• Title/Summary/Keyword: $Hg_{1-x}Cd_{x}Te$

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Properties of Infrared Detector and Growth for HgCdTe Epilayers

  • Hong, Kwang-Joon;You, Sang-Ha
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.11a
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    • pp.116-119
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    • 2003
  • [ $Hg_{1-x}Cd_xTe$ ] (MCT) was grown by hot wall epitaxy method. Prior to the MCT growth, the CdTe (111) buffer layer was grown on the GaAs substrate at the temperature of 590 C for 15 min. When the thickness of the CdTe buffer layer was 5 m or thicker, the full width at half maximum values obtained from the x-ray rocking curves were found to significantly decrease. After a good quality CdTe buffer layer was grown, the MCT epilayers were grown on the CdTe (111) /GaAs substrate at various temperature in situ. The crystal quality for those epilayers was investigated by means of the x-ray rocking curves and the photocurrent experiment. The photoconductor characterization for the epilayers was also measured. The energy band gap of MCT was determined from the photocurrent measurement and the x composition rates from the temperature dependence of the energy band gap were turned out.

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Tunneling Current Contribution to RoA of $Hg_{1-x}Cd_{x}$Te Photodiodes ($Hg_{1-x}Cd_{x}$Te 광다이오드에서 터널링 전류가 RoA에 미치는 영향)

  • 박장우;곽계달
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.29A no.10
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    • pp.42-48
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    • 1992
  • RoA is an important figure of merits for estimating the performance of p-n junction infrared detectors. This paper presents the tunneling current contribution to RoA of $Hg_{1-x}Cd_{x}$Te n$^{+}$-p juction photodiodes. Then, a diffusion model, a thermal generation-recombination model, an indirect tunneling model via trap, and a band-to-band direct tunneling model are considered to calculate RoA. Using these models, RoA depending on temperature, doping concentration, and mole fraction is calculated. Also from these results, under various operating conditions the dominant dark current mechanisms cna be understood.

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Growth of HgCdTe thin film by the hot-wall epitaxy method (Hot-wall epitaxy 방법에 의한 HgCdTe 박막 성장)

  • 최규상;정태수
    • Journal of the Korean Vacuum Society
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    • v.9 no.4
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    • pp.406-410
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    • 2000
  • Using the hot-wall epitaxy method, we grew a $Hg_{1-x}Cd_xTe$ (MCT) thin film in-situ after growing (111) CdTe of 9 $mu \textrm{m}$ as a buffer layer. The value of FWHM of double crystal x-ray diffraction rocking curve was 125 arcsec and the surface morphology was clean with a small roughness of 10 nm. From measuring the photocurrent of the grown MCT thin film, the maximum peak wavelength and the cut-off wavelength were 1.1050 $\mu\textrm{m}$ (1.1220 eV) and 1.2632 $\mu\textrm{m}$ (0.9815 eV), respectively. This peak wavelength corresponds to the peak of the band gap due to the intrinsic transition of the photoconductor. Therefore, the MCT thin film could be used as the photoconducting detector sensing a near-IR wavelength band from 1.0 to 1.6 $\mu\textrm{m}$.

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Fabrication of a Large-Area $Hg_{1-x}Cd_{x}$Te Photovoltaic Infrared Detector ($Hg_{1-x}Cd_{x}$Te photovoltaic 대형 적외선 감지 소자의 제작)

  • Chung, Han;Kim, Kwan;Lee, Hee-Chul;Kim, Jae-Mook
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.31A no.2
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    • pp.88-93
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    • 1994
  • We fabricated a large-scale photovoltaic device for detecting-3-5$\mu$m IR, by forming of n$^{+}$-p junction in the $Hg_{1-x}Cd_{x}$Te (MCT) layer which was grown by LPE on CdTe substrate. The composition x of the MCT epitaxial layer was 0.295 and the hole concentration was 1.3${\times}10^{13}/cm^{4}$. The n$^{+}$-p junction was formed by B+ implantation at 100 keV with a does 3${\times}10^{11}/cm^{2}. The n$^{+}$ region has a circular shape with 2.68mm diameter. The vacuum-evaporated ZnS with resistivity of 2${\times}10^{4}{\Omega}$cm is used as an insulating layer over the epitaxial layer. ZnS plays the role of the anti-reflection coating transmitting more than 90% of 3~5$\mu$m IR. For ohmic contacts, gole was used for p-MCT and indium was used for n$^{+}$-MCT. The fabrication took 5 photolithographic masks and all the processing temperatures of the MCT wafer were below 90$^{\circ}C$. The R,A of the fabricated devices was 7500${\Omega}cm^{2}$. The carrier lifetime of the devices was estimated 2.5ns. The junction was linearly-graded and the concentration slope was measured to be 1.7${\times}10^{17}/{\mu}m$. the normalized detectivity in 3~5$\mu$m IR was 1${\times}10^{11}cmHz^{12}$/W, which is sufficient for real application.

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MBE로 성장한 CdTe 박막의 photoconductivity

  • 임재현;허유범;류영선;전희창;현재관;강철기;강태원
    • Proceedings of the Korean Vacuum Society Conference
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    • 1998.02a
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    • pp.113-113
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    • 1998
  • C CdTe와 HgCdTe는 광전소자나 태양전지,x 선 및 y 선 감지 소자 그리고 적외선 감지소 자로의 웅용둥으로 인하여 많은 연구가 진행되고 있다. 광전소자를 제작함에 있어서 깊은 준위나 얄은 준위에 있는 몇들은 운반자 수명에 매우 큰 영향을 미치고 있음에도 불구하고 광전도도 측정에 의한 운반자 수명 연구에 대하여는 보고된 것이 별로 없다. 이에 본 논문에서는 CdTe 시료의 광전도도를 측정하여 운반자 수명 및 깊은 준위의 위치를 알아보았다 M MBE방법을 이용하여 CdTe 기판위에 In을 도핑한 CdTe를 성장하였다. 광전도 붕괴(PCD) 측정은 300 K에서부터 400 K까지 온도를 변화시켜주면서 측정을 하였고 광원으로서 G GaP- LED를 사용하였으며 전압 신호를 읽기 위하여 Tektronix 2430A 오실로스코프를 이용하 였다 .. Fig. 1. 에서 보인바와 같이 광전도 붕괴곡선은 접선으로 나타낸 하나의 지수 함수적 붕 괴(a2exp( -t/ r 2))보다는 설선으로 나타낸 두 개의 지수함수적 붕괴(alexp( νr 1)+a2exp( -νr 2)) 가 더욱 잘 실험결과와 일치함을 알 수 있었다. 이러한 것은 과잉 전하에 대한 깊은준위를 가 지고 있는 반도체물질에서 일반적으로 관찰되는 것으로 시료가 n 형이기 때문에 소수 운반자 인 정공의 벚에 의한 것으로 생각된다 .. Fig. 2. 에서는 운반자 수명의 온도에 대한 변화를 나타 낸 것이다. 온도가 증가함에 따라 운반자 수명이 감소하는 경항올 보이고 있으며 이것올 이용 하여 딪익 활성화 에너지를 계산 하여 본 결과 0.35 eV 와 0.43 eV염을 알수 있었다.

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Study on electrical properties of photoconductors for radiation detector application based on liquid crystal (액정 기반 방사선 검출기 적용을 위한 광도전체의 전기적 특성 연구)

  • Kang, Sang-Sik;Choi, Young-Zoon;Lee, Mi-Hyun;Kim, Hyun-Hee;No, Si-Chul;Cho, Kyu-Suck;Park, Ji-Koon
    • Journal of the Korean Society of Radiology
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    • v.4 no.2
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    • pp.27-30
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    • 2010
  • A X-ray optical modulator measures x-ray dose using optical transmissivity ratio change of the liquid crystal cell. To apply in this optical modulator, we made photoconductor films and compared electrical properties of this films in this study. Photoconductors are deposited on ITO glass with $200{\mu}m$ using the percipitation method and print method. I-V test was conducted to alalyze electrical properties of this films and measured darkcurrent and SNR was acquired using the measured dark current and sensitivity. As a result of this measurements, $HgI_2$ film made by precipitation method is lower(about 40%) darkcurrent than $HgI_2$ films made by precipitation method and sensitivity is two times greater than print method. And we knew that $HgI_2$ films were also 10~25 times greater SNR at $1v/{\mu}m$ than $PbI_2$, PbO, CdTe film made by precipitation method. This results suggest that $HgI_2$ films made by precipitation method has improved characteristics of x-ray dose meter by applying in x-ray optical modulator.

Mineralogy and Geochemistry of Iron Hydroxides in the Stream of Abandoned Gold Mine in Kwangyang, Korea (광양 폐금광 수계에 형성된 철수산화물에 대한 광물학적 및 지구화학적 특성)

  • Park, Cheon-Young;Jeoung, Yeon-Joong;Kim, Seoung-Ku
    • Journal of the Korean earth science society
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    • v.22 no.3
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    • pp.208-222
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    • 2001
  • Geochemical investigations on suspended amorphous iron oxide material from the Kwangyang gold mine and its surrounding area, Cheonnam, Korea have been carried out. The sediments samples were collected from 11 location along Kwangyang mine area and were air dried and sieved to -80 mesh. These samples consist mainly of iron, silicon and alumina. The Fe$_2$O$_3$ contents ranges from 17.9 wt.% to 72.3 wt.%. The content of Fe$_2$O$_3$ increase with decreasing Si, Al, Mg, Na, K, Mn, and Ti, whereas the contents of Te, Au, Ga, Bi, Cd, Hg, Sb, and Se increase in the amorphous stream sediments. Amorphous stream sediments have been severely enriched for As (up to 54.9 ppm), Bi (up to 3.77 ppm), Cd (up to 3.65 ppm), Hg (up to 64 ppm), Sb (up to 10.1 ppm), Cu (up to 37.1 ppm), Mo (up to 8.86 ppm), Pb (up to 9.45 ppm) and Zn (up to 29.7 ppm). At the upstream site, the Au content (up to 4.4 ppm) in the amorphous stream sediments are relatively high but those contents decrease with distance of mine location. The content of Ag (up to 0.24 ppm) were low in upstream site but those contents increase significantly in the downstream sites. The X-ray diffraction patterns of the samples have virtually no sharp and discrete peaks, indicating that some samples are amorphous or poorly-ordered. The quartz, goethite, kaolinite and illite were associated in amorphous stream sediments. The infrared spectra for amorphous stream sediments show major absorption bands due to OH stretching, adsorbed molecular water, sulfate and Fe-O stretching, respectively.

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The Design and Fabrication of Conversion Layer for Application of Direct-Detection Type Flat Panel Detector (직접 검출형 평판 검출기 적용을 위한 변환층 설계 및 제작)

  • Noh, Si-Cheol;Kang, Sang-Sik;Jung, Bong-Jae;Choi, Il-Hong;Cho, Chang-Hoon;Heo, Ye-Ji;Yoon, Ju-Seon;Park, Ji-Koon
    • Journal of the Korean Society of Radiology
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    • v.6 no.1
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    • pp.73-77
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    • 2012
  • Recently, Interest to the photoconductor, which is used to flat form X-ray detector such as a-Se, $HgI_2$, PbO, CdTe, $PbI_2$ etc. is increasing. In this study, the film layer by using the photoconductive material with particle sedimentation was fabricated and evaluated. The quantization efficiency of the continuous X-ray with the 70 kVp energy bandwidth was analyzed by using the Monte Carlo simulation. With the results, the thickness of film with 64 % quantization efficiency was 180 ${\mu}m$ which is similar to the efficiency of 500 ${\mu}m$ a-Se film. And $HIg_2$ film has the high quantization efficiency of 74 % on 240 ${\mu}m$ thickness. The electrical characteristics of the 239 ${\mu}m$ $Hgl_2$ films produced by particle sedimentation were shown as very low dark current(under 10 $pA/mm^2$), and high sensitivity(19.8 mC/mR-sec) with 1 $V/{\mu}m$ input voltage. The SNR, which is influence to the contrast of X-ray image, was shown highly as 3,125 in low driving voltage on 0.8 $V/{\mu}m$. With the results of this study, the development of the low-cost, high-performance image detector with film could be possible by replacing the film produced by particle sedimentation instead to a-Se detector.