• Economic and Environmental Geology
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• v.50 no.3
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• pp.181-193
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• 2017

Mn-Fe phosphate mineral complexes included within the pegmatite are observed at Jurassic Cheolwon two-mica granite in Gyeonggi Massif, South Korea. The genetic evolution between the Cheolwon two-mica granite and pegmatite, and various trend of Mn-Fe phosphate minerals is made by later magmatic, hydrothermal, and weathering process based on mineralogical, geochemical analysis. The Cheolwon two-mica granite is identified as S-type granite, considering its chemical composition (metaluminous ~ peraluminous), post-collisional environment, low magnetic susceptibility, and existence of biotite and muscovite. The K-Ar age (ca. 153 Ma) of pegmatite is well coincident with age of the Cheolwon two-mica granite ($151{\pm}4Ma$). It indicates that these two rocks are originated from the same magma. Pegmatite indicates the LCT geochemical signature, and was classified as muscovite-rare element class / Li subclass / beryl type / beryl-columbite-phosphate subtype pegmatite. The triplite $\{(Fe^{2+}{_{0.4}},Mn_{1.6})(PO_4)(F_{0.9})\}$ is dominant phosphates in later magmatic stage which partly altered to leucophosphite $\{KFe^{3+}{_2}(PO_4)_2OH{\cdot}2H_2O\}$ and jahnsite $\{(Fe^{3+}{_{0.7}},Mn_{2.3})(PO_4)_2OH{\cdot}4H_2O\}$ by hydrothermal alteration. In particular, near fractures, the triplite has been separatelty replaced by the phosphosiderite ($Fe^{3+}PO_4{\cdot}2H_2O$) and Mn-oxide minerals during weathering stage.

• Journal of the Korean Society of Fisheries and Ocean Technology
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• v.32 no.4
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• pp.411-420
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• 1996

The structure of the scale formed on the surface of Fe - Cr - X alloys exposed to 1143K high sulfidation($Ps_2$ = 1.11$\times$$10^-7$ atm, $Po_2$ = 3.11$\times$$10^-20$ atm) or sulfidation/oxidation(($Ps_2$= 1.06$\times$$10^-7$ atm, ($Po_2$ = 3.11$\times$$10^-18$ atm) environment has been observed and analysed using XRD, SEM/EDS. To investigate the possibility of protective film formed on the surface of the alloys, Aluminium, Nickel were selected as alloying elements. Thermodynamic phase stability diagram was used to predict the reaction path of scale formed on Fe - Cr - X alloys. Parabolic rate constant($K_p$) value with 6wt% Al in Fe - 25Cr alloy decreased significantly compared with the Fe - 25Cr alloy without 6wt% Al. Since thin layer of defect free sulfide film, (Al, Cr)Sx, was formed at the alloy/scale interface. Fe - rich sulfide scale at outer layer and Cr - rich sulfide scale containing porosity at inner layer of Fe - 25Cr alloy have been observed. The reaction path for these scales could be predicted by the thermodynamic stability diagram.

• Journal of the Korean Chemical Society
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• v.17 no.5
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• pp.337-345
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• 1973

The nonstoichiometry of the iron oxide system has been studied by analyzing the weight loss of a sample, measured by using a quartz microbalance, in a temperature range from $0^{\circ}C$ to $1200^{\circ}C$ under oxygen pressures from $10^{2}mmHg$ to $10^{-4}mmHg$. The Y values of the formula, $FeO_{1+\gamma}$, that have been obtained by this means for various conditions of temperature and pressure in this range are considered to be more accurate than values obtained by methods requiring thste quenching of the sample before measurements are made. The plots of log Y vs $log PO_2$ (or $log Y =_n log PO_2$) show linearity and n calculated from the slope of the plot is about 1/10 at $1000^{\circ}C$, indicating a difference between the nonstoichiometric and oxidation mechanisms. The condition for the formation of stoichiometric FeO was determined to be $1200^{\circ}C$ under $10^{-3}mmHg$ of $O_2$ and the composition of the oxide under standard conditions was $FeO_{1.11185}$. As in general more oxygen dissolves into the oxide system at lower temperatures and higher oxygen pressures, the deviation from stoichiometric FeO is greater under those conditions. A comparison of the change in conductivity of the sample indicates that full phase transition does not take place with conductivity transition.

• Bulletin of the Korean Chemical Society
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• v.30 no.8
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• pp.1719-1723
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• 2009

The LiFeP$O_4$ powder was synthesized by using the solid state reaction method with Fe($C_2O_4){\cdot}2H_2O,\;(NH_4)_2HPO_4,\;Li_2CO_3$, and chitosan as a carbon precursor material for a cathode of a lithium-ion battery. The chitosan added LiFePO4 powder was calcined at 350 ${^{\circ}C}$ for 5 hours and then 800 ${^{\circ}C}$ for 12 hours for the calcination. Then we calcined again at 800 ${^{\circ}C}$ for 12 hours. We characterized the synthesized compounds via the crystallinity, the valence states of iron ions, and their shapes using TGA, XRD, SEM, TEM, and XPS. We found that the synthesized powders were carbon-coated using TEM images and the iron ion is substituted from 3+ to 2+ through XPS measurements. We observed voltage characteristics and initial charge-discharge characteristics according to the C rate in LiFeP$O_4$ batteries. The obtained initial specific capacity of the chitosan added LiFeP$O_4$ powder is 110 mAh/g, which is much larger than that of LiFeP$O_4$ only powder.

• Journal of Korean Society of Water and Wastewater
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• v.27 no.5
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• pp.631-639
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• 2013

The removal of phosphate from surface water is becoming increasingly vital to prevent problems such as eutrophication, particularly near urban areas. Recent requirements to reduce high concentrations of phosphate rely on physicochemical methods and adsorbents that must be effective even under strict conditions. The phosphate removal efficiencies of two adsorbents, Fe-Mn-Si oxide and Fe-Mn oxide, were investigated and the data used to compare kinetics and isotherm models. The maximum adsorption capacities of the two adsorbents were 47.8 and 35.5 mg-$PO{_4}^{3-}/g$, respectively. Adsorptions in both cases were highly pH dependent; i.e., when the pH increased from 3 to 9, the average adsorption capacities of the two adsorbents decreased approximately 32.7 % and 20.3 %, respectively. The Freundlich isotherm model fitted the adsorption of Fe-Mn-Si oxide more closely than did the Langmuir model. Additionally, anionic solutions decreased adsorption because of competition with the anions in the adsorbing phosphate. Although affected by the presence of competing anions or a humic substance, Fe-Mn-Si oxide has better adsorption capacity than Fe-Mn oxide.

• Proceedings of the Korean Vacuum Society Conference
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• 2007.02a
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• pp.38-38
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• 2007

• The Magazine of the IEIE
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• v.34 no.12
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• pp.30-37
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• 2007

• Proceedings of the Korean Environmental Sciences Society Conference
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• 1997.10a
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• pp.65-66
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• 1997

우리나라의 대부분 하천과 인공댐의 경우 조류발생에 기여하는 영양염은 질소, 인 그리고 규소 등인데 특히 인이 생산제한 인자로 작용하고 있다. 따라서 인을 적절히 제거할 경우에는 조류 발생에 의한 수질의 악화와 수이용의 저해요인을 배제할 수 있어 이에 대한 연구가 많이 진행되어 왔다. 지금까지와 연구는 인의 화학적 응집 침전법, 생물학적 처리법에 대하여 수행되어 왔으나 설비자금, 운영비, 운전기술, 슬러지 생성 그리고 제거효율 등에서 만족스런 결과가 도출되지 못하여 현장 적용을 하지 못하고 있는 실정이다. 이러한 현실을 감안하여 우리의 자연 환경에서 쉽게 자할 수 있는 황토를 모재로하여 Al3-과 Fe3-, Ca2-을 적절히 배합하여, 주로 인을 선택적으로 제거하 고자 개발된 황토의 흡착능력 그리고 흡착 메카니즘에 대한 기본적인 연구를 하고자 (1) 등온흡착실험을 통하여 흡착용량을 평가하고 (2) 흡착제거속도를 평 가하였고 (3)파과시간 및 흡착특성을 파악하기 위해 column 흡착실험을 하였다 또한 (4) 황토내의 Al3-, Fe3-과 Ca2- 등이 인의 화학적 흡착에 기여하는 정도를 파악하여 흡착메카니즘을 규명하고자 하였다. 먼저 흡착용량실험을 위하여 PO3-4-P 농도 3ppm의 용액 200mf에 황토 0.2g, 0.5g, 1.0g, 2.0g을 각각 투여한 후 충분한 흡착평형이 일어나게 24시간 동 안 130rpm으로 $25^{\circ}C$ 등온반웅조에서 저어주어 흡착평형에 도달하면 상등액을 GF/C Filter로 여과한 후, 여액에 대해 PO3-4-P의 농도를 Ascrobic he건법으로 측정한 결파, Freundlich 등온흡착식에 의하면 K값은 17.34와 16.28이었으며 1/n 값은 1.32와 1.42로 인흡착 성능이 뛰어난 것으로 평가되었다. 둘째, 흡착속도 실험은 PO3-4-P 농도 1.5ppm의 용액 2f에 259의 황토를 투여하고 충분한 혼합이 일어날 수 있도록 170rpm으로 교반하면서 시간별 용액 의 농도 변화를 측정한 결과, 0.45mg/g/m교의 속도로 15분만에 94.3%의 인 제거 효율을 보였다. 셋째, 직경 12mm의 glass column에 황토를 209 채우고 1.5ppm의 PO34P 용액을 2.Sne11in의 유량으로 통수 시킨 후, 시간에 따른 농도 변화를 측정한 결과, 원수 농도의 50%에 해당하는 파과점까지 약 70시간 만에 도달하였다. 넷째, Al3-, Fe3-과 Ca2- 등이 화학적 흡착에 기여하는 정도를 파악하기 위 하여 황토 2g에 대하여 Hieltijes and Lijklema 방법에 의해 Adsorbed-p, Nonapatite inorganic-P(NAI-P), Apatite-p, Organic-P로 구분하여 분석하고, 총인(Total Phosphorus)을 Standard Methods에 따라 Persulfate digestion후 0.45 m membrane 여지 여과하여 여액에 대해 PO3-4-P의 농도를 Ascorbic Acid 법으로 측정한 결과, NAI-P가 가장 큰 비율을 차지하였고, 부원료로 첨가된 금속 양이온 중 Fe3-이온이 흡착에 기여하는 정도가 가장 큰 것으로 평가되었다.

• Korean Journal of Microbiology
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• v.39 no.1
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• pp.51-55
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• 2003

To develop environment-friendly biofertilizer solubilizing insoluble phosphates, a bacterium possessing a high ability to solubilize $Ca_{3}(PO_{4})_{2}$) was isolated from the rhizosphere of peas. On the basis of its morphological, cultural, physiological characteristics, and Vitek analysis, this bacterium was identified as Pantoea agglomerans. The optimal medium composition and cultural conditions for the solubilization of insoluble phosphate by P. agglomerans R-38 were 3% of glucose.0.1% of TEX>$NH_{4}NO_{3}$, 0.02% of $MgSO_{4}\cdot\7H_{2}O$, and 0.06% of $CaCl_{2}\cdot\2H_{2}O$ along with initial pH 7.5 at $30^{\circ}C$. The highest soluble phosphate production under optimum condition was 898 mg/L after 5 days of cultivation. The solubilization of insoluble phosphate was associated with a drop in the pH of the culture medium. The strain produced soluble phosphate to the culture broth with the concentrations of 698 mg/L against CaHPO$_4$, 912 mg/L against hydroxyapatite, 28 mg/L against $FePO_{4}\cdot\4H_{2}O$, and 19 mg/L against $AIPO_{4}$, respectively.

• Proceedings of the Korean Magnestics Society Conference
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• 2016.11a
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• pp.64-65
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• 2016