• Title/Summary/Keyword: $H_v-group$

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Formation and Growth of Cu Nanocrystallite in Si(100) by ion Implantation

  • Kim, H.K.;Kim, S.H.;Moon, D.W.
    • Journal of the Korean Vacuum Society
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    • v.4 no.S2
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    • pp.115-130
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    • 1995
  • In order to produce Cu nanocrystallite in silicon wafer, the implantation technique was used. The samples of silicon (100) wafers were implanted by $Cu^+$ ions at 100 keV and with varying the doses at room temperature. Post-annealing was performed at $800^{\circ}C$ with Ar environment. To investigate the formation of Cu nanocrystallite with ion doses and growth process by thermal annealing, SIMS and HRTEM(high resolution transmission electron microscopy)spectra were studied.

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Electrochemical Characteristics of Ruthenium Oxide Electrode-Organic Electrolyte System (유기전해액에서 루테늄산화물 전극의 전기화학적 특성)

  • Doh, Chil-Hoon;Jin, Bong-Soo;Moon, Seong-In;Yun, Mun-Soo;Choi, Sang-Jin;Yug, Gyeong-Chang;Park, Jeong-Sik;Kim, Sang-Gil;Lee, Joo-Won
    • Journal of the Korean Electrochemical Society
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    • v.6 no.3
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    • pp.169-173
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    • 2003
  • Electrochemical capacitor made with metal oxide electrode uses rapid and reversible protonation/deprotonation of metal oxide material under the aqueous acidic solution, generally. Electrochemical stability window of aqueous electrolyte-type capacitor is narrow compared to that of organic electrolyte-type capacitor. Electrochemical characteristics of electrochemical capacitor made with metal oxide electrode and lithium or ammonium cation based organic electrolyte were evaluated. Electrochemical capacitor based on $RuO_2$ electrode material and 1M $LiPF_6$ in mixed solvents of EC, DEC, and EMC has anodic and cathodic specific capacitance of 145 and $142F/g-RuO_2{\cdot}nH_2O$, respectively, by using cyclic voltammetry with scan rate of 2mV/sec $g-RuO_2$ in potential range of $2.0\~4.2V(Li|Li^+))$.

Separation and Recovery of Ce, Nd and V from Spent FCC Catalyst (FCC 폐촉매로부터 Ce, Nd 및 V의 분리 회수 프로세스)

  • Jeon, Sung Kyun;Yang, Jong Gyu;Kim, Jong Hwa;Lee, Sung Sik
    • Applied Chemistry for Engineering
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    • v.8 no.4
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    • pp.679-684
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    • 1997
  • The major constituents in spent FCC catalysts are Si, Al, Fe, Ti, alkali metals and some others. The spent catalyst is also composed small amounts of rare metals such as Ce, Nd, Ni and V. The selective adsorption and concentration of Ce and Nd from the leaching solution of spent FCC catalysts with sulfuric acid($0.25mol/dm^3$) were carried out by the column method with a chelate resin having a functional group of aminophosphoric acid type. Ce and Nd were separated from eluate liquor containing Al, Nd and V by the precipitation process with oxalic acid. Vanadium is purified from chloride ion coexistance by solvent extraction, employing tri-n-octyl phosphine oxide as extractant with Al in the raffinate solution. Rare metals with the purity of 99 percent were obtained from the spent FCC catalyst.

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Synthesis and Crystal Structure of 1-(dimethylbromotin)-2-[(methoxyl)methly]-o-carborane $(C_{16}H_{21}B_{10}BrOSn)$ (1-(Dimethylbromotin)-2-[(methoxyl) methly]-o-carborane $(C_{16}H_{21}B_{10}BrOSn)$의 합성 및 결정 구조)

  • Cho Sung Il;Kang Sang Ook;Chang K.
    • Korean Journal of Crystallography
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    • v.15 no.2
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    • pp.88-92
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    • 2004
  • An organometallic compound, $(C_{16}H_{21}B_{10}BrOSn)$, was synthesized from o-carborane, closo-1-[(methoxyl)methyl]-o-carborane $(HCab^o)$, and $SnMe_2Br_2$. The molecular structure of this complex has been determined by X-ray diffraction. Crystallographic data: orthorhombic, space group Pna2, a = 17.9292(15)$\AA$, b= 7.2066(4)$\AA$, c=13.0582(10)$\AA$, Z=4, V=1687.2(2) $\AA^3$. The structure was solved by direct methods and refined by full-matrix least-squares methods to give a model with a reliability factor R=0.0574 for 1724 reflections.

Chemical Modification of the Human Ether-a-go-go-related gene (HERG) $K^+$ Current by the Amino-Group Reagent Trinitrobenzene Sulfonic Acid

  • Jo Su-Hyun;Choi Se-Young;Yun Ji-Hyun;Koh Young-Sang;Ho Won-Kyung;Lee Chin-O.
    • Archives of Pharmacal Research
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    • v.29 no.4
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    • pp.310-317
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    • 2006
  • We investigated the effects of trinitrobenzene sulfonic acid (TNBS), an amino-group reagent, on the human ether-a-go-go-related gene (HERG) $K^+$ channels expressed in Xenopus oocytes. TNBS neutralizes the positively charged amino-groups of peptide N-terminal and lysine residues. External application of TNBS at 10 mM for 5 min irreversibly shifted the curves for currents at the end of the pulse and tail currents of HERG to a more negative potential and decreased the maximal amplitude of the $I_{tail}$ curve $(I_{tail,max})$. TNBS had little effect on either the activated current-voltage relationship or the reversal potential of HERG current, indicating that TNBS did not change ion selectivity properties. TNBS shifted the time constant curves of both activation and deactivation of the HERG current to a more hyperpolarized potential; TNBS's effect was greater on channel opening than channel closing. External $H^+$ is known to inhibit HERG current by shifting $V_{1/2}$ to the right and decreasing $I_{tail,max}$. TNBS enhanced the blockade of external $H^+$ by exaggerating the effect of $H^+$ on $I_{tail,max}$, not on $V_{1/2}$. Our data provide evidence for the presence of essential amino-groups that are associated with the normal functioning of the HERG channel and evidence that these groups modify the blocking effect of external $H^+$ on the current.

Effect of Nuclear Transfer Methods on In Vitro Development of Reconstituted Bovine Embryos II. Effect of Electric Voltage and In Vitro Produced Donor Embryo Quality on Fusion and In Vitro Development (소에서 핵이식 방법이 재구축배의 체외발달에 미치는 영향 II. 통전전압과 체내생산 공핵배의 질에 따른 융합과 체외발달)

  • 정영채;김창근;송학웅;정영호;윤종택;이종완;김흥률;김광식
    • Korean Journal of Animal Reproduction
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    • v.20 no.4
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    • pp.467-472
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    • 1997
  • This study was conducted to determine the optimal DC voltage for NT of in vivo donor embryo nuclei and investigate the effect of donor embryo guality on fusion and in vitro development of NT embryos . Recpient oocytes were enucleated 25~27h after IVM and further cuitured for 18~20h prior to fusion for oocyte aging. Donor embryos of molura stage were recovered from superovulated heifers and classified l into good and low quality group. Their nuclei were transferred in to the emucleated oocytes 42~44h post-IVM and fused 43-45h post-IVM with a single 0.75kV /cm or 1.0kV /cm DC voltage for 70${\mu}\textrm{A}$sec. The fusion rate of oocytes was not different between two DC voltages. However, the cleavage and M + B developmnent was more high at 1.0kV /cm DC voltage and the proportion of M+B was 19.0% at 0.75kV /cm DC and 29.4% at 1.0kV /cm DC voltage. Donor embryo qualtiy did not greatly affect the fusion and cleavage of NT oocytes, but none of NT embryos derived from low embryo quatity reached the morula stage. The results indicate that the most suitable DC v voltage for electrofusion of in vivo donor muclei was a single 1.0kV /cm DC voltage and donor embryo quality was an important factor affecting the development in vitro of NT embryos.

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Conformation of Luteinizing Hormone Releasing Hormone as Studied by $^1$H NMR

  • Yi, Gwan-Su;Chaejoon Cheon;Park, Byong-Seok;Kim, Hyoungman
    • Proceedings of the Korean Biophysical Society Conference
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    • 1996.07a
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    • pp.28-28
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    • 1996
  • NMR studies on the structure of the luteinizing hormone releasing hormone (LHRH) in aqueous buffer and trifluoroethanol (TFE)/aqueous buffer (1:1, v/v) solution were performed. The NMR data under these conditions suggested a unique conformation which includes a ${\beta}$-1 turn of the Tyr5-Arg8 segment and an unusual turn of Ser4-Gly6 segment staggered with the ${\beta}$-I turn. (omitted)

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Discovery of an Ultra Faint Dwarf Galaxy in the Virgo Core

  • Jang, In Sung;Lee, Myung Gyoon
    • The Bulletin of The Korean Astronomical Society
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    • v.39 no.2
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    • pp.51.2-51.2
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    • 2014
  • Ultra faint dwarf galaxies (UFDs) are larger but fainter than globular clusters, being the faintest galaxies in the universe. They have been found only in the Local Group. We report the discovery of an UFD in the intracluster field of the Virgo cluster (Virgo UFD1). It is located near the core of Virgo cluster, and far from any massive galaxies. The color magnitude diagram of resolved stars in Virgo UFD1 shows narrow, metal poor red giant branch (RGB), which is very similar to the UFDs in the Local Group. by comparing RGB in this galaxy with 12 Gyr stellar isochrones, we estimate its distance, $d=16.4{\pm}0.4$ Mpc and mean metallicity, $[Fe/H]=-2.4{\pm}0.4$. We derive its integrated photometric properties and structural parameters : V-band absolute magnitude of $MV=-6.3{\pm}0.2$, effective radius of $84{\pm}7pc$, and central surface brightness of ${\mu}V,0=26.49{\pm}0.09$ mag arcsec-2. These properties are similar to these of Local Group UFDs. Virgo UFD1 is the first UFD discovered beyond the Local Group. These results indicate that it may be a fossil remnant of the first galaxies.

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Oxidation of Primary Alcohol Groups of Polysaccharides with 2,2,6,6-Tetramethyl-1-Piperidine Oxoammonium Ion (2,2,6,6-Tetramethyl-1-Piperidine Oxoammonium Ion에 의한 다당류내 1차 알코올의 특이적 산화)

  • Chang, Pahn-Shick;Cho, Gye-Bong
    • Korean Journal of Food Science and Technology
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    • v.29 no.3
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    • pp.446-451
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    • 1997
  • The primary alcohol groups of four kinds of polysaccharides (com starch, rice starch, sweet potato starch, and cellulose), with different structures and water solubilities, were oxidized to carboxyl groups using 2,2,6,6-tetramethyl-1-piperidine oxoammonium ion (TEMPO) at $25^{\circ}C$. The optimum pH, TEMPO content, and NaBr content for the TEMPO/hypobromite-catalyzed oxidation of the polysaccharides were $10.5{\sim}11.0$, 10 mmol/mol primary alcohol, and 0.49 mmol/mol primary alcohol, respectively. The oxidation degree for the primary alcohol group was more than 90% for all four kinds of the polysaccharides. The oxidation process greatly increased the water solubility of the polysaccharides. Water-insoluble polysaccharide such as cellulose became water-soluble to the extent of 8.42% (w/v). And also, the polysaccharides with very low water solubility (less than 0.10% (w/v)) such as com starch, rice starch, and sweet potato starch had high water solubility of approximately 45%(w/v). The gel-forming abilities with calcium ion were determined. The oxidized polysaccharides are new anionic polymers with unique structures that could have application as gums, gels, and films.

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Characteristics of Site Amplification of the Broad-band Seismic Stations in Korea (국내 광대역 지진관측소의 부지증폭 특성)

  • Kim, Seo-Young;Kim, Sung-Kyun
    • Journal of the Korean earth science society
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    • v.30 no.7
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    • pp.810-823
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    • 2009
  • One of the critical factors in accurate determination of earthquake source parameters, and in prediction of seismic hazards is the detailed information related to the site amplification characteristics. The site amplification characteristics of the broad-band seismic stations in Korea were estimated as a function of frequency in the range of 0.2 to 20 Hz. A total of 1275 seismograms recorded from 43 earthquakes observed from 2003 to 2008 in the southern Korean Peninsula were used. It was found that the site amplification ratios for 28 stations estimated from the inversion of the ground motion model were approximately concordant with those obtained from the horizontal-to-vertical (H/V) spectral ratio except for some stations. The spectral site amplification characteristics obtained in this study did not show any considerable spatial distribution. It revealed to be largely correlated with the degree of weathering rather than the basement rock type. Considering the spectral site amplification ratio, 28 broad-band stations were classified into four groups and the characteristics of each group were described in the text.