• 제목/요약/키워드: $Cr/TiO_2$

검색결과 275건 처리시간 0.027초

Cr2O3 첨가에 따른 PSS-PZT 압전 세라믹스의 유전 및 압전 특성 (Dielectric and Piezoelectric Characteristics of PSS-PZT Piezoelectric Ceramics with CrS12TOS13t Addition)

  • 홍재일;이개명;윤석진;유주현;박창엽
    • 대한전기학회논문지
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    • 제41권6호
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    • pp.687-693
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    • 1992
  • To improve dielectric, piezoelectric and temperature stability in 0.50Pb(SnS11/2TSbS11/2T)OS13T - 0.35PbTiOS13T - 0.60PbZrOS13T + 0.4[wt%]MnOS12T piezoelectric ceramics which is used for surface acoustic wave devices, CrS12TOS13T was added and the specimens were fabricated by Hot Press method, and their characteristics were measured with CrS12TOS13T addition. From the results, in the specimen added by 0.2[wt%]CrS12TOS13T, dielectric constant and mechanical quality factor were 380 and 2307, respectively, and it was suited for surface acoustic wave device and the temperature coefficient of the resonant frequency in the specimen added by 0.4[wt%]CrS12TOS13T was the least value of 74.96[ppm/$^{\circ}C$].

TiO₂/H₂O₂/UV 공정을 이용한 염색폐수처리에 관한 연구 (A Study on the Treatment of Dyeing Wastewater Using TiO₂/H₂O₂/UV Processes)

  • 조일형;정효준;박경렬;성기석;이용규;이홍근
    • 환경위생공학
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    • 제15권4호
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    • pp.27-27
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    • 2000
  • In order to treat the dyeing wastewater, the UV/TiO₂/H₂O₂ system was investigated, and proper pretreatment methods were examined to reduce the load on the system considering economical and technical efficiency. The results of this study were as follows: 1.UV/TiO₂/H₂O₂ system with pretreatment process was adopted, the result of Chemical coagulation and pH control units was pH 11→ coagulation → pH 4 and the optimum dosage of FeCl₃ was 600㎎/ℓ 2. Proper dosage of TiO₂in the UV/TiO₂/H₂O₂ system with pretreatment process was 2g/ℓ and H₂O₂ was 1000㎎/ℓ, UV contact time was 20min to get below 200㎎/ℓ of $COD_{Cr}$

적외선 센서를 위해 흡수층으로서 rf Magnetron Sputtering에 의해 제조된 NiCr 박막의 특성 (Characteristics of NiCr Thin Films Prepared by rf Magnetron Sputtering as Absorption Layer for Infrared Sensors)

  • 허성기;최은석;윤순길
    • 한국재료학회지
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    • 제13권10호
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    • pp.640-644
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    • 2003
  • NiCr thin films were fabricated by rf magnetron sputtering for applying to both the top electrode and absorption layer on Pb(Zr, Ti)O$_3$(PZT) thin films for infrared sensors. The rms roughness and resistivity of NiCr films prepared with Ni power of 80 W and Cr power of 50 W showed the most stable oxidation resistance after annealing at $600^{\circ}C$ for 5 min in oxygen ambient. The rms roughness and resistivity of NiCr films annealed at $V^{\circ}C$ in oxygen ambient were about 2$0\AA$ and $70 \mu$Ω-cm, respectively. As-deposited Ni/PZT/Pt and NiCr (Ni 80 W, Cr 50 W)/PZT/Pt structures showed well saturated hysteresis loops. However, in case of the samples annealed at $500^{\circ}C$ in oxygen ambient, only NiCr/PZT/Pt showed saturated loops having a remanent polarization of 20$\mu$C/$\textrm{cm}^2$. Ultra-thin NiCr films showed a possibility as a top electrode for infrared sensors.

고출력 변환기용 PZT-PFN계 및 $Cr_2O_3$ 변성 PZT-PFN계의 압전특성 (Piezoelectric characteristics of PZT-PFN and $Cr_2O_3$ modified PZT-PFN ceramics used in high power transducer)

  • 손은영;박창엽;홍재일
    • E2M - 전기 전자와 첨단 소재
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    • 제3권4호
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    • pp.279-286
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    • 1990
  • 고출력 변환기재료로 이용하기 위하여 유전손실에 기인한 압전 특성의 열화를 방지할 수 있는 큐리점이 비교적 높은 Pb$_{2}$FeNbO$_{6}$의 제3성분을 PZT에 고용한 고용체에서 양호한 압전특성을 갖는 조성을 찾고, 기계적 품질계수를 개선하고자 Cr$_{2}$O$_{3}$를 첨가한 변성 3성분계에 대하여 조사하였다. 그 결과, 전기기계결합계수가 가장 큰 조성은 0.05Pb(FeNb)O$_{3}$-0.4275PbTiO$_{3}$-0.5225 PbZrO$_{3}$이었으며 이조성의 기계적 품질계수, 상전이점은 170, 399.deg.C이었으며 이조성에 0.1wt% Cr$_{2}$O$_{3}$첨가한 변성 3성분계의 기계적 품질계수는 320으로 개선되었다.

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Chlorella vulgaris의 흡광도, 클로로필 및 개체수 통합 영향에 근거한 중금속 및 나노입자 독성 조사 (Toxicity Evaluation of Metals and Metal-oxide Nanoparticles based on the Absorbance, Chlorophyll Content, and Cell Count of Chlorella vulgaris)

  • 장현진;이문희;이은진;양신;공인철
    • 청정기술
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    • 제23권1호
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    • pp.27-33
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    • 2017
  • 본 연구에서는 중금속 7종(Cu, Cd, Cr, As(III), As(V), Zn, Ni) 및 나노입자 5종(CuO, ZnO, NiO, $TiO_2$, $Fe_2O_3$)에 대한 독성을 수계 대표 생물종인 녹조류 Chlorella vulgaris를 이용한 생물검정법으로 평가하였다. 조류에 미치는 영향은 흡광도, 클로로필 및 개체수 측정에 대한 결과를 통합하여 평가하였다. 중금속의 통합결과독성($TEC_{50}$) 순서는 Cr ($0.7mgL^{-1}$) > Cu ($1.7mgL^{-1}$) > Cd ($3.2mgL^{-1}$) > Zn ($3.9mgL^{-1}$) > Ni ($13.2mgL^{-1}$) > As(III) ($17.8mgL^{-1}$) ${\gg}$ As(V) (> $1000mgL^{-1}$)로 나타났다. 중금속은 측정종말점에 따라 일부 상이한 민감도와 독성이 조사되었다. 나노입자의 독성($TEC_{50}$) 순서는 ZnO ($2.4mgL^{-1}$) > NiO ($21.1mgL^{-1}$) > CuO ($36.6mgL^{-1}$) > $TiO_2$ ($62.5mgL^{-1}$) > $Fe_2O_3$ ($82.7mgL^{-1}$)로 나타났다. 나노입자는 측정종말점간에 비슷한 민감도와 독성을 보였다. 따라서 오염물의 독성을 평가하기 위해서 단일 방법에 의한 결과보다는 다양한 측정종말점의 통합결과에 근거한 접근이 적절할 것이다.

압전복합센서용 PZT 세라믹스의 미세구조 및 압전특성에 미치는 $Cr_2O_3$$Nb_2O_5$ 첨가효과 (Effect of $Cr_2O_3$ and $Nb_2O_5$ Additives on the Microstructure and Piezoelectric Properties of PZT Ceramics for Piezoelectric Composite Sensor)

  • 백종후;엄형근;임은경;김창일;이미재;최병현;김세기
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 추계학술대회 논문집 Vol.18
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    • pp.27-28
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    • 2005
  • 본 연구에서는$Cr_2O_3$$Nb_2O_5$ 를 첨가한 $Pb(Zr_{0.54}Ti_{0.48})O_3$ 세라믹스에서 $Nb_2O_5$ 첨가량에 따른 소결 및 압전, 유전특성을 조사하였다. $Pb(Zr_{0.54}Ti_{0.48})O_3$ + 0.2 wt% $Cr_2O_3$ + wt% $Nb_2O_5$ ($0.{\sim}2wt.%$)의 첨가량에 따른 압전, 유전특성 및 미세구조에 관해 연구하였다. 본조성에서 $Nb_2O_5$ 첨가량이 증가함에 따라 입경의 크기는 증가하였으며, 0.5 wt% $Nb_2O_5$ 첨가조성에서 $4\sim5\mu m$의 최대 평균입경을 보이다가 그 이상의 첨가 조성에서 급격히 감소하였다. 유전상수와 kp 는 $Nb_2O_5$ 첨가량이 1.0 wt% 조성까지 증가하였다가 그 이상 조성에서 감소하였다. $Nb_2O_5$ 첨가량이 증가함에 따라 삼방정(rhombohedral)구조에서 정방정(tetragonal)구조로 상전이 일어났으며, 본 조성의 상경계 영역인 0.5 wt% 조성에서 $\varepsilon_r$ = 730, $k_p$ = 0.72, $d_{33}$ = 450, $g_{33}$ = 70의 우수한 압전 특성을 나타내었다. 이러한 조성은 접촉센서용 복합압전소재의 실용가능성을 제시하였다.

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The Effect of Photocatalysis using $TiO_2$ and UV for COD Degradation of Wastewater in Linerboard Mill

  • Kang, Kwang-Ho;Kim, Hyoung-Jin
    • 펄프종이기술
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    • 제40권5호
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    • pp.53-59
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    • 2008
  • This study was carried out to investigate the effect of photocatalysis using $TiO_2$ and UV applied for the COD reduction of wastewater in linerboard mill. Trials were done to obtain the optimum addition amounts of $TiO_2$ and $H_2O_2$ to the wastewater and find an appropriate pH condition for photocatalysis on $TiO_2$ for degrading COD. The photocatalytic reaction was applied to the wastewater collected after secondary activated sludge treatment in WWTP of linerboard mill. The optimum application of photocatalysis reaction was obtained under the addition conditions of 2 g/L of $TiO_2$ and 200 mg/L of $H_2O_2$ at pH 3.0, respectively. The removal efficiency of $SCOD_{Cr}$ by photocatalytic treatment was 86.4 % and higher than Fenton treatment in which removal efficiency was 67.4 %. It was concluded that the photocatalytic process using $TiO_2$ and UV could be applied to the wastewater treatment in linerboard mill and also to the dramatic drop-off in NBDCOD load from wastewater of tertiary treatment in WWTP.

$Cr_{2}O_{3}$이 첨가된 PNN-PZT 압전세라믹스에서의 미세구조 및 특성 (Microstructure and Properties of $Cr_{2}O_{3}$additive ternary PZT Ceramics)

  • 박정호;김철수;김성곤;이상렬
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 하계학술대회 논문집
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    • pp.972-975
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    • 2001
  • The effect of Cr$_2$O$_3$(0 to 0.5 wt%) doping on the microstructure and electrical properties of ternary Pb(Zr,Ti)O$_3$-Pb(Ni,Nb)O$_3$piezoelectric ceramic has been investigated. Abnormal grain growth (grain size 3.3 to 11.2 $\mu$m) and densification are found. Minor additives of $\leq$0.1 wt% improve the mechanical coupling factor, but with more additives of $\geq$0.2 wt% electrical properties deteriorate. Thus, these phenomna can be ascribed mainly to anomalous developed microstructure. The large grains were composed of a core region that is free of Cr and a surrounding shell region rich in Cr. The interfaces between the core and the shell were composed of misfit dislocations. The mechanical properties of the specimens were strongly influenced by this microstructural change. The microstrutural and compositonal evolution of the specimens containing different amounts of Cr$_2$O$_3$were monitored. Electrical properties were measured and related to the variations in the microstructure.

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