• 한국재료학회지
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• 제14권8호
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• pp.587-594
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• 2004

Three-dimensionally ordered macroporous (3DOM) structures of the $LiCoO_2$ electrode materials for Li secondary batteries were fabricated by using the close-packed arrays of PMMA spheres served as templates. In order to successfully fabricate the cathode materials with highly ordered array form, the metal citrates were applied to new precursors. The precursor/template composites were prepared by the infiltration with metal citrate precursors into the voids of template. By removing the PMMA templates, then, the inverse opal structures with the uniform pores of narrow size distribution were resulted. It was confirmed that the 3DOM $LiCoO_2$ material is to take a single phase of rocksalt (R3m) structure. In addition, 3DOM $LiNiO_2$ and $LiMn_{2}O_4$ cathode materials were fabricated using an identical preparation procedure. Also, the morphology of the 3DOM cathode materials calcined at $500^{\circ}C\;to\;700^{\circ}C$ was observed by scanning electron microscope.

• 한국결정성장학회지
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• 제15권2호
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• pp.51-56
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• 2005

We prepared orthorhombic $LiMnO_2$ by emulsion drying method. The thermo-gravimetric measurement and X-ray diffraction studies indicated that the orthorhombic $LiMnO_2$ phase was formed above $800^{\circ}C$ by oxygen evaporation process from $LiMn_2O_4$ and $Li_2MnO_3$. In this process, we could control the ordering of $LiMnO_2$ with heating rate. It was observed that electrochemical properties depended on the ordering of this material; the ordered one exhibited good capacity retention, whereas the disordered one suffered capacity fading upon cycling, especially in the 3 V region. Transmission electron microscopic (TEM) study showed that this difference is related with difference in the stress relieving effects in the samples.

• Nuclear Engineering and Technology
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• 제54권7호
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• pp.2427-2434
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• 2022

Series of unequal quantity Nd/Ce co-doped ceramic nuclear waste forms, (Gd, Nd)₂(Zr, Ce)₂O₇, were prepared to tailor its ordered pyrochlore or disordered fluorite structure. The phase transition, microtopography, and elemental composition of the ceramic samples were systematically investigated, especially the effect of order-disorder structure on the chemical stability. It was confirmed that unequal quantity of Nd/Ce could synchronously replace the Gd/Zr-sites of Gd₂Zr₂O₇. And the phase transition of order-disorder structure could be successfully tailored by regulating the average cationic radius ratio of (Gd, Nd)₂(Zr, Ce)₂O₇ series. The elements of Gd, Nd, Zr, and Ce are uniformly distributed in the ordered or disordered structures. The MCC-1 leaching results showed that (Gd, Nd)₂(Zr, Ce)₂O₇ pyrochlore ceramic nuclear waste forms had excellent chemical stability, whose elements' normalized leaching rates were as low as 10^-4-10^-7 g·m^-2·d^-1 after 7 days. In particular, the chemical stability of disordered structure was superior to that of ordered structure. It was proposed that the force constant and the closest packing were changed with the structure transformation resulting the chemical stability difference.

• 열처리공학회지
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• 제22권3호
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• pp.155-161
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• 2009

An investigation of the deformation behavior of ${\gamma}'-Ni_3Al$ single crystals containing fine dispersion of disordered ${\gamma}$ particles was performed for several different crystal orientations. Deformation structures were observed by the weak-beam method of transmission electron microscopy (TEM). The critical resolved shear stress (CRSS) for (111) [$\bar{1}$01] slie. increases with increasing temperature in the temperature range where (111) slip operates. The CRSS for (111) [$\bar{1}$01] slip is dependent on crystal orientation in the corresponding temperature range. The temperature where the strenjlth reaches a maximum is dependent on crystal orientation; the higher the ratio of the Schmid factors of (010) [$\bar{1}$01] to that of (111) [$\bar{1}$01], the higher the peak temperature. The peak temperatures were increased by the precipitation of y particles for the samples of all orientations. Electron microscopy of deformation induced dislocation arrangements under peak temperature has revealed that most of dislocations are straight screw dislocations. The mobility of screw dislocations decreases with increasing temperature. Above the peak temperature, dislocations begin to cross slip from the (111) [$\bar{1}$01] slip system to the (010) [$\bar{1}$01] slip system, thus decreasing the strength.