• Title/Summary/Keyword: $H_2$

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Adsorption Dynamics of Activated Carbon and Carbon Molecular Sieve Beds for Ethylene Recovery (배가스로부터에틸렌 회수를 위한 활성탄과 CMS 흡착탑의 흡착거동 특성)

  • Yoon, Ki-Yong;Jun, Phillip;Woo, En-Ji;Ahn, Hyungwoong;Lee, Chang-Ha
    • Korean Chemical Engineering Research
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    • v.50 no.3
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    • pp.527-534
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    • 2012
  • The adsorption dynamics of activated carbon (AC) and carbon molecular sieve (CMS) beds were studied to recover ethylene from FCC fuel gas. In this study, the FCC fuel gas used consisted of six-component mixture ($CH_4/C_2H_4/C_2H_6/C_3H_6/N_2/H_2$,32:15:14:2:12:25 vol.%). And the breakthrough experiments of adsorption and desorption were carried out. The breakthrough sequence in the AC bed was $H_2$ < $N_2$ < $CH_4$ < $C_2H_4$ < $C_2H_6$ while the sequence in the CMS bed was $H_2$ < $CH_4$ < $N_2$ < $C_2H_6$ < $C_2H_4$. The separation performance of the CMS bed during the adsorption step was lower than that of the AC bed. However, due to the characteristics of kinetic separation, the CMS bed could remove $CH_4/N_2$ as well asthe molecules that are larger than $C_2H_6$, which was not easy to be done by the AC bed. Since it was hard to regenerate the adsorption bed by simple depressurization, vacuum regeneration should be adopted. As a result, the pressure vacuum swing adsorption (PVSA) process, consisting of CMS pretreatment process and AC main process, was suggested to recover ethylene efficiently.

The PGC-II Polymorphism of the Peroxisome Proliferator-activated Receptor ${\gamma}$ Coactivator $1{\alpha}$ (PGC-$1{\alpha}$) Gene in Korean Subjects with the Metabolic Syndrome

  • Im, Sun-Ok;Kim, In-Sik;Kang, Sang-Sun;Hyun, Sung-Hee
    • Biomedical Science Letters
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    • v.18 no.2
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    • pp.139-145
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    • 2012
  • RFLP of PGC-$1{\alpha}$ gene of 285 Korean women was analyzed by PCR and HpaII restriction. We evaluated the correlation between PGC 1 genotypes and biochemical results, using the results of RFLP. Study subjects were divided into 3 groups: normal group (who has been average value of serum biochemical analysis), upper group (who has been higher value than average value), and low group (who have been lower value than average value). The frequencies of $H_1H_1$, $H_1H_2$, and $H_2H_2$ genotypes were 92 (32%), 85 (32%), and 108 (38%) respectively, and the ratio between $H_1$ and $H_2$ alleles was 1:1.1. There were no meaningful differences between biochemical results and PGC-$1{\alpha}$ genotypes in the normal group. But, in upper group, there was significant difference in total cholesterol (P=0.04) level. In the result of Turkey multiple comparison test, the P value of $H_1H_1$ and $H_2H_2$ was 0.059. In upper group, there were noticeable differences also in triglyceride (P=0.034) level and glucose (P=0.043) level, respectively. There were important differences between $H_1H_1$ type and $H_1H_2$ type in triglyceride (P=0.029) level and between $H_1H_2$ type and $H_2H_2$ type in glucose (P=0.040) level. This study may provide the PGC-$1{\alpha}$ genotype patterns for the amounts of lipid and glucose in the serum. $H_2$ allele (Ser482) of PGC-$1{\alpha}$ gene may be related with upper group in Korean women.

Hydrogen Storage Properties of Pure MgH2

  • Kwak, Young Jun;Lee, Seong Ho;Park, Hye Ryoung;Song, Myoung Youp
    • Korean Journal of Materials Research
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    • v.23 no.5
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    • pp.266-270
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    • 2013
  • The hydrogen storage properties of pure $MgH_2$ were studied and compared with those of pure Mg. At the first cycle, pure $MgH_2$ absorbed hydrogen very slowly at 573 K under 12 bar $H_2$. The activation of pure $MgH_2$ was completed after three hydriding-dehydriding cycles. At the $4^{th}$ cycle, the pure $MgH_2$ absorbed 1.55 wt% H for 5 min, 2.04 wt% H for 10 min, and 3.59 wt% H for 60 min, showing that the activated $MgH_2$ had a much higher initial hydriding rate and much larger $H_a$ (60 min), quantity of hydrogen absorbed for 60 min, than did activated pure Mg. The activated pure Mg, whose activation was completed after four hydriding-dehydriding cycles, absorbed 0.80 wt% H for 5 min, 1.25 wt% H for 10 min, and 2.34 wt% H for 60 min. The particle sizes of the $MgH_2$ were much smaller than those of the pure Mg before and after hydriding-dehydriding cycling. The pure Mg had larger hydrogen quantities absorbed at 573K under 12 bar $H_2$ for 60 min, $H_a$ (60 min), than did the pure $MgH_2$ from the number of cycles n = 1 to n = 3; however, the pure $MgH_2$ had larger $H_a$ (60 min) than did the pure Mg from n = 4 to n = 6.

Synthesis and Spectroscopic Studies of Metal Complexes Formed in the Reaction of Metal Ions with Urea at High Temperature (높은 온도에서 Urea와 금속이온과의 반응으로 얻어진 금속 Complexes의 합성과 분광학적 연구)

  • Gaballa, Akmal S.;Teleb, Said M.;Nour, El-Metwally
    • Journal of the Korean Chemical Society
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    • v.51 no.4
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    • pp.339-345
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    • 2007
  • Urea reacts with PtCl2, H2[PtCl6]·6H2O, H2[IrCl6] and Ni(CH3CO2)2 in aqueous solution at high temperature (60-80 °C) yielding [PtCl2(Urea)]·2H2O (1), (NH4)2[PtCl6] (2), (NH4)2[IrCl6]·H2O (3) and [Ni2(OH)2(NCO)2(H2O)2] (4) complexes, respectively. In complex 1, urea coordinates to Pt(II) as a neutral bidentate ligand via amido nitrogen atoms. In complexes 2, 3 and 4 it seems that the coordinated urea molecules decompose during the reaction at high temperature and a variety of reaction products are obtained. All complexes were isolated in moderate yields as dark green (1), yellow (2), pale brown (3) and faint green (4) precipitates, respectively. The reaction products were characterized by their microanalysis, IR, 1H and 13C NMR spectra as well as thermal analysis. General mechanisms describing the formation of these complexes were suggested.

A Study on Improvement of Gesture Function according to the Sleeve's Height and Existence of Elastic - Focused on Female High School Student's Summer Blouses - (소매산의 높이와 신축성 유무에 따른 동작기능성에 관한 연구 - 여고생 여름 교복 블라우스를 중심으로 -)

  • Park, Kil-Soon;Ryu, Sin-A
    • The Research Journal of the Costume Culture
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    • v.17 no.6
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    • pp.992-1008
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    • 2009
  • This study is to present a female high school summer blouse with high movement functionality and satisfying appearance. For the experimental research 6 subjects with closest average body shapes and their body surface was measured at beginning and after selecting a representative movement the tested uniform was worn and the appearance and movement functionality was evaluated. The results of this research are as follows. In the research with the aims to improve the sleeve designed the height in 3 types as A.H/4+3, A.H/4+2, A.H/4+1 and their evaluation showed that in the order of best appearance was A.H/4+2, A.H/4+1, A.H/4+3. In the order of best comfort was A.H/4+2, A.H/4+3, A.H/4+1 and the best order for movement functionality was A.H/4+1, A.H/4+2, A.H/4+3. Additional height types designed produced from elastic materials were A.H/4+3, A.H/4+2, A.H/4+1 and the resulting order of appearance was A.H/4+3, A.H/4+2, A.H/4+1, order of comfort was A.H/4+3, A.H/4+2, A.H/4+1 and the order of movement functionality was A.H/4+1, A.H/4+2, A.H/4+3. Integrating these results shows that in using the same concurrent materials, the experiment pattern of setting the sleeve height as A.H/4+2 was the best while in using elastic materials, the experiment pattern of setting the sleeve height as A.H/4+3 was the best.

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Decolorization of Rhodamine B by Photo-Fenton Oxidation (광-펜톤 산화반응을 이용한 Rhodamine B의 탈색)

  • Park, Young-Seek
    • Journal of Korean Society on Water Environment
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    • v.23 no.2
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    • pp.274-280
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    • 2007
  • The photochemical decolorization of Rhodamine B (RhB) in water has been carried out by photo-Fenton process. The effect of applied $H_2O_2$, $Fe^{2+}$ dose, solution pH and UV dose have been studied. The influence of constituent processes of photo-Fenton such as UV, $H_2O_2$ and Fenton has been investigated. Comparison of RhB removal was made between the photo-Fenton and $UV/H_2O_2$ process. The results obtained showed that the optimum dosage of $Fe^{2+}$ and $H_2O_2$ were 0.0031 mmol and 0.625 mol, respectively. pH 3 is found to be the optimum pH of for photo-Fenton process. pH and UV dose strongly influenced the decolorization of RhB in photo-Fenton process. The photo-Fenton and $UV/H_2O_2$ processes showed similar decolorization and seem to be appropriate for the decolorization of dye wastewater.

Mixed H_2/H_{\infty}$ controller design algorithm for robust performance optimization (견실성능 최적화를 위한 혼합 H_2/H_{\infty}$ 제어기설계 알고리즘)

  • 김종해;방경호;박홍배
    • Journal of the Korean Institute of Telematics and Electronics B
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    • v.33B no.5
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    • pp.10-16
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    • 1996
  • In this paper, we consider a generalized mixed H_2/H_{\infty}$ output feedback problem. It is finding an internally stabilizing controller that minimizes a mixed $H_{2}$/ $H_{performance}$ measure. We show that a generalized mixed H_2/H_{\infty}$ system with two exogenous inputs and two controlled signals is transformed into auxiliary system with two exogenous inputs and one controlled signal. The two systems have equivalent performance. Therefore, a complete solution of generalized mixed H_2/H_{\infty}$ output feedback problem is achieved by existing results of mixed H_2/H_{\infty}$ control theory.

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Fuzzy H2H Controller Design for Delayed Nonlinear Systems (시간지연을 갖는 비선형 시스템의 퍼지 H2H 제어기 설계)

  • Jo, Hui-Su;Lee, Gap-Rae;Park, Hong-Bae
    • Journal of Institute of Control, Robotics and Systems
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    • v.8 no.7
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    • pp.578-583
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    • 2002
  • This paper presents a method for designing fuzzy $H_2/H_{\infty}$ controllers of nonlinear systems with time varying delay. Takagi-Sugeno fuzzy model is employed to represent nonlinear systems with time varying delay. Using a single quadratic Lyapunov function, the globally exponential stability and $H_2/H_{\infty}$ performance problem are discussed. A sufficient condition for the existence of fuzzy $H_2/H_{\infty}$ controllers is then presented in terms of linear matrix inequalities(LMls). The proposed fuzzy $H_2/H_{\infty}$ controllers minimizes the upper bound on the linear quadratic performance measure.

Mixed $H^{2}$/$H^{\infty}$ controller design for linear system with time delay and parameter uncertainty (시간지연 및 파라미터 불확실성을 갖는 선형시스템의 혼합 $H^{2}$/$H^{\infty}$ 제어기 설계)

  • 이갑래;정은태;박홍배
    • 제어로봇시스템학회:학술대회논문집
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    • 1996.10b
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    • pp.560-564
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    • 1996
  • A mixed H$^{2}$/$H^{\infty}$ controller design method for linear systems with time delay in all variables and parameter uncertainties in all system matrices is proposed. Robust $H^{\infty}$ performance and H$^{2}$ performance condition that accounts for model-matching of closed loop system and disturbance rejection is also derived. With expressing uncertain system with linear fractional transformation form, we transform the robust stability and performance problem to the H$^{2}$/$H^{\infty}$ optimization problem and design a mixed H$^{2}$/$H^{\infty}$ controller. Using the proposed method, mixed H$^{2}$/$H^{\infty}$ controller for underwater vehicle with time delay and parameter variations are designed. Simulations of a design example with hydrodynamic parameter variations and disturbance are presented to demonstrate the achievement of good robust performance.t performance.ance.

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Effect of $H_O_2$ on the Corrosion Behavior of 304L Stainless Steel ($H_O_2$ 가 304L 스텐리스강의 부식거동에 미치는 영향)

  • Song, Taek-Ho;Kim, In-Sup;Park, Sung-Ki
    • Nuclear Engineering and Technology
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    • v.27 no.4
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    • pp.453-462
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    • 1995
  • In connection with the safe storage of high level nuclear waste, effect of $H_2O$$_2$ on the corrosion behavior of 304L stainless steel was examined. Open circuit potentials and polarization curves were measured with and without $H_2O$$_2$. The experimental results show that $H_2O$$_2$ increased corrosion potential and decreased pitting potential. The passive range, therefore, decreased as $H_2O$$_2$ concentration increased, indicating that pitting resistance was decreased by the existence of $H_2O$$_2$ in the electrolyte. These effect of $H_2O$$_2$ on corrosion of 304L stainless steel are considered to be similar to those of ${\gamma}$-irradiation. To compare the effects of $H_2O$$_2$ with those of $O_2$, cathodic and anodic polarization curves ore made in three types of electrolyte such as aerated, deaerated, and stirred electrolyte. The experimental results show that the effects of $H_2O$$_2$ on the corrosion behavior were tory similar to those of $O_2$ such as increase of corrosion potential, decrease of pitting resistance, and increase of repassivation potential. In acid and alkaline media, the corrosion potential shifts by $H_2O$$_2$ were restricted by the large current density of proton reduction and by the le Chatelier's principle respectively.y.

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