• Title/Summary/Keyword: $D_2{^+}$ retention

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Effect of PCE superplasticizers on rheological and strength properties of high strength self-consolidating concrete

  • Bauchkar, S.D.;Chore, H.S.
    • Advances in concrete construction
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    • v.6 no.6
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    • pp.561-583
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    • 2018
  • A variety of polycarboxylate ether (PCE)-based superplasticizers are commercially available. Their influence on the rheological retention and slump loss in respect of concrete differ considerably. Fluidity and slump loss are the cardinal features responsible for the quality of concrete. These are related to the dispersion of cement particles and the hydration process which are greatly influenced by type of polycarboxylate ether (PCE)-based superplasticizers. On the backdrop of relatively less studies in the context of rheological retention of high strength self-consolidating concrete (HS-SCC), the experimental investigations were carried out aiming at quantifying the effect of the six different PCE polymers (PCE 1-6) on the rheological retention of HS-SCC mixes containing two types of Ordinary Portland Cements (OPC) and unwashed crushed sand as the fine aggregate. The tests that were carried out included $T_{500}$, V-Funnel, yield stress and viscosity retention tests. The supplementary cementitious materials such as fly ash (FA) and micro-silica (MS) were also used in ternary blend keeping the mix paste volume and flow of concrete constant. Low water to binder ratio was used. The results reveal that not only the PCEs of different polymer groups behave differently, but even the PCEs of same polymer groups also behave differently. The study also indicates that the HS-SCC mixes containing PCE 6 and PCE 5 performed better as compared to the mixes containing PCE 1, PCE 2, PCE 3 and PCE 4 in respect of all the rheological tests. The PCE 6 is a new class of chemical admixtures known as Polyaryl Ether (PAE) developed by BASF to provide better rheological properties in even in HS-SCC mixes at low water to binder mix. In the present study, the PCE 6, is found to help not only in reduction in the plastic viscosity and yield stress, but also provide good rheological retention over the period of 180 minutes. Further, the early compressive strength properties (one day compressive strength) highly depend on the type of PCE polymer. The side chain length of PCE polymer and the fineness of the cement considerably affect the early strength gain.

Quantitative Determination of Solvents in Food Packaging Film Using Headspace Gas Chromatography (헤드스페이스 가스크로마토그라프에 의한 식품포장재 중의 잔류용제 분석연구)

  • Kim, Hyeon-Wee;Cha, Ik-Soo;Kim, Jin-Ho;Park, Ki-Moon
    • Korean Journal of Food Science and Technology
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    • v.28 no.6
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    • pp.1177-1179
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    • 1996
  • A static headspace gas chromatographic (HSGC) technique was used to quantify toluene and other solvents (methanol, isopropyl alcohol, methyl ethyl ketone and ethyl acetate) in food packaging films. Comparison of retention times and coefficient variations for standard solvents showed consistent retention time and good reproducibility. Therefore, this method using static HSGC proved to be superior in rapidity and reproducibility, and is thought to be adaptable to analysis of a large number of samples. The methanol content was $N.D.\;(not\;detected){\sim}0.939\;mg/m^2$, toluene $N.D.{\sim}1.403\;mg/m^2$, melthyl ethyl ketone $N.D.{\sim}0.932\;mg/m^2$, total solvent content was $N.D.{\sim}2.433\;mg/m^2$.

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Use of real-time ultrasound imaging for biofeedback of diaphragm motion during normal breathing in healthy subjects

  • Cho, Ji-Eun;Hwang, Dal-Yeon;Hahn, Joohee;Lee, Wan-Hee
    • Physical Therapy Rehabilitation Science
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    • v.7 no.3
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    • pp.95-101
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    • 2018
  • Objective: To determine if the provision of visual biofeedback using real-time rehabilitative ultrasound imaging (RUSI) enhances the acquisition and retention of diaphragm muscle recruitment during exercise. Design: Two group pretest posttest design. Methods: Thirty healthy subjects were randomly assigned to the verbal feedback group (VG, n=15) or the visual and verbal feedback group (VVG, n=15). The VG performed breathing exercises 10 times with verbal feedback, and the VVG also performed breathing exercises 10 times with verbal feedback and visual feedback with the use of RUSI to measure changes in diaphragm thickness (DT). For DT, the mid-axillary lines between ribs 8 and 9 on both sides were measured in standing, and then the chest wall was perpendicularly illuminated using a linear transducer with the patients in supine to observe the region between rib 8 and 9 and to obtain 2-dimensional images. DT was measured as the distance between the two parallel lines that appeared bright in the middle of the pleura and the peritoneum. After one week, three repetitions (follow-up session) were performed to confirm retention effects. Intra- and between- group percent changes in diaphragm muscle thickness were assessed. Results: In the VVG, the intervention value had a medium effect size compared to the baseline value, but the follow-up value decreased to a small effect size. In the between-group comparisons, during the intervention session, the VVG showed no significant effect on percent change of DT but had a medium effect size compared to the VG (p=0.050, Cohen's d=0.764). During the follow-up session, retention effect did not persist (p=0.311, Cohen's d=0.381). Conclusions: RUSI can be used to provide visual biofeedback and improve performance and retention in the ability to activate the diaphragm muscle in healthy subjects. Future research needs to establish a protocol for respiratory intervention to maintain the effect of diaphragmatic breathing training using RUSI with visual feedback.

Retention Behavior of Poly(Ethylene-co-Vinyl Acetate)s in Thermal Field-Flow Fractionation (열장 흐름 분획법에서 에틸렌-아세트산 비닐 혼성중합체들의 머무름거동에 관한 연구)

  • Jeon, Seon Ju;Jo, Gyeong Ho;Lee, Dae Un;Mun, Myeong Hui
    • Journal of the Korean Chemical Society
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    • v.38 no.6
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    • pp.427-434
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    • 1994
  • The retention behaviors of poly(ethylene-co-vinyl acetate)s have been studied by thermal field-flow fractionation(ThFFF) with respect to effective separation and characterization of thermal diffusion coefficients($D_{\tau}$) as one of the physicochemical properties of polymers. The eight copolymers are different in vinyl acetate composition ranging from 25% to 70% and in molecular weight ranging from 110,000 to 285,000. The carrier solvents are THF, toluene and chlorobenzene which have different viscosities and thermal conductivities. It is shown that the retention of a copolymer is dependent on the type of the carrier, the molecular weight and chemical composition of the copolymer. The results show that the retention of a copolymer increases when either vinyl acetate composition or the molecular weight increase. $D_{\tau}$ values measured by experiments vary from 1.36∼5.97 $\cm^2/(s.K)$ depending on the copolymer composition and the type of the carrier solvent. These values increase $(r^2{\geq}0.928)$ with increase of weight % of vinyl acetate. THF is found to be the proper carrier solvent for separation of copolymers employed in this study due to the fact that a $D_{\tau}$ value greatly changes with variation of copolymer composition. From the above results, ThFFF can be used for separation of copolymers with similar molecular sizes but different compositions.

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Radiolabeled 2D graphitic nanomaterials and their possibility for molecular imaging applications

  • Kang, Seok Min;Kim, Chul Hee;Kim, Dong Wook
    • Journal of Radiopharmaceuticals and Molecular Probes
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    • v.4 no.2
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    • pp.115-120
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    • 2018
  • In recent years, many researchers have attempted to make use of 2D nanoparticles as molecular imaging probes since extensive investigations proved that 2D nanoparticles in the body tends to accumulate certain lesions by enhanced permeability and retention (EPR) effect. For example, graphene and carbon nitride which have high surface area and modifiable properties showed good biocompatibility and targetability when it used as imaging probes. However, poor dispersibility in physiological mediums and its uncontrolled size limited its usage in bio-application. Therefore, oxidation process and mechanical exfoliation have been developed for overcoming these problems. In this paper, we highlight the several major methods to synthesize biocompatible 2D nanomaterials like graphene and carbon nitride especially for molecular imaging study including positron emission tomography (PET).

Decrease of Interface Trap Density of Deposited Tunneling Layer Using CO2 Gas and Characteristics of Non-volatile Memory for Low Power Consumption (CO2가스를 이용하여 증착된 터널층의 계면포획밀도의 감소와 이를 적용한 저전력비휘발성 메모리 특성)

  • Lee, Sojin;Jang, Kyungsoo;Nguyen, Cam Phu Thi;Kim, Taeyong;Yi, Junsin
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.7
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    • pp.394-399
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    • 2016
  • The silicon dioxide ($SiO_2$) was deposited using various gas as oxygen and nitrous oxide ($N_2O$) in nowadays. In order to improve electrical characteristics and the interface state density ($D_{it}$) in low temperature, It was deposited with carbon dioxide ($CO_2$) and silane ($SiH_4$) gas by inductively coupled plasma chemical vapor deposition (ICP-CVD). Each $D_{it}$ of $SiO_2$ using $CO_2$ and $N_2O$ gas was $1.30{\times}10^{10}cm^{-2}{\cdot}eV^{-1}$ and $3.31{\times}10^{10}cm^{-2}{\cdot}eV^{-1}$. It showed $SiO_2$ using $CO_2$ gas was about 2.55 times better than $N_2O$ gas. After 10 years when the thin film was applied to metal/insulator/semiconductor(MIS)-nonvolatile memory(NVM), MIS NVM using $SiO_2$($CO_2$) on tunneling layer had window memory of 2.16 V with 60% retention at bias voltage from +16 V to -19 V. However, MIS NVM applied $SiO_2$($N_2O$) to tunneling layer had 2.48 V with 61% retention at bias voltage from +20 V to -24 V. The results show $SiO_2$ using $CO_2$ decrease the $D_{it}$ and it improves the operating voltage.

The effect on gene expression profile of rat hippocampus caused by administration of memory enhancing herbal extract (육미지황탕가미방(六味地黃湯加味方)이 흰쥐의 기억능력과 중추신경계 유전자 발현에 미치는 영향)

  • Choi, Bo-Eop
    • Korean Journal of Oriental Medicine
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    • v.8 no.1
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    • pp.109-126
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    • 2002
  • The herbal extract (YMT_02) is a modified herbal extracts from Yukmijihwangtang (YMJ) to promote memory-enhancing. The YMJ extracts has been widely used as an anti-aging herbal medicine for hundred years in Asian countries. The purpose of this study is to; 1) quantitatively evaluate the memory-enhancing effect of YMT_02 by hehavior task, 2) identify candidate genes responsible for enhancing memory by cDNA microarray and 3) assess the anti-oxidant effect of YMT_02 on PC12 cell. Memory retention abilities are addressed by passive avoidance task with Sprague-Dawley (SD) male rat. Before the training session, the rats are subdivided into four groups and administrated with YMT_02, Ginkgo biloba, Soya lecithin and normal saline for 10 days. The retention test was performed. 24 hours after the training session. The retention time of the YMT_02 group was significantly (p<0.05) delayed $({\sim}100%)$, whereas Ginkgo biloba and Soya lecithin treatment delayed 20% and 10% respectively. The hippocampi of YMT_02 and control group were dissected and mRNA was further purified. After synthesizing cDNA using oligo-dT primer, the cDNA were applied and mRNA was further purified. After synthesizing cDNA using oligo-dT primer, the cDNA were applied to Incyte rat GEMTM 2 cDNA microarray. The microarray results show that prealbumin(transthyretin), phosphotidy lethanolamine N-methyltransferase, and PEP-19 are expressed abundantly in the YMT_02 treated group. Especially, PEP-19 is a neuron-specific protein, which inhibits apoptotic processes in neuronal cell. On the other hand, transcripts of RAB15, glutamate receptor subunit 2 and CDK 108 are abundant in control group. Besides, neuronal genes involved in neuronal death or neurodegeneration such as neuronal-pentraxin and spectrin are abundantly expressed in control group. Additionally, the YMT_02 shows an anti oxidative effect in the PC12 cell. The list of differentially expressed genes may implicate further insight on the action and mechanism behind the memory-enhancing effect of herbal extracts YMT_02, for example, anti-apoptotic, anti-oxidative, and neuroprotective effects.

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Differences of Zooplankton Development Along a Lake and a River Stretch of the River Spree (Germany) (스프리 강 (독일) 내의 호수와 강 구획에서의 동물플랑크톤 성장의 차이)

  • Joo, Gea-Jae;Walz, Norbert;Kim, Hyun-Woo
    • Korean Journal of Ecology and Environment
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    • v.33 no.3 s.91
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    • pp.197-205
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    • 2000
  • Factors most strongly related to zooplankton growth rates were studied along a lake and a river stretch in the middle part of the lowland River Spree. The study was conducted at the lake inflow (S1), the lake outflow (S2), and at the end of a 21 km stretch of the outflow (S3) from March to November of 1999. Total zooplankton biomass increased significantly at S2 and then sharply decreased at S3. The abundance of microzooplankton (rotifers and nauplii) was strongly higher than macrozooplankton (cladocerans and copepodids) at all station. However, macrozooplankton biomass (${\mu}$g dw 1$^{-1}$) was similar or much higher than microzooplankton biomass. Large-bodied cladocerans (Daphnia cucullata) dominated at S2 while small-bodied cladocerans (Bosmina longirostris) dominated at S1 and S3. Patterns in growth rates (r$_{t}$ in d$^{-1}$ of the major zooplankton community were greatly different between S1 and S2 (lake stretch) and between S2 and S3 (river stretch). In the lake, growth rates generally were positive, while values of growth rates were negative in the river stretch. Among the environmental variables considered, partial retention time (PRT, d$^{-1}$) seemed to play the most important role in determining characteristics of the zooplankton community structure in the middle part of River Spree.

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Synthesis and Antiviral Activity of $2^1$-Fluorohexopyranosyl Nucleosides

  • Jeong, Lak-Shin;Lee, Jong-Eun;Kim, Hea-Ok;Chun, Moon-Woo
    • Archives of Pharmacal Research
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    • v.21 no.3
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    • pp.338-343
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    • 1998
  • $2^1$-Fluorohexopyranosyl nucleosides 1a and 1b which contained a bioisosteric double bond and a fluorine were synthesized in 12 steps, starting from D-galactose. During diethylaminosulfur trifluoride (DAST) fluorination, retention of stereochemistry was observed through the participation of methoxy or chloro group at the 6-posiition of the purine base. The final nucleosides 1a and 1b were found to be inactive against HIV-1 and HSV-1,2.

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A STUDY ON COMPARISON OF VARIOUS KINDS OF CLASSII AMALGAM CAVITIES USING FINITE ELEMENT METHOD (유한요소법을 이용한 수종 2급 아말감 와동의 비교연구)

  • Seok, Chang-In;Um, Chung-Moon
    • Restorative Dentistry and Endodontics
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    • v.20 no.2
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    • pp.432-461
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    • 1995
  • The basic principles in the design of Class II amalgam cavity preparations have been modified but not changed in essence over the last 90 years. The early essential principle was "extension for prevention". Most of the modifications have served to reduce the extent of preparation and, thus, increase the conservation of sound tooth structure. A more recent concept relating to conservative Class II cavity preparations involves elimination of occlusal preparation if no carious lesion exists in this area. To evaluate the ideal ClassII cavity preparation design, if carious lesion exists only in the interproximal area, three cavity design conditions were studied: Rodda's conventional cavity, simple proximal box cavity and proximal box cavity with retention grooves. In this study, MO amalgam cavity was prepared on maxillary first premolar. Three dimensional finite element models were made by serial photographic method. Linear, eight and six-nodal, isoparametric brick elements were used for the three dimensional finite element model. The periodontal ligament and alveolar bone surrounding the tooth were excluded in these models. Three types model(B option, Gap option and R option model) were developed. B option model was assumed perfect bonding between the restoration and cavty wall. Gap option model(Gap distance: $2{\mu}m$) was assumed the possibility of play at the interface simulated the lack of real bonding between the amalgam and cavity wall (enamel and dentin). R option model was assumed non-connection between the restoration and cavty wall. A load of 500N was applied vertically at the first node from the lingual slope of the buccal cusp tip. This study analysed the displacement, 1 and 2 direction normal stress and strain with FEM software ABAQUS Version 5.2 and hardware IRIS 4D/310 VGX Work-station. The results were as followed. 1. Rodda's cavity form model showed greater amount of displacement with other two models. 2. The stress and strain were increased on the distal marginal ridge and buccopulpal line angle in Rodda's cavity form model. 3. The stress and strain were increased on the central groove and a part of distal marginal ridge in simple proximal box model and proximal box model with retention grooves. 4. With Gap option, Rodda's cavity form model showed the greatest amount of the stress on distal marginal ridge followed by proximal box model with retention grooves and simple proximal box model in descending order. 5. With Gap option, simple proximal box model showed greater amount of stress on the central groove with proximal box model with retention grooves. 6. Retention grooves in the proximal box played the role of supporting the restorations opposing to loads.

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