• Title/Summary/Keyword: $LiNbO_3$

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The growth and characteristics $K_3$$Li_2$$Nb_5$$O_{15}$ of single crystals ($K_3$$Li_2$$Nb_5$$O_{15}$ 단결정의 성장과 특성에 관한 연구)

  • 김진수;김정남;김태훈;노지현;진병문
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.9 no.5
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    • pp.463-469
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    • 1999
  • The potassium lithium niobate $K_3$$Li_2$$Nb_5$$O_{15}$ single crystals were growing in $K_x$$Li_{1-x}$$NbO_3$ (x = 0.4~0.6) chemical formular by the Czorchralski method. Crystal growth is studied in two orientations with growth along a-axis and c-axis. We have subjected this crystal to x-ray diffraction studies and found that they are single-crystalline and belong to tetragonal system with the lattice parameters a = b = 12.577 $\AA$ and c = 3.997$\AA$. The temperature dependence of dielectric constant was measured in the region of the phase transition. Curie temperature and diffuseness of phase transition are influenced by composition concentration. The composition and cation distribution of ferroelectric TB-type niobate crystals has a strong influence on the ferroelectric properties. Growth condition, optical transmittance, etching pattern and dielectric properties are presented and discussed.

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Piezoelectric Properties and Microstructures of $Li_2O$ excess $(Na_{0.47}K_{0.47}Li_{0.06})NbO_3$ Ceramics ($Li_2O$ 첨가에 따른 $(Na_{0.47}K_{0.47}Li_{0.06})NbO_3$ 세라믹스의 압전특성과 미세조직의 변화)

  • Kim, Min-Soo;Jeon, So-Hyun;Park, Jeong-Joo;Jeong, Soon-Jong;Min, Bok-Ki;Song, Jae-Sung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.256-256
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    • 2007
  • As a candidate for lead-free piezoelectric materials, dense ($(Na_{0.47}K_{0.47}Li_{0.06})NbO_3$ (LNKN6) ceramics were developed by conventional sintering process. Sintering temperature was lowered by adding $Li_2O$ as a sintering aid. Abnormal grain growth in the LNKN6 ceramics was observed with varying $Li_2O$ content. The electrical properties of LNKN6 ceramics were investigated as a function of $Li_2O$ concentration. When the sample sintered at $1000^{\circ}C$ for 4h with the addition of 1 mol% $Li_2O$, electromechanical coupling factor ($k_p$) and piezoelectric coefficient ($d_{33}$) of LNKN6 ceramics were found to reach the highest values of 0.40 and 184 pC/N, respectively.

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New Fabrication Method of $Ti:LiNbO_3$ Waveguide with Suppressed Out-Diffusion ($Li_2O$의 삼출이 없는 $LiNbO_3$ 광도파로의 제조방법)

  • 김상혁;김상국;조재철;최상삼
    • Korean Journal of Optics and Photonics
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    • v.2 no.3
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    • pp.149-152
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    • 1991
  • We report a new method of fabricating a Ti:LiNb03 waveguide with no out-diffusion by coating the waveguide with $SiO_2$ thin film. It was coated before diffusion process, and the $LiO_2$ out-diffusion was prevented in the diffusion process. We compare the near field patterns of the guided modes between the typical waveguide and the waveguide fabricated by new method proposed here.

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Microwave Dielectric Properties of Ca(Li1/4Nb3/4)O3-CaTiO3 Ceramics added with Zinc-borosilicate Glass Frit (Zinc-borosilicate Glass Frit 첨가에 따른 Ca(Li1/4Nb3/4)O3-CaTiO3 세라믹스의 마이크로파 유전 특성)

  • Yoon Sang-Ok;Kim Kwan-Soo;Jo Tae-Hyun;Shim Sang-Heung;Park Jong-Guk
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.6
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    • pp.524-530
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    • 2006
  • $xCa(Li_{1/4}Nb_{3/4})O_{3}-(1-x)CaTiO_{3}$ ceramics were sintered under the presence of zinc-borosilicate(ZBS) glass and resultant microwave dielectric properties were investigated with a view to applying the composition to low-temperature co-fired ceramic(LTCC) technology. The addition of $5{\sim}15wt%$ ZBS glass ensured successful sintering below $900\;^{\circ}C$. In general, increased addition of ZBS glass increased sinterability but it decreased the quality factor($Q{\times}f_{0}$) significantly due to the formation of an excessive liquid and second phases. As for the addition of $CaTiO_3$, the dielectric constant(${\epsilon}_r$) and temperature coefficient of resonant frequency(${\tau}_f$) increased, while the quality factor($Q{\times}f_{0}$) did not show an apparent change. The sintered $0.9Ca(Li_{1/4}Nb_{3/4})O_{3}-0.1CaTiO_{3}$ specimen at $900\;^{\circ}C$ with 10 wt% ZBS glass demonstrated 39.6 in dielectric constant(${\epsilon}_r$), 4,400 in quality factor$(Q{\times}f_{0}),\;and\;-11ppm/^{\circ}C$ in temperature coefficient of resonant frequency(${\tau}_f$).

A Study on Electrooptic $Ti:LiNbO_3$ Mach-Zehnder integrated-optic interferometers for Electric-Field Measurement (전계측정용 전기광학 $Ti:LiNbO_3$ Mach-Zehnder 집적광학 간섭기에 관한 연구)

  • Jung, Hong-Sik
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.48 no.12
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    • pp.15-22
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    • 2011
  • Integrated-optic symmetric/asymmetric Mach-Zehnder interferometers at $1.3{\mu}m$ wavelength were studied as sensing part for electric-field measurement system. The devices were simulated based on the BPM software and fabricated utilizing Ti-diffused $LiNbO_3$ channel optical waveguides and lumped-type electrodes. A half-wave voltage of $V_{\pi}$=6.6V and modulation depth of 100% and 75% for a symmetric structure were measured for 200Hz and 1kHz electrical signal bandwidth, respectively. By the way, almost half-maximum power transmission was observed for asymmetric interferometers with ${\pi}$/2 intrinsic phase difference. Expected experimental measurements were observed for 1kHz electrical signal bandwidth.