• Journal of Electrochemical Science and Technology
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• v.15 no.3
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• pp.388-404
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• 2024

In the present work, the operating parameters were optimized using Box Behnken Design (BBD) in response surface methodology (RSM) to maximize the hydrogen production rate (R₁) and hydrogen production rate per unit watt consumed (R₂) of a proton exchange membrane electrolysis cell (PEMEC), a third response (R₃) which was the sum of the scaled values of R₁ and R₂ were selected to be maximized so that both hydrogen production rate and hydrogen production rate per unit watt consumed could be maximized. The major parameters which were influencing the experiment for enhancing the output responses were oxygen electrode/anode electrocatalyst loading (A), current supplied (B) and water inlet temperature (C). The commercial proton exchange membrane Nafion^® was used as the electrolyte. The acetylene black carbon (C_AB) supported IrO₂ was used as the electrocatalyst for preparing oxygen electrode/anode whereas commercial Pt (40 wt%)/C_HSA was used as the H₂ electrode/cathode electrocatalyst. The quadratic model was developed to predict the output/ responses and their proximity to the experimental output values. The developed model was found to be significant as the P values for both the responses were < 0.0001 and F values were greater than 1. The optimum condition for both the responses were O₂ electrode/anode electrocatalyst loading of 1.78 mg/cm², supplied current of 0.33 A and water inlet temperature of 54℃. The predicted values for hydrogen production rate (R₁) and hydrogen production rate per unit watt consumed (R₂) were 2.921 mL/min and 2.562 mL/(min·W), respectively obtained from the quadratic model. The error % between the predicted response values and experimental values were 1.47% and 3.08% for R₁ and R₂, respectively. This model predicted the optimum conditions reasonably in good agreement with the experimental conditions for the enhancement of the output responses of the developed PEM based electrolyser.

• Journal of computational fluids engineering
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• v.15 no.1
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• pp.1-8
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• 2010

RCCS is a passive safety-related system that removes the decay heat of VHTR when normal decay heat removal systems are in failure. Understanding thermo-hydraulics of RCCS is important to design a safer VHTR. RCCS consists of 292 cooling panels, which are placed in the reactor cavity. The layout of RCCS gives an idea that, for CFD simulations, cooling panels can be assumed to be one annulus tube. This assumption can reduce significantly the computational time, especially for the unsteady simulation. To simulate RCCS in an axisymmetric manner, three models were suggested and compared. Each model has (1) the same outer radius, (2) the same cross-sectional area (3) the same pressure drop, respectively, as the RCCS cooling panels. The steady-state simulation was conducted with these three models and the DO radiation model. It is found that over 90% of the heat from the outer wall of the reactor pressure vessel is transported to the RCCS by radiative heat transfer. The simulation with the third model, which has the same pressure drop as the design, estimates the closest wall temperature profiles to a thermo-hydraulic code, GAMMA+, result.

• The Bulletin of The Korean Astronomical Society
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• v.35 no.2
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• pp.81.2-81.2
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• 2010

Based on Yonsei Evolutionary Population Synthesis (YEPS), we have investigated the effect of horizontal branch stars (HBs) on the age-dating of simple stellar populations (SSPs). A detailed comparison of YEPS SSP with H_beta of M31 globular clusters (GCs) reveals (1) that the age dating without HB prescription gives ~5 Gyr younger ages for metal-poor M31 GCs, and (2) the age dating with HB prescription does not need any age gap between metal-poor and metal-rich GCs. This result is parallel to the well-known discrepancy in ages derived from integrated Balmer strengths and isochrone fittings of Milky Way GCs (MWGCs). Without a synthetic blue HB model, we cannot explain strong Balmer indices of metal-poor and old MWGCs. Our results suggest that the SSP model with well calibrated HBs should be used for the age-dating of SSPs to avoid a serious underestimation of ages due to the strong Balmer indices.

• 유체기계공업학회:학술대회논문집
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• 2002.12a
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• pp.298-303
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• 2002

Dispersion of coolant jets in a film cooling flow field is the result of a highly complex interaction between the film cooling jets and the mainstream. In order to investigate the effect of blowing ratios on the film cooling of turbine blade, cylindrical body model was used. Mainstream Reynolds number based on the cylinder diameter was $7.1{\times}10^4$. The effect of coolant flow rates was studied for blowing ratios of 0.7, 0.9, 1.2 and 1.5, respectively. The temperature distribution of the cylindrical model surface is visualized by infrared thermography (IRT). Results show that the film-cooling performance could be significantly improved by the shaped injection holes. For higher blowing ratio, the spanwise-diffused injection holes are better due to the lower momentum flux away from the wall plane at the hole exit.

• Journal of the Korean Ceramic Society
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• v.40 no.6
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• pp.513-518
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• 2003

La/sub 2/3-x/Li/sub 3x/□/sub 1/3-2x/TiO₃ compounds with x=0.13 and 0.12 were prepared by slow cooling (x=0.13) and rapid quenching (x=0.12) into the liquid nitrogen after sintering at 1350℃ for 6 h. Their crystal structure has been determined by Rietveld refinement of both the powder neutron and X-ray diffraction data. From neutron diffraction data, we found that the main phase was not tetragonal (P4/mmm), but trigonal (R3cH). The refinement of neutron diffraction for the slow cooled samples were in a good agreement with a new model; a mixture of trigonal (R3cH, 45.7 wt％), tetragonal (p4/mmm, 37.0 wt％), and Li/sub 0.57/Ti/sub 0.86/O₂(pbnm, 17.2 wt%), but the quenched sample was found not to contain tetragonal (p4/mmm). X-ray diffraction data couldn't be well fitted because of the Poor scattering factor of lithium ions and the similar reflection patterns among trigonal (R3cH), tetragonal (p4/mmm), and cubic (Pm3m). We also knew that one transport bottlenecks is destroyed by one La vacancy in the case of trigonal (R3cH).

• Journal of Korean Society of Environmental Engineers
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• v.32 no.7
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• pp.649-655
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• 2010

This study investigated the degradation of phenol using sonication and/or UV-C. The effects of frequency, temperature, pH in solution, argon purging, with UV intensity were estimated in sonication-only, UV-only, and the combined reaction of sonication with UV. The optimum condition for degrading phenol in the sonication-only reaction was 35 kHz, $5^{\circ}C$, and pH 4. As this condition approximately 30% degradation of phenol was achieved within 360 min. However, phenol in the UV-only at $19.3\;mw/cm^2$ under the same condition was completely degraded within 60 min. In the combined system of sonication with UV, the degradation of phenol was well fitted to first-order rate model, and phenol was completely degraded within 360 min and 45 min at UV intensity of $7.6\;mW/cm^2$($17.3{\times}10^{-3}\;min^{-1}$) and $19.3\;mW/cm^2$($138.1{\times}10^{-3}\;min^{-1}$), respectively. Adding methanol, as a radical scavenger, in the phenol degradation in the sonication reaction indicates that OH radical is a major factor in the degradation of phenol. The order of degradation efficiencies of phenol was in the order of as follows; combined reaction of sonication with UV > UV-only > sonication-only.

• Journal of Biosystems Engineering
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• v.37 no.4
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• pp.233-244
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• 2012

Purpose: The kinetic evaluation was performed for swine manure (SM) degradation and biogas generation. Methods: The SM was anaerobically digested using batch digesters at feed to inoculum ratio (F/I) of 1.0 under mesophilic conditions ($36.5^{\circ}C$). The specific gas yield was expressed in terms of gram total chemical oxygen demand (mL/g TCOD added) and gram volatile solids added (mL/g VS added) and their effectiveness was discussed. The biogas and methane production were predicted using first order kinetic model and the modified Gompertz model. The critical hydraulic retention time for biomass washout was determined using Chen and Hashimoto model. Results: The biogas and methane yield from SM was 346 and 274 mL/ TCOD added, respectively after 100 days of digestion. The average methane content in the biogas produced from SM was 79% and $H_2S$ concentration was in the range of 3000-4108 ppm. It took around 32-47 days for 80-90% of biogas recovery and the TCOD removal from SM was calculated to be 85%. When the specific biogas and methane yield from SM (with very high TVFA concentration) was expressed in terms of oven dried volatile solids (VS) basis, the gas yield was found to be over estimated. The difference in the measured and predicted gas yield was in the range of 1.2-1.5% when using first order kinetic model and 0.1% when using modified Gompertz model. The effective time for biogas production ($T_{Ef}$) from SM was calculated to be in the range of 30-45 days and the critical hydraulic retention time ($HRT_{Critical}$) for biomass wash out was found to be 9.5 days. Conclusions: The modified Gompertz model could be better in predicting biogas and methane production from SM. The HRT greater than 10 days is recommended for continuous digesters using SM as feedstock.

• Publications of The Korean Astronomical Society
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• v.7 no.1
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• pp.231-253
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• 1992

A model for the distribution of stars in the disk and the spheroid of our Galaxy is reexamined from an edge-on view of the Galaxy obtained by selecting infrared sources from the IRAS Point Source Catalog. The sources are counted as a function of galactic latitude. longitude and $12{\mu}m$ apparent magnitude. The source counts are reasonably separated into the disk component and the spheroid component contributions and each of the contributions is further interpreted as a convolution of a spatial density distribution and a luminosity function based on the least-square fit method. The spatial density of the disk component has an exponential radial scale length of $h_R{\sim}2.6\;kpc$ and the vertical distribution follows a canonical $sech^2$ law with a scale height $h_z{\sim}240\;pc$. The distribution of the spheroid component can be represented by an oblate spheriod with an axis ratio $k{\sim}0.61$ and a de Vaucouleurs' $r^{1/4}$ law with an effective radius of $R_e{\sim}120\;pc$. The steep density gradient of the spheroid component is consistent with that of late M giants in the central bulge. The luminosity functions of the disk and the spheroid component stars resemble respectively those of the K luminosity function of disk M giants (Garwood and Jones 1986) and the bolometric luminosity function of M giants in bulge fields (Frogel et al, 1990).

• Journal of the Korea Academia-Industrial cooperation Society
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• v.18 no.3
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• pp.122-126
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• 2017

The aim of this study was to develop a device for solving the heating problem of living space using heated air, utilizing a simple air heater type collector for solar energy. At the present time, this study assessed the possibility of a development system through theoretical calculations for the amount of available energy according to the size change of the air-heated solar energy collector. To produce and supply hot water using the heat energy of the sun, hot water at $100^{\circ}C$ or less was produced using a flat or vacuum tube type collector. The purpose of this study was to research the air heating type solar collector that utilizes heating energy with heating air above $75^{\circ}C$, by designing and manufacturing an air piping type solar collector that is a simpler type than a conventional solar collector system. The analysis results were obtained for the generated air temperature ($^{\circ}C$) and the production of air (kg/h) to determine the performance of air heating by an air-heated solar collector according to the heat transfer characteristics in the collector of the model when a specified amount of heat flux was dropped into a solar collector of a certain size using PHOENICS, which is a heat flow analysis program applying the Finite Volume Method. From the analysis result, the temperature of the air obtained was approximately $40.5^{\circ}C$, which could be heated using an air heating tube with an inner diameter of 0.1m made of aluminum in a collector with a size of $1.2m{\times}1.1m{\times}0.19m$. The production of air was approximately 161 m3/h. This device can be applied to maintain a suitable environment for human activity using the heat energy of the sun.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2000.04a
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• pp.251-253
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• 2000

본 연구는 대전 1,2 공단 지역을 대상으로 발암 금속 6종(As Be, Cd, Cr, Ni 및 Pb)을 포함한 15종의 독성 금속을 선정하여 유도결합 플라스마 분광법(ICP-MS)을 이용하여 3년간 분석하고 이 농도 자료에 근거하여 각 금속의 확률론적 농도를 평가하고자 한다. 대기중 부유분진은 대전시 대화동(대전 1,2 공단내 대화동 동사무소 건물 옥상)에 high-volume air sampler(Graseby Andersen : SAUB-10H Model, USA)를 약 0.85$\textrm{m}^3$/min으로 운전하여 시료당 공기량이 약 1,200 $\textrm{m}^3$가 유지되도록 포집하였다. (중략)