• 제목/요약/키워드: $C_s$ symmetry

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다원화합물 반도체 $ZnGaInS_4:Er^{3+}$ 단결정의 광발광 특성 (Photoluminescence of Multinary-compound Semiconductor $ZnGaInS_4:Er^{3+}$ Single Crystals)

  • 김남오;김형곤;방태환;현승철;김덕태
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2000년도 학술대회 논문집 전문대학교육위원
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    • pp.35-39
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    • 2000
  • $ZnIn_2S_4$ and $ZnGaInS_4:Er^{3+}$ single crystals crystallized in the rhombohedral (hexagonal) space group $C_{3v}^5(R3m)$, with lattice constants $a=3.852{\AA},\;c=37.215{\AA}$ for $ZnIn_2S_4$, and $a=3.823{\AA}$, and $c=35.975{\AA}$ for $ZnIn_2S_4:Er^{3+}$. The optical absorption measured near the fundamental band edge showed that the optical energy band structure of there compounds had a direct and indirect band gap, the direct and indirect energy gaps are found to be 2.778 and 2.682 eV for $ZnIn_2S_4$, and 2.725 and 2.651eV for $ZnIn_2S_4:Er^{3+}$ at 293 K. The photoluminescence spectra of $ZnIn_2S_4:Er^{3+}$ measured in the wavelength ranges of $500nm{\sim}900nm$ at 10 K. Eight sharp emission peaks due to $Er^{3+}$ ion are observed in the regions of $549.5{\sim}550.0nm,\;661.3{\sim}676.5nm$, and $811.1{\sim}834.1nm$, and $1528.2{\sim}1556.0nm$ in $CdGaInS_4:Er^{3+}$ single crystal. These PL peaks were attributed to the radiative transitions between the split electron energy levels of the $Er^{3+}$ ions occupied at $C_{2v}$, symmetry of the $ZnIn_2S_4$ single crystals host lattice.

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Crystal Structure of Antiinflammatory Sulindac

  • 구정회;김상헌;신완철
    • Bulletin of the Korean Chemical Society
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    • 제6권4호
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    • pp.222-224
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    • 1985
  • The crystal structure of sulindac, $C_{20}H_{17}Fo_3S$, one of the nonsteroid antiinflammatory agents, has been determined by the X-ray diffraction techniques using diffractometer data obtained by the $\varpi-2{\theta}$ scan technique with Cu $$K_{\alpha}$$ radiation from a crystal with space group symmetry Pbca and unit cell parameters a = 8.166(1), b = 18.291(8), c = 23.245(10) ${\AA}.$ The structure was solved by direct methods and refined by full-matrix least-squares to a final R = 0.11 for the 1153 observed reflections. The carboxyl group is nearly perpendicular to the indenyl ring as observed in indomethacin. The dihedral angle between the indenyl and phenyl rings is $35^{\circ}while$ the corresponding angle in indomethacin is $67^{\circ}.$ Crystal packing consists of a hydrogen bond and partial ring stacking between the indenyl rings.

Magnetic Properties of Cr-doped LiNbO3 by Using the Projection Operator Technique

  • Park, Jung-Il;Lee, Hyeong-Rag;Lee, Haeng-Ki
    • Journal of Magnetics
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    • 제16권2호
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    • pp.108-113
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    • 2011
  • The electron spin resonance lineshape (ESRLS) function for the electron spin resonance linewidth (ESRLW) of $Cr^{3+}$ (S = 3/2) in ferroelectric lithium niobate single crystals doped with 0.05 wt% of Cr, is obtained by using the projection operator technique (POT), developed by Argyres and Sigel. The ESRLS function is calculated to be axially symmetric about the c - axis and analyzed by using the spin Hamiltonian $H_{SP}={\mu}_B(B{\cdot}{^\leftrightarrow_{g}}{\cdot}S)+S{\cdot}{^\leftrightarrow_{D}}{\cdot}S$ with the parameters g = 1.972 and D = $0.395\;cm^{-1}$. In the ca plane, the linewidths show a strong angular dependence, whereas in the ab plane, they are independent of the angle. This result implies that the resonance center has an axial symmetry along the c - axis. Further, from the temperature dependence of the linewidths that is shown, it can be seen that the linewidths increase as the temperature increases, at a frequency of v = 9.27GHz. This result implies that the scattering effect increases with increasing temperature. Thus, the POT is considered to be more convenient to explain the scattering mechanism as in the case of other optical resonant systems.

PIV를 이용한 액체램제트 연소기내의 3차원 유동특성 연구 (Investigations of Three Dimensional Flow Characteristics in the Liquid Ramjet Combustor using PIV Method)

  • 양근수;김규남;조동우;손창현;문수연;이충원
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2001년도 춘계학술대회논문집E
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    • pp.271-275
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    • 2001
  • Three dimensional flow characteristics in a liquid fuel ramjet combustor are investigated using PIV method. The combustors have two rectangular inlets that form 90 degree each other. Three guide vane is installed in each rectangular inlet to improve the flow stability. We made three cases of test combustors in which those inlet angles are 30 degree, 45 degree and 60 degree. Each combustor easily changes the size of combustor's recirculation zone with the replacement of combustors dome. The experiments are performed in the water tunnel test with the same Reynolds number in the case of Mach 0.3 at inlet. PIV software is developed to measure the flow field in the combustor and the accuracy of developed PIV program is verified with rotating disk experiment and standard data. The experimental results show that the two main streams from rectangular inlet collide near the plane of symmetry and generate two large longitudinal vortex, A large and complex three-dimensional recirculating flow is measured in the recirculation zone.

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Epitaxial growth of Pt Thin Film on Basal-Plane Sapphire Using RF Magnetron Sputtering

  • 이종철;김신철;송종환;이충만
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 1998년도 제14회 학술발표회 논문개요집
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    • pp.41-41
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    • 1998
  • Rare earth metal films have been used as a buffer layer for growing ferroelectric t thin film or a seed layer for magnetic multilayer. But when it was deposited on s semiconductor substrates for the application of magneto-optic (MO) storage media, it i is difficult to exactly measure magnetic cons떠nts due to shunting current, and so it n needs to grow metal films on insulator substrate to reduce such effect. Recently, it w was reported that ultra-thin Pt layer were epitaxially grown on A12O:J by ion beam s sputtering in 비떠 high vacuum and it can be used as a seed layer for the growth of C Co-contained magnetic multilayer. In this stu$\phi$, Pt thin film were epi떠xially grown on AI2D3 ($\alpha$)OJ) by RF magnetron s sputtering. The crystalline structure was analyzed by transmission electron microscope ( (TEM) and Rutherford Back Scattering (RBS)/Ion Channeling. In TEM study, Pt was b believed to be twinned on AI잉3($\alpha$)01) su$\pi$ace about Pt(ll1) plane.Moreover, RBS c channeling spectra showed that minimum scattering yield of Pt(111)/AI2O:J(1$\alpha$)OJ) was 4 4% and Pt(11J)/AI2D3($\alpha$)OJ) had 3-fold symmetry.

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유한요소법을 이용한 가변 스트레치 성형공정의 적합성 검증 (Usefulness Verification for Flexible Stretch Forming Process using finite Element Method)

  • 서영호;허성찬;박중원;송우진;구태완;김정;강범수
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2009년도 추계학술대회 논문집
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    • pp.241-244
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    • 2009
  • This paper deals with a usefulness verification of stretch forming process using flexible die. The stretch forming method is widely used in aircraft and high-speed train industries for manufacturing of skin structure, which is made of sheet metal. A great number of solid dies are originally used and developed for specific shapes with respect to different curvature radii of the skin structures. Accordingly, flexible stretch forming process is proposed in this study. It replaces the conventional solid dies with a set of height adjustable discrete punches. A usefulness of the flexible die is verified through extensive numerical simulations of the stretch forming process for simply curved sheet plate. The elastic recovery is considered and formability evaluations are conducted through a comparison of symmetry plane configurations.

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High-Performance Liquid Chromatographic Method for Quantitative Estimation of an Antioxidant Principle Chlorogenic Acid in Saussarea costus and Arctium lappa

  • Pandey, Madan Mohan;Govindarajan, Raghavan;Rawat, Ajay Kumar Singh;Pangtey, Yashpal Singh;Mehrotra, Shanta
    • Natural Product Sciences
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    • 제10권1호
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    • pp.40-42
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    • 2004
  • A simple quantitative HPLC method has been developed for differentiating two plants of Asteraceae family viz. S. costus and A. lappa by using a pharmacologically active constituent chlorogenic acid and symmetry C18 column clubbed with a binary gradient using acetonitrile: 0.1% phosphoric acid and detected using a PDA at 327 nm. Quantitatively chlorogenic acid was found to be more in A. lappa (0.140%) than in S. costus (0.087%).

SYMMETRY AND UNIQUENESS OF EMBEDDED MINIMAL HYPERSURFACES IN ℝn+1

  • Park, Sung-Ho
    • 대한수학회보
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    • 제58권1호
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    • pp.21-30
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    • 2021
  • In this paper, we prove some rigidity results about embedded minimal hypersurface M ⊂ ℝn+1 with compact ∂M that has one end which is regular at infinity. We first show that if M ⊂ ℝn+1 meets a hyperplane in a constant angle ≥ ��/2, then M is part of an n-dimensional catenoid. We show that if M meets a sphere in a constant angle and ∂M lies in a hemisphere determined by the hyperplane through the center of the sphere and perpendicular to the limit normal vector nM of the end, then M is part of either a hyperplane or an n-dimensional catenoid. We also show that if M is tangent to a C2 convex hypersurface S, which is symmetric about a hyperplane P and nM is parallel to P, then M is also symmetric about P. In special, if S is rotationally symmetric about the xn+1-axis and nM = en+1, then M is also rotationally symmetric about the xn+1-axis.

Spectral and Geometrical Study of Two Cadmium Complexes, mer-R,S-[Cd(aepn)2]X2 (X: I-, Cl-, aepn: N-(2-Aminoethyl)-1,3-propanediamine) Supported by Solution Experiments

  • Hakimi, Mohammad;Mardani, Zahra;Moeini, Keyvan
    • 대한화학회지
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    • 제57권4호
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    • pp.447-454
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    • 2013
  • In this research, two new complexes of N-(2-aminoethyl)-1,3-propanediamine (aepn), $[Cd(aepn)_2]I_2$ (1) and $[Cd(aepn)_2]Cl_2{\cdots}H_2O$ (2), were prepared and identified by elemental analysis, FT-IR, Raman spectroscopy and single-crystal X-ray diffraction. Geometry around the cadmium atom in two complexes by coordination of six nitrogen atoms of two aepn is distorted octahedral. If distortion in the mer-$[Cd(aepn)_2]^{2+}$ cation is disregarded, it has a $C_2$ axis and $C_2$ symmetry. The cyclic voltammetry experiments were carried out to study the complexation process. Two structural surveys on coordination modes and complexes of aepn are presented. A study was carried out using CSD data to estimate the averages of bond lengths for different types of the Cd-N bonds. It was found that the intermolecular $N-H{\cdots}I$, $C-H{\cdots}I$ hydrogen bonds in 1 and $N-H{\cdots}Cl$, $N-H{\cdots}O$, $C-H{\cdots}O$, $O-H{\cdots}Cl$ in 2 stabilized the crystal networks.

The Crystal and Molecular Structure of $N_1$-Cyclohexyl-$N_1$-(o-Chlorobenzal) Imino Thiourea

  • Koo, Chung-Hoe;Kim, Hojing;Kim, Hoon-Sup;Chang, Chong-Whan
    • 약학회지
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    • 제21권3호
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    • pp.146-158
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    • 1977
  • N$_{1}$-cyclohexyl-$N_{2}$-(o-chlorobenzal) imino thiourea, $C_{14}$H$_{18}$N$_{3}$SCI, crystallizes in $C_{2}$/c, with a=19.68, b=7.74, c=20.42$\AA$, ${\beta}$=$92.$8^{\circ}$ and eight formula units in the unit cell. The structure was solved by the study of Patterson sections, calculated from three-dimensional film data, and was refined by block-diagonal least-squares methods to R=0.16 based on 1288 independent intensity data. The rest atoms of N$_{1}$-cyclohexyl-$_{2}$-(o-chlorobenzal) imino thiourea molecule excluding cyclohexan ring and chlorine atoms approximately lie on a plane. A pair of molecules related by the symmetry centers are connected directly with the N-H.......S hydrogen bonds. Apart from the hydrogen bonding system the structure is held together by the van der Waals forces.

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