• Title/Summary/Keyword: $In_2S_3$

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Total Synthesis of Sodium (3S,4R)-3-[2-(2-Aminothiazol-4-yl)-(Z)-2-methoxyiminoacetamido]-4-methoxymethyl-2-azetidinone-1-sulfonate from D-Aspartic Acid

  • Chung Bong Young;Kim, Jin Yeon;Nah Cha Soo;Han Kee Jong;Park, Jong Ok
    • Bulletin of the Korean Chemical Society
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    • v.13 no.3
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    • pp.315-316
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    • 1992
  • Sodium (3S,4R)-3-[2-(2-aminothiazol-4-yl)-(Z)-2-methoxyi minoacetamido]-4-methoxymethyl-2-azetidinone-1- sulfonate (2) was synthesized in fourteen steps from D-aspartic acid. Starting from D-aspartic acid, (3S,4R)-3-amino-1-t-butyldimethylsilyl-4-methoxym ethyl-2-azetidinone (12) was synthesized in ten steps. Acylation of the amino group of 12 with $2-amino-{\alpha}-(methoxyimino)-4-thiazoleacetic$ acid, desilylation, sulfonation, and ion exchange afforded sodium (3S,4R)-3-[2-(2-aminothiazol-4-yl)-(Z)-2-methoxyi minoacetamido]-4-methoxymethyl-2-azetidinone-1- sulfonate (2). This new ${\beta}-lactam$ compound 2 showed low antibacterial activities.

Development of Optimal Nutrient Solution of Tomato(Lycopercicon esculentum Mill.) in a Closed Soilless Culture System (순환식 수경재배에 적합한 토마토 배양액 개발)

  • Yu, Sung-Oh;Bae, Jong-Hyang
    • Journal of Bio-Environment Control
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    • v.14 no.3
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    • pp.203-211
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    • 2005
  • The experiment was conducted to investigate the nutrition absorption pattern in the growth stages and develope the optimal nutrient solution hydroponically grown the tomato in closed substrate culture system with the nutrient solution of National Horticultural Research Station in Japan into 1/2S, 1 S, and 2S. When plant was grown in 1/2 S, the growth and yield were high and the pH and EC in the rooting zone were stable. Suitable composition of nutrient solution for tomato was $NO_3-N$ 7.1, $PO_{4}$-P 2.1, K 4.0, Ca 3.1, Mg 1.2, and $SO_{4}-S\;1.2\;me{\cdot}L^{-1}$ in the early growth stage and $NO_3-N$ 6.5, $PO_4-P$ 2.3, K 3.4, Ca 3.1, Mg 1.1, and $SO_4-S\;1.1\;me{\cdot}L^{-1}$ in the late growth stage by calculating a rate of nutrient and water uptake. To estimate the suitability for the nutrient solution of tomato in a development of optimum nutrient solution of tomato developed by Wonkwang university in korea (WU), plant was grown in perlite substrate supplied with different solution and strengths(S) by research station for greenhouse vegetable and floricultuin in the Netherlands (Proefstation voor tuinbouw onder glas te Naaldwijk; PTG) of 1/2 S, 1 S and 2 S, respectively, The growth was good at the PTG and WU of 2 S in early growth stage, and at the WU 2S in late growth stage. The highest yield of tomato obtained in the WU of 2 S, although blossom-end rot was appeared in all treatments. pH and EC in root zone of WU of 2 S were stable during the early and late growth stage. Therefore when plant was grown in WU of 2 S, N and P content in the nutrient solution need to low, according N and P content of their leaves were high in WU of 2 S.

Effect of Sulphate on the Formation of $C_3S$ and Its Properties ($C_3S$의 生成反應 및 特性에 미치는 黃酸鹽의 影響)

  • 김병권;최상흘;한기성
    • Journal of the Korean Ceramic Society
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    • v.25 no.3
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    • pp.207-216
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    • 1988
  • Effect of $SO_3$ on the formation of $C_3S$ and its properties were investigated through studies for diffusion of reacting component, the size variation of $C_3S$ and compositional change of the phases in the clinker. When less than 2.0% of $SO_3$ was added to the clinker composition, the formation of $C_3S$ was enhanced, however, addition of more than 2.0% of $SO_3$ rather restrained the reaction remarkably. The diffusion coefficient of Si into the melt was about $3.6~4.2{\times}10^{-7}Cm^2$/sec and it was slightly decreased with the amount of $SO_3$. The crystal size of $C_3S$ formed in the clinker was grown gradually according to the amount of $SO_3$, when more than 1.0% of $SO_3$ was added. With increasing of $SO_3$ content in the clinker composition of CaO and decreasing of $SiO_2$ were found in the melt of the clinker. Consequently, it is considered that the decreasing of $C_3S$ formation is caused by dissolution and transportation of CaO component into liquid phase is interrupted.

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Effect of Sulfur on Corn(Zea mays L.) Seedling Growth under Nutrient Solution Culture (양액재배하(養液栽培下)에서 유황시비(硫黃施肥)가 옥수수(Zea mays L.) 생육(生育)에 미치는 영향(影響))

  • Kim, Moo-Sung;Kim, Se-Young;Oh, Jong-Seo
    • Korean Journal of Soil Science and Fertilizer
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    • v.28 no.4
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    • pp.306-311
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    • 1995
  • A nutrient solution culture experiment was conducted in the greenhouse of Suwon Campus, Kyung-Hee University from May 22 to July 10, 1995, to determine the effects of sulful application on seedling growth of Kwanganok and Hwengsungok cultivars of corn. Plants were harvested at weekly interval for seven weeks, at which time plant height, leaf area and dry matter yield of corn seedling were measured. Sulfer was treated with $MgSO_4{\cdot}7H_2O$ so that sulfur concentrations of cultural solution are 0, 68, 136 and 204ppm for treatments of without sulfer(-S), control(C), twofold concentration(2S) of control and threefold contration(3S) of control, respectively. The plant height, leaf area and dry matter yield during the seven weeks of Kwanganok cultivar was decreased in order of C>2S>3S>-S, 2S>C>3S>-S and 2S>3S>C>-S application pot, respectively. In Hwengsungok cultivar, those were decreased in order of C>-S>3S>2S, C>3S>2S>-S and C>3S>-S>2S application pot, respectively. The total plant height, leaf area and dry matter yield during the whole period of Kwanganok and Hwengsungok cultivars were decreased in the seedling grown under without sulfur treatment compared with the other sulfur treatments. In Hwengsungok cultivar, plant height, leaf area and dry matter yield of seedlings were increased more in control sulfur treatment pot than the other sulfur treatment pot during the whole period. The crop growth rates of seedling of both cultivars in all treatments were slowly increased until the 3th week after planting and its were showed up and down CGR's thereafter, but Hwengsungok cultivar with C treatment pot maintained a steady increase in CGR until the end of the experiment period.

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A Study on Decomposition in Synthesis of $BaTiO_3$ by Soild-solid Reaction ($BaTiO_3$고상반응 합성시 분해 반응의 고찰)

  • Kim, Jong-Ock;Lim, Dae-Young
    • The Journal of Natural Sciences
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    • v.4
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    • pp.85-93
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    • 1991
  • In solid reaction of the eqimolecular mixture of $BaCO_3$ and $TiO_2$, $CO_2$ generates by the following reaction ; $BaCO_3 + TiO_2\longrightarrow$ $BaTiO_3 + CO_2$ The solid reaction is studied as the kinetics of decomposition reaction with DTA-TG. The results are as follows. 1. $BaCO_3$ with is coexisted with $TiO_2$ decompose at lower temperature than pure $BaCO_3$. The reason is decreasing free eneragy of products. 2. Carter's equation is more important than Jander's equation in solid reaction of $BaCO_3$ decomposi-tion. The activation energy obtained by Carte r's equation is 42.8 Kcal/mol.

Optical Properties of PbS Quantum Dots (QDs) Precipitated in Nd3+-Containing Glasses

  • Park, Won Ji;Heo, Jong
    • Journal of the Korean Ceramic Society
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    • v.52 no.2
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    • pp.146-149
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    • 2015
  • Silicate glasses with different $Nd_2O_3$ concentrations were prepared through conventional melt-quenching methods while PbS quantum dots (QDs) were precipitated through heat treatment. The peak wavelengths of absorption and the photoluminescence of PbS QDs shifted to the short-wavelength side as the concentration of $Nd_2O_3$ increased. The electron energy loss spectroscopy (EELS) indicated that $Nd^{3+}$ ions were preferentially distributed inside the PbS QDs instead of the glass matrix. In addition, there was no significant change in the lifetimes of the $Nd^{3+}:^4F_{3/2}$ fluorescence between the as-prepared glass ($607{\mu}s$) and the heat-treated glass($576{\mu}s$). $Nd^{3+}$ ions were surrounded by oxygen instead of sulfur and the Nd-O clusters probably acted as nucleating centers for the formation of PbS QDs inside the glasses.

Overexpression of Heat Shock Factor Gene HsfA3 Increases Galactinol Levels and Oxidative Stress Tolerance in Arabidopsis

  • Song, Chieun;Chung, Woo Sik;Lim, Chae Oh
    • Molecules and Cells
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    • v.39 no.6
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    • pp.477-483
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    • 2016
  • Heat shock factors (Hsfs) are central regulators of abiotic stress responses, especially heat stress responses, in plants. In the current study, we characterized the activity of the Hsf gene HsfA3 in Arabidopsis under oxidative stress conditions. HsfA3 transcription in seedlings was induced by reactive oxygen species (ROS), exogenous hydrogen peroxide ($H_2O_2$), and an endogenous $H_2O_2$ propagator, 2,5-dibromo-3-methyl-6-isopropyl-p-benzoquinone (DBMIB). HsfA3-overexpressing transgenic plants exhibited increased oxidative stress tolerance compared to untransformed wild-type plants (WT), as revealed by changes in fresh weight, chlorophyll fluorescence, and ion leakage under light conditions. The expression of several genes encoding galactinol synthase (GolS), a key enzyme in the biosynthesis of raffinose family oligosaccharides (RFOs), which function as antioxidants in plant cells, was induced in HsfA3 overexpressors. In addition, galactinol levels were higher in HsfA3 overexpressors than in WT under unstressed conditions. In transient transactivation assays using Arabidopsis leaf protoplasts, HsfA3 activated the transcription of a reporter gene driven by the GolS1 or GolS2 promoter. Electrophoretic mobility shift assays showed that GolS1 and GolS2 are directly regulated by HsfA3. Taken together, these findings provide evidence that GolS1 and GolS2 are directly regulated by HsfA3 and that GolS enzymes play an important role in improving oxidative stress tolerance by increasing galactinol biosynthesis in Arabidopsis.

Physiological Response of Potato Variety to Soil Salinity (토양염농도에 따른 감자 품종들의 생장특성)

  • Kim, Sun;Yang, Chang-Hyu;Jeong, Jae-Hyeok;Choi, Weon-Young;Lee, Kyu-Seong;Kim, Si-Ju
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.58 no.2
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    • pp.85-90
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    • 2013
  • This study was conducted to examine the basis for the information to select the suitable potato varieties grown in new reclaimed land. The potatoes of five varieties were planted in the port with 4 different electrical conductivities of saturated extracts of soil taken the Saemangeum reclamation area, which was made of non-treatment salt and three concentrations of salt treatment, 1.6 dS $m^{-1}$, 3.2 dS $m^{-1}$, 4.8 dS $m^{-1}$, respectively. All of the potato varieties were uniformly emerged without missing plant in all treatment groups, even 4.8 dS $m^{-1}$ treatment group. According to the salt concentration of soil, required date to the emergence of the potato comparing to non-treatment salt was delayed 3-4 days in 1.6 dS $m^{-1}$, 6-10 days in 3.2 dS $m^{-1}$, 7-13 days in 4.8 dS $m^{-1}$, respectively, and the number of its branch decreased by 14-58% comparing to non-treatment salt depending on varieties. Since the increase of the salt concentration of the soil was more serious the decrease of the number of its branch, but plant height tended to increase when branch number per plant was small, which was depending on more number of its branch than salt concentration. Fresh tuber yield of potato comparing to non-treatment salt were decrease 33.7% in 1.6 dS $m^{-1}$, 59.5% in 3.2 dS $m^{-1}$, 79.3% 7-13 days in 4.8 dS $m^{-1}$, respectively. The threshold EC starting the growth inhibition of fresh weight decreased was 1.2 dS $m^{-1}$ for Chudong, 1.8 $m^{-1}$ for Chubeak, 1.9 $m^{-1}$ for Chugang and Chuyeong, and 2.0 $m^{-1}$ for Sumi, and EC which decreased 50% of dry weight index was 2.4 dS $m^{-1}$ for Chubaek, 2.45 dS $m^{-1}$ for Chudong, 2.81 dS $m^{-1}$ for Chugang, 3.03 dS $m^{-1}$ for Chuyeong, and 3.29 dS $m^{-1}$ for Sumi. The present results suggest that Sumi is considered to the suitable potato variety grown on saline soils.

Determination of Leaching Requirements in the Unripened Tidal Reclaimed Paddy Fields (간척초기답의 제염용수량 결정을 위한 기초연구)

  • 손재권
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.42 no.2
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    • pp.55-62
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    • 2000
  • In order to make the reasonable irrigation plan in the unripended tidal reclaimed paddy fields, the estimation of irrigation water requirements by soil textures and water management methods for the normal growth of crops is very important . This study was carried out to determine leaching requirements before cultivating crops. For the purpose of this study, the physical and chemical properties of soil samples used in the desalinization experiments were analyzed, and change of salinity by supplying water and leaching water were investigated in the experimental field with lysimeters. As a result considering the soil textures, desalinization effects of good drainage soils(S1) were better than those of poor drainage soils (S2). In the changes of salinity of the soils with supplying water by water management methods, among the good grainage soils with culvert treatment(S1CW), salinity of S1CW3 with 1, 120mm and S1W4 with 1, 440mm supplying water were 2.6dS/m and 1.1dS/m respectively, and salinity of S1NW4 with 1.680mm among those non-culvert treatment (S1NW) was 3.0dS/m, less than critical salanity value 3.0dS/m. On the other hand, of the poor drainage soils with cultvert treatment , salinity of S2CW3 was ranged 9.4-6.0dS/m with supplied water, and that of non-culverted treatment S2NW as 12.3-8.4dS/m.

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Isolation Frequency and Antimicrobial Susceptibility of Streptococcus spp. from Clinical Specimens (임상검체에서 분리된 사슬알균종의 분리빈도와 항균제 감수성)

  • Shin, Hyun-Sung;Park, Youn-Bo
    • Korean Journal of Clinical Laboratory Science
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    • v.40 no.1
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    • pp.6-17
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    • 2008
  • From the total 116,429 clinical specimens submitted to "C" hospital from January 2005 to December 2006, 2,195 strains of streptococci were isolated. Twenty four species of Streptococcus were identified with 0.1~19.8% isolation frequencies, of which S. pneumoniae was 19.8%, S. agalactiae 16.2%, S. anginosus 9.8%, S. constellatus 5.0%, S. oralis 3.9%, S. mitis 3.3%, S. pyogenes 2.7%, S. salivarius subsp. salivarius 2.2%, S. sanguinis 1.9%. For S. pneumoniae, clinical specimens showing over 9.0% isolation rate were 82.8% in sputum, 9.2% in blood, and for Streptococcus species other than S. pneumoniae, 18.0% in sputum, 16.0% in urine and 9.7% in blood. The antimicrobial agents that showed over 90.0% susceptibility were cefotaxime, gatilfloxacin, imipenem, levofloxacin, linezolid, moxifloxacin, rifampin and sporfloxacin in S. pneumoniae, ampicillin, cefotaxime, cetriaxone, levofloxacin, linezolid, penicillin, quinupristin/dalfopristin and vancomycin in S. agalactiae, chloramphenicol, clindamycin, levofloxacin and vancomycin in S. anginosus, levofloxacin, vancomycin in S. constellatus subsp. constellatus, vancomycin in S. oralis, vancomycin in S. mitis, chloramphenicol, clindamycin, levofloxacin, quinupristin/dalfopristin and vancomycin in S. pyogenes, chloramphenicol, levofloxacin and vancomycin in S. salivarius subsp. salivarius, chloramphenicol, levofloxacin and vancomycin in S. bovis II, chloramphenicol, levofloxacin, quinupristin/dalfopristin and vancomycin in S. dysgalactiae subsp. dysgalactiae, levofloxacin, chloramphenicol and vancomycin in the whole group of 10 Streptococcus spp. other than Streptococcus pneumoniae.

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