• Title/Summary/Keyword: $H_2$ sensor

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Electronic Tongue Composed of Mini-Electrode Array in Flow Cell (소형전극 어레이로 구성한 흐름계형 전자혀)

  • Shim, Jun Ho;Shim, Jae Hoon;Seo, Sung Seok;Oh, Hyun Joon;Han, Jong Ho;Nam, Hakhyun;Cha, Geun Sig
    • Analytical Science and Technology
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    • v.17 no.3
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    • pp.217-224
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    • 2004
  • A taste sensor system composed of mini electrode array was built in a flow cell. Potentiometric signals from 9 electrodes were collected for drinking waters and alcoholic beverages which were diluted in a low concentration buffer solution (0.005 M Tris-$H_2SO_4$ pH 7.2) for the measurement. The measured results were treated with the principal component analysis (PCA), and grouped on a two or three dimensional PCA coordinate to discriminate the tastes of each beverage. It is demonstrated that the taste sensor system of this work may be used for the quality control of beverages in production or the examination of their taste variation in the market.

Development of a Fiber-optic Noncontact Temperature Sensor for Measuring the Temperature of Cooled Secondary Water in a Nuclear Power Plant (냉각된 원전 2차계통수의 온도측정을 위한 비접촉식 광섬유 온도센서의 개발)

  • Yoo, Wook-Jae;Lee, Bong-Soo;Park, Byung-Gi;Cho, Young-Ho
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.5
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    • pp.1730-1734
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    • 2010
  • Generally, a pH value of secondary water in a nuclear power plant should be estimated after sampling and cooling down. In this process, the measurement of temperature is very important because a pH value is varied according to the temperature of secondary water. In this study, a noncontact fiber-optic temperature sensor using a silver halide optical fiber is fabricated to measure the temperature of cooled secondary water. And we have measured an infrared radiation, which is transferred by a silver halide optical fiber from a heat source, using a thermopile sensor. The relationships between the temperature of a heat source and the output voltage of the fiber-optic temperature sensor according to the change of distance and angle are determined. The measurable temperature range of the fiber-optic temperature sensor is from 25 to $60^{\circ}C$. Based on the results of this study, a noncontact temperature sensor using a silver halide optical fiber can be developed for the temperature measurement of the pH sample in the secondary water system.

Micromachined pH Sensor Using Open Well Structures (개방형 우물 구조를 이용한 마이크로머신형 pH 센서)

  • Kim, Heung-Rak;Kim, Young-Deog;Jeong, Woo-Cheol;Kim, Kwang-Il;Kim, Dong-Su
    • Journal of the Korean Society for Nondestructive Testing
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    • v.22 no.4
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    • pp.347-353
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    • 2002
  • A structure of a glass electrode-type pH sensor for measuring any concentration of $H^+$ in an aqueous solution was embodied with bulk micromachining technology. Two open well structures were formed, and a reference electrode was secured by the Ag/AgCl thin film in the sloped side of the etched structure. A sensitive membrane of an indicator electrode for generating a potential by an exchange reaction to $H^+$ was made with a glass containing Na 20% or more finely so that its thickness might be $100{\mu}m$ or so, and then it was bonded to one pyramidal structure. A liquid junction for a current path was formed by filling an agar in the anisotropically etched part of the Si wafer, which had a size of $50{\mu}m{\times}50{\mu}m$, and then bonded it to the other. After complete fabrication of each part, it was filled with a 2M KCl reference solution and encapsulated the sensor structure with a cold expoxy. The potential value of fabricated pH sensor was about 90mV/pH in the standard pH solutions.

Fabrication of High-Performance Colorimetric Fiber-Type Sensors for Hydrogen Sulfide Detection (황화수소 가스 감지를 위한 고성능 변색성 섬유형 센서의 제작 및 개발)

  • Jeong, Dong Hyuk;Maeng, Bohee;Lee, Junyeop;Cho, Sung Been;An, Hee Kyung;Jung, Daewoong
    • Journal of Sensor Science and Technology
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    • v.31 no.3
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    • pp.168-174
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    • 2022
  • Hydrogen sulfide(H2S) gas is a high-risk gas that can cause suffocation or death in severe cases, depending on the concentration of exposure. Various studies to detect this gas are still in progress. In this study, we demonstrate a colorimetric sensor that can detect H2S gas using its direct color change. The proposed nanofiber sensor containing a dye material named Lead(II) acetate, which changes its color according to H2S gas reaction, is fabricated by electrospinning. The performance of this sensor is evaluated by measuring RGB changes, ΔE value, and gas selectivity. It has a ΔE value of 5.75 × 10-3 ΔE/s·ppm, showing improved sensitivity up to 1.4 times that of the existing H2S color change detection sensor, which is a result of the large surface area of the nanofibers. The selectivity for H2S gas is confirmed to be an excellent value of almost 70 %.

H2S Gas Sensing Properties of CuO Nanotubes

  • Kang, Wooseung;Park, Sunghoon
    • Applied Science and Convergence Technology
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    • v.23 no.6
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    • pp.392-397
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    • 2014
  • CuO nanotubes are synthesized using $TeO_2$ nanorod templates for application to $H_2S$ gas sensors. $TeO_2$ nanorod templates were synthesized by using the VS method through thermal evaporation. Scanning electron microscopy, transmission electron microscopy and X-ray diffraction showed that the synthesized nanotubes were monoclinic-structured polycrystalline CuO with diameter and wall thickness of approximately 100~300 nm and 5~10 nm, respectively. The CuO nanotube sensor showed responses of 136~325% for the $H_2S$ concentration of 0.1~5 ppm at room temperature. These response values are approximately twice as high as that of the CuO nanowire sensor for the same concentrations of $H_2S$ gas. Along with the investigation of the performance of the sensors, the mechanisms of $H_2S$ gas sensing of the CuO nanotubes are also discussed in this study.

Fabrication and Evaluation of a New High-Temperature pH Sensor for Use in PWR Nuclear Power Plants

  • Jung, Yong-Ju;Yeon, Jei-Won
    • Bulletin of the Korean Chemical Society
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    • v.31 no.10
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    • pp.2939-2942
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    • 2010
  • A new high-temperature pH sensor has been successfully developed by reforming the internal reference systems of the pH sensors based on oxygen-ion conducting ceramic membrane. The conventional internal reference system, a mixture of Ni and NiO, has been replaced with partially oxidized Ni powders, where Ni and NiO coexist on the surface of particles, in order to avoid the cumbersome mixing step of Ni and NiO particles. The partially oxidized Ni particles were made by oxidizing Ni under air atmosphere at $600^{\circ}C$ and characterized by X-ray diffraction (XRD) and FTIR spectroscopy. The viability of the pH sensor developed was assessed in boric acid (1000 ppm-B)/ lithium hydroxide (1 to 3 ppm-Li) buffer solutions at $280^{\circ}C$. The pH sensor showed excellent accuracy with a small error less than ${\pm}0.2$ pH units.

Characteristics and Fabrication of Dissolved Oxygen and pH Measurement System based on the Optical Sensor for Analysis of Cell Metabolic Functions (세포대사 기능 분석을 위한 광학센서 기반 용존산소와 pH 측정 시스템의 제작 및 특성 분석)

  • Jang, Jiwoon;Hwang, Insook;Lee, Jongmok;Lee, Sunmin;Kang, Sora;Kim Pak, Youngmi;Kim, Nayoung
    • Journal of Sensor Science and Technology
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    • v.25 no.1
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    • pp.51-56
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    • 2016
  • This study evaluates the performance of an optical sensor and measurement system (CMA-24) which can analyze the fluctuation of dissolved oxygen and pH simultaneously. In the optical sensor system, the fluorescent materials, Rudpp and HPTS which are sensitive to dissolved oxygen and pH, respectively, are coated on the bottom of a 24-well -plate by the sol-gel technology. The detection times of the emission light of the oxygen sensor were $4,186{\pm}13.90{\mu}s$ and $4,452{\pm}36.68{\mu}s$ for the dissolved oxygen of 17% $O_2$ and 7.6% $O_2$, respectively. On the other hand, the detection times of the pH sensor were $6,699.43{\pm}14.64{\mu}s$, $6,722.24{\pm}6.21{\mu}s$, and $6,748.52{\pm}2.63{\mu}s$ using pH 6, 7, and 8, respectively. When we determined cellular respiration levels of C2C12 myocytes with CMA-24, $O_2$/pH measurement system, the ratio of the uncoupled to coupled OCR (oxygen consumption rate) was 1.41. The results mean that this CMA-24 system shows almost the same sensitiveness as the commercial system.

Sensitivity enhancement of H2 gas sensor using PbS quantum dots (황화납 양자점 감지막을 통해 감도가 개선된 수소센서)

  • Kim, Sae-Wan;Kim, Na-Ri;Kwon, Jin-Beom;Kim, Jae Keon;Jung, Dong Geon;Kong, Seong Ho;Jung, Daewoong
    • Journal of Sensor Science and Technology
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    • v.29 no.6
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    • pp.388-393
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    • 2020
  • In this study, a PbS quantum dots (QDs)-based H2 gas sensor with a Pd electrode was proposed. QDs have a size of several nanometers, and they can exhibit a high surface area when forming a thin film. In particular, the NH2 present in the ligand of PbS QDs and H2 gas are combined to form NH3+, subsequently the electrical characteristics of the QDs change. In addition to the resistance change owing to the reaction between Pd and H2 gas, the resistance change owing to the reaction between the NH2 of PbS QDs and H2 gas increases the current signal at the sensor output, which can produce a high output signal for the same concentration of H2 gas. Using the XRD and absorbance properties, the synthesis and particle size of the synthesized PbS QDs were analyzed. Using PbS QDs, the sensitivity was significantly improved by 44%. In addition, the proposed H2 gas sensor has high selectivity because it has low reactivity with heterogeneous gases such as C2H2, CO2, and CH4.

Study on Optimal Structure of Low Power Microheater to Remain Stability at High Temperature (고온에서 안정한 저전력 마이크로히터 구조 최적화 연구)

  • Lim, Woonhyun;Kondalkar, Vijay;Lee, Keekeun
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.68 no.1
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    • pp.69-76
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    • 2019
  • Microheaters with different structures were fabricated and compared to find an optimal configuration enhancing the performances of $C_2H_2$ gas sensor. Three temperature sensors were integrated on the surface of the insulation layer over the microheater, and resistance changes were observed to check the generated heat from the microheater. A low operating voltage of 1mV was applied to the temperature sensor to minimize any influence of thermal heat from the resistance type temperature sensor, whereas high voltages in the range between 10 and 20V were applied to the microheater. A microheater structure generating maximum heat at low voltage was determined. The generated heat was verified by the temperature sensors on the top of the $Si_3N_4$ and infrared camera. A long term stability and accuracy of the microheater were observed. The developed microheater was applied to enhance the performances of $C_2H_2$ gas sensor and successfully confirmed that the developed microheater greatly contributes to the improvement of sensitivity and selectivity of gas sensor.

pH-Drift Characteristics of Sol-Gel-Deposited $Ta_{2}O_{5}$-Gate ISFET (Sol-Gel 법으로 형성한 $Ta_{2}O_{5}$ 게이트 ISFET의 pH 드리프트 특성)

  • Kwon, Dae-Hyuk;Cho, Byung-Woog;Kim, Chang-Soo;Sohn, Byung-Ki
    • Journal of Sensor Science and Technology
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    • v.5 no.2
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    • pp.15-20
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    • 1996
  • The diffusion of hydrogen ions into a sensing membrane causes the output voltage of pH-ISFET to vary with time, which might be considered to be drift in this sensor. We tried to deposit ultra-thin film for minimizing tile drift that has been considered to be main obstacle for putting pH-ISFET to practical use. In this paper, tantalum pentoxide, known as a good pH sensing membrane, was formed to about $70{\AA}$ thick by sol-gel method on $Si_{3}N_{4}/SiO_{2}$-gate of pH-ISFET. The fabricated $Ta_{2}O_{5}$-gate pH-ISFET showed good sensitivity(about 59mV/ pH) and good lineality in the range of pH $3{\sim}11$, and had relatively small average pH drift of about 0.06 pH/day.

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