• Korean Chemical Engineering Research
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• 제45권4호
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• pp.372-377
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• 2007

본 연구에서는 생물학적 공정을 사용하여 황화수소를 제거하는데 있어 망상구조의 폴리우레탄 담체의 바이오필터 충진물로서의 특성을 유입가스농도와 유입가스량의 두 변수를 대상으로 조사하였다. 실험결과 망상구조의 폴리우레탄 담체를 적용한 바이오필터의 황화수소 최대제거용량은 $488.3g-H_2S/m^3{\cdot}h$이었으며, 추정된 임계부하속도는 $330.1g-H_2S/m^3{\cdot}h$이었다. 본 연구의 결과 망상구조의 폴리우레탄 담체를 황화수소의 생물학적 처리를 위한 바이오필터의 담체로서 적용가능성을 확인하였다.

• 한국환경과학회지
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• 제18권7호
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• pp.709-714
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• 2009

Catalytic activities of $V_2O_5/TiO_2$ catalyst were investigated under reaction conditions such as reaction temperature, catalyst size, inlet concentration and space velocity. A 1,2-dichlorobenzene(1,2-DCB) concentrations were measured in front and after of the heated $V_2O_5/TiO_2$ catalyst bed, and conversion efficiency of 1,2-DCB was determined from it's concentration difference. The conversion of 1,2-DCB using a pellet type catalyst in the bench-scale reactor was lower than that with the powder type used in the micro flow-scale reactor. However, when the pellet size was halved, the conversion was similar to that with the powder type catalyst. The highest conversion was shown with an inlet concentration of 100 ppmv, but when the concentration was higher or lower than 100 ppmv, the conversion was found to decrease. Complete conversion was obtained when the GHSV was maintained at below 10,000 $h^{-1}$, even at the relatively low temperature of $250^{\circ}C$. Water vapor inhibited the conversion of 1,2-DCB, which was suspected to be due to the competitive adsorption between the reactant and water for active sites.

• 동력기계공학회지
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• 제18권3호
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• pp.42-50
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• 2014

The main object of this study is to investigate the collection characteristics of wet-type multi-layered and multi-staged porous plate system experimentally. The experiment is carried out to analyze the characteristics of pressure drop and collection efficiency for the present system with the experimental parameters such as water spray, inlet velocity, stage number and inlet particle concentration, etc. In results, for the present system of wet-type, the pressure drop represents 158 $mmH_2O$ higher 3% than that in dry-type at 5 stage and $v_{in}$=3.53 m/s. In case of 5 stage, $v_{in}$=3.53 m/s and water spray 250 ml/min, the collection efficiency of the present system becomes significantly higher as 99.7% comparing to that of the conventional wet-type scrubber. Additionally, for 5 stage and 250 ml/min, $SO_2$ removal efficiencies decrease with the increment of inlet velocity representing 75.0, 62.5, 50.0%, at $v_{in}$=2.12, 2.82, 3.53 m/s, respectively.

• 동력기계공학회지
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• 제7권4호
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• pp.25-30
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• 2003

Hydrocyclone has been widely used for the solid-Liquid separation in many industrial sites because of its comparatively preferable applications that can be applied to wide-range panicle sizes. If seawater with impurities flows through pumps or heat exchanger, it might cause an decrease in efficiency of cooling system. In this paper, we have suggested solid methods of separating impurities from seawater in the cooling system by using a Hydrocyclone. The effects of design factors as solid concentration, cyclone inlet pressure, flow rate and diameter of underflow on the seperating performance of the Hydrocyclone were investigated. The results from the study are summarized as follows: 1) In proportion to the increase of solid concentration, the efficiency of solid-liquid separation is improved. 2) According as the cyclone inlet pressure increases the efficiency of separation is improved. Conclusively, this research suggested that the Hydrocyclone will be used as a pre-treatment system of cooling water in ships, and eventually prevent unexpected accidents in engine systems.

• 대한환경공학회지
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• 제33권8호
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• pp.598-605
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• 2011

본 연구의 주 목적은 다층 다단 다공성 시스템에 편극전하 방식을 부가하여 본 시스템의 집진특성을 실험적으로 해석하는데 있다. 본 시스템의 압력손실 및 집진효율 특성 해석을 위해 실험은 인가전압, 시스템 유입유속, 유입농도 및 stage 수 등의 실험적 변수들에 의해 수행된다. 실험결과, 기류유입 시 유입유속 $v_{in}$ = 3.11 m/s에서 단(stage) 수 변화($1{\rightarrow}5$단)에 따라 압력손실은 $18{\sim}134mmH_2O$를 나타낸다. 인가전압 0 kV 및 기류유입이 없을 때, 시스템 유입유속 $v_{in}$ = 2.58 m/s인 경우 5 stage에서 집진효율은 92.5% 인 데 비해, 동일 유속에서 플레이트 별 편극전하(alternating polarization charge-applied voltage 2.5 kV) 및 기류유입 시스템인 경우 5 stage 효율은 98.5%로 전자에 비해 6% 정도 매우 높은 효율 상승을 보인다.

• 한국분무공학회지
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• 제18권2호
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• pp.81-86
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• 2013

To comply with the regulation of the reinforcing Clean Air Conservation Act, it is necessary for the semiconductor manufacturers to develop effective low-concentration acid gas abatement system to treat the flue gas. The low-concentration acid gas was found to be harder to deal with than the high-concentration one. In this study, the effect of various potential treatments such as air-assist nozzle spraying, magnetizing the scrubbing water, and adding surfactants to spraying and scrubbing water were investigate through the application of the statistical ANCOVA method, which was proved to be very useful tool when the inlet concentration of acid gas could not be controlled precisely and it affected the removal efficiency of the abatement system.

• 대한환경공학회지
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• 제29권7호
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• pp.820-825
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• 2007

지렁이 분변토는 낙엽이나 땅 속의 썩은 뿌리 등을 먹고 장 내의 효소에 의해 부숙화시켜 섭취한 먹이의 80% 이상을 그대로 배설한 질소, 인산, 칼륨 등의 함량이 매우 높고 미생물량도 $10^8$ CFU 이상이 되는 천연비료이다. 또한, 분변토의 단립 구조는 통기성 및 투수성이 매우 우수하며, 비표면적이 크고 양이온 교환용량(2.30-4.60 mg/g-soil)이 높아 탈취 능력이 있는 것으로 알려져 있다. 따라서 본 연구에서는 분변토의 특성을 유지하고 내구성을 향상시켜주기 위해 폐 polyurethane form을 binder로 하여 담체를 제조한 후, 이를 충전한 바이오필터를 대상으로 악취가스 중 황화수소의 제거 성능을 평가하였다. 본 담체는 별도의 배지를 사용하지 않고 분변토 자체에 포함된 유기, 무기물질을 이용하고, 분변토 자체에 있는 미생물을 이용하여 황화수소를 제거할 수 있었다. 황화수소 주입직후부터 lag phase없이 100%의 제거효율을 보였다. 공간속도 50 $h^{-1}$인 경우 입구농도 450 ppmv까지 출구에서 황화수소가 검출되지 않았으며, 악취가스의 입구 농도가 증가함에 따라 바이오필터의 제거효율이 감소하여 출구의 황화수소 농도가 증가하였다. 이 후 950 ppmv까지 약 93% 이상의 우수한 제거효율은 보였고, 약 61.2 g $S{\cdot}m^{-3}{\cdot}h^{-1}$의 최대제거용량을 얻을 수 있었다. 90% 이상의 제거효율을 갖는 황화수소의 최대제거용량은 SV 50 $h^{-1}$에서 300 $h^{-1}$로 증가함에 따라, 61.2, 65.9, 84.7, 89.4 g $S{\cdot}m^{-3}{\cdot}h^{-1}$로 증가하다가 SV 400 $h^{-1}$ 에서는 약 59.3 g $S{\cdot}m^{-3}{\cdot}h^{-1}$로 감소하였다. 공간속도의 증가에 따른 최대제거속도$(V_m)$와 포화상수$(K_s)$를 Michaelia-Menten식으로부터 구한 결과, 각각 66.04, 88.96, 117.35, 224.15, 227.54 g $S{\cdot}m^{-3}{\cdot}h^{-1}$로 비례적으로 증가하였으며, 반면 포화상수는 79.97, 64.95, 65.37, 127.72, 157.43 ppmv으로 감소한 후 다시 증가하는 경향을 보였다.

• 설비공학논문집
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• 제9권2호
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• pp.171-179
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• 1997

During the day time in summer, peak of air conditing load, and electric power management system lies under overloaded condition. The reason is the enlarged peak load value of electric power caused by increased air-cooling load in summer. To prevent load concentration during day time and overloaded condition of power management system, some energy storage methods are suggested. One of these methods is ice storage system. Water has some good properties as P.C.M.(Phase Chang Material) : Its melting point is the range of required operation temperature. It has large specific latent heat and is chemically stable compared to other organic or inorganic substances. It is cheap and easy to treat. This study represents experimental results of heat transfer characteristics of P.C.M. under the outward melting process in a vertical cylinder. We experimented with twelve combinations of conditions, i.e., three different inlet temperatures($7^{\circ}C,\;4^{\circ}C\;and\;1^{\circ}C$), two working fluid directions(upward and downward), and two aspect ratios, H/R(4 and 2). At the inlet temperature of $7^{\circ}C$ and $4^{\circ}C$, there was temperature stagnation region where the temperature of P.C.M. remains constant at $4^{\circ}C$ regardless of aspect ratio and direction of working fluid. This temperature stagnation occurs as the water, at its maximum density, flows down to the lower region. The phase change interface formed bell-shaped curve as the melting process continued. With a new set of conditions(4H/R, inlet temperature $4^{\circ}C$ and $1^{\circ}C$, downward/upwerd inlet direction), the movement of phase change interface was faster when the working flued inlet direction was downward. With the same set of conditions, melting rate and total melting energy were larger when the working fluid inlet direction was downward. The results were reversed when the other sets of conditions were applied.

• 한국미생물·생명공학회지
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• 제32권4호
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• pp.328-333
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• 2004

고농도의 황화수소 가스를 제거하기 위하여 철촉매인 $Fe^{3+}$ 을 생산할 수 있는 철산화 세균 A. ferrooxidans를 다공성 세라믹 담체에 고정화한 생물반응기와 황화수소가 $Fe^{3+}$ 와 화학반응에 의해 elemental sulfur로 제거되는 흡수탑 반응기로 구성된 2단계 생물학적 탈황공정을 연구하였다. 생물반응기는 4회 이상의 반복 회분식 배양을 통해 안정화 되었고, 정상상태에서의 평균 철산화 속도는 $0.89kg{\cdot}m^{-3}{\cdot}h^{-1}$ 이었다. 2단계 생물 탈황공정은 약 54일 동안 장기간 성공적으로 조업이 가능하였다. 흡수탑 반응기에서는 공간속도를 70 $h^{-1}$ 의 조건하에서 37.000 ppm의 고농도 $H_{2}S$ 제거 임계 부하량은 3.3 kg $S{\cdot}m^{-3}{\cdot}h^{-1}$ 로 우수하였다. 장기간 조업하는 동안 고정화 세포의 농도는 일정하게 유지되었다.

• Environmental Engineering Research
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• 제13권1호
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• pp.19-27
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• 2008

Simultaneous removal of ternary gases of $NH_3$, $H_2S$ and toluene in a contaminated air stream was investigated over 180 days in a biofilter. A commercially available inorganic/polymeric composite chip with a large void volume (bed porosity > 0.80) was used as a microbial support. Multiple microorganisms including Nitrosomonas and Nitrobactor for nitrogen removal, Thiobacillus thioparus (ATCC 23645) for $H_2S$ removal and Pseudomonas aeruginosa (ATCC 15692), Pseudomonas putida (ATCC 17484) and Pseudomonas putida (ATCC 23973) for toluene removal were used simultaneously. The empty bed residence time (EBRT) ranged from 60 - 120 seconds and the inlet feed concentration was $0.0325\;g/m^3-0.0651\;g/m^3$ for $NH_3$, $0.0636\;g/m^3-0.141\;g/m^3$ for $H_2S$, and $0.0918\;g/m^3-0.383\;g/m^3$ for toluene, respectively. The observed removal efficiency was 2% - 98% for $NH_3$, 2% - 100% for $H^2S$, and 2% - 80% for toluene, respectively. Maximum elimination capacity was about $2.7\;g/m^3$/hr for $NH_3$, > $6.4\;g/m^3$/hr for $H_2S$ and $4.0\;g/m^3$/hr for toluene, respectively. The inorganic/polymeric composite carrier required 40 - 80 days of wetting time for biofilm formation due to the hydrophobic nature of the carrier. Once the surface of the carrier was completely wetted, the microbial activity became stable. During the long-term operation, pressure drop was negligible because the void volume of the carrier was two times higher than the conventional packing materials.