• Title/Summary/Keyword: $H_2O$ content

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Effect of Application Rate of a Slow-release Fertilizer in Three Media Containing Polyacrylic Acid Sodium Salt on Growth and Nutrient Contents of Potted Chrysanthemum 'Lima Honey' (Polyacrylic Acid Sodium Salt를 혼합한 세 종류 상토에 지효성 비료의 시비 수준이 포트-멈 'Lima Honey'의 생육과 무기원소 흡수에 미치는 영향)

  • Choi Jong-Myung;Wang Hyun-Jin
    • Journal of Bio-Environment Control
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    • v.15 no.1
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    • pp.35-46
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    • 2006
  • Objective of this research was to determine the effect of application rate of a slow release fertilizer (SRF) in three root media, peatmoss+vermiculite (1:1, v/v; PV), peatmoss+composted rice hall (1:1, v/v; PR), and peatmoss+composted pine bark (1:1, v/v; PB), on growth and nutrient contents of potted chrysanthemum 'Lima Honey'. All media contained polyacrylic acid sodium salt at a rate of $4.5g L^{-1}$. The fresh and dry weights at 43 days after transplanting did not show statistical differences among treatments in each root media. Elevated application rate of SRF increased fresh and dry weights at 80 days after transplanting in PV and PB media, but not in PR medium. Elevated application rates of SRF resulted in the increase of tissue phosphorus content and decrease of tissue Ca, Na, and Zn contents at both 43 and 80 days after transplanting. Elevated application rates of SRF resulted in the decrease of pH and increase of EC and concentrations of ${NO_3}^-$ and ${P_2O_5}^{3-}$, K, Ca, and Mg in the soil solution of PV and PR media. The trends of those in PR media were also similar except ${NO_3}^-$. The differences among treatments in EC at 80 days after transplanting were less significant as compared to those at 43 days after transplanting in three media.

Supercritical Fluid Extraction of Safflower Yellow Pigments from Carthamus tinctorius L. (초임계 이산화탄소를 이용한 홍화로부터 황색소 추출)

  • Han, Byung-Seok;Kim, Kong-Hwan;Chung, In-Sik
    • Applied Biological Chemistry
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    • v.41 no.5
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    • pp.363-366
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    • 1998
  • Supercritical fluid(SCF) carbon dioxide was used to extract safflower yellow pigments from Carthamus tinctorius L. In this work, supercritical fluid extractions were performed at various conditions; pressure (2000, 3000, 4000, 5000 psig), temperature $(40,\;50,\;60,\;70,\;80^{\circ}C)$ and co-solvent $(0,\;3,\;6,\;10,\;14\;wt%\;H_2O)$. Total concentrations of safflower yellow pigments extracted were determined by spectrophotometric method. A maximum yield of yellow pigments was obtained at 4000psig, $60^{\circ}C$ and 10% co-solvent. The extraction yield of pigments was also closely related to moisture content of the raw material. Extraction yield of safflower yellow pigments by SCF extraction at optimized conditions was 6% higher than that by solvent extraction. Supercritical carbon dioxide was proved to be suitable for the extraction of safflower yellow pigments from Carthamus tinctorius L.

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Tallium(I) Ion-Selective Electrodes Based on Crown Ethers (크라온에테르를 이용한 탈륨(I) 이온 선택성 전극)

  • Sung Min Kim;Sung Uk Jung;Jineun Kim;Jae Sang Kim
    • Journal of the Korean Chemical Society
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    • v.37 no.8
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    • pp.773-778
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    • 1993
  • Poly(vinyl chloride)(PVC) membrane electrodes based on the lipophilic neutral carrier, dibenzo-18-crown-6(DB18C6) and benzo-15-crown-5 (B15C5) as the active sensors for Tl$^+$ ion have been prepared and tested in different content of the potassium tetrakis(4-chlorophenyl)borate (KTClPB) as lipophilic salt. Dioctyl adipate (DOA), 2-nitrophenyl phenyl ether (NPPE) and o-nitrophenyl actyl ether (NPOE) were used as plasticizing solvent mediators. Electrodes exhibited good linear responses of 40∼55 mV decade$^{-1}$ for Tl$^+$ ion within the concentration ranges 10$^{-1}$∼10$^{-5}$M TlNO$_3$. Selectivity coefficients of interfering ions (alkali metal, alkaline earth metal and some transition metal ions) for Tl$^+$-ISE were determined by separate solution method and were sufficiently small for most of them. These crown ether type ion-selective electrodes are suitable for use with aqueous solution at pH > 3.

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Spectral and Thermal Studies of Transition Metal PSSA Ionomers

  • Shim, Il-Wun;Risen, William M. Jr.
    • Bulletin of the Korean Chemical Society
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    • v.9 no.6
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    • pp.368-376
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    • 1988
  • Transition metal PSSA ionomers containing Co(II), Ni(II), Cr(III), Ru(III), and Rh(III) are investigated by IR, Far-IR, UV-Vis and DSC. Reliable IR Spectroscopic criteria are established for assessing the degree of ion-exchange of PSSA ionomers and the local structures around metal cations in them. In the hydrated transition metal PSSA ionomers, the ionic groups are solvated by water molecules and there is no significant interactions between sulfonate group and metal cations. The visible spectra indicated that metal cations are present as [M$(H_2O)_6$]$^{n+}$ with Oh symmetry. Their $T_g$ values increase as the extent of ionic site concentration increases, but there is no direct dependence of $T_g$ on the nature of metal cations or their oxidation states. Thus, the water content in PSSA ionomer is found to have dominant influence on $T_g$ of hydrated transition metal PSSA ionomers. Dehydration of the hydrated transition metal PSSA ionomers results in direct interaction between ionic groups and significant color changes of the ionomers due to the changes of the local structures around metal cations. On the base of spectral data, their local structures are discussed. In case of dehydrated 12.8 and 15.8 mol % transition metal PSSA ionomers, no glass transition is observed in 25-$250^{\circ}C$ region and this is believed to arise from the formation of highly crosslinked structures caused by direct coordination of sulfonate groups of metal cations. In the 6.9 mol % transition metal PSSA ionomers, the glass transition is always observed whether they are hydrated or dehydrated and this is though to be caused by the sufficient segmental mobility of the polymer backbone.

Effect of Mixed Treatment of Nitrogen Fertilizer and Zeolite on Soil Chemical Properties and Growth of Hot Pepper

  • Park, Jun-Hong;Park, Sang-Jo;Kwon, Oh-Heun;Choi, Seong-Yong;Park, So-Deuk;Kim, Jang-Eok
    • Korean Journal of Soil Science and Fertilizer
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    • v.48 no.1
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    • pp.44-49
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    • 2015
  • Urea has been the most useful N-source, due to lower cost per unit of N. But nitrogen use efficiency of urea may be reduced because of losses from agricultural system by volatilization of ammonia to atmosphere. This study was conducted to evaluate the nitrogen efficiency and growth of hot pepper (Capsicum annuum L.) by mixed treatment with nitrogen and zeolite. They were treated with N $161kg\;ha^{-1}$, N $230kg\;ha^{-1}$, nitrogenzeolite mixture (NZM) $161kg\;ha^{-1}$, NZM $230kg\;ha^{-1}$ and N $0kg\;ha^{-1}$, respectively. In the soil chemical properties after experiment, soil pH decreased but available $P_2O_5$, EC and total nitrogen increased in nitrogen-zeolite mixture treatment. $NO_3-N$ content in the soil showed the highest level in NZM $230kg\;ha^{-1}$. NZM $161kg\;ha^{-1}$ treatment increased growth and yield of hot pepper compared to urea alone. Nitrogen utilization efficiency of hot pepper plant was 47.15% at the treatment of NZM $161kg\;ha^{-1}$, while 36.74% at N $230kg\;ha^{-1}$. These results showed that application of mixture of nitrogen and zeolite had positive influence to improve the efficiency of nitrogen utilization and increase of red pepper yield.

Low-Molecular-Weight Collagen Peptide Ameliorates Osteoarthritis Progression through Promoting Extracellular Matrix Synthesis by Chondrocytes in a Rabbit Anterior Cruciate Ligament Transection Model

  • Lee, Mun-Hoe;Kim, Hyeong-Min;Chung, Hee-Chul;Kim, Do-Un;Lee, Jin-Hee
    • Journal of Microbiology and Biotechnology
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    • v.31 no.10
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    • pp.1401-1408
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    • 2021
  • This study examined whether the oral administration of low-molecular-weight collagen peptide (LMCP) containing 3% Gly-Pro-Hyp with >15% tripeptide (Gly-X-Y) content could ameliorate osteoarthritis (OA) progression using a rabbit anterior cruciate ligament transection (ACLT) model of induced OA and chondrocytes isolated from a patient with OA. Oral LMCP administration (100 or 200 mg/kg/day) for 12 weeks ameliorated cartilage damage and reduced the loss of proteoglycan compared to the findings in the ACLT control group, resulting in dose-dependent (p < 0.05) improvements of the OARSI score in hematoxylin & eosin (H&E) and Safranin O staining. In micro-computed tomography analysis, LMCP also significantly (p < 0.05) suppressed the deterioration of the microstructure in tibial subchondral bone during OA progression. The elevation of IL-1β and IL-6 concentrations in synovial fluid following OA induction was dose-dependently (p < 0.05) reduced by LMCP treatment. Furthermore, immunohistochemistry illustrated that LMCP significantly (p < 0.05) upregulated type II collagen and downregulated matrix metalloproteinase-13 in cartilage tissue. Consistent with the in vivo results, LMCP significantly (p < 0.05) increased the mRNA expression of COL2A1 and ACAN in chondrocytes isolated from a patient with OA regardless of the conditions for IL-1β induction. These findings suggest that LMCP has potential as a therapeutic treatment for OA that stimulates cartilage regeneration.

Adsorption characteristics of NH4-N by biochar derived from pine needles

  • Kang, Yun-Gu;Lee, Jun-Young;Chun, Jin-Hyuk;Lee, Jae-Han;Yun, Yeo-Uk;Oh, Taek-Keun
    • Korean Journal of Agricultural Science
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    • v.48 no.3
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    • pp.589-596
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    • 2021
  • Nitrogen applied to soil is highly prone to leaching and volatilization leading to gaseous emissions of nitrous oxide (N2O) and ammonia (NH3) which are of great environmental concern. Usage of biochar to reduce the discharge of nitrogen to the environment has attracted much interest in the recent past. Biochar is produced by pyrolyzing various biomasses under oxygen-limited conditions. Biochar is a carbonized material with high adsorptive powers for not only plant nutrients but also heavy metals. The objective of this study was to investigate the adsorption characteristics of NH4-N onto biochar made from pine needles. The biochar was produced at various pyrolysis temperatures including 300, 400 and 500℃ and holding times of 30 and 120 minutes. The Langmuir isotherm was used to evaluate the adsorption test results. The chemical properties of the biochar varied with the pyrolysis conditions. In particular, the pH, EC and total carbon content increased with the increasing pyrolysis conditions. The rate of adsorption of NH4-N by the biochar decreased with the increasing pyrolysis conditions. Of these conditions, biochar that was pyrolyzed at 300℃ for 30 minutes showed the highest adsorption rate of approximately 0.071 mg·g-1. Thus, the use of biochar pyrolyzed at low temperatures with a short holding time can most efficiently reduce ammonia emissions from agricultural land.

Do platelet concentrates accelerate orthodontic tooth movement?: a systematic review

  • Sergio Herrero-Llorente;Angel-Orion Salgado-Peralvo;Jan G.J.H. Schols
    • Journal of Periodontal and Implant Science
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    • v.53 no.1
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    • pp.2-19
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    • 2023
  • Purpose: Surgical techniques in orthodontics have received widespread attention in recent years. Meanwhile, biomaterials with high molecular content have been introduced, such as platelet concentrates (PCs), which may accelerate orthodontic tooth movement (OTM) and reduce periodontal damage. The present systematic review aimed to answer the following PICO question: "In patients in whom orthodontic surgical techniques are performed (P), what is the effectiveness of using PCs over the surgical site (I) when compared to not placing PCs (C) to achieve faster tooth movement (O)?" Methods: A search was performed in 6 databases. The criteria employed were those described in the Preferred Reporting Items for Systematic Reviews and Meta-Analyses declaration. The present review included studies with a control group that provided information about the influence of PCs on the rate of OTM. Results: The electronic search identified 10 studies that met the established criteria. Conclusions: The included studies were very diverse, making it difficult to draw convincing conclusions. However, a tendency was observed for OTM to be accelerated when PCs were used as an adjuvant for canine distalization after premolar extraction when distalization was started in the same session. Likewise, studies seem to indicate an association between PC injection and the amount of canine retraction. However, it is not possible to affirm that the use of PCs in corticotomy shortens the overall treatment time, as this question has not been studied adequately.

Effect of Reduced N Application and Planting Density on Paddy Rice (수도에 대한 질소감량시비 및 재식밀도의 영향)

  • Hong, Ki-Chang;Shim, Jae-Han;Seo, Yong-Tack;Park, Ro-Dong;Kim, Kil-Yong;Shon, Boe-Kyun;Kim, Yong-Woong
    • Korean Journal of Soil Science and Fertilizer
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    • v.32 no.1
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    • pp.12-21
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    • 1999
  • This study was carried out to improve the cultivation method of paddy rice when the application amount of nitrogen decreased. We investigated the growth and the yield of paddy rice, the changes of nutrients in the soil solution, soil and paddy rice. The results are as follows. The yield at the N4 plot(N $73kg\;ha^{-1}$) was higher than that of control(N $110kg\;ha^{-1}$). N1(N $55kg\;ha^{-1}$), N2(N $55kg\;ha^{-1}$), and N3(N $73kg\;ha^{-1}$). The number of panicle per square meter at the N4 plot was larger than that of control plot. The increase in yield at the N4 plot was due to increased number of panicle where planting density was two times higher compared to the control plot. The availability of nitrogen at the N4 plot also was two times higher than that of control plot. The pH in soil solution was around 7 and did not change largely. The $K^+$ concentration in soil solution at all plots decreased gradually. The $Ca^{2+}$ concentration in soil solutions increased gradually, and decreased at the later stage slightly. The P concentration in soil solution decreased gradually, increased after the heading stage, and then decreased due to decrease of soil temperature. Leaching of $Ca^{2+}$ was higher, while that of $K^+$ and P was lower compared to other ions. Total content of nutrients in soil after harvest decreased. Contents of total N, total P, and O.M. at the N4 plot were higher than those of the other plots. The content of total N and O.M. was correlated to yield. Contents of N, P and K in rice straw and grain at the N4 plot were the highest among all plots. In conclusion, to decrease N application amount in paddy rice cultivation as well as to maintain yield, planting density should be twice of control and the amount of application of N fertilizer should be two-third of control where N fertilizer should be applied mainly at 20 and 10 day before heading.

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Effect of Liming on the Extractability of Phosphate Added to Uncultivated Acid Soil (미경지(未耕地)의 산성토양(酸性土壤)에서 시용인산(施用燐酸)의 침출성(浸出性)에 미치는 석회(石灰)의 영향(影響))

  • Yoo, Sun-Ho;Lee, Won-Chu;Park, Sung-O
    • Applied Biological Chemistry
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    • v.20 no.1
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    • pp.88-94
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    • 1977
  • A laboratory study was made of liming on the extractability of phosphate added to the uncultivated acid soils differing in clay content. The experiments were conducted with different rates of calcium carbonate and triple superphosphate at field capacity and 50% field capacity. The concentration of extractable phosphate was greatly reduced by simultaneous addition of calcium carbonate in the loam soil. When samples of the loam soil were preincubated for ranging from 0 to 50 days in the presence of calcium carbonate prior to phosphate application, the extractable phosphate concentration increased with preincubation time, and more phosphate was extracted from the soil maintained at 50% field capacity during the incubation. However, the extractable phosphate concentration in the sandyloam soil did not change with preincubation time and was not affected by moisture status. It may be concluded that the extractability of added phosphate was influenced by not only liming time but physical properties of soil.

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