgO and N 60 % of the blended biochar pellet, respectively, based on nitrogen application of recommended rates to cabbage cultivation. Changes of $NH_4-N$, $NO_3-N$, $P_2O_5$ and $K_2O$ concentrations in the soil and growth characteristic and yield components were investigated and observed during the cabbage cultivation. The experimental result shown that contents of $NH_4-N$, $NO_3-N$ and $K_2O$ of soil in the N 40% were significantly difference(p<0.01) with the control. $P_2O_5$ concentrations of soil in the N 40% were highest among the treatments. The fresh weight per cabbage in the N 40% was not significantly different(p>0.05) from the control, but in the N 40% and 0.07M MgO and N 60% was lower than that of the control. It was considered that an optimum blended biochar application rate for cabbage cultivation was 40% of recommended nitrogen application.

Research on Improvement of CH4 Reduction Performance of NGOC for CNG Bus (CNG 버스용 NGOC의 CH4 저감 성능 향상을 위한 연구)

  • Seo, Choong-Kil
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.5
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    • pp.708-715
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    • 2017
  • Recently, in order to meet the stricter emission regulations, the proportion of after-treatments for vehicles and vessels has been increasing gradually. The objective of this study is to investigate the improvement of $CH_4$ reduction ability of natural gas oxidation catalyst (NGOC), which reduces toxic gases emitted from CNG buses. Thirteen NGOCs were prepared, and the conversion performance of noxious gases according to the type of supports, the loading amount of noble metal, and surfactant and aging were determined. Support Zeolite supported on No. 3 $NGOC(1Pt-1Pd-3MgO-3CeO_2/(46TiO_2+23Al_2O_3+23Zeolite)$ is an anionic alkali metal/earth metal component that improved the oxidation reactivity between CO and NO and noble metal dispersion, and thus enhanced the $CH_4$ reduction ability. As the loading amount of Pd, a noble metal with a high selectivity to $CH_4$, was increased, the number of reaction sites was increased and the ability to reduce $CH_4$ was improved. No. 11 $NGOC(1Pt-1Pd-3MgO-3CeO_2/(Z20+Al80)$(pH=8.5), to which nitrate surfactant had been added, exhibited well dispersed catalyst particles with no agglomeration and improved the $CH_4$ reduction ability by 5-15%. The $NGOC(2Pt-2Pd-3Cr-3MgO/90Al_2O_3)$(48h aging), which was mildly thermal aged for 48h, increased the $CH_4$ reduction ability to about 10% or less as compared with No. 12 NGOC(Fresh).

Synthesis of High-Aspect-Ratio BaTiO3 Platelets by Topochemical Conversion and Fabrication of Textured Pb(Mg1/3Nb2/3)O3-32.5PbTiO3 Ceramics

  • Zhao, Wei;E, Lei;Ya, Jing;Liu, Zhifeng;Zhou, Heping
    • Bulletin of the Korean Chemical Society
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    • v.33 no.7
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    • pp.2305-2308
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    • 2012
  • Perovskite structured barium titanate particles ($BaTiO_3$) platelets were synthesized by molten salt synthesis and topochemical microcrystal conversion. As the precursors of $BaTiO_3$, plate-like $BaBi_4Ti_4O_{15}$ particles were first synthesized by the reaction of $Bi_4Ti_3O_{12}$, $BaCO_3$, and $TiO_2$ at $1080^{\circ}C$ for 3 h in $BaCl_2$-KCl molten salt. After the topochemical reactions, layer-structured $BaBi_4Ti_4O_{15}$ particles transformed to the perovskite $BaTiO_3$ platelets. $BaTiO_3$ particles with thickness of approximately $0.5{\mu}m$ and a length of $10-15{\mu}m$ retained the morphology feature of the $BaBi_4Ti_4O_{15}$ precursor. For <001> $Pb(Mg_{1/3}Nb_{2/3})O_3-32.5PbTiO_3$ (PMNT)-5 wt % PbO piezoelectric ceramics textured with 5 vol % of $BaTiO_3$ templates, the Lotgering factor reached 0.82, and $d_{33}$ was 870 pC/N.

Piezoelectric and Dielectric Characteristics of Low Temperature Sintering Pb(Mg1/2W1/2)O3-Pb(Mn1/3Nb2/3)O3-Pb(Zr1/2Ti1/2)O3 Ceramics With the Substitution of Pb(Mg1/2W1/2)O3 (Pb(Mg1/2W1/2)O3 치환에 따른 저온소결 Pb(Mg1/2W1/2)O3-Pb(Mn1/3Nb2/3)O3-Pb(Zr1/2Ti1/2)O3 세라믹스의 압전 및 유전특성)

  • Yoo Ju-Hyun;Lee Hyun-Seok;Chung Kwang-Hyun;Jeong Yeong-Ho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.5
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    • pp.417-421
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    • 2006
  • In this study, in order to develop low temperature sintering piezoelectric ceramics for LTCC (Low-Temperature Cofired Ceramic) multilayer piezoelectric actuator, PMW-PMN-PZT ceramics using $0.2wt%\; Li_2CO_3$ and $0.25wt%\;CaCO_3$ as sintering aids were investigated according to the varation of PMW substution. Composition ceramics could be sintered at $900^{\circ}C$ by adding sintering aids. As the amount of PMW substitution increased, the crystal structure of PMW-PMN-PZT ceramics moved from tetragonal phase to rhombohedral phase gradually, and MPB(Morphotrophic Phase Boundary) region appeared at 2 mol% PMW substitution. At the sintering temperature of $900^{\circ}C$, the density, electromechanical coupling factor(kp), mechanical quality factor(Qm), dielectric constant(${\epsilon}r$), piezoelectric constant(d33) and Curie temperature(Tc) of 2 mol% PMW substituted PMW-PMN-PZT ceramics showed the optimal values of $7.88g/cm^3$, 0.58, 1002, 1264, 352 pC/N and $336^{\circ}C$, respectively, for LTCC multilayer piezoelectric actuator application.

Changes in th Chemical Components and Antioxidant Activity of Strawberry by Slow-released ClO2 Gas Gel-Pack during Storage (서방형 이산화염소 가스 젤팩을 이용한 딸기저장 중 주요 성분 및 항산화 활성의 변화)

  • Lee, Kyung-Haeng;Yoon, Ye-Ji;Lee, Bom;Bong, So-Jung;Kim, Hyun-Kyoung;Kwak, Il-Hwan;Kim, Hong-Gil
    • The Korean Journal of Food And Nutrition
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    • v.30 no.4
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    • pp.823-829
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    • 2017
  • To increase the shelf-life of strawberry, samples were treated with two gel packs containing slow-released chlorine dioxide ($ClO_2$) gas at 3~5 ppm for 6 days at room temperature and the changes in the major chemical components (ascorbic acid, polyphenols, flavonoids and anthocyanin) contents and antioxidative activities (DPPH, ABTS radical scavenging and metal chelating activity) were investigated. The content of ascorbic acid of control was 40.38 mg% and contained 35.67~44.75 mg% during 6 days. There was no tendency to increase or decrease during storage period. The contents of ascorbic acid of control and 3~5 ppm $ClO_2$ gas treated samples were not significantly different during storage period. The content of polyphenol compounds of initial stage was 111.23 mg% and contained 117.78~132.40 mg% during 6 days. The contents of polyphenol compounds of 3~5 ppm $ClO_2$ gas treated samples were 103.51~130.25 mg%. There were no significant different between them during storage. The flavonoids and anthocyanin contents were not different from the control during storage period regardless of 3~5 ppm $ClO_2$ gas treatment. Furthermore, antioxidative activities were not different among the control and $ClO_2$ gas treatments during storage.

Effect of Silicon Source and Application Method on Growth of Kalanchoe 'Peperu' (규산염 종류와 적용방법이 칼랑코에 '페페루'의 생육에 미치는 영향)

  • Son, Moon-Sook;Oh, Hye-Jin;Song, Ju-Yeon;Lim, Mi-Young;Sivanesan, Iyyakkannu;Jeong, Byoung-Ryong
    • Horticultural Science & Technology
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    • v.30 no.3
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    • pp.250-255
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    • 2012
  • The effect of different source silicon ($CaSiO_3$, $K_2SiO_3$, and $NaSiO_3$) and their application methods (foliar application and subirrigation) on the growth of potted kalanchoe was investigated. Rooted terminal cuttings of Kalanchoe blossfeldiana 'Peperu' were transplanted into 10.5 cm plastic pots containing a commercial growing medium. Then, a nutrient solution, containing 0 or $50mg{\cdot}L^{-1}$ Si as $K_2SiO_3$, $Na_2SiO_3$, or $CaSiO_3$ and adjusted to EC 1.4-$1.6mS{\cdot}cm^{-1}$ and pH 6.0, was supplied through subirrigation along with the nutrient solution or by a foliar application. Plants were grown in a glasshouse under a mean temperature of $23^{\circ}C$ and RH of 70-80%. After 12 weeks of cultivation, plant growth characteristics and leaf tissue contents of P, K, Ca, Mg, Na, S, and Si were measured. Both subirrigational supply and foliar application of Si decreased the plant height and flower stem length. However, the plant condition in the foliar application resulted in disease-like soft rot on the leaf. Among three silicon sources tested, $CaSiO_3$ supplied through a subirrigation system increased shoot tissue contents of Si and chlorophyll as compared to the $Na_2SiO_3$ or $K_2SiO_3$ treatment. Shoot tissue contents of Ca, K, and Na increased when the plant was supplied with $CaSiO_3$, $K_2SiO_3$, and $Na_2SiO_3$, respectively. Subirrigational supply of $K_2SiO_3$ and $NaSiO_3$ decreased the shoot tissue contents of Ca and Mg, and K and Ca, respectively. Therefore, $CaSiO_3$ supplied through a subirrigation system could improve plant quality of kalanchoe 'Peperu' making compact potted plants.

Studies on the Change of Mineral Nutrients Content in Rice Plant in the Ripening Process I. Translocation and Cumulation of Mineral Nutrients in Different Parts of Rice Plant in the Ripening Process (등숙 진전에 따른 도체내 부위별 양분 동태에 관한 연구 I. 도체내 부위별 무기양분의 동태)

  • Lee, Yang-Ku;Lim, Moo-Sang;Im, Byeong-Gi
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.31 no.2
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    • pp.195-203
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    • 1986
  • In order to clarify the trend of change in mineral nutrients in rice plant on various ripening process, P$_2$O$\sub$5/, K$_2$O, MgO, CaO, SiO$_2$ and ash contents were determined for the grain, internode, leaf-5heath and leaf blade respectively for 9 times at an week interval after heading. Four rice cultivars with different maturity and ecotype were grown under normal cultural conditions for the trial. The contents of mineral nutrients in the brown rice were in the order of Ash, P$_2$O$\sub$5/, K$_2$O and MgO. CaO and SiO$_2$ were found in minute quantity in the brown rice. The hull contained SiO$_2$ in large quantity, and it also contained the mineral nutrients in the order of K$_2$O, P$_2$ O$\sub$5/O. The CaO content of hull was extremely minute.

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Characteristics of Removal and Precipitation of Heavy Metals with pH change of Artificial Acid Mine Drainage (인공 산성광산배수의 pH변화에 의한 중금속 제거 및 침전 특성 연구)

  • Lee, Min Hyeon;Kim, Young Hun;Kim, Jeong Jin
    • Economic and Environmental Geology
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    • v.52 no.6
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    • pp.529-539
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    • 2019
  • In this study, heavy metal removal and precipitation characteristics with pH change were studied for artificial acid mine drainage. Artificial acid mine drainage was prepared using sulfates of iron, aluminum, copper, zinc, manganese which contained in acid mine drainage from abandoned mines. The single and mixed five heavy metal samples of Fe, Al, Cu, Zn, and Mn were prepared at initial concentrations of 30 and 70 mg/L. Fe and Al were mostly removed at pH 4.0 and 5.0, respectively, and other heavy metals gradually decreased with increasing pH. Concentration changes with increasing pH show generally similar trend for single and mixed heavy metal samples. The effect of removing heavy metals from aqueous solutions is not related to the initial concentration and depends on the pH change. XRD were used for mineral identification of precipitates and crystallinity of the mineral tended to increase with increasing pH. The precipitates that produced by decreasing the concentration of heavy metals in the aqueous solution composed of Fe-goethite(FeOOH), Al-basaluminite(Al4(SO4)(OH)10·4H2O), Cu-connellite(Cu19(OH)32(SO4)Cl4·3H2O) and tenorite(CuO), Zn-zincite(ZnO), and Mn-hausmannite(Mn3O4).

Study on the Salt Tolerance of Rice and Other Crops in Reclaimed Soil Areas (Ⅶ) On the Optimum Ratio of Phosphate and Potash to N Fertilization for Rice Plant in the Reclaimed Salty Areas (간척지에서 수도 및 기타작물의 내염성에 관한 연구 (제7보) 염분간척지에서 수도의 N 세포의 변동에 따르는 P와 K의 반응에 관하여)

  • 임형빈
    • Journal of Plant Biology
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    • v.13 no.2
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    • pp.21-31
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    • 1970
  • The rice variety, Nongkwang was used in two factorial experiments with the combination of 15 kg and 20 kg of N per 10 a, 3 levels of P2O5 (0, 4 and 8 kg per 10 a) and 4 levels of potash(0, 2, 4 and 8 kg per 10 a) in the reclaimed soil areas containing 0.48% on the average salt content throughout the year(0.67% at the end of April). The absorption of N, K and Ca was accelerated by increased N applications. The absorption of P itself was not enhanced by the increased application of P2O5 but the absorption of K2O reduced the absorption of Mg was affected. The increased application of K2O reduced the absorption of Si and seemed to increase the content of carbohydrate in the rice plants. Twenty kg of N and 4kg of P2O5 per 10 a produced satisfactory yields of rough rice, potash applications are ineffective in this experiment on rice grain production.

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Studies on proteolytic enzyme from A New Strain in Serratia sp. (Serratia속의 신균주가 생산하는 단백질분해효소)

  • 최완수;정계종;이주경;박주웅;이상훈;이진복;이송락;최신원
    • YAKHAK HOEJI
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    • v.37 no.2
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    • pp.129-135
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    • 1993
  • Serratia sp. Y-4 was isolated from soil. Many characteristics of the strain and optimum cultivation condition for protease production were investigated.,The protease from Serratia sp. Y-4 was purified and studied for the properties of the enzyme. The isolated strain was identified to the genus Serratia. The strain was cultivated in 1%-casein, 0.5%-Na$_{3}$PO$_{4}$.7H$_{2}$O, 0.1%-NaCl, 0.05%-KCI, 0.02%-MgSO$_{4}$.7H$_{2}$O, 0.02%-CaCl$_{2}$.2H$_{2}$O, 0.02%-ZnSO$_{4}$.7H$_{2}$O, 0.02%-MnCl$_{2}$.4H$_{2}$O and 0.5%-soy bean oil at pH 7.0 for 35 hrs. The enzyme was purified about 5.89 fold from the culture broth with 31.1% recovery and 19,613 u/mg through ultrafiltration, ammonium sulfate, DEAE-sephacel and Superose-12 chromatography. The purified enzyme was identified as one band by isoelectric focusing, SDS- and native-PAGE. It has maxium activity at $37^{\circ}C$ and pH 9.0. Molecular weight of it is approx. 50 kD and pl is about 6.70. Its Km value for casein was 20 mg/ml. 5 mM-EDTA, 5mM-SDS, Ag$^{+1}$, Cu$^{+2}$, Hg$^{+2}$ and Pb$^{+2}$ inhibited the enzyme.

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