• 제목/요약/키워드: $H_2S$ partial pressure

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아세틸렌 플라스마를 이용한 다이아몬드성 탄소 박막의 제작 및 특성 (Preparation and Investigation of Characteristics of Diamond-like Carbon Thin Films by Acetylene Plasma)

  • 육도진;강성수;이원진
    • 한국안광학회지
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    • 제3권1호
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    • pp.1-8
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    • 1998
  • 지주파 PECVD 방법으로 아세틸렌 분암비를 달리하면서 제작한 비정질 탄소 박막에서의 분광 특성을 조사하였다. Raman 분광으로부터 D 피크와 G 피크의 상대적인 세기로부터 $sp^3/sp^2$은 수소함량에 대한 경향성을 알 수가 있었으며, FTIR 분광으로부터 계산된 수소함량은 16~37 atm %, $sp^3/sp^2$d,s 0.22~1.44로 변화하였다. 이와 같은 분광특성에 의하여 최적의 아세틸렌 분압비는~15%임을 알 수가 있었다.

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CO와 $H_2$ 혼합기체에 대한 Quadrupole Mass Spectrometer의 감도 특성 (Characteristics of Quadrupole Mass Spectrometer for Partial Pressure Measurement in CO-$H_2$ Gas Mixture)

  • 신용현;홍승수;정광화
    • 한국진공학회지
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    • 제2권3호
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    • pp.314-318
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    • 1993
  • Quadrupole mass spectrometer는 부분압 측정 및 잔류기체 분석에 널리 이용되고 있는 장비이다. CO, H2, Ar이 혼합되어 존재할 때 quadrupole mass spectrometer의 감도를 10-4∼10-8torr영역에서 측정하고 단일기체로 존재할 때의 감도와 비교하였다. 그 결과 일정한 부분압을 유지하고 있는 경우라도, 주위 분위기 기체 종류와 부위기 기체 압력에 따라 감도 별화가 심한 것을 알 수 있었다. 따라서 QMS를 부분압 측정이나 조성분석에 이용하기 위해서는 이에 대한 특성조사가 반드시 필요하다.

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동시증발법을 이용한 SmBCO/IBAD-MgO 박막 장선재 제조 (Fabrication of long SmBCO coated conductor on IBAD-MgO template using co-evaporation method)

  • 하홍수;김호섭;고락길;유권국;양주생;김호겸;정승욱;이정훈;이남진;김태형;송규정;하동우;오상수;염도준;박찬;유상임;문승현;주진호
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2007년도 추계학술대회 논문집
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    • pp.241-241
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    • 2007
  • We fabricated SmBCO coated conductors(CCs) on IBAD-MgO templates using co-evaporation method. IBAD-MgO templates consist of PLD-LMO/epi-MgO/IBAD-MgO/Ni-alloy and showed good in-plane texture of below FWHM 7 degree. Evaporation rates of Sm, Ba, and Cu were precisely controlled to get the optimum composition ratio after deposition process. To optimize the oxygen partial pressure of reaction region, wide range of the partial pressure was investigated from 1 mTorr to 15 mTorr. By reducing the oxygen partial pressure to 5mTorr, (103)grains in SmBCO layer have been increased. On the other hand, there were only (001)grains in SmBCO layer deposited at 15 mTorr $O_2$. Deposition temperature was also investigated from $600^{\circ}C\;to\;800^{\circ}C$ to make high Ic SmBCO CCs. SmBCO on IBAD MgO template showed that the Ic increased gradually at higher growth temperature to $800^{\circ}C$, which the highest Jc and Ic is $2.6\;MA/cm^2$ and 500 A/cm-w., respectively.

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PDP용 CuN/Cu/CuN 전극재료의 개발에 관한 연구 (A Study on Developement of CuN/Cu/CuN Electrode Material for PDP)

  • 조정수;박정후;성열문;정신수;석복렬;류주연;김준호
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1996년도 하계학술대회 논문집 C
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    • pp.1572-1575
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    • 1996
  • A new type $Cu_{x}N/Cu/Cu_{x}N$ thin film electrode material with high adhesion to glass was developed by the dc reactive planar magnetron sputtering system for the PDP(Plasma Display Panel). The adhesive force of the $Cu_{x}N$ thin film was in the range of $20{\sim}40(N)$ under the conditions of the $N_2$ partial pressure of 15%, discharge current of 70mA, discharge voltage of 450V and substrate bias voltage of -100V. The adhesive force was depended on the $N_2$ partial pressure, discharge current and substrate bias voltage.

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보텍스튜브의 노즐에 대한 실험적 연구 (Experimental Study to Nozzle of Vortex Tube)

  • 유갑종;방창훈
    • 태양에너지
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    • 제19권4호
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    • pp.1-10
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    • 1999
  • The phenomena of energy separation through the vortex tube was investigated experimentally, to see the effect of nozzle area ratio and partial admission rate on the energy separation and cooling capacity. The experiment was tarried out with various nozzle area ratios from 0.031 to 0.232 and partial admission rate from 0.176 to 0.956 by varying input pressure($0.2{\si\m}0.5$ MPa) and cold air mass fraction($y=0.1{\sim}1.0$). From the experimental result, we found the optimum nozzle area ratio and the effective partial admission rate for the available use and best cooling performance in given operation condition. While the maximum drop of cold air temperature was observed at around y=0.3 and $S_n=0.155$, the maximum cooling capacity was observed at around y=0.6 and $S_n=0.094$.

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Thermodynamics of 2, N-Dimethyl Pyridinium Iodide in Ethanol-Water Mixture under High Pressure

  • Jee, Jong-Gi;Lee, Young-Hwa;Woo, Eui-Ha;Lee, Kyung-Hee
    • Bulletin of the Korean Chemical Society
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    • 제4권3호
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    • pp.115-119
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    • 1983
  • The ionic association constants (K) of 2, N-dimethyl pyridinium iodide (2NDMPI) in 95 volume percentage ethanol-water mixture were determined by a modified UV and conductance method at $20^{\circ}C{\sim}50^{\circ}C$ under 1 to 2000 bars. The K values increase with increasing pressure and decrease with temperature. The total partial molar volume change (${\Delta}V$) has relatively small negative value and the absolute ${\Delta}V$ value decrease with increasing pressure and temperature. The ion size (a) and solvation number (n) of 2NDMPI were about 5 $\AA$ and changed from 1 to 3 with decreasing temperature. Other thermodynamic parameters such as enthalpy (${\Delta}H^{\circ}$) and entropy (${\Delta}S^{\circ}$) for the equilibrium of the 2NDMPI were evaluated. From all the parameters mentioned above, we came to conclusion that the electrostriction effect of 2NDMPI in the ethanol-water mixture is enhanced with increasing pressure and decreasing temperature.

혐기성 생물수소 발효에서 이산화탄소 및 수소의 분압과 부산물의 거동 (Partial Pressures of $CO_2\;and\;H_2$ and Fate of By-products in Anaerobic Bio-Hydrogen Fermentation)

  • 박우신;김인수
    • KSBB Journal
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    • 제20권6호
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    • pp.408-412
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    • 2005
  • Headspace의 이산화탄소 제거는 수소의 수율을 올릴 수 있는 효과적인 방법이지만, 증가된 수소의 분압(최대 91.2%)과 이산화탄소의 부재에 의해 글루코즈의 발효 경향에 상당한 영향을 미치는 것으로 나타났다. 이산화탄소의 제거는 homoacetogenesis에 의한 수소의 소모를 효과적으로 억제하였지만, 주요발효 부산물인 ethanol 및 기타 발효 부산물의 분해 또한 억제하는 결과를 나타내었다. 또한 소량으로 발생한 부산물들의 분석결과에서 이산화탄소가 제거된 반응에서 반응 후반부에 butyrate의 증가하는 현상이 관찰되었다. 하지만, 기존의 연구결과들처럼 증가된 수소의 분압에 의한 과다한 solvent의 생성은 관찰되지 않았으며, acetate의 과도한 발생을 방지할 수 있어 acetate에 의한 저해현상을 다소 억제할 수 있을 것으로 사료된다. 이산화탄소가 제거될 경우 최종 산물이 수소와 ethanol이므로 목적 반응이 hydrogen-ethanol fermentation이라면 이상적인 방향을 제시할 수 있을 것이다.

High Frequency Properties of Patterned Fe-Al-O Thin Films

  • N.D. Ha;Park, B.C.;B.K. Min;Kim, C.G.;Kim, C.O.
    • 한국자기학회:학술대회 개요집
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    • 한국자기학회 2003년도 하계학술연구발표회 및 한.일 공동심포지엄
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    • pp.194-194
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    • 2003
  • As a result of the recent miniaturization an enhancement in the performance of thin film inductors and thin film transformers, there are increased demands for the thin films with high magnetic permeability in the high frequency range, high saturation magnetization, in high electrical resistivity, and low coercive force. In order to improve high frequency properties, we will investigate anisotropy field by shape and size of pattern. The Fe-Al-O thin films of 16mm and 1 $\mu\textrm{m}$ thickness were deposited on Si wafer, using RF magnetron reactive sputtering technique with the mixture of argon and oxygen gases. The fabricating conditions are obtained in the working partial pressure of 2mTorr, O$_2$ partial pressure of 5%, input power of 400W, and Al pellets on an Fe disk with purity of 99,9%. Magnetic properties of the continuous films as followed: the 4$\pi$M$\_$s/ of 19.4kG, H$\_$c/ of 0.6Oe, H$\_$k/ of 6.0Oe and effective permeability of 2500 up to 100㎒ were obtained. In this work, we expect to enhance effect of magnetic anisotropy on patterned of Fe-Al-O thin films.

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독수리(Aegypius monachus)의 흡입마취에서 Capnography를 이용한 호기말 이산화탄소분압 모니터링 (Capnographic Monitoring of End-Tidal Partial Pressure of Carbon Dioxide in Anesthetized Cinereous vultures (Aegypius monachus))

  • 박원규;석성훈;박세진;이승용;김영기;황재민;정동혁;이희천;연성찬
    • 한국임상수의학회지
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    • 제32권4호
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    • pp.380-384
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    • 2015
  • The relationships between end-tidal partial pressure of carbon dioxide ($P_{ET}CO_2$) and arterial partial pressure of carbon dioxide ($P_aCO_2$), and between $P_{ET}CO_2$ and blood pH in isoflurane-anesthetized cinereous vultures were evaluated. Nine cinereous vultures (weighing 7.3-9.5 kg) were anesthetized via mask with isoflurane, intubated, and connected to a mechanical ventilator. By mechanical ventilator, respiratory rate was altered to achieve a $P_{ET}CO_2$ randomly selected among 30 to 35 mmHg. $P_aCO_2$ and blood pH were determined in serial arterial samples and compared with concurrent $P_{ET}CO_2$ measured with a sidestream capnography. Thirty six samples, nine cinereous vultures were tested 4 times each, were used to determine correlations coefficients between $P_aCO_2$ and $P_{ET}CO_2$, and between $P_{ET}CO_2$ and blood pH. Strong correlations were observed between $P_aCO_2$ and $P_{ET}CO_2$ (r = 0.951, P = 0.000, y = 1.679x - 30.236, $R^2=0.905$) as well as between $P_{ET}CO_2$ and blood pH (r = -0.728, P = 0.000, y = -0.024x + 8.389, $R^2=0.530$) with Pearson's correlation coefficient and simple linear regression. These results suggest that the capnography used provided a sufficiently accurate estimation of $P_aCO_2$ and blood pH. Thus, the monitoring of $P_{ET}CO_2$ can be useful method to prevent hypoventilation for cinereous vultures receiving mechanical ventilation.