• Title/Summary/Keyword: $H_2O $

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Slow-Cooling Calcination Process to Potassium Tetratitanate and Potassium Hexatitanate Fibers (서냉소성법에 의한 사티탄산칼륨 및 육티탄산칼륨 섬유의 합성)

  • 최진호;한양수;송승완
    • Journal of the Korean Ceramic Society
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    • v.30 no.8
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    • pp.664-670
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    • 1993
  • Potassium tetratitanate (K2Ti4O9) and Potassium hexatitanate (K2Ti6O13) fibers have been prepared by the slow-cooling calcination process in a temperature range from 125$0^{\circ}C$ to 95$0^{\circ}C$ using the K2CO3 and TiO2 as the starting materials. Optimum fiber growth conditions have been also investigated by changing the physical parameters, such as calcination time and temperature, and cooling rate. Relatively long K2Ti4O9 fibers ( 1.2mm) have been grown with quite a high aspect ratio (c/a 500)when the starting material with a nominal composition of K2O and TiO2 with 1:4 was calcined at 115$0^{\circ}C$ for 4h, and then was slowly cooled to 95$0^{\circ}C$ with a rate of 2$0^{\circ}C$/h. In case of a K2O.6TiO2 composition, acicular shaped K2Ti6O13 fibers with 20~300${\mu}{\textrm}{m}$ long and low aspect ratio (c/a 10~15) have been formed irrespective of the coolign rate. The growth condition of fibers have been discussed based upon the phase diagram of K2O-TiOa2.

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Development and Validation of Predictive Models of Esherichia coli O157:H7 Growth in Paprika (파프리카에서 병원성 대장균의 성장예측 모델 개발 및 검증)

  • Yun, Hyejeong;Kim, Juhui;Park, Kyeonghun;Ryu, Kyoung-Yul;Kim, Byung Seok
    • Journal of Food Hygiene and Safety
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    • v.28 no.2
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    • pp.168-173
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    • 2013
  • This study was carried out to develop and validate predictive models of E. coli O157:H7 growth. Growth data of E. coli O157:H7 in Paprika were collected at 12, 24, 30 and $36^{\circ}C$. The population increased into 3.0 to 3.8 log10 CFU/g within 4 days, then continued to increase at a slower rate through 10 days of storage at $12^{\circ}C$. The lag time (LT) and maximum specific growth rate (SGR) obtained from each primary model was then modeled as a function of temperature using Davey and square root equations, respectively. For interpolation of performance evaluation, growth data for a mixture of E. coli O157:H7 were collected at time intervals in paprika incubated at the different temperatures, which was not used in model development. Results of model performance for interpolation data demonstrated that induced secondary models showed acceptable goodness of fit. Relative errors in the LT and SGR model for interpolation data (18 and $27^{\circ}C$) was 100%, which show acceptable goodness of fit and validated for interpolation. The primary and secondary models developed in this study can be used to establish tertiary models to quantify the effects of temperature on the growth of E. coli O157:H7 in paprika.

Nanostructured Metal Organic Framework Modified Glassy Carbon Electrode as a High Efficient Non-Enzymatic Amperometric Sensor for Electrochemical Detection of H2O2

  • Naseri, Maryam;Fotouhi, Lida;Ehsani, Ali
    • Journal of Electrochemical Science and Technology
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    • v.9 no.1
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    • pp.28-36
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    • 2018
  • Metal-organic frameworks have recently been considered very promising modifiers in electrochemical analysis due to their unique characteristics among which tunable pore sizes, crystalline ordered structures, large surface areas and chemical tenability are worth noting. In the present research, $Cu(btec)_{0.5}DMF$ was electrodeposited on the surface of glassy carbon electrode at room temperature under cathodic potential and was initially used as the active materials for the detection of $H_2O_2$. The cyclic voltammogram of $Cu(btec)_{0.5}DMF$ modified GC electrode shows distinct redox peaks potentials at +0.002 and +0.212 V in 0.1 M phosphate buffer solution (pH 6.5) corresponding to $Cu^{(II)}/Cu^{(I)}$ in $Cu(btec)_{0.5}DMF$. Acting as the electrode materials of a non-enzymatic $H_2O_2$ biosensor, the $Cu(btec)_{0.5}DMF$ brings about a promising electrocatalytic performance. The high electrocatalytic activity of the $Cu(btec)_{0.5}DMF$ modified GC electrode is demonstrated by the amperometric response towards $H_2O_2$ reduction with a wide linear range from $5{\mu}M$ to $8000{\mu}M$, a low detection limit of $0.865{\mu}M$, good stability and high selectivity at an applied potential of -0.2 V, which was higher than some $H_2O_2$ biosensors.

Protective Effects of Glycyrrhiza uralensis Radix Extract and Its Active Compounds on H2O2-induced Apoptosis of C6 Glial Cells (H2O2로 유도된 C6 신경교세포의 세포사멸에 대한 감초 추출물과 감초 활성물질의 보호효과)

  • Park, Chan Hum;Kim, Ji Hyun;Choi, Seung Hak;Shin, Yu Su;Lee, Sang Won;Cho, Eun Ju
    • Korean Journal of Medicinal Crop Science
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    • v.25 no.5
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    • pp.315-321
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    • 2017
  • Background: Glycyrrhiza uralensis Radix (GR) is a crude drugs used in Asian countries that has been reported to prevent the progression of neurodegenerative diseases such as Alzheimer's disease. The present study examined whether GR and its active compounds, glycyrrhizic acid (GA) and isoliquiritigenin (IL), exerted protective effects on $H_2O_2$-induced oxidative damage in C6 glial cells. Methods and Results: We exposed C6 glial cells to hydrogen peroxide ($H_2O_2$) for 24 h and investigated the cellular response to GR and its active compounds by evaluating cell viability, reactivie oxygen species (ROS) production, and apoptosis-related protein expression. GR successfully mitigated the reduced cell viability and ROS production induced by $H_2O_2$ in C6 glial cells, IL and GA significantly increased the cell viability and decreased ROS production. In addition, IL and GA down-regulated apoptotic Baxdependent caspase-3 activation, but each compound exerted different mechanisms, i.e., IL dose-dependently decreased ROS production and, GA up-regulated anti-apoptotic Bcl-2 expression. Conclusions: These results demonstrated that GR and its active components, IL and GA, exhibit potential for use as natural neurodegenerative agents for the modulation of apoptosis in C6 glial cells.

Hydrophobic modification conditions of Al2O3 ceramic membrane and application in seawater desalination

  • Lian li;Zhongcao Yang;Lufen Li
    • Membrane and Water Treatment
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    • v.15 no.1
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    • pp.21-29
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    • 2024
  • 1H,1H,2H,2H-perfluorodecytriethoxysilane (C16H19F17O3Si) be successfully applied to the hydrophobic modification of Al2O3 tubular ceramic membrane. Taking the concentration of modification solution, modification time, and modification temperature as factors, orthogonal experiments were designed to study the hydrophobicity of the composite membranes. The experiments showed that the modification time had the greatest impact on the experimental results, followed by the modification temperature, and the modification solution concentration had the smallest impact. Concentration of the modified solution 0.012 mol·L-1, modification temperature 30 ℃ and modification time 24 h were considered optimal hydrophobic modification conditions. And the pure water flux reached 274.80 kg·m-2·h-1 at 0.1MPa before hydrophobic modification, whereas the modified membrane completely blocked liquid water permeation at pressures less than 0.1MPa. Air gap membrane distillation experiments were conducted for NaCl (2wt%) solution, and the maximum flux reached 4.20 kg·m-2·h-1, while the retention rate remained above 99.8%. Given the scarcity of freshwater resources in coastal areas, the article proposed a system for seawater desalination using air conditioning waste heat, and conducted preliminary research on its freshwater production performance using Aspen Plus. Finally, the proposed system achieved a freshwater production capacity of 0.61 kg·m-2·h-1.

Magnetic Properties of Chip Inductors Prepared with V2O5-doped Ferrite Pastes (V2O5 도핑한 페라이트 페이스트로 제조된 칩인덕터의 자기적 특성)

  • Je, Hae-June
    • Journal of the Korean Magnetics Society
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    • v.13 no.3
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    • pp.109-114
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    • 2003
  • The purpose of this study Is to investigate the effect of $V_2$O$_{5}$ addition on the microstructures and magnetic properties of 7.7${\times}$4.5${\times}$1.0 mm sized multi-layer chip inductors prepared by the screen printing method using 0∼0.5 wt% $V_2O_{5}$-doped NiCuZn ferrite pastes. With increasing the $V_2O_{5}$ content, the exaggerated grain growth of ferrite layers was developed due to the promotion of Ag diffusion and Cu segregation into the grain boundaries oi ferrites, which affected significantly the magnetic properties of the chip inductors. After sintering at $900^{\circ}C$, the inductance at 10 MHZ of the 0.5 wt% $V_2O_{5}$-doped chip inductor was 3.7 ${\mu}$H less than 4.2 ${\mu}$H of the 0.3 wt% $V_2O_{5}$-doped one, which was thought to be caused by the residual stress at the ferrite layers increased with the promotion of Ag diffusion and Cu segregation. The quality factor of the 0.5 wt% $V_2O_{5}$-doped chip inductor decreased with increasing the sintering temperature, which was considered to be caused by the electrical resistivity of the ferrite layer decreased with the promotion of Ag/cu segregation at the grain boundaries and the growth of the mean grain size of ferrite due to exaggerated grain growth of ferrite layers.

Effect of Excess MgO on Dielectric and Electrostrictive Properties of $0.99Pb(Mg_{1/3}Nb_{2/3})O_3-0.01Pb(Mn_{2/3}W_{1/3})O_3$ ($0.99Pb(Mg_{1/3}Nb_{2/3})O_3-0.01Pb(Mn_{2/3}W_{1/3})O_3$계의 유전 및 전왜 특성에 미치는 과잉 MgO의 영향)

  • 윤기현;김승연;남윤우;조용수;강동헌
    • Journal of the Korean Ceramic Society
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    • v.30 no.8
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    • pp.629-634
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    • 1993
  • Dielectric and electrostrictive properties of 0.99Pb(Mg1/3Nb2/3)O3-0.01Pb(Mn2/3W1/3)O3 system using KCl-NaCl salts have been investigated as a function of the amount of excess MgO. For the specimens calcined at $700^{\circ}C$ for 1h and then sintered at 115$0^{\circ}C$ for 4h, the perovskite phase and the relative density were about 98% and 95%, respectively. With the addition of excess MgO up to 10mol%, the dielectric constant and the electrostrictive strain increased due to the increase of density and grain size, and these properties were degraded by the further addition of excess MgO. For the 10mol% excess MgO added specimen, the maximum electrostrictive strain, Xmax, and the electrostrictive coefficient, Q11, were 4.5$\times$10-4, 3.5$\times$10-2m4/C2, respectively. These results were correlated with the property of PMW and microstructure.

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Characteristics of diamond-like nanocomposite films grown by plasma enhanced chemical vapor deposition (플라즈마 화학기상증착에 의해 성장된 유사 다이아몬드 나노복합체 박막의 특성 평가)

  • 양원재;오근호
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.13 no.1
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    • pp.36-40
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    • 2003
  • The diamond-like nanocomposite (DLN) thin films were deposited on Si substrates using $CH_4/(C_2H_5O)_4Si/H_2$/Ar gas mixtures as source gases by the plasma enhanced chemical vapor deposition (PECVD). The chemical structure and microstructure of grown films were investigated and their tribological properties were evaluated by a ball-on-plate type tribometer. The deposited DLN films mainly consisted of diamond-like a-C:H and quartz-like a-Si:O networks. The DLN films had a good agreement with tribological coating applications due to their extremely low friction coefficients and low wear rates.