• Journal of the Korean Society of Safety
• /
• v.23 no.5
• /
• pp.54-60
• /
• 2008

The objective of this study is to obtain the optimal process condition and the maximum decomposition efficiency by measuring the decomposition efficiency, electricity consumption, and voltage in accordance with the change of the process variables such as the frequency, maintaining time period, concentration, electrode material, thickness of the electrode, the number of windings of the electrode, and added materials etc. of the harmful atmospheric contamination gases such as NO, $NO_2$, and $SO_2$ etc. with the plasma which is generated by the discharging of the specially designed and manufactured $TiO_2$ catalysis reactor and SPCP reactor. The decomposition efficiency of the NO, the standard samples, is obtained with the plasma which is being generated by the discharge of the combination effect of the $TiO_2$ catalysis reactor and SPCP reactor with the variation of those process variables such as the frequency of the high voltage generator($5{\sim}50kHz$), maintaining time of the harmful gases($1{\sim}10.5sec$), initial concentration($100{\sim}1,000ppm$), the material of the electrode(W, Cu, Al), the thickness of the electrode(1, 2, 3mm), the number of the windings of the electrode(7, 9, 11turns), basic gases($N_2$, $O_2$, air), and the simulated gas($CO_2$) and the resulting substances are analyzed by utilizing FT-IR & GC.

• Transactions of the Korean hydrogen and new energy society
• /
• v.13 no.2
• /
• pp.143-150
• /
• 2002

The thermal behavior of $(Co_{0.5}\;Mn_{0.5})Fe_2O_4$ prepared by a co-precipitation wasinvestigated for Hz generation by the thermochemical cycle. The reduction reaction of $(Co_{0.5}\;Mn_{0.5})Fe_2O_4$ started from $480^{\circ}C$, and the weight loss was 1.6 wt% up to $1100^{\circ}C$. At this reaction, $(Co_{0.5}\;Mn_{0.5})Fe_2O_4$ was reduced by release of oxygen bonded with the $Fe^{3+}$ ion in the B site of ($CO_{0.5}$ $(Co_{0.5}\;Mn_{0.5})Fe_2O_4$. In the $H_2O$ decomposition reaction, $H_2$ was generated by oxidationof reduced $(Co_{0.5}\;Mn_{0.5})Fe_2O_4$. The crystal structure of $(Co_{0.5}\;Mn_{0.5})Fe_2O_4$ for reduction reaction maintained spinel structure and the lattice constant of $(Co_{0.5}\;Mn_{0.5})Fe_2O_4$ ($8.41\AA$) was enlarged to $8.45\AA$. But the lattice constant of $(Co_{0.5}\;Mn_{0.5})Fe_2O_4$ after $H_2O$ decomposition reaction did not change to $8.45\AA$. Then, $(Co_{0.5}\;Mn_{0.5})Fe_2O_4$ is excellent material in the thermochemical cyclic reaction due to release oxygen at low temperature for the reduction reaction and produce $H_2$ maintaining crystal structure for redox reaction.

• Journal of the Korean Ceramic Society
• /
• v.35 no.5
• /
• pp.505-511
• /
• 1998

The silicide formation mechanisms of Co/Hf and Co/Nb bilayer on (100) Si have been investigated. We ob-served that crystallographic orientationso f the 500$^{\circ}C$ formed cobalt silcides were different each other with the varying intermediate layers. Epitaxial and non-epitaxial CoSi2 formed simultaneously in Co/Hf/(100Si. While only non-epitaxial CoSi2 formed in Co/Nb/(100) Si. The reason why the crystallographic orientation of CpSi2 is different for those two systems seemed to be relate to the formation and decomposition of stable reaction barriers at high temperature. The stable reaction barrier formed at high temperature could control the uniform diffusion of Co atoms which enables epitaxial growth of CoSi2.

• KEPCO Journal on Electric Power and Energy
• /
• v.6 no.4
• /
• pp.447-454
• /
• 2020

Since SF₆ gas was discovered in the early 1900s, it has been widely used as an insulation material for electrical equipment. While various indicators have been developed to diagnose oil-immersed transformers, there are still insufficient indicators for the diagnosis of gas-insulated transformers. When necessary, chemical diagnostic methods can be used for gas-insulated transformers. However, the field suitability and accuracy of those methods for transformer diagnosis have not been verified. In addition, since various types of decomposition gases are generated therein, it is also necessary to establish appropriate analysis methods to cover the variety of gases. In this study, a gas-insulated transformer was diagnosed through the analysis of decomposition gases. Reliability assessments of both simple analysis methods suitable for on-site tests and precise analysis methods for laboratory level tests were performed. Using these methods, a gas analysis was performed for the internal decomposition gases of a 154 kV transformer in operation. In addition, simulated discharge and thermal fault experiments were demonstrated. Each major decomposition gas generation characteristics was identified. The results showed that an approximate diagnosis of the inside of a gas-insulated transformer is possible by analyzing SO₂, SOF₂, and CO using simple analysis methods on-site. In addition, since there are differences in the types of decomposition gas generation patterns with various solid materials of the internal transformer, a detailed examination should be performed by using precise analysis methods in the laboratory.

• 한국신재생에너지학회:학술대회논문집
• /
• 2009.06a
• /
• pp.761-764
• /
• 2009

The thermocatalytic decomposition of methane is an environmentally attractive approach to $CO_2$-free production of hydrogen. The fluidized bed was proposed for the continuous withdraw of product carbon from the reactor. The usage of carbon black was reported as stable catalyst for decomposition of methane. Therfore, carbon black (DCC-N330) is used as catalyst. A fluidized bed reactor made of quartz with 0.055 m I.D. and 1.0 m in height was selected for the thermo-catalytic decomposition. The porpane-containg methnae decomposition reaction was operated at the temperature range of 850-900 $^{\circ}C$ methane gas velocity of 1.0 $U_{mf}$ and the operating pressure of 1.0 atm. In this work, propane was added as reactant to make methane conversion higher. Therefore we compared with methane conversion and pre-experiment methane conversion that using only methane as reactant. The carbon black, after experiment, was measured in particle size and surface area and analyzed surface of the carbon black by TEM.

• 한국신재생에너지학회:학술대회논문집
• /
• 2006.11a
• /
• pp.388-391
• /
• 2006

A fluidized bed reactor made of quartz with 0.055m I.D. and 1.0m in height was employed for the thermocatalytic decomposition of propane to produce $CO_2-free$ hydrogen. The fluidized bed was proposed for the continuous withdraw of product carbons from the reactor The propane decomposition rate used carbon black DCC-N330, Hi-900L as a catalyst. The propane decomposition reaction was carried out at the temperature range of $600-800^{\circ}C$, propane gas velocity of $1.0U_{mf}$ and the operating pressure of 1.0 atm. Effect of operating parameters such as reaction temperature on the reaction rates was investigated. Resulting production in our experiment were not only hydrogen but also several by products such as methane, ethylene, ethane, and propylene.

• Journal of Environmental Science International
• /
• v.22 no.9
• /
• pp.1097-1103
• /
• 2013

Tetrafluoromethane($CF_4$) have been widely used as etching and chemical vapor deposition gases for semiconductor manufacturing processes. $CF_4$ decomposition efficiency using microwave system was carried out as a function of the microwave power, the reaction temperature, and the quantity of $Al_2O_3$ addition. High reaction temperature and addition of $Al_2O_3$ increased the $CF_4$ removal efficiencies and the $CO_2/CF_4$ ratio. When the SA30 (SiC+30wt%$Al_2O_3$) and SA50 (SiC+50wt%$Al_2O_3$) were used, complete $CF_4$ removal was achieved at $1000^{\circ}C$. The $CF_4$ was reacted with $Al_2O_3$ and by-products such as $CO_2/CF_4$ and $AlF_3$ were produced. Significant amount of by-product such as $AlF_3$ was identified by X-ray powder diffraction analysis. It also showed that the ${\gamma}-Al_2O_3$ was transformed to ${\alpha}-Al_2O_3$ after microwave thermal reaction.

• Journal of the Korean Society for Railway
• /
• v.15 no.3
• /
• pp.286-293
• /
• 2012

Korean government is enforcing 'Greenhouse gas target management' in order to achieve Greenhouse gas reduction target. To attain Greenhouse gas reduction target, companies in Korea must establish their GHG inventory system and analysis their GHG emissions characteristics for deduction of mitigation measures. LMDI(Log Mean Divisia Index) decomposition analysis is widely used to understand characteristics of GHG emission and energy consumption. In this paper, the characteristics of GHG emission from the line of railroad in Korea is respectively analyzed in terms of conversion effect, intensity effect, production effect and distance effect. Data of railroad GHG emission from 2000 to 2007 are used. As a result, total effect of railroad's GHG emission is $96,813tCO_2eq$. Production effect ($39,865tCO_2eq$) and distance effect ($327,923tCO_2eq$) affect increase of railroad GHG emissions while Conversion effect ($-158,161tCO_2eq$) and intensity effect ($-112,814tCO_2eq$) influence decrease of the emissions.

• Journal of Climate Change Research
• /
• v.8 no.4
• /
• pp.357-367
• /
• 2017

Electricity generation in Korea mainly depends on thermal power and nuclear power. Especially the coal power has led to the increase in $CO_2$ emissions. This paper intends to analyze the current status of $CO_2$ emissions from electricity generation in Korea during the period 1990~2016, and apply the logarithmic mean Divisia index (LMDI) technique to find the nature of the factors influencing the changes in $CO_2$ emissions. The main results as follows: first, $CO_2$ emission from electricity generation has increased by $165.9MtCO_2$ during the period of analysis. Coal products is the main fuel type for thermal power generation, which accounts about 73% $CO_2$ emissions from electricity generation. Secondly, the increase of real GDP is the most important contributor to increase $CO_2$ emissions from electricity generation. The carbon intensity and the electricity intensity also affected the increase in $CO_2$ emission, but the energy intensity effect and the dependency of thermal power effect play the dominant role in decreasing $CO_2$ emissions.

• Journal of the Korea Organic Resources Recycling Association
• /
• v.26 no.2
• /
• pp.43-51
• /
• 2018

The objective of this research was to assess the effect of moisture content and water injection method into the landfill on waste decomposition in an aerobic landfill. Firstly, respirometric experiments were performed in order to assess the effect of initial moisture content (20%, 30%, 40% and 50% respectively) on landfilled waste decomposition. The cumulative oxygen uptake and oxygen uptake rate were highly increased with the increase of initial moisture content. Secondly, lysimeter experiments showed that in comparison with the vertical injection method, dry fog system enhanced decomposition of organic wastes. Also, dry fog system provided uniform moisture distribution more than the vertical injection method within landfill.