• Journal of Powder Materials
• /
• v.11 no.2
• /
• pp.118-123
• /
• 2004

A formation of aluminum hydroxide by hydrolysis reaction in the water has been studied by using nano aluminum powder fabricated by pulsed wire evaporation(PWE) method. The hydroxide type and morphology depending on temperature and pH were examined by structural analysis. The Boehmite($Al_2O_3$.$H_2O$ or AIO(OH)) was predominantly formed in high temperature region over 4$0^{\circ}C$, while the Bayerite($Al_2O_3$.$H_2O$ or $Al(OH)_3$) below $30^{\circ}C$ of hydrolysis temperature. The Boehmite formation was preferred to the Bayerite in acidic solution in the same hydrolysis temperature. The slowly formed Bayerite phase showed facet crystalline structure, while the fast formed Boehmite was fine fiber with a large aspect ratio of several nm in diameter and several hundred nm in length, and with much larger specific surface area(SSA) than that of Bayerite. The highest SSA was about $420m^2$/g.

• KIEE International Transactions on Electrophysics and Applications
• /
• v.3C no.3
• /
• pp.106-112
• /
• 2003

A combined discharge type ozonizer was designed and manufactured. The increase or decrease of temperature greatly influences the characteristics of ozone concentration ( $O_{3con}$), ozone generation ( $O_{3g}$) and ozone yield ( $O_{3Y}$) of a discharge type ozonizer. The characteristics of ozone concentration, ozone generation and ozone yield rate were investigated by varying the gas flow rate (Q), the discharge power ( $W_{d}$) and the temperature (T). At T=25[$^{\circ}C$] the values of $O_{3con}$ were found as 5632, 4200, 2500 and l800[ppm] at Q = 1, 2, 4 and 6[l/min] respectively. At the same temperature the corresponding values of $O_{3g}$ were found as 662, 988, 1176 and l270[mg/h] and those of $O_{3Y}$ were found as 67, 102, 119 and 135[g/kWh] respectively. When the temperature is decreased to -50[$^{\circ}C$], the values of $O_{3con}$ were found as 9000, 6700, 4000 and 2800[ppm] respectively at Q = 1, 2, 4 and 6[l/min]. At the same value of temperature the corresponding values of $O_{3g}$ were found as 1220, 1576, 1882 and 2050[mg/h] and those of $O_{3Y}$ were found as 120, 159, 188 and 202[g/kWh] respectively. Hence as the temperature was decreased from 25 to -50[$^{\circ}C$], the efficiencies of ozone generation were increased by 79, 55, 58 and 49[%] respectively at Q = 1, 2, 4 and 6[l/min].]. 6[l/min].].

• Journal of Environmental Science International
• /
• v.12 no.3
• /
• pp.319-324
• /
• 2003

The characteristics of photocatalytic decomposition of dye waste water by titanium dioxide was studied in a batch reactor under constant strength of ultra-violet ray. The decomposition rate of methyl orange by TiO$_2$ was pseudo-first order, anatase type TiO$_2$ was more effective than rutile type below the dosage of 5g. The decomposition rate was increased with decreasing initial pH, increasing reaction temperature and oxidant concentration. The decomposition rate of water soluble dyes was decreased in order of rhodamine B>eosin Y>methyl orange.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2016.02a
• /
• pp.418.2-418.2
• /
• 2016

$Al_2O_3$ passivation layer has excellent passivation properties at p-type Si surface. This $Al_2O_3$ layer forms thin $SiO_2$ layer at the interface. There were some studies about inserting thermal oxidation process to replace naturally grown oxide during $Al_2O_3$ deposition. They showed improving passivation properties. However, thermal oxidation process has disadvantage of expensive equipment and difficult control of thin layer formation. Wet chemical oxidation has advantages of low cost and easy thin oxide formation. In this study, $Al_2O_3$/$SiO_2/Si(100)$ interface was formed by wet chemical oxidation and PA-ALD process. $SiO_2$ layer at Si wafer was formed by $HCl/H_2O_2$, $H_2SO_4/H_2O_2$ and $HNO_3$, respectively. 20nm $Al_2O_3$ layer on $SiO_2/Si$ was deposited by PA-ALD. This $Al_2O_3/SiO_2/Si(100)$ interface were characterized by capacitance-voltage characteristics and quasi-steady-state photoconductance decay method.

• Journal of the Korean Chemical Society
• /
• v.16 no.1
• /
• pp.40-45
• /
• 1972

An electron spin resonance study has been made on lysozyme in. frozen aqueous solutions irradiated with $_{60}Co$ r-rays in air at $77^{circ}K.$ Water resonances are dominant when the concentration and the temperature are both below 20% and $130^{circ}K$ respectively. More solute radicals are produced in the solution of higher concentration. Majority of the solute radicals results from direct hit of the radiation. The same types of radicals are induced at $77^{circ}K$ whether the substances are irradiated in the dry state or in frozen aqueous solution. Based on these results, it is assumed that the number of ESR centers produced by the secondary intermolecular radical reacions and stabilized in aqueous solutions may depend on the concentration of the solution, and the presence of water may facilitate the secondary radical reactions occuring in the solute molecules after heat treatment. Majority of the solute radicals above around $193^{circ}K$ are believed to react with oxygen to form peroxytype radicals. However, when the solution is subiected to heat-treatment at $265^{circ}K$ after irradiation at $195^{circ}K$ the peroxy-type resonance was not observed, suggestin that an appreciable amount of oxygen is condensed into the ice, at $77^{circ}K.$ in addition to the oxygen that has already been dissolved in solution and react with solute free radicals during the process of heat-treatment. When the solution contains $H_2O_2$, no water resonance but $HO_2$, type resonance was observed probably indicating that the radiation-induced OH radicals are trapped in $H_2O_2$ aggregates and react readily with $H_2O_2$ molecules to poroduce $HO_2$ type radicals even at $77^{circ}K.$.

• The Bulletin of The Korean Astronomical Society
• /
• v.40 no.1
• /
• pp.90.2-90.2
• /
• 2015

We present the high-resolution spectrum of the S-type symbiotic star V455 Sco obtained with the Dupont telescope in 2014 June. We note that the Raman-scattered O VI ${\lambda}1032$ at $6825{\AA}$ exhibits a triple-peak profile. Adopting an accretion disk model with an additional contribution from a collimated bipolar outflow, we attempt to fit the profile. We propose that the blue and central peaks are formed via Raman-scattering of O VI line photons from the accretion flow and that the bipolar flow is responsible for the remaining red peak. It is also noted that V455 Sco exhibits the Raman-scattered He II features blueward of $H{\alpha}$ and $H{\beta}$.

• Journal of Ceramic Processing Research
• /
• v.13 no.spc2
• /
• pp.394-397
• /
• 2012

In this work, we studied the influence of the dopant elements concentration on the properties of SnO2 thin films deposited by pulsed laser deposition. X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), Hall effect measurement and UV-Vis studies were performed to characterize the deposited films. XRD results showed that the films had polycrystalline nature with tetragonal rutile structure. FE-SEM micrographs revealed that the as deposited films composed of dense microstructures with uniform grain size distribution. All the films show n-type conduction and the best transparent conductive oxide (TCO) performance was obtained on 6 wt% Sb2O5 doped SnO2 film prepared at pO2 of 60mtorr and Ts of 500 ℃. Its resitivity, optical transmittance, figure of merit are 7.8 × 10-4 Ω cm, 85% and 1.2 × 10-2 Ω-1, respectively.

• Bulletin of the Korean Chemical Society
• /
• v.33 no.10
• /
• pp.3407-3412
• /
• 2012

The Ti incorporation at Fe-site in the double perovskite lattice of $Sr_2FeNbO_6$ (SFNO) system is studied. The Ti concentration optimization yielded an efficient photocatalyst. At an optimum composition of Ti as x = 0.07 in $Sr_2Fe_{1-x}Ti_xNbO_6$, the photocatalyst exhibited 2 times the quantum yield for photolysis of $H_2O$ in presence of $CH_3OH$, than its undoped counterpart under visible light (${\lambda}{\geq}420nm$). Heavily Ti-doped $Sr_2Fe_{1-x}Ti_xNbO_6$ lattice exhibited poor photochemical properties due to the existence of constituent impurity phases as observed in the structural characterization, as well as deteriorated optical absorption. The higher electron-density acquired by n-type doping seem to be responsible for the more efficient charge separation in $Sr_2Fe_{1-x}Ti_xNbO_6$ (0.05 < x < 0.4) and thus consequently displays higher photocatalytic activity. The Ti incorporated structure also found to yield stable photocatalyst.

• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.13 no.1
• /
• pp.36-40
• /
• 2003

The diamond-like nanocomposite (DLN) thin films were deposited on Si substrates using $CH_4/(C_2H_5O)_4Si/H_2$/Ar gas mixtures as source gases by the plasma enhanced chemical vapor deposition (PECVD). The chemical structure and microstructure of grown films were investigated and their tribological properties were evaluated by a ball-on-plate type tribometer. The deposited DLN films mainly consisted of diamond-like a-C:H and quartz-like a-Si:O networks. The DLN films had a good agreement with tribological coating applications due to their extremely low friction coefficients and low wear rates.

• Bulletin of the Korean Chemical Society
• /
• v.27 no.7
• /
• pp.1038-1042
• /
• 2006

A new type of DTPA-bis-amides (L1-L4) and their Gd(III)-complexes of the type $[Gd(L)(H_2O)]{\cdot}nH_2O$ (5: L1; 6: L2; 7: L3; 8: L4) have been prepared and characterized by analytical and spectroscopic techniques. The X-ray crystal structure of 8 has been determined for structural confirmation. The coordination geometry adopts a tricapped trigonal prism geometry with L4 acting as a chelate octadentate and a water molecule in the coordination sphere. Crystals are monoclinic, $P2_1$, a = 14.468(3), b = 19.235(4), c = 13.527(2) $\AA$ $\beta$ = $107.245(3)^{\circ}$, V = 3595.2(11) $\AA^3$, Z = 4, $D_{calc}$ = 1.570. Significant increases in relaxivities are observed with 6 and 7 as compared with that of $Omniscan^{(R)}$, a commercial MR agent: R1 = 12.46 $mM^{-1}\;s^{-1}$, R2 = 8.76 $mM^{-1}\;s^{-1}$ for 6; R1 = 12.77 nm-1 s-1, R2 = 7.60 mM-1 s-1 for 7; R1 = 4.9 $mM^{-1}\;s^{-1}$, R2 = 4.8 $mm^{-1}\;s^{-1}$ for $Omniscan^{(R)}$. In the case of 5, however, both R1 and R2 are found to be lower to show 2.09 $mM^{-1}\;s^{-1}$, and 1.82 $mM^{-1}\;s^{-1}$, respectively.