• 전력전자학회:학술대회논문집
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• 전력전자학회 2002년도 전력전자학술대회 논문집
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• pp.257-262
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• 2002

Water-Electrolyzed gas is a mixed gas has the constant volume ratio 2 1 Hydrogen and Oxygen gained from electrolyzed water, and it has better characteristics in the field of economy, efficiency of energy, and environmental intimacy than acetylene gas and LPG used for existing gas welding equipment. So nowdays many studies of Water-Electrolyzed gas are progressed, and commercially used as a source of thermal energy for gas welding in the industry. For Water-Electrolyzed Source, it was used diode rectifier or SCR rectifier for get DC source. This method which is not looking to improve a source for impossible current control or voltage and limited control intervals. In this paper, it was relized and designed In source of pulse type for complementing existing - DC source type, also by experiment it was acquired producting characteristics of Hydrogen -Oxygen Gas through feature of source

• 전력전자학회:학술대회논문집
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• 전력전자학회 2002년도 추계학술대회 논문집
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• pp.89-93
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• 2002

Hydrogen - Oxygen gas has obtained from water electrolysis reaction. It is mixed gas havingconstant volume ratio 2:1 Hydrogen and Oxygen, and it is used as a source of thermal energy by combustion reaction. This gas has betterristics in the field of economy, efficiency of energy, and environmental intimacy than used both of acetylene gas and LPG for gas welding machin. So nowdays many studies of Water-Electrolyzed gas are progressed, and commercially used as a source of thermal energy for gas welding In the industry. For Water-Electrolyzed Source, it was used diode rectifier or SCR rectifier for get DC source. This method which is not looking to improve a source for impossible current control or voltage and limited control intervals. In this paper, it was relized and designed in source of pulse type for complementing existing-DC source type, also by experiment it was acquired producting characteristics of Hydrogen -Oxygen Gas through feature of source

• 한국대기환경학회지
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• 제14권5호
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• pp.455-464
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• 1998

Removal teals of Soxmox were performed using low density ceramic filters doped with various catalysts. Disc type (50 mmO.Dx10 mmt) low density ceramic filters were doped with three different catalysts such as Cu to remove SOx and NOx, and Mn and Co to remove NOx. The air permeabilities and specific surface areas were 40~50cc/min.cm2.cmH2O and 4.1~8.88 m2/g, respectively. Also, the peak pore sizes of catalyst support were 3~5nm. Tests were focused to search optimum operating temperatures for different catalysts. It was found that as the CuO content increases, SOx removal efficiency was increased. NOx removal efficiencies for Mn, Cu and Co, were 85% at 30$0^{\circ}C$, 90% at 40$0^{\circ}C$ and 90% at 45$0^{\circ}C$, respectively.

• Korean Chemical Engineering Research
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• 제47권5호
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• pp.580-586
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• 2009

본 연구에서는 2 MWe 규모 순환유동층 발전소에서 중국산 유연탄과 북한산 무연탄의 혼합연소특성을 실험적으로 고찰하였다. 중국유연탄과 호주유연탄을 과잉공기량과 층온도 등을 변수로 실험한 결과, 연소효율은 석탄입자의 입도와 석탄중의 휘발분의 영향을 받으며, 이 때 미연탄소분은 Fly ash 5~7%, 바닥회 0.3% 수준으로 중국 유연탄의 연소효율은 99.5% 이상을 보였다. 북한산 무연탄과 유연탄의 혼소시 혼합비 20%에서 무연탄의 평균입도가 작아 연소실에서 비산되는 입자로 인해 연소효율은 5% 이상 저하되었다, 그러나 $SO_2$와 NOx의 배출농도는 크게 변화하지 않았다. 배출되는 대기오염물질의 농도는 $NO_x$ 200~250 ppm($O_2$ 6%), $SO_2$ 100~320 ppm($O_2$ 6%)이었다. SCR 공정에서 2~13 l/min 범위의 $NH_3$ 공급으로 30~65%의 $NO_x$가 저감되었다. Limestone을 이용한 노내탈황에서 약 Ca/S 몰비 6.5를 공급했을 때 $SO_2$가 75% 제거되었고, $Mg(OH)_2$를 흡수제로 하는 FGD를 운전했을 때 pH 5.0 이상에서 100% 탈황효과를 보였다.

• 대한수학회지
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• 제43권4호
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• pp.899-909
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• 2006

Let T be a bounded linear operator on a complex infinite dimensional Hilbert space $\scr{H}$. We say that T is a quasi-class A operator if $T^*\|T^2\|T{\geq}T^*\|T\|^2T$. In this paper we prove that if T is a quasi-class A operator and f is a function analytic on a neigh-borhood or the spectrum or T, then f(T) satisfies Weyl's theorem and f($T^*$) satisfies a-Weyl's theorem.

• 한국산학기술학회논문지
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• 제10권8호
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• pp.2015-2020
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• 2009

상압, $200^{\circ}C - 500^{\circ}C$ 조건에서 연소후 배기가스중의 질소산화물 감소 연구가 금속 담지 ZSM-5 촉매에서 수행되었다. 제조된 촉매의 특성은 XRD, SEM, EDX, ICP, ITR 분석 장치를 사용하여 분석하였다. EDX와 ICP 결과로부터 전이 금속이 촉매 표면에 분산된 것을 확인하였다. 금속 담지 ZSM-5 촉매중 Fe/ZSM-5가 최대 NOx 제거율을 보이는 온도 범위($380^{\circ}C-400^{\circ}C$)는 ITR 결과의 최대 환원 속도를 나타내는 온도 $400^{\circ}C$와 일치하므로, 환원 속도가 HC-SCR 반응 속도를 조절하는 것으로 판단된다.

• 한국수소및신에너지학회논문집
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• 제28권2호
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• pp.129-136
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• 2017

Characteristics of $ZrO_2$ felt supported Cu/Zn catalysts have been investigated for the production of hydrogen via methanol steam reforming. Cu and Zn in different weight percent were loaded using wet impregnation over $ZrO_2$ felt support. The catalysts were characterized with BET and FE-SEM. The performance of these synthesized catalysts were investigated at SCR=1.5, $GHSV=2000h^{-1}$, temperature=$300{\sim}400^{\circ}C$, and pressure=2.5~19.5 barA. The results showed that the $Cu^{32.5}Zn^{7.5}ZrO_2$ catalyst was most active in terms of methanol conversion and hydrogen production. The methanol conversion in steam reforming of methanol was 84.6% at 19.5 barA and furnace $400^{\circ}C$ over $Cu^{32.5}Zn^{7.5}ZrO_2$ catalyst. The catalysts prepared using $ZrO_2$ felt show higher reactor temperature than the pellet type catalyst at same furnace temperature.

• Korean Journal of Chemical Engineering
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• 제35권12호
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• pp.2365-2378
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• 2018

We investigated the correlation between vanadium surface density and VOx structure species in the selective catalytic reduction of NOx by $NH_3$. The properties of the $VOx/TiO_2$ catalysts were investigated using physicochemical measurements, including BET, XRD, Raman spectroscopy, FE-TEM, UV-visible DRS, $NH_3-TPD$, $H_2-TPR$, $O_2-On/Off$. Catalysts were prepared using the wet impregnation method by supporting 1.0-3.0 wt% vanadium on $TiO_2$ thermally treated at various calcination temperatures. Through the above analysis, we found that VOx surface density was $3.4VOx/nm^2$, and the optimal V loading amounts were 2.0-2.5 wt% and the specific surface area was $65-80m^2/g$. In addition, it was confirmed that the optimal VOx surface density and formation of vanadium structure species correlated with the reaction activity depending on the V loading amounts and the specific surface area size.

• 한국재료학회지
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• 제12권2호
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• pp.129-134
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• 2002

The optimum condition for fabricating cordierite disc type filter element was deduced. Cordierite monolith was used as starting material for filter element because it has many advantages such as high thermal shock resistance and good catalytic activity compared with $TiO_2$and SiC. The contents of organic additives and foaming agent were optimized to control the porosity and mechanical strength of cordierite filter. Among the required properties to be adopted as filter elements, the pressure drop and NOx removal efficiency were investigated depending on processing variables. It was found that pressure drop depends on particle size distribution of cordierite monolith and organic additives added as forming agent. The pressure drop at 5cm/sec of face velocity was in the range of 15~655mm$H_2O$ at room temperature. The NOx removal efficiency of catalytic filter with $V_2O_5$ as catalyst was over 85% at $450^{\circ}C$.

• Journal of Advanced Marine Engineering and Technology
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• 제30권1호
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• pp.81-87
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• 2006

In marine air pollution control, SCR (Selective Catalytic Reduction) is reconized as the most effect method to control NOx, but on the other hand. seawater scrubber applying the basic characteristic that is naturally alkaline (pH typically around 8.1) is viewed as an economical SOx removal system at present. Especially, seawater scrubber would not be necessary to follow any of the various land based flue gas desulfurization methods. i.e. wet, dry or alkali scrubbing. However, these methods are not readily adaptable to marine conditions due to the quantifies of consumables required i.e. lime or limestone, the means of operation and the commercial availability. This research is undertaken to develop a new method as the main target of eliminating all exhaust emissions, particularly vessel, because of easy access to seawater and apt to apply a wet scrubber system. First, using the acidic seawater by seawater electrolysis, nitric monoxide(NO) is adequately oxidized to nitric dioxide $(NO_2)$by ClOx-in the acidic seawater, the electrolyzed alkaline seawater by electrolysis which contains mainly NaOH together with alkali metal ions $(i.e\;Na^{+}\;K^{+},\;Mg_{2}\;^{+},\;Ca_{2}\;^{+})$, is used as the absorption medium of NOx, the SOx are absorbed by relatively high solubility compared to other components of exhaust pollutants. The results found that the NOx and SOx removals could be achieved nearly Perfect.