• Title/Summary/Keyword: $Co_2(CO)_8$

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Effects of Storage Conditions on Quality Change after Storage of Deastringencied Persimmons (저장조건이 탈삽감의 저장 후 품질변화에 미치는 영향)

  • 정혜승;정헌식;이주백;성종환;최종욱
    • Food Science and Preservation
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    • v.8 no.1
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    • pp.1-8
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    • 2001
  • Effects of storage method and duration on the post-storage quality changes of deastringencied persimmons were investigated. Astringent persimmons(Diospyros kaki T. cv. Chungdobansi) were treated for 39 hours in 70% CO$_2$+5% O$_2$ at 25 $\^{C}$ for astringency removal, and then stored in CA(5%CO$_2$+3%O$_2$, 8%CO$_2$+3%O$_2$), MAP(0.06 mm LDPE film, 5.2%CO$_2$+6.8%O$_2$) and air at 0$\^{C}$ for 15, 45, 75 arnd 105 days. Subsequent to the storage, persimmons were held in air at 10$\^{C}$ for 4 days. The difference of firmness loss in relations to storage methods at O$\^{C}$ during holding at 10$\^{C}$ observed in fruits stored above 45 days at 0$\^{C}$, CA(8%CO$_2$+3%O$_2$) storage was more retarded the firmness loss than the others. Soluble solids during holding at 10$\^{C}$ trended to decrease in fruits stored above 75 days at 0$\^{C}$, CA and MAP storage were a little effective to keeping soluble solids. Titratable acidity during holding at 10$\^{C}$, decreased in fruits stored until 75 days at 0$\^{C}$ regardless storage methods. Sensory characteristics, color, hardness and overall acceptability of fruits stored in CA were significantly higher than those of fruits stored in MAP and air during shelf-life at 10$\^{C}$ after long-term storage at 0$\^{C}$ . These results show that the storage conditions had residual effect on the quality of deastringencied persimmons during shelf-life after long-term storage.

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3D-QSAR Studies of 8-Substituted-2-aryl-5-alkylaminoquinolines as Corticotropin-releasing Factor-1 Receptor Antagonists

  • Nagarajan, Santhosh Kumar;Madhavan, Thirumurthy
    • Journal of Integrative Natural Science
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    • v.8 no.3
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    • pp.176-183
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    • 2015
  • Corticotropin-releasing actor receptors (CRFRs) activates the hypothalamic pituitary adrenal axis, one of the 2 parts of the fight or flight response to stress. Increased CRH production has is associated with Alzheimer's disease and major depression and hypoglycemia. In this study, we report the important structural and chemical parameters for CRFR inhibitors using the derivatives of 8-substituted-2-aryl-5-alkylaminoquinolines. A 3D QSAR study, Comparative molecular field analysis (CoMFA) was performed. The best predictions were obtained for the best CoMFA model with a $q^2$ of 0.607 with 6 components and $r^2$ of 0.991. The statistical parameters from the generated CoMFA models indicated that the data are well fitted and have high predictive ability. The contour map resulted from the CoMFA models might be helpful in the future designing of novel and more potent CRFR derivatives.

An Investigation of Indoor Air Quality of Public Transportation System in Seoul City (서울시의 대중교통수단내 실내공기질에 대한 연구)

  • 김윤신;홍승철;전준민
    • Journal of Environmental Health Sciences
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    • v.20 no.1
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    • pp.28-38
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    • 1994
  • The objective of this study were to measure concentrations of indoor pollutants in public transportation systems to provide importance of indoor air quality in transportation systems to policy makers. Indoor air quality of the pollutants (CO, CO$_2$, PM-10) and environmental sources (temperature, humidity) were measured at subway, seat-type bus, and city-type bus in the Seoul area from April to September 1992. The same pollutants and environmental sources were also measured at selected bus stops and subway stations during October 1991-September 1992. The mean concentrations of indoor pollutants in the public transportation systems were showed 115.5 $\mu$g/m$^3$ in PM-10, 6.8 ppm in CO, and 2167.9 ppm in CO$_2$, respectively. The mean values of PM-10 and CO showed below the U.S. 24 hour standard value of PM-10 and the Korea ambient CO standard, while the mean concentrations of CO$_2$ exceeded the Korea CO$_2$ standard. The highest levels of indoor concentration at public transportation systems were PM-10 of 134.6 $\mu$g/m$^3$ in the subway, CO of 8.9 ppm in the city-type bus, CO$_2$ of 2,511.1ppm in seat-type bus, respectively. The results showed that indoor air quality in bus and subway seemed likely to be affected by number of passengers and outdoor air infiltrated from exhausted gases of automobiles.

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HDDR Characteristics and Magnetic Properties of Nd15(Fe1-xCox)77B8(x=0-0.6) Alloys

  • Kwon, H.W.
    • Journal of Magnetics
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    • v.7 no.4
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    • pp.127-131
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    • 2002
  • HDDR characteristics and magnetic properties of $Nd_{15}{(Fe_{1-x}Co_{x})}_{77}B_{8}$(x=0-0.6) alloys were investigated. The effect of applying magnetic field during the recombination step on the anisotropic nature of the HDDR-treated material was also examined. The $Nd_{15}{(Fe_{1-x}Co_{x})}_{77}B_{8}$ phase in the Nd-Fe-B alloys with high Co-substitution alloy had remarkably enhanced phase stability. The $Nd_{15}{(Fe_{1-x}Co_{x})}_{77}B_{8}$(x=0-0.6) alloys with high Co-substitution could be HDDR-treated successfully by only using high pressure hydrogen. However, these alloys had no appreciable coercivity. The poor coercivity of the HDDR-treated $Nd_{15}{(Fe_{1-x}Co_{x})}_{77}B_{8}$(x=0-0.6) alloys with high Co-substitution was attributed to the $Nd{(Fe,Co)}_2$ phase in the alloys. The magnetic filed applied during the recombination step had little effect on the anisotropic nature of the HDDR-treated powder.

Preparation of Honeycomb Carbon Dioxide Adsorbent Impregnated $K_2CO_3$ and Its Characterization ($K_2CO_3$를 담지시킨 고체 허니컴 이산화탄소 흡수제의 제조 및 이의 특성 평가)

  • Lee, Dong-Chul;Kim, Jin-Bae;You, Yoon-Jong
    • Applied Chemistry for Engineering
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    • v.23 no.6
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    • pp.624-629
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    • 2012
  • To capture and recover carbon dioxide ($CO_2$), we impregnated honeycomb made of ceramic paper with $K_2CO_3$ and its absorption characteristics of $CO_2$ were investigated. The absorption amount of $CO_2$ on the honeycomb absorbent impregnated with $K_2CO_3$ was 13.8 wt% at a constant temperature ($70^{\circ}C$) and relative humidity (66%) condition. Because the absorption amount of $CO_2$ achieved almost the same loading ratio of $K_2CO_3$ (17.6 wt%), the absorption reaction of $CO_2$ by $K_2CO_3$ on the honeycomb absorbent seems to be going smoothly. In addition, $CO_2$ absorption breakthrough characteristics of the honeycomb absorbent were analyzed at the temperature range of $50{\sim}80^{\circ}C$, and the water vapor was fed to an absorption column before the feeding of $CO_2$ or simultaneously with $CO_2$. As a result, the absorption capacity of $CO_2$ was more enhanced using the water vapor supplying before $CO_2$ than that of simultaneous supplying. It was confirmed by temperature programmed desorption analysis that the $KHCO_3$ produced by the absorption reaction of $K_2CO_3$ and $CO_2$ is regenerated by the desorption of $CO_2$ at a temperature of about $128^{\circ}C$.

Syntheses and Spectroscopic Studies of [$Cp_2ZrR]_2Fe(CO)_4$

  • Ko, Jae-Jung
    • Bulletin of the Korean Chemical Society
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    • v.7 no.6
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    • pp.413-421
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    • 1986
  • Hydrocarbon solution of $Cp_2Zr(CH_3)Cl$ react rapidly with $Na_2Fe(CO)_4$ (1/2 equiv.) to yield $[Cp_2Zr(CH_3)]_2Fe(CO)_4$ and NaCl. The more soluble metal-metal bonded complex $[Cp_2ZrC_8H_{17}]_2Fe(CO)_2$ has also been prepared through the reaction of $Cp_2Zr(C_8H_{17})BF_4$ and $Na_2Fe(CO)_4 (1/2 equiv.). The complexes were characterized by IR, $^1H$ NMR, ^{13}C$ NMR, and elemental analysis. The infrared spectrum of $[Cp_2ZrR]_2Fe(CO)_4$ shows four bands, which is indicative of a cis-structure. The $^{13}C$ NMR spectrum provides evidence for the cis-structure.

Magnetoresistance Characteristics of Magnetic Tunnel Junctions Consisting of Amorphous CoNbZr Alloys for Under and Capping Layers

  • Chun, Byong Sun;Lee, Seong-Rae;Kim, Young Keun
    • Journal of Magnetics
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    • v.9 no.1
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    • pp.13-16
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    • 2004
  • Magnetic tunnel junctions (MTJs) comprising amorphous CoNbZr layers have been investigated. $Co_{85.5}Nb_8Zr_{6.5}$(in at. %) layers were employed to substitute the traditionally used Ta layers with an emphasis given on under-standing underlayer effect. The typical junction structure was $SiO_2/CoNbZr$ or Ta 2/CoFe 8/IrMn 7.5/CoFe 3/Al 1.6 + oxidation/CoFe 3/CoNbZr or Ta 2 (nm). For both as-deposited state and after annealing, the CoNbZr-underlayered structure showed superior surface smoothness up to the tunnel barrier than Ta-underlayerd one (rms roughness of 0.16 vs. 0.34 nm). CoNbZr-based MTJs was proven beneficial for increasing thermal stability and increasing $V_h$ (the bias voltage where MR ratio becomes half) characteristics than Ta-based MTJs. This is because the CoNbZr-based junctions offer smoother interface structure than the Ta-based one.

Analysis of Background $CO_2$Concentrations at Anmyeon-do Using Selecting Method of World Data Centre for Greenhouse Gases (배경대기 중 $CO_2$ 자료 선정 방법에 따른 안면도 자료의 분석)

  • 김정식;최재천
    • Journal of Korean Society for Atmospheric Environment
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    • v.17 no.3
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    • pp.277-288
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    • 2001
  • Continuous atmospheric CO$_2$measurements measured during the 1 year(1998.8∼1999.8) at Korea Global Atmosphere Watch Observatory (KGAWO) in Anmyeon-do are analyzed by the selecting method which is recommended by WDCGG to get background CO$_2$. This method can reject data based on two criteria: the instability of CO$_2$ concentration within 1 hour from hourly standard deviation (hourly variability$\leq$ 0.6 ppm first selection) and the large changes in the CO$_2$ concentration from one hour to the nex(∼$\leq$0.3 ppm, second selection). We could obtain hourly background CO$_2$ of 37% in first selection and 20% in second selection during the l year. That are a little less than those of Ryori station in Japan. especially, the cases of background CO$_2$ which is selected were few during the summer. That is caused by affection of vegetation and anthropogenic source. After the selecting methods are applied, the cases which is selected for easterly wind decrease remarkably according to the analysis of wind direction about continuous CO$_2$ .That was affected by anthropogenic source from the east area.

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Carbonate scale reduction in reverse osmosis membrane by CO2 in wastewater reclamation

  • Shahid, Muhammad Kashif;Pyo, Minsu;Choi, Young-Gyun
    • Membrane and Water Treatment
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    • v.8 no.2
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    • pp.125-136
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    • 2017
  • Reverse osmosis technology is being used on large scale for treatment of ground water, brackish water, wastewater and sea water. The most challenging issue in RO process is carbonate scaling which is directly linked with the efficiency and economy. Considering the natural phenomena of carbonate scaling different adaptations have been made to control scaling on the surface of RO membrane including acid dosage and antiscalant addition. As carbonate scaling is directly related with pH level of feed water, present study describes an experimental approach to reduce scaling on RO membrane by lowering the feed water pH by purging $CO_2$. In this comparative study four different conditions including control process (without any scale inhibitor), with dosage of antiscalant, with purging of $CO_2$ and with co addition of antiscalant and $CO_2$ in a feed stream line; it was established that $CO_2$ is a better appliance to reduce carbonate scaling on the membrane surface by reduce pH of feed stream. It was also observed that $CO_2$ and antiscalant mutually function better for scale control.

Diagnostic Techniques for SARS-CoV-2 Detection (SARS-CoV-2의 진단기술)

  • Kim, Jong-Sik;Kang, Na-Kyung;Park, Seon-Mi;Lee, Eun-Joo;Chung, Kyung Tae
    • Journal of Life Science
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    • v.30 no.8
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    • pp.731-741
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    • 2020
  • Coronavirus disease 19 (COVID-19) is caused by SARS-CoV-2 (Severe Acute Respiratory SyndromeCoronavirus 2). To date, seven coronaviruses that can infect humans were reported. Among them, infections with four coronavirus strains (HCoV-229E, HCoV-OC43, HCoV-NL63, and HCoV-HKU1) resulted in mild symptoms such as common cold, whereas SARS-CoV and MERS-CoV caused severe symptoms and epidemics in 2002 and 2012, respectively. In the most recent, SARS-CoV-2 was first reported in Wuhan, China in December 2019 and became a notorious cause of the ongoing global pandemics. To diagnose, treat, and prevent COVID-19, the development of rapid and accurate diagnostic tools, specific therapeutic drugs, and safe vaccines essentially are required. In order to develop these powerful tools, it is prerequisite to understand a phenotype, a genotype, and life cycle of SARS-CoV-2. Diagnostic techniques have been developing rapidly around world and many countries take the fast track system to accelerate approval. Approved diagnostic devices are rapidly growing facing to urgent demand to identify carriers. Currently developed commercial diagnostic devices are divided into mainly two categories: molecular assay and serological & immunological assay. Molecular assays begins the reverse transcription step following polymerase chain reaction or isothermal amplification. Immunological assay targets SARS-CoV-2 antigen or anti-SARS-CoV-2 antibody of samples. In this review, we summarize the phenotype, genome structure and gene expression of SARS-CoV-2 and provide the knowledge on various diagnostic techniques for SARS-CoV-2.