• Title/Summary/Keyword: $MgO-P_2O_5$

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Preparation of Chlorine Dioxide Aqueous Solution by Un-divided Electrochemical Cell using RuO2 anode (RuO2를 양전극으로 사용한 무격막 전해셀에서의 이산화염소수 제조)

  • Kwon, Tae Ok;Park, Bo Bae;Roh, Hyun Cheul;Moon, Il Shik
    • Applied Chemistry for Engineering
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    • v.20 no.3
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    • pp.296-300
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    • 2009
  • Generation of chlorine dioxide ($ClO_2$) was studied by the un-divided electrochemical cell system using $RuO_2$ anode material. Sodium chlorite ($NaClO_2$) was used as a precursor compound of chlorine dioxide. Effect of various operating parameters such as feed solution flow rate, initial solution pH, $NaClO_2$ and NaCl conc., and applied current density on the produced chlorine dioxide concentration and solution pH were investigated in un-divided electrochemical cell system. Produced chlorine dioxide concentration and solution pH were strongly depends on the initial solution pH and feed solution flow rate. Sodium chloride (NaCl) was not only good electrolyte, it was also used as a raw material of chlorine dioxide with $NaClO_2$. Observed optimum conditions were flow rate of feed solution (90 mL/min), initial pH (2.3), $NaClO_2$ concentration (4.7 mM), NaCl concentration (100 mM), and current density ($5A/dm^2$). Produced chlorine dioxide concentration was around 350 mg/L and solution pH was around 3.

The Effect of Long-Term Fertilization on the Yield and Quality of Soybean (동일비료 24년 연용이 콩의 수량(收量) 및 품질(品質)에 미치는 영향(影響))

  • Park, No-Kwaun;Kim, Jae-Kyu;Seo, Young-Jin;Park, Seon-Do;Choi, Boo-Sull
    • Korean Journal of Soil Science and Fertilizer
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    • v.31 no.4
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    • pp.330-333
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    • 1998
  • This experiment was conducted to investigate the effect of long-term fertilization on the yield and quality of soybean. The yield of soybean was highest in the NPK+lime $1.5Mg\;ha^{-1}$ treatment. Carbohydrate content of soybean was high in the non-fertilizer treatment and crude protein content was high in the NPK+lime $1.5Mg\;ha^{-1}$ and NPK+silicate $1.5Mg\;ha^{-1}$ treatment, and crude lipid and ash content was high in the NPK+silicate $1.5Mg\;ha^{-1}$ treatment. The content of inorganic compounds were not different among treatments. Correlation between $P_2O_5$/T-N and carbohydrate, crude lipid was $-0.99^{**}$, $-0.94^{**}$ respectively. Correlation between Mn and carbohydrate was $0.95^*$, but others were not significantly different. Yield of soybean increased with lime application and protein content increased with silicate application.

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Petrochemistry of Granitoids in the Younggwang-Kimje area, Korea (영광-김제 지역 화강암류의 암석화학적 연구)

  • Park, Young-Seog;Kim, Jong-Kyun;Kim, Jin
    • Economic and Environmental Geology
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    • v.34 no.1
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    • pp.55-70
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    • 2001
  • Granitoids in the Younggwang-Kimje area can be divided into two types of granite. One is foliated granite (Cheongup and Kochang foliated granites) developed along the NE-SW direction kwangju fault system and the other is undeformed granite (Kimje and Younggwang granites) developed in the western part of the area. $SiO_2$ content of study area, Younggwang granite is 62.8-74.0%, Kochang foliated granite is 64.5-74.4%, Cheongup foliated granite is 64.5-70.2%, Kimje granite is 63.4-72.0%. The result indicated that these granitoids belong to the intermediate and acidic rock. In Harker's diagram, as $SiO_2$ increases, $Al_2O_3$, $Fe_2O_3$, MgO, CaO, $TiO_2$> $P_2O_{5}$s and MnO decrease, but $K_2O$ increases. In AFM diagram, Younggwang granite, Kochang foliated granite, Cheongup foliated granite and Kimje granite belong to calk-alkaline rock series. And in triangular diagrams of normative Qz-Or-Pl and An-Ab-Or, they are located in granodiorite and granite region. On the co-variation diagrams of trace elements with silica, Ba, Co, Li, Nb, An, Rb elements show increasing patterns. The diagrams of ACF and $Na_2O$ vs. $K_2O$ ratios indicate that granitoids of the study area belong to I-type.

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PZT-PMN Ceramics for Large Displacement Piezoelectric Devices

  • Lim, Kee-Joe;Park, Jae-Yeol;Lee, Jong-Sub;Kang, Seong-Hwa;Kim, Hyun-Hoo
    • Transactions on Electrical and Electronic Materials
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    • v.5 no.2
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    • pp.76-80
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    • 2004
  • Piezoelectric and dielectric properties as functions of x and y mole ratio in yPb(ZrxTil-x)O$_3$(1-y)Pb(Mn$\_$1/3/Nb/2/3/)O$_3$, ceramics, PZT-PMN, are investigated for large displacement piezoelectric devices. From the experimental results, when y is 0.95 and x is 0.505, the piezoelectric and dielectric properties are maximum, that is, electromechanical coupling coefficient(kp), piezoelectric strain constant(d$\_$33/), permittivity($\varepsilon$$\_$33/$\^$T//$\varepsilon$$\_$0/), and Curie temperature are 58 %, 272 pC/N, 1520 and about 350$^{\circ}C$, respectively. Also, when y is 0.90 and x is 0.50, their properties are 56 %, 242 pC/N, 1220, and 290$^{\circ}C$, respectively. As MgO dopant is added from 0 wt% to 1 wt%, kp increases to 63 % and Qm decreases to 500 at the MgO dopant of 0.1 wt%, and then kp decreases to 57 % as MgO is added.

A Study on Removal of Phenol and Its By-Product by Ozone, Ozone/Hydrogen Peroxide and Ozone/Granular Activated Carbon (오존, 오존/과산화수소와 오존/활성탄 처리에 의한 페놀 및 그 부산물의 제거에 관한 연구)

  • 배현주;김영규;정문호
    • Journal of Environmental Health Sciences
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    • v.23 no.3
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    • pp.121-129
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    • 1997
  • This study was performed to delineate the removal phenol in solutions using of ozone, ozone/$H_2O_2$ and ozone/GAC. The disinfection by-product of phenol by ozonation, hydroquinone, was analyzed and it's control process was investigated. The followings are the conclusions that were derived from this study. 1. The removal efficiency of phenol by ozonation was 58.37%, 48.34%, 42.15%, and 35.41% which the initial concentration of phenol was 5 mg/l, 10 mg/l, 15 mg/l, and 20 mg/l, respectively. 2. The removal efficiency of phenol by ozonation was 42.95% at pH 4.0 and 69.39% at pH 10, respectively. The removal efficiencies were gradually increased, as pH values were increased. 3. With the ozone/$H_2O_2$ combined system, the removal efficiency of phenol was 72.87%. It showed a more complete degradation of phenol with ozone/$H_2O_2$ compared with ozone alone. 4. When ozonation was followed by filtration on GAC, phenol was completely removed. 5. Oxidation, if carried to completion, truly destroys the organic compounds, converting them to carbon dioxide. Unless reaction completely processed, disinfection by-products would be produced. To remove them, ozone/GAC treatment was used. The results showed that disinfection by-product of phenol by ozonation, hydroquinone, was completely removed. These results suggested that ozone/GAC should also be an appropriate way to remove phenol and its by-product.

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Effect of Genotype on Whole-body and Intestinal Metabolic Response to Monensin in Mice

  • Fan, Y.K.;Croom, W.J.;Daniel, Linda;McBride, B.W.;Koci, M.;Havenstein, G.B.;Eisen, E.J.
    • Asian-Australasian Journal of Animal Sciences
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    • v.19 no.4
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    • pp.554-562
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    • 2006
  • Two lines of mice, M16 selected for rapid growth and a randomly selected control ICR as well as their reciprocal crosses were used to study the effects of genotype on whole-body energetics and intestinal responses to monensin. Six mice, eight weeks of age, from each line or reciprocal cross were assigned to one of two treatments, 1) drinking water containing 20 mmol/L monensin dissolved in 0.5% V/V ethanol, and 2) drinking water containing 0.5% V/V ethanol (control) for two weeks. After 11 days (age of 9 weeks and 4 days), whole-body $O_2$ consumption was measured. At the end of two weeks, jejunal $O_2$ consumption, intestinal tissue composition and histomorphometrics as well as the rate and efficiency of glucose absorption were estimated. In comparison with the control, monensin administration in drinking water resulted in less daily water intake (13.4 vs. 15.5 ml/mouse, p<0.01), less protein to DNA ratio of jejunal mucosa (5.41 vs. 6.01 mg/mg, p<0.05), lower villus width (88 vs. $100{\mu}m$, p<0.05), and less jejunal tissue $O_2$ consumption enhancement by alcohol (7.2 vs. 10.5%, p<0.01) in mice. Other than those changes, monensin had little (p>0.05) effect on variables measured in either line of mice or their reciprocal cross. In contrast, the M16 line, selected for rapid growth, as compared to the ICR controls or the reciprocal crosses, had less initial (pre-monensin treatment) whole-body $O_2$ consumption per gram of body weight (1.68 vs. $2.11-2.34{\mu}mol/min{\cdot}g$ BW, p<0.01) as compared to the ICR and reciprocal crosses. In addition, the M16 mice exhibited greater growth (412 vs. 137-210 mg/d, p<0.05), better feed efficiency (41.7 vs. 19.9-29.3 mg gain/g feed, p<0.05), shorter small intestines adjusted for fasted body weight (1.00 vs. 1.22-1.44 cm/g FBW, p<0.05), wider villi (109 vs. $87-93{\mu}m$, p<0.05), more mature height of enterocytes (28.8 vs. $24.4-25.1{\mu}m$, p<0.05) and a lower rate (91 vs. $133-145{\eta}mol\;glucose/min{\cdot}g$ jejunum, p<0.05) and less energetic efficiency (95 vs. $59-72{\eta}mol$ ATP expended/${\eta}mol$ glucose uptake, p<0.05) of glucose absorption compared to the ICR line and the reciprocal cross. Monensin had little (p>0.05) effect on whole-body $O_2$ consumption and jejunal function, whilst selection for rapid growth resulted in an apparent down-regulation of intestinal function. These data suggest that genetic selection for increased growth does not result in concomitant changes in intestinal function. This asynchrony in the selection for production traits and intestinal function may hinder full phenotypic expression of genotypic growth potential.

Changes in Nutrients Uptake and Dry Matter Yield of Orchardgrass ( Dactylis glomerata L. ) and Alfalfa ( medicago sativa L. ) by Gypsum Application. (석고시용이 Orchargrass ( Dactylis glomerata L. ) 와 Alfalfa ( Medicago sativa L. )의 양분흡수 및 목초수량에 미치는 영향)

  • 윤순강;송기웅;김재규
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.10 no.3
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    • pp.141-146
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    • 1990
  • Changes in dry matter yield, crude components, nutrients uptake($P_2O_5$, $K_2O$, CaO, MgO) and sulphur containing amino acid(cysteine, methionine) of orchardgrass(Dacty1is glomerata. L) and alfalfa(A4edicago sativa. L) by gypsum application(as sulphur source, 0, 2. 5, 10, 20kg SIlOa) were investigated to understand the effect of sulphur on herbage production in pasture, which was established in 1987 as means of hand broadcasting. The effect of gypsum on dry matter yield at different cutting times during growing seasons has not been found both in orchardgrass and in alfalfa, but in respect to annual total dry matter yield there were increment in herbage yield (P<0.05) of alfalfa at 5, 10, 20kg SIlOa in 1989 and the amounts of sulphur taken up in herbage slightly increased according to the rates of gypsum application. Maximum apparent recovery of sulphur was 7.55% at 2kg SIlOa in orchardgrass and was 17.8% at 5kg S/lOa in alfalfa. There were no any great differences in the content of crude components of both species and this trend was similar with the mineral contents of orchardgrass. But in alfalfa, the amounts of $K_2O$, CaO, and $P_2O_5$ taken up were increased by gypsum application and the increment in the amounts of minerals taken up in herbage at 20kg SIlOa were 14.9 of $K_2O$, 9.1 of CaO, and 2.5kgIlOa of $P_2O_5$ as compared to those of at untreated plot. Cysteine and methionine were not influenced by gypsum applicaton not only in orchardgrass but also cysteine in alfalfa, however, the content of methionine in alfalfa was slightly increased at 2, 5, lOkg SIlOa and at 20kg SIlOa was reverse.

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Decentralized Composting of Garbage in a Small Composter for Dwelling House;III. Laboratory Composting of the Household Garbase in a Small Bin with Double Layer Walls (가정용 소형 퇴비화용기에 의한 부엌쓰레기의 분산식 퇴비화;III. 실험실조건에서 이중벽 소형 용기에 의한 퇴비화 연구)

  • Seo, Jeoung-Yoon;Joo, Woo-Hong
    • Korean Journal of Environmental Agriculture
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    • v.14 no.2
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    • pp.232-245
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    • 1995
  • The garbage from the dwelling house was composted in two kinds of small composter in the laboratory, and the possibility of garbage composting was examined. The composters were general small. One (type 3) was constructed with the double layer walls and the other (type 4) was the same as the first except for being insulated. Because it was found that type 3 was not available for composting under our meteorological conditions through the winter experiment, only type 4 was tested in spring and summer. The experiment was performed for 8 weeks in each season. The seasonal variation of several components in the compost was evaluated and discussed. The results summarized below were those obtained at the end of the experiment, if the time was not specified. 1) The maximum temperature was $43^{\circ}C$ in winter, $55^{\circ}C$ in spring and $56^{\circ}C$ in summer. 2) The mass was reduced to an average of 63% and the volume reduction was an average of 78%. 3) The density was estimated as 1.5 kg/l in winter and 0.8 kg/l in spring and summer. 4) The water content was not much changed during the composting periods. It was 79.3% in winter, 75.0% in spring and 70.0% in summer. 5) After pH value increased during the first week, it decreased until the second week and increased again continuously thereafter. It reached pH 6.19 in winter, pH 7.59 in spring and pH 8.69 in summer. 6) The faster the organic matter was decomposed, the greater the ash content increased. The contents of cellulose and lignin increased, but that of hemicellulose decreased during the composting period. 7) Nitrogen contents were in the range of 3.3-6.8% and especially high in summer. After ammonium contents increased at the early stage of the composting period, they decreased. The maximum ammonium-nitrogen content was 2,404mg/kg after 8 weeks in winter, 12,400mg/kg after 3 weeks in spring and 20,718mg/kg after 3 weeks in summer. C/N-ratios decreased with the lapse of composting time, but they were not much changed. Nitrification occurred actively in summer. 8) The contents of volatile and higher fatty acids increased at the early stage of composting and reduced after that. The maximum content of total fatty acid was 9.7% after 6 weeks in winter, 14.8% after 6 weeks in spring and 15.8% after 2 weeks in summer. 9) The contents of inorganic components were not accumulated as composting proceeded. They were in the range of 0.9-4.4% $P_2O_5$, 1.6-2.4% $K_2O$, 2.2-5.4% CaO and 0.30-0.61% MgO. 10) CN and heavy metal contents did not show any tendency. They were in the range of 0.21-14.55mg/kg CN, 11-166mg/kg Zn, 5-65mg/kg Cu, 0.5-10.8mg/kg Cd, 6- 35mg/kg Pb, ND-33 mg/kg Cr and ND-302.04 g/kg Hg.

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Effects of Vanadate Solution Property on the Precipitation of Ammonium (Meta, Poly)Vanadate (바나데이트 수용액 특성이 암모늄(메타, 폴리)바나데이트 침전에 미치는 영향)

  • Ho-Sung Yoon;Seo Jin Heo;Yujin Park;Rina Kim;Chul-Joo Kim;Kyeong Woo Chung;Hong In Kim
    • Resources Recycling
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    • v.32 no.3
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    • pp.26-37
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    • 2023
  • Good control of the solution pH and temperature is required to recover vanadium from the water leaching solution of vanadium ore after sodium roasting. However, such adjustments could lead to aluminum-vanadium and sodium-vanadium co-precipitation, which greatly affects the efficiency of vanadium recovery. In this study, a process that can increase the efficiency of vanadium recovery as ammonium metavanadate [NH4VO3] and ammonium polyvanadate [(NH4)2V6O16·H2O] was investigated by examining the characteristics of vanadium-containing aqueous solutions during precipitation. The aluminum content of vanadium-containing water leaching solutions has a great effect on the loss of vanadium when the pH of the aqueous solution is adjusted to 9. Therefore, a process to minimize aluminum leaching is also required. In this study, ~99% or more of vanadium present in vanadium-containing aqueous solutions was precipitated and recovered as NH4VO3 by adding 3 equivalents of ammonium chloride relative to the vanadium content at pH 9 and room temperature. (NH4)2V6O16·H2O was precipitated from the aluminum-vanadium coprecipitates generated during the pH-adjustment of the aqueous solutions to 9 by dissolving the coprecipitate in the solutions at pH 2.5 and controlling their sodium content to 2,000 mg/L or less. Approximately, 98% or more of the available (NH4)2V6O16·H2O could be precipitated and recovered from a solution with a vanadium content of 2,200 mg/L and a sodium content of 1,875 mg/L at pH 2.5 by adding approximately 3 equivalents of ammonium chloride relative to the vanadium content at 95℃ or higher. The overall process could precipitate and recover, approximately 91% or more of the total vanadium in the water leaching solution as NH4VO3 and (NH4)2V6O16·H2O.

The Effect of Combination of Ondansetron and Droperidol on Prevention of Postoperative Nausea and Vomiting (Ondansetron과 Droperidol의 혼합 투여가 술 후 오심과 구토 예방에 미치는 효과)

  • Kim, Dong-Hee;Cho, Duk-Hyun
    • The Korean Journal of Pain
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    • v.14 no.1
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    • pp.46-50
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    • 2001
  • Background: Ondansetron is both a central and peripheral serotonin (5HT) receptor antagonist and droperidol is a dopaminergic blocking drug which acts centrally at the chemoreceptor trigger zone. We assessed the efficacy and adverse effects of ondansetron, droperidol or both, in the prevention of postoperative emesis during postoperative intravenous patient-controlled analgesia (PCA) using butorphanol and ketorolac medication. Methods: We studied 60 women, aged 25-60 yrs, who underwent total abdominal hysterectomy (TAH), under general anesthesia using $N_2O-O_2$-enflurane. A bolus dose of 1 mg of butorphanol and 4 mg of ondansetron were given to patients and thereafter, PCA was started using 10 mg of butorphanol and 240 mg of ketorolac mixed into the 5% D/W solution (total volume; 100 ml, 1 ml of bolus dose, and 10 min of lockout interval). We also added ondansetron 4 mg (Group O, n = 20), ondansetron 4 mg and droperidol 2.5 mg (Group OD, n = 20), or droperidol 2.5 mg (Group D, n = 20) to the PCA drug. The severity of pain, nausea, vomiting, sedation and other side effects were assessed at 0, 1, 2, 6, 12, 24, 36 and 48 hr after awakening. Results: There was no difference in the incidence of nausea and vomiting between the three group [Group O: 4 (20%) and 3 (15%), respectively; Group OD: 1 (5%) and 1 (5%), respectively; Group D: 3 (15%) and 3 (15%), respectively]. Group O showed a lower sedation score than the other groups (P < 0.05). The pain score and other side effects did not show any difference between the groups. Conclusions: The combination of ondansetron and droperidol showed no clinical benefit compared with ondansetron or droperidol alone for prevention of postoperative nausea and vomiting during postoperative PCA using butorphanol and ketorolac.

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