• Title/Summary/Keyword: $HoMnO_3$

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The Effect of Cr from STS Interconnect on the Polarization Resistance of LSCF Cathode (스테인리스 스틸 연결재의 Cr이 LSCF 양극의 분극저항에 미치는 영향)

  • Hwang, Ho-June;Choi, Gyeong-Man
    • Journal of the Korean Ceramic Society
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    • v.44 no.12
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    • pp.715-719
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    • 2007
  • STS444 with or without $La_{0.9}Sr_{0.1}MnO_3$ (LSM)-coating was contacted to $La_{0.6}Sr_{0.4}Co_{0.2}Fe_{0.8}O_3$ (LSCF) cathode on various electrolyte materials and the polarization resistance $(R_p)$ was measured by impedance spectroscopy. By making a symmetric half-cell and contacting only one side of the cathode with the interconnect, the effect of chromium (Cr) poisoning was separated from the aging effects. When the LSCF cathode was contacted with LSM-coated STS (stainless steel), $R_p$ of LSCF was lower than that contacted with the uncoated STS. Impedance patterns measured for the working electrode (W.E.), the counter electrode (C.E.) at $600^{\circ}C$ in air were analyzed. Normalized data of net Cr effect showed that $Ce_{0.9}Gd_{0.1}O_2$ (GDC) electrolyte is more tolerant to the chromium poisoning than $La_{0.9}Sr_{0.1}Ga_{0.8}Mg_{0.2}$ (LSGM) or 8 mol% $Y_2O_3-doped$ $ZrO_2$ (YSZ) electrolytes.

Concentration and Geochemical Phases of Heavy Metals in Marine Sediments in the Vicinity of the Coal-fired Power Plant of Korea (석탄화력발전소 주변해역 퇴적물 내의 중금속원소의 함량과 지화학적 존재형태)

  • Lee, Doo-Ho;Jeong, Yeon-Tae
    • Journal of Environmental Impact Assessment
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    • v.9 no.4
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    • pp.301-314
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    • 2000
  • Marine surface sediments in the vicinity of Samcheonpo coal-fired power plant were analyzed by a total analysis($HF+HNO_3+HClO_4$) and sequential extraction procedure for heavy metals in order to investigate the total concentrations and geochemical phases of heavy metals. The result showed that the concentrations of Cr, Cu, Fe and Zn were within ranges typical for coastal areas, which reflected the mineralogical composition of the sediments in the studied area. However, the distributions of Cd, Co, Mn, Ni and Pb were rather different from the former, indicating that these heavy metals had a different origin, or that they were affected by a different geochemical mechanism. Chemical partitioning of heavy metals using sequential extraction procedure revealed that Cu, Fe, Pb, Zn were significantly bound to the residual phases of the sediments, whereas carbonate phases contained considerable amounts of Mn. The significant association of Pb with the exchangeable fraction also indicated that Pb was more mobile and bioavailable than Cu, Fe, Mn, Zn.

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Effects of Scutellaria Radix Extract on the Membranous Nephropathy Induced by Cationic Bovine Serum Albumin in Mouse Model (황금(黃芩)이 Cationic Bovine Serum ALbumin투여로 유발된 Membranous Nephropathy Mouse Model에 미치는 영향)

  • Kim, Man-Ho;Cho, Chung-Sik;Kim, Cheol-Jung
    • The Journal of Korean Medicine
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    • v.30 no.5
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    • pp.61-76
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    • 2009
  • Background: Membranous nephropathy (MN) is the most common cause of adult nephrotic syndrome worldwide and has been defined as granular subepithelial deposition of immune complexes along the glomerular basement membrane (GBM). MN has few known treatments and gives rise to side effects under treatment with steroids and immunosuppressives. Objective: The purpose of this experimental study was to demonstrate the effects of Scutellariae Radix extract (SRE) treatment on MN mouse model induced by cBSA. Methods: We divided mice into 4 groups. The Normal group had no treatment. We induced MN mouse model to the other 3 groups by injecting cBSA into the abdominal cavity. The control group was treated with cBSA (10 mg/kg, i.p.) only. The second group, 'SRE-250', was treated with cBSA (10 mg/kg, i.p.) and SRE (250 mg/kg, p.o.). The third group, 'SRE-500', was treated with cBSA (10 mg/kg, i.p.) and SRE (500 mg/kg, p.o.). After cBSA and SRE treatment for 4 weeks, gain in body weight, 24hrs proteinuria, serum albumin, total cholesterol, triglyceride, BUN and creatinine of all groups were measured. TNF-$\alpha$, IL-6, IL-1$\beta$, IL-10, IFN-$\gamma$, IgA, IgM and IgG levels of all groups were gauged. H&E staining and electron microscopy of the kidney were observed. Results: SRE showed significant decrease in the 24hrs proteinuria, serum triglyceride, BUN, TNF-$\alpha$, IL-6, serum IgA, IgM and IgG levels compared with the control group. SRE showed increase in the serum IL-10 and IFN-$\gamma$ levels compared with control on RT-PCR. SRE considerably decreased in the thickening of the GBM on H&E staining and deposition of electron-density on electron microscopy of the kidney compared with the control. Conclusions: According to the above results, it is suggested that SRE decreases the symptoms of MN induced by cBSA in mouse model. Therefore, SRE seems to be applicable to MN in clinical practice.

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Determination of Chemical Compositions and Oxidation States for Corrosion Products in LiCl Molten Salts

  • Park, Yong-Joon;Pyo, Hyung-Ryul;Kim, Do-Yang;Jee, Kwang-Yong;Kim, Won-Ho
    • Nuclear Engineering and Technology
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    • v.32 no.5
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    • pp.514-520
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    • 2000
  • The mechanism of corrosion behavior has to be understood clearly to select an optimum material for handling molten salts to be used in the oxide reduction process of PWR spent fuel. In this study, the oxidation states of corrosion products on the surface of Inconel 600 and 800H as well as their chemical compositions and structural informations were determined by using XPS, ICP-AES, AAS, EPMA and XRD after the corrosion experiment with lithium molten salts at 75$0^{\circ}C$ for 25 hours. Nickel and oxygen were detected from the corrosion products on the surface of Inconel plates and chromium was found to be dissolved out into lithium molten salts leaving cracks on the surface. The corrosion products were identified as metal oxides such as Fe$_2$O$_3$, Cr$_2$O$_3$, NiO, NiFe$_2$O$_4$and MnO by using XPS and XRD.

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A study of standardizing Critical-Current Measurements for coated conductor I (고온초전도 coated conductor의 임계전류 측정 표준화 연구 I)

  • Oh, Sang-Soo;Lee, Nam-Jin;Kim, Ho-Sup;Youm, Do-Jun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.363-364
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    • 2009
  • For the application of superconductor technology, we need critical properties of superconductors such as a critical current ($I_c$). $I_c$ is varied as processing method by action of flux pinning center. Our research activities are reported on the establishment of standard measurement method for critical current in coated conductor. And then, we researched pre-studies for standardization of critical current evaluation method using IEC/TC 90 standard.

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Study for Manufacturing of Zinc Sulfate from Electric Arc Furnace Dust by Hydrometallrugical Process (제강분진으로부터 습식제련공정에 의한 황산아연의 제조 연구)

  • Dong Ju Shin;Sung-Ho Joo;Dongseok Lee;Shun Myung Shin
    • Resources Recycling
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    • v.32 no.1
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    • pp.33-41
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    • 2023
  • Herein, we selectively recovered Zn and produced ZnSO4 from electric arc furnace dust using a hydrometallurgical process. The analysis of the properties of the electric arc furnace dust revealed that the Fe content (9.9%) was relatively low while the Mn content (19%) was high as compared to the composition of general dust. Therefore, an appropriate hydrometallurgical process was designed based on the properties of the raw materials. In the leaching process involving the use of 1.6 M sulfuric acid and 20% solid-liquid ratio at 60℃ for 1 h, 85% of the Zn and Mn got dissolved while the Fe was not leached. To selectively recover Zn, a solvent extraction process using D2EHPA as the extractant was chosen, and 99% of the Zn was extracted using 0.8 M D2EHPA with 32% saponification and an O/A ratio of 2 using counter-current 3-stage extraction. Mn was entirely scrubbed with an aqueous sulfuric acid solution of pH 1.5. Finally, Zn was concentrated and stripped using 1.5 M sulfuric acid at an O/A ratio of 4 using counter-current 4-stage stripping. The stripping solution contained 40 g/L of Zn, and 99.9% of ZnSO4∙H2O was obtained by vacuum distillation.

Removal of copper ion from the waste water by Manganese Nodules using fixed bed and column (고정형(固定形) Bed와 컬럼을 이용(利用)한 망간 단괴(團塊)에 의한 폐수(廢水) 중의 구리이온 제법(除去))

  • Park, Kyung-Ho;Nam, Chul-Woo;Kang, Nam-Hee
    • Resources Recycling
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    • v.20 no.5
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    • pp.64-68
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    • 2011
  • The typical properties of manganese nodules are its high porosity and high specific surface area and manganese in nodules is existed as ${\delta}$-MnO$_2$. These properties suggest that manganese nodules ran be used as an adsorbent for heavy metal ions. This study investigated the practical applicability for the removal of copper ions in the waste water by manganese nodules as an adsorbent using fixed column and fix bed systems. Manganese nodules of 1kg (size 1-3 cm) can absorb 4.0g Cu in fixed column system and 2.3g Cu in fixed bed system from waste water for 3 hours respectively.

Effects of Substrate and Annealing Temperature on the Characteristics of Mn-Ni oxide Thin Films (Mn-Ni계 산화물 박막의 특성에 대한 기판과 열처리 온도의 영향)

  • Kim, Cheol-Su;Cho, Seong-Ho;Lee, Yong-Seong;Cho, Byeong-Ryeol;Kim, Byeong-Su
    • Korean Journal of Materials Research
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    • v.8 no.5
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    • pp.424-428
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    • 1998
  • Mn-Ni oxide thin films for NTC thermistor application were deposited on alumina substrates by using rf magnetron sputter. Effects of various substrate temperatures and annealing temperatures on the microstructure. crystal phase, resistivity and B constant were investigated. Microstructure of the films deposited below 178$^{\circ}C$ was fibrous microcrystalline and at 32$0^{\circ}C$and 40$0^{\circ}C$their microstructure was changed to columnar grain structure. After annealing at 90$0^{\circ}C$, the microstructure was transformed to equiaxed grain structure. Most of the phases were mixture of cubic spinel and $Mn_2O_2$ The crystal phase of the film deposited at 40$0^{\circ}C$ was changed to cubic spinel after annealing above 700"c. As the substrate temperature increased, the resistivity and B constant were greatly decreased, and these values become low and stable after annealing between $600^{\circ}C$and $700^{\circ}C$, All thin films deposited in the present study showed NTC thermistor characteristicsstics.

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A Characteristics Analysis of Archaeological Chemistry on the Ceramics Excavated from Kiln Site in Dongkok-Town, Gimje in Korea (김제 청도리 동곡마을 도요지 출토 도자기의 고고화학적 특성 분석)

  • Park, Yeong A;Kim, Gyu-Ho;Jeon, Yu Ree;Kim, Na-Young
    • Journal of Conservation Science
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    • v.33 no.2
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    • pp.131-147
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    • 2017
  • The purpose of this study is to analyze the characteristics of Punchong and Whiteware pottery excavated from the kiln site in Dongkok-Town, Gimge. Scientific analysis is carried out to evaluate the physical and chemical properties of the body and glaze. The physical properties indicate the gradual development of the production technology with respect to the kiln operating conditions and period. In chemical properties, the ceramic body is found to be made of raw materials from the same source, but the mixing method depends on the type of Punchong and Whiteware pottery, the production kiln, and period. Whiteware pottery is manufactured with less over 1.3% of the colorant content and more about 1.2% of the $K_2O$ flux content than Punchong pottery. This compositions allow easier vitrification at the same temperature. These characteristics which is low colorant content and high flux content become more prominent as lately. The ceramic glaze is likely to have changed the type of raw materials used after 16~17C, as the contents of MgO, $TiO_2$, MnO, $P_2O_5$ are less three to ten times than 15C.

Magamtism and Metamorphism of the Proterozoic in the Northeastern Part of Korea: Tectonomagmatic Characteristics of the Imgye Hornblendites (한국(韓國) 북동부지역(北東部地域) 원생대(原生代)의 화성활동(火成活動)과 변성작용(變成作用) : 임계(臨溪) 각섬암(角閃岩)의 암석성인(岩石成因)과 조구조적(造構造的) 특징(特徵))

  • Chang, Ho-Wan;Lee, Dong-Hwa
    • Economic and Environmental Geology
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    • v.26 no.4
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    • pp.499-505
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    • 1993
  • The Imgye hornblendites occur as intrusive sills or dykes within the mylonite zone developed along the contact boundary between Precambrian Jungbongsan granite and Cambrian Jangsan quartzite or Myobong slate formations. The hornlendites belong to the subalkaline and tholeiitic series. In tectonomagmatic discrimination diagrams such as $TiO_2-K_2O-P_2O_5$, 2Nb-Zr/4-Y and $TiO_2-10MnO-10P_2O_5$, the hornblendites are classified into continental- and island-arc tholeiites. The hornblendites show fractionated REE patterns with $(La/Yb)_{CN}$ ranging from 3.73-4.56. In incompatible element abundance variations, the hornblendites show distinctive positive and negative anomalies for Rb and Nb, respectively, and unfractionated patterns of immobile incompatible elements such as Y and Yb. The REE patterns of the hornblendites are also similar to those of typical continental back-arc tholeiites and those of the Precambrian Okbang amphibolites in the Socheon-meon, Bonghwa-gun. Accoiding to geochemical characteristics above-mentioned, the hornblendites seem to have been formed from tholeiitic magmas of depleted upper mantle source, contaminated by crustal material en route to continental back-arc basin.

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