• Title/Summary/Keyword: $Fe_2SiO_4$

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Hydrogen Permeation of ZnO-SiC Membranes Encapsulated with SiO2

  • Choi, Hyunji;Hwang, Hyeyoun;Jung, Miewon
    • Journal of the Korean Ceramic Society
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    • v.51 no.6
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    • pp.566-569
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    • 2014
  • ZnO and SiC powders were fabricated to make crack-free composite membranes. Parts of some membranes were re-treated with an encapsulation process. These membranes were characterized by XRD, BET, and FE-SEM analyzes. The hydrogen permeation fluxes of the encapsulated and heat-treated membranes after encapsulation were observed using Sievert's type equipment. Values were measured at 1 bar with increasing temperatures. The obtained values of encapsulated and further heat-treated membrane at 298 K were $4.20{\times}10^{-6}$ and $8.64{\times}10^{-5}mol/m^2sPa$, respectively.

Effect of Flooding and Organic Matter to the Release of Iron, Manganese, and Silica in Soils (침수처리(湛水處理) 및 유기물(有機物) 첨가(添加)가 답토양(畓土壤)의 Fe, Mn 및 SiO2의 용출량(溶出量)에 미치는 영향(影響)에 관(關)한 연구(硏究))

  • Park, Y.S.;Oh, W.K.;Park, N.J.
    • Korean Journal of Soil Science and Fertilizer
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    • v.1 no.1
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    • pp.1-5
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    • 1968
  • A low yielding paddy soil was water logged at $30{\pm}2^{\circ}C$ with soluble starch as a easily decomposable organic matter for 3 weeks in the laboratory. The relation of pH and Eh changes and soluble iron, manganese and silica was investigated. The experimental results obtained were summarized as follows; 1. When organic matter was applied, reduction of the soil was severer, that is, Eh value was lower by 200 mv. for a week in the beginning of submergence. 2. pH of the untreated soil was dropped a little just after submergence, and then gradually increased to 60. When treated, pH was increased due to abrupt drop of Eh in the beginning but decreased to 4.5 after a week, and became constant at this pH value. 3. Slight increase in soluble iron, manganese and silica was observed in the untreated soil whereas soluble iron, manganese and silica in the treated soil were increased about 20, 10, and 3 times, respectively. 4. When soluble starch was treated, pH and soluble silica or manganese was highly correlated[($H^+$) and Mn ${\gamma}=0.734^{**}$, ($H^+$) and $SiO_2$ ${\gamma}=0.923^{**}$] and below pH 5.0, release of these element was rapidly increased.

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High Resistivity Characteristics of the Sinter Dust Generated from the Steel Plant

  • Lee, Jae-Keun;Hyun, Ok-Chun;Lee, Jung-Eun;Park, Sang-Deok
    • Journal of Mechanical Science and Technology
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    • v.15 no.5
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    • pp.630-638
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    • 2001
  • The electrical resistivity of sinter dusts generated from the steel industry and coal fly ash from the coal power plant has been investigated using the high voltage conductivity cell based on JIS B 9915 as a function of temperature and water content. Dust characterization such as the chemical composition, size distribution, atomic concentration, and surface structure has been conducted. Major constituents of sinter dusts were Fe$_2$O$_3$(40∼74.5%), CaO (6.4∼8.2%), SiO$_2$(4.1∼6.0%), and unburned carbon (7.0∼14.7%), while the coal fly ash consisted of mainly SiO$_2$(51.4%), Al$_2$O$_3$(24.1%), and Fe$_2$O$_3$(10.5%). Size distributions of the sinter dusts were bi-modal in shape and the mass median diameters (MMD) were in the range of 24.7∼137㎛, whereas the coal fly ash also displayed bi-modal distribution and the MMD of the coal fly ash was 35.71㎛. Factors affecting resistivity of dusts were chemical composition, moisture content, particle size, gas temperature, and surface structure of dust. The resistivity of sinter dusts was so high as 10(sup)15 ohm$.$cm at 150$\^{C}$ that sinter dust would not precipitate well. The resistivity of the coal fly ash was measured 1012 ohm$.$cm at about 150$\^{C}$. Increased water contents of the ambient air lowered the dust resistivity because current conduction was more activated for absorption of water vapor on the surface layer of the dust.

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Effects of Processed Slag as Glassmaking Raw Material (on Soda-Lime Glass) (개질 고로 슬래그에 관한 연구 (유리 제조에 관한 연구))

  • 양중식
    • Journal of the Korean Ceramic Society
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    • v.18 no.2
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    • pp.112-118
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    • 1981
  • A study was made on the processing of domestic blast furnace slag by flotation and chemical purification for the use of slag as a raw material in making soda lime glasses. Feasibility study has been made for the use of reprocessing slag as a source material for both coloring and chemical components (such as CaO, $Al_2O_3$, MgO and etc.) in the glass making process. Chemical composition of chemically purified slags ranges; $SiO_2$ 34.5~37.5, $Al_2O_3$, 16.2~14.1, $Fe_2O_3$ 0.33~0.14, CaO 34.5~38.8, MgO 4.0~5.2, NmO 0.16~0.39, $TiO_2$ 0.23~0.35, S 0.08~0.42, ignition loss 3.3~8.4 and others 0.48~0.51%. It was found that either amber or greenish color could be easily obtained with the addition of salg up to 24%, however the slag addition to glass batches much impaired the transmitancy of glass products, thus a glass made with 7% slag addition showed 82% in transmitancy value at 510 nm.

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Estimation of Volume Change and Fluid-Rock Ratio of Gouges in Quaternary Faults, the Eastern Blocks of the Ulsan Fault, Korea (울산단층 동부지역 제4기단층 비지대의 체적변화와 유체-암석비에 대한 고찰)

  • Chang Tae-Woo;Chae Yeon-Zoon;Choo Chang-Oh
    • The Journal of Engineering Geology
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    • v.15 no.3
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    • pp.349-363
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    • 2005
  • Many Quaternary faults are recognized as thin gouge and narrow cataclastic zone juxtaposing the Bulguksa granite and Quaternary deposit bed in the eastern block of the Using Fault, Korea: Gaegok 1, Caegok 2, Singye, Madong Wonwonsa and Jinhyeon faults. This study was performed to calculate chemical change, volume change, silica loss and fluid-rock ratio taken place in gouge zones of these Quaternary faults using XRF, XRD, EPMA. The chemical compositions of fault rocks reveal that the fault gouges are depleted in $SiO_2,\;Na_2\;O,and\;K_2O$ and enriched in $Al_2O_3,\;Fe_2O_3,\;P_2O_5,\;MgO,\;MnO,\;CaO,\;and\;LOI(H_2O+CO_2)$ relative to protoliths. The fact that there is enrichment of relatively immobile elements and depletion of the more soluble elements in the fault gouges relative to protoliths can be explained by fluid-assisted volume loss of $56\%$ for Caegok 1 fault, $22\%$ for Caegok 2 fault,$34\%$, for Singye fault, $8\%$ for Madong fault, $2\%$ for the Wonwonsa fault and $53\%$ for the linhyeon fault. Madong fault and Wonwonsa fault where ratios of the volume change, silica loss and fluid-rock are low might have acted as a closed system for fluid activity, whereas Caegok 1 fault and Jinhyeon fault with high ratios in those factors be an open system. The volumetric fluid-rock ratios range $10^2\sim10^4$ for all faults, being highest in Caegok 1 fault and Jinhyeon fault whose fluid activity was most significant.

Structural and Electrical Properties of the Y-Cr Bilayer Deposited on Fe-l6Cr Ferritic Alloy after Heat Treatment at 800℃ (Fe-l6Cr 페라이틱 합금에 증착된 Y-Cr 이층 박막의 800℃ 열처리 후의 구조 및 전기적 특성)

  • Lee, Yong-Jin;Kim, Sang-Woo;Kim, Gyeung-Ho;Lee, Jong-Ho;Ahn, Jin-Ho
    • Korean Journal of Materials Research
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    • v.13 no.1
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    • pp.36-42
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    • 2003
  • The oxidation behaviors of Y-Cr bilayer deposited on ferritic steel by magnetron-sputtering for application of the Fe-Cr alloys as interconnectors of planar-type solid oxide fuel cells (SOFCs) were studied. After oxidation at $800^{\circ}C$ for 40 hours, the major phase of $Y_2$$O_3$and the minor phase of $YCrO_3$, $Mn_{1.5}$ $Cr_{1.5}$ $O_4$and Cr$_2$SiO$_4$were formed in the Y/Cr bilayered samples, while the major phase of Cr$_2$O$_3$and the minor phase of $Y_2$$O_3$were formed as the major phase in the Cr/Y bilayered samples. The Log(ASR/T) that expresses electric resistance of the Y/Cr coated specimen with nonconducting $_Y2$$O_3$oxide showed high value of -2.80 Ω$\textrm{cm}^2$$K^{-1}$ / and that of the Cr/Y coated specimen with conducting $Cr_2$$O_3$oxide appeared to be -4.11 Ω$\textrm{cm}^2$$^{K}$ . The electric resistance of the Y/Cr coated specimen was largely increased due to the formation of high resistance oxide scales. However, the Cr/Y coated specimen did not show any increase in the electric resistance and had the long-term stability of oxidation because there was no formation of the secondary phases with low conductivity.

Effect of Temperature on Growth of Tin Oxide Nanostructures (산화주석 나노구조물의 성장에서 기판 온도의 효과)

  • Kim, Mee-Ree;Kim, Ki-Chul
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.4
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    • pp.497-502
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    • 2019
  • Metal oxide nanostructures are promising materials for advanced applications, such as high sensitive gas sensors, and high capacitance lithium-ion batteries. In this study, tin oxide (SnO) nanostructures were grown on a Si wafer substrate using a two-zone horizontal furnace system for a various substrate temperatures. The raw material of tin dioxide ($SnO_2$) powder was vaporized at $1070^{\circ}C$ in an alumina crucible. High purity Ar gas, as a carrier gas, was flown with a flow rate of 1000 standard cubic centimeters per minute. The SnO nanostructures were grown on a Si substrate at $350{\sim}450^{\circ}C$ under 545 Pa for 30 minutes. The surface morphology of the as-grown SnO nanostructures on Si substrate was characterized by field-emission scanning electron microscopy (FE-SEM) and atomic force microscopy (AFM). Raman spectroscopy was used to confirm the phase of the as-grown SnO nanostructures. As the results, the as-grown tin oxide nanostructures exhibited a pure tin monoxide phase. As the substrate temperature was increased from $350^{\circ}C$ to $424^{\circ}C$, the thickness and grain size of the SnO nanostructures were increased. The SnO nanostructures grown at $450^{\circ}C$ exhibited complex polycrystalline structures, whereas the SnO nanostructures grown at $350^{\circ}C$ to $424^{\circ}C$ exhibited simple grain structures parallel to the substrate.

Nano inclusions in sapphire samples from Sri Lanka

  • Jaijong, K.;Wathanakul, P.;Kim, Y.C.;Choi, H.M.;Bang, S.Y.;Choi, B.G.;Shim, K.B.
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.19 no.2
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    • pp.84-89
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    • 2009
  • The turbid/translucent, near colorless(milky) metamorphic sapphire samples from Sri Lanka have been characterized after the heat treatment in $N_2$ at $1650^{\circ}C$. As-received sapphire specimens became bluish-colored and exhibited more clarity after the heat treatment. It was found that the color change at inclusions zoning region is attributed by the dissolution. As received samples contain the micro/nano inclusions such as rutile($TiO_2$), ilmenite($FeTiO_3$), spinel($MgAl_{2}O_{4}$)/ulvospinel($Fe_{2}TiO_{4}$) and apatite($Ca_5(PO_4)_3$), which were dissolved by the heat treatment and form the blue color through $Fe^{2+}/Ti^{4+}$ charge transferring. The microstructures become different because as the dissolution of apatite($Ca_5(PO_4)_3(OH,F,Cl)$) in alumino silicates($Al_{2}SiO_{5}$) occurred, resulting in morphological change with the appearance of(Ca, Mg, Al) silicate on the surface. Both as-received and heat treated samples showed the rhombohedral crystal structure of $Al_{2}O_{3}$.

Current Status and Prospects of FET-type Ferroelectric Memories

  • Ishiwara, Hiroshi
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.1 no.1
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    • pp.1-14
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    • 2001
  • Current status and prospects of FET-type FeRAMs (ferroelectric random access memories) are reviewed. First, it is described that the most important issue for realizing FET-type FeRAMs is to improve the data retention characteristics of ferroelectric-gate FETs. Then, necessary conditions to prolong the retention time are discussed from viewpoints of materials, device structure, and circuit configuration. Finally, recent experimental results related to the FET-type memories are introduced, which include optimization of a buffer layer that is inserted between the ferroelectric film and a Si substrate, development of a new ferroelectric film with a small remnant polarization value, proposal and fabrication of a 1T2C-type memory cell with good retention characteristics, and so on.

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Physical and Chemical Characteristics of Pinkish Granite Core in the Mungyeong Area (문경지역 담홍색 화강암 코아의 물리적 및 화학적 특성)

  • 윤현수
    • The Journal of the Petrological Society of Korea
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    • v.3 no.3
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    • pp.234-240
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    • 1994
  • The Wongyeong site, one of massive pinkish granite quarries in the Mungyeong area, was drilled to study the physical and chemical properties following the rock classification from fresh rock to highly, moderately and slightly weathered one. The physical properties such as specific gravity, absorption ratio, porosity and compressive strength were tested from the core samples. Specific gravity and absorption ratio are 2.37-2.64 and 0.27-1.87% respectively, while porosity and compressive strength are 0.70-4.38% and 110- 1, 695 kg/$cm^2$. With increased weathering, absorption ratio vs. porosity shows a positive correlation. The absorption ratio is in reverse proportion to compressive strength. Toward the surface in the drilled core, the $SiO_2$, CaO and $K_2O$ contents slightly decrease, but the $Al_2O_3$+FeO(t) contents increase by the enrichment of residual clay in the weathered rock.

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