• Title/Summary/Keyword: $L_C$-property

Search Result 458, Processing Time 0.023 seconds

Mechanical Properties and Changes in Microstructure for IN738LC with Thermal Exposure (열 노출에 의한 IN738LC의 기계적 특성 및 미세조직 변화)

  • Yoon, Yong-Keun;Kim, Jae-Hoon;Jeong, Dong-Hee;Yoo, Keun-Bong
    • Transactions of the Korean Society of Mechanical Engineers A
    • /
    • v.35 no.10
    • /
    • pp.1155-1160
    • /
    • 2011
  • High-strength nickel-based super alloys have been widely used in aircraft engines, vessel engines, and turbine blades because of their high strength and excellent fatigue and oxidation resistance. In this study, tests were carried out to determine the total strain range and temperature for high-strength nickel-based super alloys. Prepared specimens of IN738LC were exposed to temperatures of $871^{\circ}C$ and $982^{\circ}C$ for 1,000.10,000 h. These specimens were subjected to tests of mechanical properties and microstructure observations. The changes in mechanical properties were related to changes in ${\gamma}$ according to the thermal exposure time.

Synthesis and Property Evaluation of Cationic Gemini Surfactants Using 1,4-Butanediol (1,4-부탄디올을 이용한 양이온 제미니 계면활성제의 합성 및 물성 평가)

  • Kim, Kyung-Sil;Park, Jong-Kwon;Cho, Jung-Eun;Shin, Hye-Lin;Jeong, Noh-Hee
    • Applied Chemistry for Engineering
    • /
    • v.30 no.1
    • /
    • pp.17-22
    • /
    • 2019
  • In this study, cationic gemini surfactants were synthesized by increasing the length of the hydrophobic chain and using 1,4-butanediol as a spacer, and the result was confirmed by $^1H-NMR$. The synthesized surfactant was a white powder, and Kraffts point was below $0^{\circ}C$. Surface tension measurements revealed that the evaluated critical micelle concentration (c.m.c) was $1.8{\times}10^{-3}{\sim}6.5{\times}10^{-4}mol/L$ with a surface tension of 22.5~26.1 dyne/cm at the c.m.c. The initial foam height for CG 14-6E-14 estimated by Ross-Miles method was 16 cm and after 5 minutes the height was 14 cm. It was confirmed that the initial foam force and foam stability were the highest. The foam test and emulsion stability of synthesized gemini cationic surfactants were also compared to those of cetyltrimethylammonium bromide (CTAB), a commoly used surfactant.

Preparation, Structure, and Property of Re(Nar)$(PR_3)_2Cl_3$, $(PR_3 = PMe_3, PEt_3, P(Ome)_3;Ar = C_6H_5, 2,6-i-Pr_2-C_6H_3)$

  • 박병규;최남선;이순우
    • Bulletin of the Korean Chemical Society
    • /
    • v.20 no.3
    • /
    • pp.314-320
    • /
    • 1999
  • Several bisphosphine- and bisphosphite-substituted Re-imido complexes have been prepared from Re(NPh)(PPh3)2Cl3, 1, and Re(N-C6H3-i-Pr2)2Cl3(py), 4. Compound 1 reacted with trimethyl phosphate (P(OMe)3) to give a mixture of two isomers,mer,trans-Re(NPh)(P(OMe)3)2Cl3, 2, and fac,cis-Re(NPh)(P(OMe)3)2Cl3, 2a. In this reaction, the mer,trans-isomer is a major product. Complex 1 also reacted with triethylphosphine (PEt3) to exclusively give mertrans-Re(NPh)(PEt3)2Cl3, 3. Compound 4 reacted with trimethylphosphine (PMe3) to give mer,trans-Re(N-C6H3-i-Pr2)(PMe3)2Cl3, 5, which was converted to mer-Re(N-C6H3-i-Pr2)(PMe)(OPMe3)Cl3, 6, on exposure to air. Crystallographic data for 2: monoclinic space group P21/n, a = 8.870(2) Å, b = 14.393(3) Å, c = 17.114(4) Å, β = 101.43(2)°, Z = 4, R(wR2) = 0.0521(0.1293). Crystallographic data for 5: orthorhombic space group P212121, a = 11.307(l) Å, b = 11.802(l) Å, c = 19.193(2) Å, Z = 4, R(wR2) = 0.0250(0.0593). Crystallographic data for 6: orthorhombic space group P212121, a = 14.036(4) Å, b = 16.486(5) Å, c = 11.397(3) Å, Z = 4, R(wR2) = 0.0261(0.0630).

Effect of Yonggak-san on the Immuno-regulatory and Apoptosis of Leukemia cells (용각산의 면역조절 및 백혈병세포의 아폽토시스에 미치는 효과)

  • Oh Chan Ha;Kwon Jin;Lee Kwang Gyu
    • Journal of Physiology & Pathology in Korean Medicine
    • /
    • v.16 no.5
    • /
    • pp.932-937
    • /
    • 2002
  • The purpose of this research was to investigate the effect of Yonggak-san (YGS) on the immune reaction and apoptosis of leukemia cells. Administration of YGS(500 mg/kg) enhanced proliferation of splenocytes, thymocytes and mesenteric lymph node cells, and also YGS accelerated subpopulation of splenic Band T, thymic T and mesenteric lymph node-T lymphocytes, especially significantly increased CD4+-TH cells in BALB/c mice. YGS accelerated phagocytic activity and production of nitric oxide in peritoneal macrophages. YGS induced apoptosis of transplanted-L1210 cells in vivo, increased apoptotic cell death of cultured-L1210 and/or Molt4 human leukemia cells, decreased of mitochondrial transmembrane potential of both cells in vitro. These results suggest that YGS have an immune-regulatory effect and anti-cancer property.

Chemical Structural Characteristics of the Amphoteric Imidazoline Surfactants (이미다졸린형 양쪽성계면활성제의 화학구조적 특성)

  • Ro, Y.C.;Nam, K.D.
    • Applied Chemistry for Engineering
    • /
    • v.5 no.5
    • /
    • pp.749-755
    • /
    • 1994
  • Imidazoline compounds have been developed in many industrial fields(eg. cosmetic, etc.). These materials can be used in almost all pH ranges and recently its use is successively increased because of nonirritative property. Since the concern of safety has enlarged at industrial application, naturally the use of amphoteric surfactants with new special properties has more. We report general properties of chemical structures of imidazoline surfactants effect.

  • PDF

IRRADIATION EMBRITTLEMENT OF CLADDING AND HAZ OF RPV STEEL

  • Lee J.S.;Kim I.S.;Jang C.H.;Kimura A.
    • Nuclear Engineering and Technology
    • /
    • v.38 no.5
    • /
    • pp.405-410
    • /
    • 2006
  • Microstructural features and their related mechanical property changes in the 309L cladding and the heat affected zone (HAZ) of SA508 cl.3 steel were investigated through the use of TEM, tensile and small punch (SP) tests. The specimens were irradiated at 563 K up to the neutron fluences of $5.79{\times}10^{19}n/cm^2$ (>1MeV). The microstructure of the clad was mainly composed of a fcc ${\gamma}-phase$, a low percentage of bcc ${\delta}-ferrite$, and a brittle ${\sigma}-phase$. Along the weld fusion line there formed a heavy carbide precipitation with a width of $20{\sim}40{\mu}m$, showing preferential cracking during plastic deformation. The yield stress and ductile-to-brittle transition temperature (DBTT) of the irradiated clads increased. The origin of the hardening and the shift of the DBTT are discussed in terms of the irradiation-produced defect clusters of a fine size and brittle ${\sigma}-phase$.

Effect of rheological properties on chemical absorption of carbon dioxide with MEA

  • Park, Sang-Wook;Kim, Tae-Young;Park, Byoung-Sik;Lee, Jae-Wook
    • Korea-Australia Rheology Journal
    • /
    • v.16 no.1
    • /
    • pp.35-45
    • /
    • 2004
  • Rates of chemical absorption of $CO_2$ in water-in-oil (w/o) emulsion were measured in a flat-stirred vessel at $25^{\circ}C$. The w/o emulsion was composed of aqueous monoethanolamine (MEA) droplets as a dispersed phase and non-Newtonian viscoelastic benzene solutions of polybutene (PB) and polyisobutylene (PIB) as a continuous phase. The liquid-side-mass transfer coefficient ($k_L$) was obtained from the dimensionless empirical equation containing Deborah number expressed as the properties of pseudoplasticity of the non-Newtonian liquid. $k_L$ was used to estimate the enhancement factor due to chemical reaction between $CO_2$ and MEA in the aqueous phase. PIB with elastic property of non-Newtonian liquid made the rate of chemical absorption of $CO_2$ accelerate compared with Newtonian liquid.

The effect of fly ash/slag on the property of reactive powder mortar designed by using Fuller's ideal curve and error function

  • Hwang, C.L.;Hsieh, S.L.
    • Computers and Concrete
    • /
    • v.4 no.6
    • /
    • pp.425-436
    • /
    • 2007
  • This study is mainly focused on applying Fuller's ideal gradation curve to theoretically design blended ratio of all solid materials of a reactive powder mortar (RPM), also known as reactive powder concrete (RPC), with the aid of error function, and then to study the effect of fly ash/slag on the performance of RPM. The solid particle is assumed to be spherical particles. Then, the void volume of paste ($V_{\nu}$) and the paste content with specific quality can be obtained. As conclusion, under Fuller's ideal grading curve, the amount of fly ash/slag mixture is higher than that with silica fume along due to it better filled the void within solid particle and obtains higher packing density.

한국산 도꼬마리 추출물의 항균효과 및 분리 정제

  • 김현수;신재욱
    • Microbiology and Biotechnology Letters
    • /
    • v.25 no.2
    • /
    • pp.183-188
    • /
    • 1997
  • Antimicrobial activity of various extracts of Xanthium strumarium L. was tested against 25 strains of bacteria, yeast and fungus. The crude ethylacetate extract exhibited strong growth inhibition to the tested strains with the exception of partial Gram-negative bacteria. The property of antimicrobial compound was very stable under heat treatment at $120^{\circ}C$, but it was unstable in acid (pH 3.0) and alkali (pH 10.0) treatment. The antimicrobial compounds were purified by boiling water extraction, ethylacetate extraction, charcoal column chromatography, silica gel column chro- matography and reverse phase HPLC. The purified compound A and B were detected in a single peak (each above 98% purity) through the HPLC analysis. The compound A and B showed a strong growth inhibition against Gram-negative and positive bacteria in the agar diffusion method. When tested by the FDA method using the esterase, compound A mainly inhibited the growth of bacteria and compound B showed the growth inhibition of both bacteria and yeasts.

  • PDF

Immuno-Regulatory Effects of Cheongsimondam-tang (청심온담탕의 면역조절 효과)

  • Park Min Chul;Jin Jae Ho;Jung Han Sol;Lee Kwang Gyu
    • Journal of Physiology & Pathology in Korean Medicine
    • /
    • v.16 no.6
    • /
    • pp.1223-1229
    • /
    • 2002
  • The purpose of this research was to investigate the effect of Cheongsimondam-tang(CSODT) on the activity of immune cell and anti-carcinogenic effect of mouse leukemia cell. The addition of CSODT(1 ㎍/ml) enhanced the proliferation of cultured-splenocytes and thymocytes. And also administration of CSODT(500 ㎍/kg) accelerated subpopulation of splenic and thymic T lymphocytes especially CD4/sup +/-T/sub H/ cells in BALB/c mice. CSODT treatment decreased cell proliferation and increased apoptotic cell death of cultured-L1210 leukemia cells, and induced apoptosis in addition to decreased mitochondrial transmembrane potential (ΔΨm) of transplanted-L1210 cells in vivo. These results suggest that CSODT have a cellular immuno-regulatory effect and anti-cancer property action.