• Title/Summary/Keyword: $Co_2(CO)_8$

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Characterization of Co-AC/TiO2 Composites and Their Photonic Decomposition for Organic Dyes

  • Chen, Ming-Liang;Son, Joo-Hee;Park, Chong-Yun;Shin, Yong-Chan;Oh, Hyun-Woo;Oh, Won-Chun
    • Korean Journal of Materials Research
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    • v.20 no.8
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    • pp.429-433
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    • 2010
  • In this study, activated carbon (AC) as a carbon source was modified with different concentrations of cobalt chloride ($CoCl_2$) to prepare a Co-AC composite, and it was used for the preparation of Co-AC/$TiO_2$ composites with titanium oxysulfate (TOS) as the titanium precursor. The physicochemical properties of the prepared Co-AC/$TiO_2$ composites were characterized by $N_2$ adsorption at 77 K, X-ray diffraction (XRD), scanning electron microscopy (SEM), and energy dispersive X-ray (EDX) analysis. The photocatalytic treatments of organic dyes were examined under an irradiation of visible light with different irradiation times. $N_2$ adsorption data showed that the composites had decreased surface area compared with the pristine AC, which was $389\;m^2/g$. From the XRD results, the Co-AC/$TiO_2$ composites contained a mixturephase structuresof anatase and rutile, but a cobalt oxide phase was not detected in the XRD pattern. The EDX results of the Co-AC/$TiO_2$ composites confirmed the presence of various elements, namely, C, O, Ti, and Co. Subsequently, the decomposition of methylene orange (MO, $C_{14}H_{14}N_3NaO_3S$) and rhodamine B (Rh.B, $C_{28}H_{31}ClN_2O_3$) in an aqueous solution, respectively, showed the combined effects of an adsorption effect by AC and the photo degradation effect by $TiO_2$. Especially, the Co particles in the Co-AC/$TiO_2$ composites could enhance the photo degradation behaviors of $TiO_2$ under visible light.

The Structural Properties of The Structural Properties of 0.8Ba($Zn_{1/3}Ta_{2/3})O_3$-0.2Ba($Co_{1/3}Nb_{2/3})O_3$ Ceramics with Sintering Temperature (소결온도에 따른 0.8Ba($Zn_{1/3}Ta_{2/3})O_3$-0.2Ba($Co_{1/3}Nb_{2/3})O_3$ 세라믹스의 구조적 특성)

  • Bae, Kyoung-In;Lee, Moon-Kee;Lim, Sung-Soo;Kim, Kang;Ryus, Ki-Won;Lee, Young-Hie
    • Proceedings of the KIEE Conference
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    • 2000.07c
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    • pp.1667-1669
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    • 2000
  • The 0.8Ba($Zn_{1/3}Ta_{2/3})O_3$-0.2Ba($Co_{1/3}Nb_{2/3})O_3$ ceramics were prepared by conventional mixed oxide method. The structural properties of the 0.8BZT-0.2BCN ceramics with the sintering temperature were investigated by XRD and SEM. The 0.8BZT-0.2BCN ceramics had a superstructure reflection plane of (100), (200). Increasing the sintering temperature. the ordering parameter of B-site atoms were increased. The lattice constant of 0.8BZT-0.2BCN ceramics was 3.97${\AA}$. Increasing the sintering temperature, the average gram sizes were increased. In the case of the 0.8BZT-0.2BCN ceramics sintered at 1500$^{\circ}C$, the average grain size and bulk density were 1.56${\mu}m$, 6.93$g/cm^3$, respectively.

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Photosynthetic Characteristics of Panax ginseng C.A. Meyer I. Photosynthetic Response to Changes of Light Intensity and Leaf Temperature (고려인삼의 광합성 특성 I. 광도와 잎온도의 변화에 따른 광합성 반응)

  • 현동윤;황종규
    • Journal of Ginseng Research
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    • v.17 no.3
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    • pp.240-245
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    • 1993
  • This study was conducted with ginseng plants to investigate photosynthetic response to changes of light intensity and leaf temperature. $CO_2$ uptake in diurnal course was highest in the first phase (8 00~5 : 30 Am.) on May 30, 1992. In $CO_2$ uptake related to stomatal conductance, these relationship was synchronized in diurnal course, but relationship between TEX>$CO_2$ uptake and intercellular $CO_2$ concentration in diurnal course was synchronized oppositely. Leaf temperature and light intensity at the highest $CO_2$ uptake were in the range of 23~$24^{\circ}C$) and 95$\mu$mol.$m^{-2}$.$s^{-1}$), $CO_2$ , respectively. In response to an increasing light intensity under a constant leaf temperature ($18^{\circ}C$), $CO_2$ uptake was increased throughout the light intensity sequence up to 250$\mu$mol.$m^{-2}$.$s^{-1}$), $CO_2$ When $CO_2$ uptake was measured with a series of leaf temperature under a constant light intensity (250 $\mu$mol.$m^{-2}$.$s^{-1}$), $CO_2$ uptake was highest at $18^{\circ}C$ as a 4.1$\mu$mol.$m^{-2}$.$s^{-1}$), $CO_2$ . Similar changes were also observed in stomatal conductance and intercellular $CO_2$ concentration. Evidences from several approaches indicate that synchronization of $CO_2$ uptake, stomatal conductance and intercellular $CO_2$ concentration were closely inter-related and changes of leaf temperature iuluenced the photo-response in photosynthetic processes.

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Solid-State $CO_2$ Sensor using ${Li_2}{CO_3}-{Li_3}{PO_4}-{Al_2}{O_3}$ Solid Electrolyte and ${LiMn_2}{O_4}$ as Reference Electrode (${Li_2}{CO_3}-{Li_3}{PO_4}-{Al_2}{O_3}$계의 고체 전해질 및 ${LiMn_2}{O_4}$의 기준전극을 사용한 $CO_2$ 가스센서)

  • 김동현;윤지영;박희찬;김광호
    • Journal of the Korean Ceramic Society
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    • v.37 no.8
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    • pp.817-823
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    • 2000
  • A solid-state electrochemicall cell for sensing CO2 gas was fabricated using a solid electrolyte of Li2CO3-Li3PO4-Al2O3 mixture and a reference electrode of LiMn2O4. The e.m.f. (electromotive force) of sensor showed a good accordance with theoretical Nernst slope (n=2) for CO2 gas concentration range of 100-10000 ppm above 35$0^{\circ}C$. The e.m.f. of sensor was constant regardless of oxygen partial pressure at the high temperature above 0.1 atm. It was, however, a little depended on oxygen partial pressure as the pressure decreased below 0.1 atm. The oxygen-dependency of our sensor gradually disappeared as the operating temperature increased. The sensing behavior of our CO2 sensor was affected by the presence of water vapor, but its effect was small comparing with other sensors.

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The effect of $Co_3O_4$ substitution on properties of Ni-Zn Ferrite (Ni-Zn 페라이트 물성의 $Co_3O_4$ 치환효과)

  • An, Yong-Woon;Kim, Jong-Ryung;Oh, Young-Woo;Kim, Hyun-Sik;Lee, Hae-Yon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07a
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    • pp.569-572
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    • 2003
  • 전력선 통신용 LC 공진필터에 사용되는 Ni-Zn 페라이트를 제조하기 위해 Ni0.8Zn0.2Fe2O4를 기본조성으로 선택하고 x (Co mol 비)를 변화시켜 전자기적 특성을 조사하였다. $Bi_2O_3$ CaO가 첨가됨으로써 균일한 입자성장과 입계에 고저항층이 형성되어 주파수 손실이 감소하였으며, $Ni_{0.8-x}Zn_{0.2}Co_xFe_2O_{\delta}$의 기본조성에 Co의 함량을 증가시키면 x = 0.05에서 투자율 75, 공진주파수 20 MHz의 특성을 나타내고 결정 입자 크기와 같은 구조적 특성에는 영향을 거의 미치지 않지만 자기이방성 변화에 따라 전자기적 특성에는 영향을 미친다. 또한, $Ni_{0.75}Zn_{0.2}Co_{0.05}Fe_2O_{4.017}$ 조성의 페라이트 코어의 발열량은 큐리온도 이하에서 일어난다.

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Relationships between Urbanization, Economic Growth, Energy Consumption, and CO2 Emissions: Empirical Evidence from Indonesia

  • BASHIR, Abdul;SUSETYO, Didik;SUHEL, Suhel;AZWARDI, Azwardi
    • The Journal of Asian Finance, Economics and Business
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    • v.8 no.3
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    • pp.79-90
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    • 2021
  • This study aims to investigate the relationship between urbanization, economic growth, energy consumption, and CO2 emissions in Indonesia. The data used in the study are time-series data for the period 1985-2017; the data utilized are sourced from World Development Indicators obtained on the World Bank database. The method uses a quantitative approach that applies the vector error correction model based on the Granger causality test. The empirical results reveal that, in the short run, there is evidence that urbanization and energy consumption can causes CO2 emissions, and they also prove that urbanization can cause energy consumption. Also, other findings prove the existence of long-run relationships flowing from energy consumption, economic growth, and CO2 emissions toward urbanization, as well as the existence of the relationship flowing from urbanization, economic growth, and CO2 emissions towards energy consumption. The results of testing the relationship between economic growth and CO2 emissions reveal that the environmental Kuznets curve hypothesis is proven in Indonesia. Thus, policies are needed to limit the impact of urbanization through high awareness-raising to maintain environmental quality and greater use of energy. Also, energy conservation policies are needed in all sectors, especially the electricity, industry, and transportation sectors.

Combustion Chracteristics of the Pinus rigida and Castanea savita Dried at Room Temperature (실온에서 건조된 리기다 소나무와 밤나무의 연소특성)

  • Chung, Yeong-Jin;Jin, Eui
    • Fire Science and Engineering
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    • v.24 no.3
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    • pp.86-92
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    • 2010
  • One of the limitation of wood as building materials is its flammability. The purpose of this paper is to examine the combustion properties of the Pinus rigida and Castanea savita which are grown in Korea and meet the desirable characteristics for use of construction materials. The cone calorimeter (ISO 5660-1) was used to determine the heat release rate (HRR) and fire smoke index, as well as CO and $CO_2$ production and smoke obscuration. The $HRR_{mean}$ of the Castanea savita and Pinus rigida at $50\;kW/m^2$ of radiant heat flux was $70.4\;kW/m^2$ and $68.5\;kW/m^2$. Furthermore, the THR of Castanea sativata was 120.8 MJ/kg and it was higher than the THR of Pinus rigida ($81.9\;MJ/m^$). These results are depend on the bulk density of tested wood species. The Castanea savita has high $CO_{mean}$ yield and high CO/$CO_2$ yield compared with that of Pinus rigida.

An Economic Feasibility Study on Fuel Transfer of A Thermal Power Plant Considering CO2 Emission Cost (CO2 배출비용을 고려한 발전소의 연료교체 경제성에 대한 연구)

  • Lee, Sang-Joong;Jeong, Yeong-Ho
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.23 no.2
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    • pp.125-130
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    • 2009
  • With respect to the goal of achieving at least 50[%] reduction of global emissions by 2050, the G8 leaders agreed to seek to share and adopt it with all Parties to the UNFCCC in the 34th Group of Eight Summit held in Toyako, Japan in July 2008. Korea is also expected to obey the Kyoto Protocol starting in 2013, which will result in a serious shock especially to the electric power industry. The power plants burning the fossil fuel produce more than 20 percent of national $CO_2$ emission. This paper presents an economic feasibility study on fuel transfer for a thermal power plant considering $CO_2$ emission cost. Calculation of the breakeven point for the fuel transfer from LNG to heavy oil of D power plant is demonstrated using the input-output coefficients obtained by the performance test.

Characteristics of Solid Regenerable $CO_2$ sorbents for Pre-combustion $CO_2$ Capture (연소전 $CO_2$ 포집용 분무건조 고체 흡수제의 물성 및 $CO_2$ 흡수 특성)

  • Baek, Jeom-In;Ryu, Jungho;Lee, Joong Beom;Eom, Tae-Hyoung;Kim, Ji-Woong;Jeon, Eon-Sik;Ryu, Chong Kul
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.110.2-110.2
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    • 2010
  • 현재 상용가능한 연소전 $CO_2$ 포집 기술은 습식 스크러빙 방식으로 고온의 합성가스를 상온 수준으로 온도를 낮춘 후 $CO_2$를 포집해야 하고 포집된 $CO_2$의 압력이 낮아 재압축하여 저장소로 보내야 함에 따라 큰 폭의 열효율 손실이 불가피하다. 고온 고압에서 이산화탄소를 포집할수 있는 고체 흡수제를 이용할 경우 이산화탄소 포집 치 저장 추가에 따른 시스템 효율 저하를 최소화할 수 있다. 고체 $CO_2$ 흡수제는 서로 연결된 두 개의 유동층 반응기를 순환하면서 흡수탑에서는 합성가스 중의 $CO_2$를 흡수하고 재생탑에서는 고온의 수증기와 접촉하여 흡수된 $CO_2$를 다시 배출함으로써 재생된다. 따라서 건식 재생 $CO_2$ 흡수제는 유동층 공정에 응용가능한 물성과 함께 높은 $CO_2$ 흡수능과 빠른 반응성이 요구된다. 본 연구에서는 유동층 공정에 적합한 물성을 가진 연소전 $CO_2$ 포집용 고체 흡수제를 분무건조법으로 제조하였으며, 모사 합성가스를 이용하여 열중량분석기와 기포유동층반응기를 이용하여 $200^{\circ}C$ 흡수, $400^{\circ}C$ 재생, 압력 20 bar 조건으로 반응성을 측정하였다. 개발된 고체 $CO_2$ 흡수제는 열중량분석기에서는 반응 후 10-13 wt%의 무게증가를 나타내었고 기포유동층반응기에서는 8-10 wt%의 $CO_2$ 흡수능을 보여주었다. 특히 수증기의 함량이 10% 이상에서 높은 흡수능을 나타내어 수증기가 반응에 크게 작용하고 있음을 알 수 있었다.

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