• Title/Summary/Keyword: $MN^+$

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Effects of MnO2on the Piezoelectric Properties of PMN-PZT-based Ceramics (PMN-PZT계 세라믹스의 압전특성에 미치는 MnO2의 영향)

  • Kim J.-C;Hwang D.-Y;Lee M.-Y;You S.-W;Kim Y.-M;Ur S.-C;Kim I.-H
    • Korean Journal of Materials Research
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    • v.14 no.5
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    • pp.334-337
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    • 2004
  • Perovskite PMN-PZT-based ceramics were prepared and the$ MnO_2$ doping effects on their piezoelectric properties were investigated. Grain size decreased with increasing the $MnO_2$ content, and the pyrochlore phase was not identified in the sintered PMN-PZT ceramics with 0.01~1.0wt% $MnO_2$. Piezoelectric voltage and charge constants were reduced and mechanical quality factor increased with increasing the $MnO_2$ content. However, electromechanical coupling coefficient slightly decreased with increasing the MnO$_2$ content without regard to the grain size.

Analysis of Oppositive Interaction between Cd and Zn Toxicity in Coastal Algae (연안 조류에서 Cd와 Zn 독성의 반대 작용 분석)

  • 이봉헌;김정호;정성옥;김성미;박흥재
    • Journal of Environmental Science International
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    • v.11 no.10
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    • pp.1069-1074
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    • 2002
  • The growth and heavy metal experiments revealed oppositive interactions between toxic metals(Zn and Cd) and Mn when the coastal diatom T. pseudonana were used. Cd and Zn inhibited the algal growth rate only at low Mn ion concentrations and this effect could be accounted for an inhibition of cellular Mn take by the toxic metals. Mn and Zn inhibited cellular Cd take and this indicated a reciprocal effects among the metals with respect to metal take. Saturation kinetics modeling of the take data was consistent with two metals competing with each other for binding to the Mn take system and with both Cd and Mn being transported into the cell by that system. Mathematical modeling of Mn and Cd take data revealed evidence fur a Cd efflux system.

Synthesis and Characterization of High Luminance ${Zn_2}{SiO_4}$:Mn Phosphors (고발광 ${Zn_2}{SiO_4}$:Mn 형광체의 제조 및 특성)

  • 성부용;정하균;박희동;김대수
    • Journal of the Korean Ceramic Society
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    • v.37 no.8
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    • pp.774-780
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    • 2000
  • In order to improve luminescence prperty of phosphors, we have synthesized Zn2SiO4:Mn phosphors by a new chemical synthetic route, i.e., the homogeneous precipitation method. This method has featured that the formation of phosphoris completed at relatively low temperature of 105$0^{\circ}C$ and the particle morphology exhibits spherical shape to be well-dispersed and uniform size. At all the Mn concentration explored, phosphors prepared by this method have exhibited the improved emission intensities. In particular, the emission intensities of phosphors with Mn doping contents between 1 at% and 3.5 at% were higher about 40% than that of commercial phosphor. On the other hand, the decay time has been decreased from 23 ms to 11 ms with increasing Mn concentration. In addition, the phosphor composition containing 3 at% Mn has displayed the most saturated color.

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$Mn^{II}$ Location and Adsorbate Interactions in (M)MnH-SAPO-34 and (W)MnH-SAPO-34 studied by EPR and Electron Spin Echo Modulation Spectroscopies

  • Back, Gern-Ho;Kim, Yang-Hee;Cho, Young-Soo;Lee, Yong-Ill
    • Journal of the Korean Magnetic Resonance Society
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    • v.6 no.2
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    • pp.118-131
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    • 2002
  • Manganese-doped H-SAPO-34 samples were prepared by an ion-exchanged reaction between H-SAPO-34 and paramagnetic Mn(II) species in methanol media and characterized by ESR and Electron Spin-Echo Modulation(ESEM) studies. In the hydrated (W)MnH-SAPO-34 measured in water, the Mn(II) ion was octahedrally coordinated with four framework oxygens and two water molecules at a displaced site IV of the eight membered ring window in the ellipsoidal cavity, while the Mn(II) ion was octahedrally coordinated to three framework oxygens and three water molecules at a displaced site I' of the six membered ring window in the ellipsoidal cavity in hydrated(M)MnH-SAPO-34 measured in methanol. The similar result was found in the experiments with methanol adsorbents except ethanol.

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Preparation and Luminescent Properties of Zn2SiO4:Mn, Ga Phosphors (Zn2SiO\4:Mn, Ga 형광체의 제조와 발광특성)

  • Lee, Ji-Young;Yu, Yun-Sik;Yu, Il
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.22 no.2
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    • pp.158-162
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    • 2009
  • $Zn_2SiO_4$:Mn green phosphors doped with Ga for PDP were synthesized by solid state reaction method. Photoluminescence measurements showed a new emission peak at around 600 nm for $Zn_2SiO_4$:Mn phosphors doped with Ga. Also, the luminescent color with doping $Ga^{3+}$ in the $Zn_2SiO_4$:Mn phosphors changed to green from yellowish green. Consequently, the new peak and charge of the luminescent color in the $Zn_2SiO_4$:Mn, Ga phosphors were attributed to $^2E{\rightarrow}^6A_2$ transition of $Mn^{4+}$.

Thermodynamic Behavior of Si in Mn-Si Melts (Mn-Si 용탕내 Si의 열역학적 거동)

  • Paek, Min-Kyu;Jang, Jung-Mock;Kang, Youn-Bae;Pak, Jong-Jin
    • Korean Journal of Metals and Materials
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    • v.50 no.2
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    • pp.116-121
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    • 2012
  • Equilibria between Mn-Si melts and $MnO-SiO_2$ slags were studied at 1673 K and 1773 K in MnO crucibles to accurately determine the thermodynamic property of the Mn-Si melts. The Unified Interaction Parameter Formalism (UIPF) was used to describe the thermodynamic property of the Mn-Si liquid. Using the UIPF, the experimental results obtained in the present study were thermodynamically analyzed to determine the activity coefficient of Si at infinite dilution and the 1st- and 2nd-order self-interaction parameters of Si in the Mn-Si melts.

ELECTRONIC STRUCTURES AND MAGNETIC PROPERTIES OF HEUSLER COMPOUNDS: XMnSb (X=Ni, Pd, and Pt)

  • Youn, S.J.;Min, B.I.;Jang, Y.R.
    • Journal of the Korean Magnetics Society
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    • v.5 no.5
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    • pp.749-752
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    • 1995
  • Electronic structures of the Heusler compounds, XMnSb (X=Ni, Pd, and Pt) are investigated systematically by using the linearized muffiu-tin orbital (LMTO) band method. LMTO band calculations yield that, by including the spinorbit interactions, the NiMnSb and PtMnSb are half-metallic, while PdMnSb is normal metallic at the experimental lattice constant. The effect of the spin-orbit interaction is substantial in PtMnSb, in contrast to NiMnSb and PdMnSb. The calculated X d and Mn 3d angular momentum projected local density of states's reveal that the hybridization between the Mn 3d X d states increases from X = Pt to Pd and Ni.

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Fast handover using MN's mobility history in PMIPv6 (PMIPv6에서 MN의 이동히스토리를 이용한 빠른 핸드오버 기법)

  • Jo, Geumsan;Choo, Hyunseung
    • Proceedings of the Korea Information Processing Society Conference
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    • 2013.05a
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    • pp.446-449
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    • 2013
  • PMIPv6(Proxy Mobile IPv6)는 네트워크 기반 이동성 지원프로토콜로 MN(Mobile Node)에 이동성을 제공하기 위해 제안되었다. PMIPv6는 기존 호스트 기반 이동성 지원 프로토콜에 비해 MN이 핸드오버 시그널링에 참여하지 않기 때문에 무선구간에서의 자원 사용량 감소, MN의 에너지 소비량 감소, 그리고 핸드오버 시그널링 비용 감소의 향상된 성능을 보인다. 하지만 PMIPv6에는 핸드오버 시그널링으로 인한 지연 및 패킷손실의 문제점이 있다. MN이 다음에 이동할 위치를 알고 핸드오버를 미리 준비할 수 있다면 빠른 핸드오버를 지원할 수 있다. 본 논문에서는 MN의 이동경로를 저장하여 이동히스토리를 구성하고 MN이 다음에 이동할 위치를 예측함으로써 빠른 핸드오버를 지원한다.

Synthesis and characterization of LiMn1.5Ni0.5O4 powders using polymerization complex method (착체중합법을 이용한 LiMn1.5Ni0.5O4 분말합성 및 특성평가)

  • Sin, Jae-Ho;Kim, Jin-Ho;Hwang, Hae-Jin;Kim, Ung-Soo;Cho, Woo-Seok
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.22 no.4
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    • pp.194-199
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    • 2012
  • The $LiMn_{1.5}Ni_{0.5}O_4$, substituting a part of Mn with Ni in the $LiMn_2O_4$, the spinel structure has good charge-discharge cycle stability and high discharge capacity at 4.7 V. In this study $LiMn_{1.5}Ni_{0.5}O_4$ powders were synthesized by polymerization complex method. The effect on the characteristics of synthesized $LiMn_{1.5}Ni_{0.5}O_4$ powders was studied with citric acid (CA) : metal ion (ME) molar ratio (5 : 1, 10 : 1, 15 : 1, 30 : 1) and calcination temperature ($500{\sim}900^{\circ}C$). Single phase of $LiMn_{1.5}Ni_{0.5}O_4$ was observed from XRD analysis on the powders calcined at low ($500^{\circ}C$) and high temperatures ($900^{\circ}C$). The crystalline size and crystallinity increased with calcination temperature. At low calcination temperature the particle size decreased and specific surface area increased as the CA molar ratio increased. On the other hand, high particle growth rate at high calcination temperature interfered the particle size reduction and specific surface area increase induced by the increase of CA molar ratio.

Effects of Supplementing with Single or Multiple Trace Minerals on Growth Performance, Fecal Mineral Excretion and Nutrient Utilization in Pullets from 1 to 18 Weeks of Age

  • Zhong, L.L.;Yao, J.H.;Cheng, N.;Sun, Y.J.;Liu, Y.R.;Wang, Y.J.;Sun, X.Q.;Xi, H.B.
    • Asian-Australasian Journal of Animal Sciences
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    • v.20 no.6
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    • pp.976-982
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    • 2007
  • This study investigated whether supplemental Cu, Fe, Zn, and Mn are needed in a practical diet for pullets. Four hundred and twenty females of an egg-laying strain (1-d-old, Lohmann Brown Layer) were randomly distributed into 4 groups, consisting of 7 replicates of 15 birds each. During the 18-week experimental period, chicks were given three basal diets in sequence, each with single or multiple Mn, Zn and Cu supplementation to improve the mineral balance gradually. In the Control, no Mn, Zn, and Cu were added; in the single Mn supplemented group (sMn) Mn was added to 120, 60, and 60 mg/kg for 1-6, 7-12, and 13-18 weeks of age, respectively; in the multiple Mn and Zn supplemented group (mMnZn), Mn was added to 180, 90, and 90 mg/kg and Zn was added to 120, 105, and 105 mg/kg for 1-6, 7-12, and 13-18 weeks of age, respectively; in the multiple Mn, Zn, Cu supplemented group (mMnZnCu), Mn, Zn, and Cu were added to the same multiple of basal Fe concentration relative to NRC (1994) recommendations. Energy and protein metabolizability were determined by subtracting energy/protein intake by energy/protein excretion (from both feces and urine) and dividing by energy/protein intake. There were no statistically significant differences between groups in terms of feed intake, final body weight or tibia length throughout the experiment. Optimal growth performance was observed in the Control, while adding trace minerals to basal diets tended to result in decreased productive performance. Protein metabolizability was increased by mMnZn and mMnZnCu treatments, but energy metabolizability was not affected. Concentrations of Mn, Zn, Cu in excreta varied greatly related to dietary content, and the retentions of Cu, Fe, Zn and Mn were all increased due to the improvement of mineral balance. Based on these results, it is suggested that the concentrations of Cu, Fe, Zn and Mn in typical basal diets used in this study were adequate for normal growth for pullets from 1 to 18 weeks of age.