• Title/Summary/Keyword: $H_2O $

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Simultaneous Observations of SiO and $H_2O$ Masers toward Symbiotic Stars

  • Cho, Se-Hyung;Kim, Jae-Heon
    • The Bulletin of The Korean Astronomical Society
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    • v.35 no.2
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    • pp.79.2-79.2
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    • 2010
  • We present the results of simultaneous observations of SiO v=1, 2, J=1-0, $^{29}SiO$ v=0, J=1-0, and $H_2O$ $6_{16}-5_{23}$ maser lines performed with the KVN Yonsei 21 m radio telescope from 2009 Nov. to 2010 Jan (ApJ, 719, 126, 2010). We searched for these masers in 47 symbiotic stars and detected maser emission from 21 stars, giving the first time detection from 19 stars. Both SiO and $H_2O$ masers were detected from seven stars of which six stars are D-type symbiotic and one is an S-type star, WRAY 15-1470. In the SiO maser emission, the $^{28}SiO$ v=1 maser was detected from 10 stars, while the v=2 maser detected from 15 stars. In particular, the $^{28}SiO$ v=2 maser emission without the v=1 maser detection was detected from nine stars with its detection rate of 60 %, which is much higher than that of isolated Miras/red giants. The $^{29}SiO$ v=0 maser emission was also detected from two stars, H 2-38 and BF Cyg, together with the $^{28}SiO$ v=2 maser. We conclude that these different observational results between isolated Miras/red giants and symbiotic stars may be related with the presence of hot companions in a symbiotic binary system.

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Electrical characteristics of 4H-SiC MIS Capacitors With Ni/CNT/SiO2 Structure (Ni/CNT/SiO2 구조의 4H-SiC MIS 캐패시터의 전기적 특성)

  • Lee, Taeseop;Koo, Sang-Mo
    • Journal of IKEEE
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    • v.18 no.4
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    • pp.620-624
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    • 2014
  • In this study, the electrical characteristics of Ni/CNT/$SiO_2$ structures were investigated in order to analyze the mechanism of carbon nanotubes in 4H-SiC MIS device structures. We fabricated 4H-SiC MIS capacitors with or without carbon nanotubes. Carbon nanotubes were dispersed by isopropyl alcohol. The capacitance-voltage (C-V) is characterized at 300 to 500K. The experimental flat-band voltage ($V_{FB}$) shift was positive. Near-interface trapped charge density and oxide trapped charge density values of Ni/CNT/$SiO_2$ structure were less than values of reference samples. With increasing temperature, the flat-band voltage was negative. It has been found that its oxide quality is related to charge carriers or defect states in the interface of 4H-SiC MIS capacitors. Gate characteristics of 4H-SiC MIS capacitors can be controlled by carbon nanotubes between Ni and $SiO_2$.

Two-step thermochemical cycles for hydrogen production using NiFe2O4/m-ZrO2 and CeO2 devices (NiFe2O4/m-ZrO2와 CeO2를 이용한 고온 태양열 열화학 싸이클의 수소 생산)

  • Kim, Chul-Sook;Cho, Ji-Hyun;Kim, Dong-Yeon;Seo, Tae-Beom
    • Journal of the Korean Solar Energy Society
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    • v.33 no.2
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    • pp.93-100
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    • 2013
  • Two-step thermochemical cycle using ferrite-oxide($Fe_2O_4$) device was investigated. The $H_2O$(g) was converted into $H_2$ in the first experiment which was performed using a dish type solar thermal system. However the experiment was lasted only for 2 cycles because the metal oxide device was sintered and broken down. Another problem was that the reaction was taken place mainly on a side of the metal oxide device. The m-$ZrO_2$, which was widely known as a material preventing sintering, was applied on the metal oxide device. The ferrite loading rate and the thickness of the metal oxide device were increased from 10.67wt% to 20wt% and from 10mm to 15mm, respectively. The chemical reactor having two inlets was designed in order to supply the reactants uniformly to the metal oxide device. The second-experiment was lasted for 5 cycles, which was for 6 hours. The total amount of the $H_2$ production was 861.30ml. And cerium oxide($CeO_2$) device was used for increasing $H_2$ production rate. $CeO_2$ device had low thermal resistance, however, more $H_2$ production rate than $Fe_2O_4$ device.

Synthesis of Lithium Titanate Whisker Using Ion-Exchange of Acid Treatment

  • Um Myeong-Heon;Lee Jin-Sik
    • Korean Journal of Materials Research
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    • v.14 no.9
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    • pp.627-633
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    • 2004
  • Lithium titanate whiske($Li_{x}Ti_{4}O_9$) was prepared by an ion-exchange reaction. To this end, the initial material, potassium tetratitanate ($K_{2}Ti_{4}O_9{\cdot}nH_{2}O$) was prepared by calcination of a mixture of $K_{2}CO_3\;and\;TiO_2$ with a molar ratio of 2.8 at $1050^{\circ}C$ for 3 h, followed by boiling water treatment of the calcined products for 10 h. Fibrous potassium tetratitanate could be transformed into layered hydrous titanium dioxide ($H_{2}Ti_{4}O_9{\cdot}nH_{2}O$) through an exchange of $K^{+}\;with\;H^{+}$ using 0.075 M HCl. Also, lithium titanate whisker was finally prepared as $Li^{+}\;and\;H^{+}$ ions were exchanged by adding 20 mL of a mixture solution of LiOH and $LiNO_3$ to 1g whisker and stirring for $5\~15$ days. The average length and diameter of the $Li_{x}Ti_{4}O_9$ whiskers were $10\~20{\mu}m\;and\;1\~3{\mu}m$, respectively.

Advanced Oxidation Processes of Secondary Effluent for Reuse (재사용을 위한 하수처리장 방류수의 고급산화처리)

  • 조일형;송경석;성기석;정문호;이홍근;조경덕
    • Journal of Environmental Health Sciences
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    • v.26 no.3
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    • pp.61-68
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    • 2000
  • The use of photo-catalytic processes in pollution abatement and resource has a significant economic importance. Therefore, the applications of photochemical oxidation of secondary effluent driven by UV, TiO2, TiO2/UV, H2O2/UV and TiO2/H2O2/UV, have been investigated in order to treat the secondary effluent from municipal sewage. Various experimental parameters such as BOD, CODcr, Nurbidity, total P, and SPC were examined in each photo-catalytic reaction system. The results showed that the application of single oxidant such as UV, TiO2 only has a minor effect on parameters reduction (CODcr, BOD, etc) to treat the secondary effluent, whereas the combinations of oxidants increase the removal efficiency. The best removal efficiency in every parameters was achieved by the combination of TiO2, H2O2 and UV. It was also found that the optimum amount of TiO2 for the treatment was 1g/ι to achieve water reuse standard. From the results, the photocatalytic reaction system can be an alternative as a post-treatment to treat the secondary effluent from municipal sewage.

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Thermal Behavior of NiFe2O4 for Hydrogen Generation (NiFe2O4를 이용한 열화학 사이클 H2 제조)

  • Han, S.B.;Kang, T.B.;Joo, O.S.;Jung, K.D.
    • Journal of Hydrogen and New Energy
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    • v.14 no.4
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    • pp.298-304
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    • 2003
  • The thermal behavior of $NiFe_2O_4$ prepared by a solid-state reaction was investigated for $H_2$ generation by the thermochemical cycle. The reduction of $NiFe_2O_4$ started from $800^{\circ}C$, and the weight loss was 0.2-0.3 wt% up to $1000^{\circ}C$. In the $H_2O$ decomposition reaction, $H_2$ was generated by oxidation of reduced $NiFe_2O_4$. The crystal structure of $NiFe_2O_4$ maintained during the redox reaction of 5 cycles. From this observation, the lattice oxygen in $NiFe_2O_4$ is released without the structural change during the thermal reduction and oxygen deficient $NiFe_2O_4$ can be restored to the spinel structure of $NiFe_2O_4$.

화학증기수송법을 이용한 금속 몰리브덴 박막 증착

  • Park, Chang-Won;Lee, Yeong-Jung;Kim, Dae-Geon;Kim, Yeong-Do
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.05a
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    • pp.53.2-53.2
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    • 2009
  • 몰리브덴(Mo)은 우수한 전기전도도와 고온 안정성으로 인해 전자부품의 전극으로 널리 사용되고, 미래 에너지인 태양전지 분야에서 CIS계 화합물박막태양전지의 후면전극으로 이용되고 있는 재료로서 현재 증착 방법으로는 D.C. sputtering이 가장 널리 이용되고 있다. 또한 $MoO_3$ 분말이 Mo 분말로 수소 환원되는 과정은 $MoO_3+H_2{\rightarrow}MoO_2+H_2O$$MoO_2+2H_2{\rightarrow}Mo+2H_2O$의 2단계를 통해서 수행되며 이중 첫 번째 단계에서 $MoO_3(OH)_2$라는 기상을 통해 지배적으로 일어난다고 알려져 있고 이를 화학증기수송(Chemical vapor transport : CVT)이라고 한다. 본 연구에서는 $MoO_3$분말의 수소 환원 과정 중에 발생하는 기상인 $MoO_3(OH)_2$을 이용하여 몰리브덴 옥사이드 박막을 증착하고 이를 다시 수소분위기에서 수소 환원하는 증착 방법을 통해 균일하고 부착성이 우수한 Mo 박막을 제조하고자 하였다. 기판으로 사용된 Glass를 $MoO_3$ 분말 위에 홀더를 이용하여 $MoO_2$ 박막을 증착하고 이를 다시 수소분위기에서의 수소 환원을 통해 Mo 박막을 성공적으로 제조하였다. 제조된 Mo박막의 결정구조 및 미세조직을 XRD 와 SEM을 통해 분석하였다.

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Synthesis and Properties of $Al_2O_3-SiC$ Composites from Alkoxides (알콕사이드로부터 $Al_2O_3-SiC$ 복합재료의 제조 및 특성)

  • 이홍림;김규영
    • Journal of the Korean Ceramic Society
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    • v.30 no.2
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    • pp.123-130
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    • 1993
  • Dispersed type Al2O3-SiC composite powders were synthesized from Al-isopropoxide (Al(i-OC3H7)3) and Si(OC2H5)4 precursors by hydrolysis of mixed alkoxides and carbothermal reaction method. The characteristics of the synthesized (dispersed type) Al2O3-SiC composite powders were investigated using XRD, SEM, TEM, BET and particle size analyzer. Carbothermal reaction to produce Al2O3-SiC composite was completed in 10h at 135$0^{\circ}C$ on 3~4㎤/s (0.21~0.28cm/s) of H2 flow rate and about 1/1 of carbon/oxides(=SiO2+Al2O3) molar ratio. The synthesized powders were observed to have the mean particle size range of 0.4~1.26${\mu}{\textrm}{m}$ and showed finer particle size with increasing SiC content.

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A Study on $CaO-SiO_2-H_2O$ System Hydrates Produced by Hydrothermal Reaction under High Pressure (高壓下의 水熱反應에 依한 $CaO-SiO_2-H_2O$ 系 硬化體에 關한 基礎的 硏究)

  • Lee, Hee-Soo
    • Journal of the Korean Chemical Society
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    • v.9 no.4
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    • pp.190-200
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    • 1965
  • It is a fundamental study for the hardened bodies of $CaO-SiO_2-H_2O$ system to clear up various physical properties and structures of the products, using the Seosan quartz and $Ca(OH)_2$(C. P. grade) as raw materials. Various samples were obtained by varying $CaO/SiO_2$ mole ratio (0.3∼2.1) and hydrothermal conditions ($100∼220^{\circ}C$ and 2∼14hr.) within the given limit. It was found that tobermorite phase as hydrate is contained in the hardened bodies and that the development of crystal has a great influence on the strengths and other physical properties of hardened bodies.

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Difference in the spatial distribution between $H_2O$ and $CO_2$ ices in M 82 found with AKARI

  • Yamagishi, Mitsuyoshi;Kaneda, Hidehiro;Oyabu, Shinki;Ishihara, Daisuke;Onaka, Takashi;Shimonishi, Takashi;Suzuki, Toyoaki;Minh, Young Chol
    • The Bulletin of The Korean Astronomical Society
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    • v.38 no.2
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    • pp.34.1-34.1
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    • 2013
  • Interstellar ices (e.g., $H_2O$, $CO_2$, and CO ices) are formed on the surface of dust grains in dense molecular clouds. In a near-infrared spectrum, we can observe deep absorption features particularly due to $H_2O$ ice at $3.05{\mu}m$ and $CO_2$ ice at $4.27{\mu}m$. These interstellar ices have many pieces of information on the interstellar environment. Among various ices, $CO_2$ ice is one of the most important ones as a probe of the interstellar environment. That is because $CO_2$ ice is a secondary product unlike $H_2O$ and CO ices which are primarily formed on dust grains. Past studies for $CO_2$ ice in nearby galaxies were performed only for the galactic center in a few galaxies. In order to utilize the information from $CO_2$ ice effectively, it is valuable to perform mapping observations of ices on a galactic scale. With AKARI, we obtain the spatially-resolved near-infrared ($2.5-5.0{\mu}m$) spectra for the central ~1 kpc region of the nearby starburst galaxy M 82. These spectra clearly show the absorption features due to interstellar $H_2O$ and $CO_2$ ices, and we created their column density maps. As a result, we find that the spatial distribution of $H_2O$ ice is significantly different from that of $CO_2$ ice; $H_2O$ ice is widely distributed, while $CO_2$ ice is concentrated near the galactic center. Our result for the first time reveals spatial variations in $CO_2/H_2O$ ice abundance ratio on a galactic scale, suggesting that the ice-forming interstellar environment changes within a galaxy. In this presentation, we discuss the cause of the variations in the ice abundance ratio.

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