• Title/Summary/Keyword: $H_2S$ gas sensor

검색결과 124건 처리시간 0.033초

광학적 가스센서 특성 향상을 위한 광 공동 구조의 고찰 (Speculation of Optical Cavity for Improving Optical Gas Sensor's Characteristics)

  • 이승환;박종선
    • 한국가스학회지
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    • 제12권4호
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    • pp.63-68
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    • 2008
  • 본 논문은 적외선 센서의 광 강도 및 효율을 증가시키기 위해 새로운 오목한 반사 벽면(curved mirror surface)과 기존의 수직 반사 벽면(vertical mirror surface)구조와의 모의해석 및 실험 결과에 대해 기술하였다. 모의해석 결과 수직 반사 벽면을 사용했을 때 적외선 센서 필터 표면에 도달하는 광의 분포는 타원 형상으로 적외선 센서 표면에 도달함을 볼 수 있고, 오목한 반사 벽면을 사용하는 경우에는 광이 원형상으로 집광되는 것을 볼 수 있었다. 따라서 초기 평행광의 면적보다 작은 면적으로 집광됨으로 인해 단위면적당 광 강도는 향상되고, 이에 따라 광학적 센서의 출력전압은 향상될 것이라 예측되었다. 이 모의해석을 근간으로 하여 $25^{\circ}C$, 45%R.H.에서 이산화탄소를 0 ppm에서 2500 ppm까지 250 ppm 간격으로 주입시켰을 때, 오목한 반사 벽면의 광 공동이 수직 반사 벽면의 광 공동보다 출력전압이 약 200 mV 증가하였다.

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Sol-Gel 방법을 이용하여 제작된 Pt이 첨가된 Fe2O3 나노 입자의 가스 감지 특성 (Gas Sensing Properties of Pt Doped Fe2O3 Nanoparticles Fabricated by Sol-Gel Method)

  • 장민형;임유성;최승일;박지인;황남경;이문석
    • 한국전기전자재료학회논문지
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    • 제30권5호
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    • pp.288-293
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    • 2017
  • $Fe_2O_3$ is one of the most important metal oxides for gas sensing applications because of its low cost and high stability. It is well-known that the shape, size, and phase of $Fe_2O_3$ have a significant influence on its sensing properties. Many reports are available in the literature on the use of $Fe_2O_3$-based sensors for detecting gases, such as $NO_2$, $NH_3$, $H_2S$, $H_2$, and CO. In this paper, we investigated the gas-sensing performance of a Pt-doped ${\varepsilon}$-phase $Fe_2O_3$ gas sensor. Pt-doped $Fe_2O_3$ nanoparticles were synthesized by a Sol-Gel method. Platinum, known as a catalytic material, was used for improving gas-sensing performance in this research. The gas-response measurement at $300^{\circ}C$ showed that $Fe_2O_3$ gas sensors doped with 3%Pt are selective for $NO_2$ gas and exhibita maximum response of 21.23%. The gas-sensing properties proved that $Fe_2O_3$ could be used as a gas sensor for nitrogen dioxide.

Quasi-Solid-State Hybrid Electrolytes for Electrochemical Hydrogen Gas Sensor

  • Kim, Sang-Hyung;Han, Dong-Kwan;Hong, SeungBo;Jeong, Bo Ra;Park, Bok-Seong;Han, Sang-Do;Kim, Dong-Won
    • Journal of Electrochemical Science and Technology
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    • 제10권3호
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    • pp.294-301
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    • 2019
  • The quasi-solid-state hybrid electrolytes were synthesized by chemical cross-linking reaction of methacrylate-functionalized $SiO_2$ ($MA-SiO_2$) and tetra (ethylene glycol) diacrylate in aqueous electrolyte. A quasi-solid-state electrolyte synthesized by 6 wt.% $MA-SiO_2$ exhibited a high ionic conductivity of $177mS\;cm^{-1}$ at room temperature. The electrochemical $H_2$ sensor assembled with quasi-solid-state electrolyte showed relatively fast response and high sensitivity for hydrogen gas at ambient temperature, and exhibited better durability and stability than the liquid electrolyte-based sensor. The simple construction of the sensor and its sensing characteristics make the quasi-solid-state hydrogen sensor promising for practical application.

MEASUREMENT OF $CO_2$ CONCENTRATION AND A/F RATIO USING FAST NDIR ANALYZER ON TRANSIENT CONDITION OF SI ENGINE

  • Lee, S.W.;Kim, W.S.;Lee, J.H.;Park, J.I.;Yoo, J.S.
    • International Journal of Automotive Technology
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    • 제7권4호
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    • pp.385-390
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    • 2006
  • A fast response $CO_2$ analyzer has been developed to study transient characteristics on an SI engine. The analyzer has the delay time of 4.5 ms and time constant of 2.8 ms, which is fast enough to measure $CO_2$ concentration on a transient condition. Wide range of A/F(Air/Fuel) ratio can be estimated using the analyzer with an additional switch type oxygen sensor. The results of measurement of $CO_2$ concentration and A/F ratio on a transient condition including rapid acceleration/deceleration and EGR(Ehxaust Gas Recirculation) on/off are presented and compared with a commercial exhaust gas analyzer and UEGO(Universial Exhaust Gas Oxyzen) sensor.

스크린 인쇄법을 이용한 NASICON 후막 SO2가스 센서의 제조 및 특성 (Fabrication and Sensing Properties of NASICON Thick Film SO2 Gas Sensor Using Screen-print Method)

  • 배재철;이상태;전희권;방영일;이덕동;허증수
    • 한국재료학회지
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    • 제13권2호
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    • pp.115-119
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    • 2003
  • The thick film type sensor having Pt/Na Super Ionic Conductor(NASICON) solid electrolyte/Pt/$Na_2$$SO_4$/Pt catalyst system for $SO_2$gas was fabricated by screen-print method. The phase of Na Super Ionic Conductor solid electrolyte sintered at different temperature of 1050, 1150,$ 1250^{\circ}C$ and for different time of 1.5, 2.5, 3.5 hr were investigated by XRD. The Electromotive Force variation of the sensor with $SO_2$concentrations and operating temperatures were investigated. The major phase of Na Super Ionic Conductor film sintered at 115$0^{\circ}C$ for 3.5 hr was sodium zirconium silicon phosphate($Na_3$Zr$_2$$Si_2$PO$_{12}$). The Nernst's slope of Na Super Ionic Conductor sensor for $SO_2$gas with the variation of concentration from 10 to 100 ppm was 167.14 ㎷/decade at the operating temperature of $500 ^{\circ}C$. The increase of oxygen partial pressure was not affected to the variation of Nernst's slope.e.

접촉연소식 가스 센서의 검지특성 (Detecting Characteristics of Catalytic Combustible Gas Sensor)

  • 박찬원;원창섭;유영한;안형근;한득영
    • 한국전기전자재료학회논문지
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    • 제13권10호
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    • pp.865-870
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    • 2000
  • In this paper, catalytic combustible gas sensor was fabricated and tested under flammable gases such as CH$_4$and $C_4$H$_{10}$by using Pt coil as a heater and/or temperature sensing element. Fine $Al_2$O$_3$powder was used for a bead and Pt, Pd noble metal powder for a catalyst. Resistance variation of Pt wire was traced by the changes of the gas concentrations in a chamber. Output voltage was then monitored to obtain the gas concentration from the resistance variation. In this experiment, MgO was used to protect cracks in the based and TiO$_2$to increase the sensitivity of the sensors. Water glass was also added to enhance the selectivity to the combustible gases.s.

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산화주석을 기반으로 한 DMMP 후막가스센서 제작 (fabrication of DMMP Thick Film Gas Sensor Based on SnO2)

  • 최낙진;반태현;곽준혁;백원우;김재창;허증수;이덕동
    • 한국전기전자재료학회논문지
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    • 제16권12S호
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    • pp.1217-1223
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    • 2003
  • Nerve gas sensor based on tin oxide was fabricated and its characteristics were examined. Target gas is dimethyl methyl phosphonate(C$_3$ $H_{9}$ $O_3$P, DMMP) that is simulant gas of nerve gas. Sensing materials were Sn $O_2$ added a-Al$_2$ $O_3$ with 0∼20wt.% and were physically mixed each material. They were deposited by screen printing method on alumina substrate. The sensor device was consisted of sensing electrode with interdigit(IDT) type in front and a heater in back side. Total size of device was 7${\times}$10${\times}$0.6㎣. Crystallite size & phase identification and morphology of fabricated Sn $O_2$ powders were analyzed by X-ray diffraction and by a scanning electron microscope, respectively. Fabricated sensor was measured as flow type and resistance change of sensing material was monitored as real time using LabVIEW program. The best sensitivity was 75% at adding 4wt.% $\alpha$-Al$_2$ $O_3$, operating temperature 30$0^{\circ}C$ to DMMP 0.5ppm. Response and recovery time were about 1 and 3min., respectively. Repetition measurement was very good with $\pm$3% in full scale.TEX>$\pm$3% in full scale.

H2S Gas Sensing Properties of SnO2:CuO Thin Film Sensors Prepared by E-beam Evaporation

  • Sohn, Jae-Cheon;Kim, Sung-Eun;Kim, Zee-Won;Yu, Yun-Sik
    • Transactions on Electrical and Electronic Materials
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    • 제10권4호
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    • pp.135-139
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    • 2009
  • $H_2S$ micro-gas sensors have been developed employing $SnO_2$:CuO composite thin films. The films were prepared by e-beam evaporation of Sn and Cu metals on silicon substrates, followed by oxidation at high temperatures. Results of various studies, such as scanning electron microscopy (SEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) reveal that $SnO_2$ and CuO are mutually non-reactive. The CuO grains, which in turn reside in the inter-granular regions of $SnO_2$, inhibit grain growth of $SnO_2$ as well as forming a network of p-n junctions. The film showed more than a 90% relative resistance change when exposed to $H_2S$ gas at 1 ppm in air at an operating temperature of $350^{\circ}C$ and had a short response time of 8 sec.

반도체식 가스센서와 패턴인식방법을 이용한 혼합가스의 정량적 분석 (Quantitative analysis of gas mixtures using a tin oxide gas sensor and fast pattern recognition methods)

  • 이정헌;조정환;전기준
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2005년도 학술대회 논문집 정보 및 제어부문
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    • pp.138-140
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    • 2005
  • A fuzzy ARTMAP neural network and a fuzzy ART neural network are proposed to identify $H_2S$, $NH_3$ and their mixtures and to estimate their concentrations, respectively. Features are extracted from a micro gas sensor array operated in a thermal modulation plan. After dimensions of the features are reduced by a preprocessing scheme, the features are fed into the proposed fuzzy neural networks. By computer simulations, the proposed methods are shown to be fast in learning and accurate in concentration estimating. The results are compared with other methods and discussed.

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