• 한국초전도학회:학술대회논문집
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• 한국초전도학회 2002년도 High Temperature Superconductivity Vol.XII
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• pp.25-25
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• 2002

• 한국결정학회지
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• 제11권2호
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• pp.84-88
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• 2000

The crystal of cholesteryl crotylcarbonate was investigated by X-ray diffraction method. Crystallographic data for the title compound: P21, a=13.510(2)Å, b=11.843(2)Å, c=19.882(2)Å, β=106.88(1)°, Z=4. Reflections were collected with an Enraf-Nonius CAD-4 diffractometer equipped with a graphite monochromator. The structure was solved by direct methods and refined by least-squares analyses. The final R value was 0.125 for 2607 reflections. The cholesterol fragment of the title compound were in good agreement with those for related cholesterol derivatives. The molecules were stacked in clearly separated layers. At the center of the layers, there were cholesteryl-cholesteryl interactions between the symmetry-related B molecules and the cholesteryl-C(17) side chain of A molecules. There were also interactions between the C(17) side chain of B molecules and the crotylcarbonate chain in the interface region between layers. The crystal structure of the title compound turned out to be isostructural with those of cholesteryl ethylcarbonate and cholesteryl propylcarbonate.

• Journal of Industrial and Engineering Chemistry
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• 제68권
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• pp.109-116
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• 2018

$Eu_2(SO_4)_3$ was synthesized by chemical precipitation method and the crystal structure was determined by Rietveld analysis. The compound crystallizes in monoclinic space group C2/c. In the air environment, $Eu_2(SO_4)_3$ is stable up to $670^{\circ}C$. The sample of $Eu_2(SO_4)_3$ was examined by Raman, Fourier-transform infrared absorption and luminescence spectroscopy methods. The low site symmetry of $SO_4$ tetrahedra results in the appearance of the IR inactive ${\nu}_1$ mode around $1000cm^{-1}$ and ${\nu}_2$ modes below $500cm^{-1}$. The band intensities redistribution in the luminescent spectra of $Eu^{3+}$ ions is analyzed in terms of the peculiarities of its local environment.

• 한국결정학회지
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• 제5권1호
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• pp.1-6
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• 1994

화합물 VP6N3018C243H60의 두 가지 가능한 공간군은 PT,a=14.O22(1), b=12.644(2), c=12.640(1)A, a=80.38(1), β=102.12(1), y =102.16(1), V=2124.1A3, Z=2, u=0.47cm-1,d==1.46g/cm3, Fo>4c IfoI인 3350윤의 독립반사강도에 대하여 R=0.083 과 C2/c, a=19.32(2), b=16.32(2), c=14.02(1)A, β= 105.98(5), V=4348.2A3, Z=4, Fo>4o IFoI인 1590개의 독립반사강도에 대하여 R=0.083 이다. 주간군 Pi의 경우 단위포내에 두 분자가 있는데 각 분자내의 바나둠 원자가 특수치치에 있어 중심대칭에 의하여 한 분자를 이루고 있으므로 단위포내의 비대칭단위는 두개의 bis(timetalhosphate)vanadate 반분자와 3개의 tetraethylammDnium분자로 되어있다. 공문군 C2/c의 경우 bis(trimetaphosphate)vanadate 한분자의 vanadium 원자가 중심대1칭을 갖는 변광단동치에 있으며, 3개의 tetrethylammonium 분자중 한 분자내의 CL2, N2, C25 원자들을 2-회회전대칭축이 지나므로 bis(trimetaphosphate)vanadate 반분자와 tetraethylammonium 3/2 분자가 비대칭단위를 이루고 있다. 두 경우 공히 vanadium원자를 배위하고 있는 6개의 산소원자가 8함체를 이루며 nitrogen원자와 결합하고 있는 4개의 carbon 원자들은 모두 disorder되어 있어 nitrogen원자의 주권에 있는 8개의 carbon 원자들은 불규칙한 12면체를 이루고 있다.

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제49권7호
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• pp.382-387
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• 2000

The $CdAl_2S_4 and CdAl_2S_4 : Co^{2+}$ single crystals were grown by the chemical transport reaction method using iodine as a transport agent. The $CdAl_2S_4 and CdAl_2S_4 : Co^{2+}$single crystals were crystallized into a defect chalcopyrite structure. The optical energy gap of the $CdAl_2S_4 and CdAl_2S_4 : Co^{2+}$ single crystals was found to be 3.377 eV and 2.924 eV, respectively, at 300 K. Blue emission with peaks in 456nm~466nm at 280K was observed in the $CdAl_2S_4$ single crystal. Optical absorption and emission peaks due to impurities in the $CdAl_2S_4 Co^{2+}$ single crystal were observed and described as originating from the electron transition between energy levels of the $Co^{2+} ion sited at the Td symmetry point.

• Bulletin of the Korean Chemical Society
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• 제15권1호
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• pp.64-74
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• 1994

The nonstoichiometric chalcogenides with NaCl-type structure were prepared and the physical and structural properties were studied. The homogeneous range and the structural change were studied based on X-ray powder diffractions using Rietveld-type full-profile fitting technique. Wide homogeneous ranges were observed in Y-S and Y-Se systems, and relatively narrow homogeneous ranges were observed in Yb-S and Yb-Se systems. Both in $Yb_{1-x}S\;and\;Yb_{1-x}Se$, a vacancy ordering transition occurred in (111) plane direction. The ordered superstructure had cubic symmetry(Fm$\bar{3}m) with doubled unit cell "a" parameter compared to the original NaCl-type. The superlattice developed in a continuous second-order transitiion was characterized by the reduced waved vector k= $(a^*+b^*+c^*)/2$. Y-S system had metallic, and YSe, YbSe system had semiconducting properties in their homogeneous ranges. It was observed that the change of electronic transport properties in extended homogeneous range did not depend on the relativeratio of metal to nonmetal, but on the quantities of vacancies.

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제54권7호
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• pp.304-307
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• 2005

The $In_2S_3\;and\;In_2S_3:Co^{2+}$ thin films were grown by the spray Pyrolysis method. The thin films crystallized into tetragonal structures. The indirect energy band gap was 2.32ev for $In_2S_3\;and\;1.81eV\;for\;In_2S_3:Co^{2+}$ at 298K. The direct energy band gap was 2.67ev for $In_2S_3:Co^{2+}$ thin films. Impurity optical absorption peaks were observed for the $In_2S_3:Co^{2+}$ thin films. These impurity absorption peaks are assigned, based on the crystal field theory to the electron transitions between the energy levels of the $Co^{2+}$ ion sited in $T_{d}$ symmetry. The electrical conductivity($\sigma$), Hall mobility(${\mu}_H$), and carrier concentration (n) of the $In_2Se_3$ thin film were measured, and their temperature dependence was investigated.

• 비파괴검사학회지
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• 제22권2호
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• pp.140-148
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• 2002

중수로 압력관으로 사용되는 Zr-2.5Nb 재료의 고온 이방성 탄성계수를 고온 초음파공명분광법(RUS)로 측정하였다. 소형 가열로 내에 알루미나 waveguide와 광대역 초음파 센서를 사용하여 초음파에너지를 시편에 가하고 시편의 공명주파수를 측정하였다. 압력관의 축 방향, 반경 방향, 원주 방향에 일치하도록 장방형 시편을 가공하였으며 각 방향에 대한 탄성계수 텐서 9개의 값을 상온${\sim}500^{\circ}C$ 온도 구간에서 측정하였다. 탄생계수 텐서, $c_{ij}$는 모두 온도가 증가함에 따라 점진적으로 감소하며 원주 방향의 탄성계수가 축 방향 및 반경 방향의 탄성계수보다 높았다. 이것은 Young's modulus나 shear modulus의 경우에도 일치하였으며 축 방향과 반경 방향의 경우 큰 차이를 나타내지 않았다. 축 방향 및 반경 방향의 비틀림 탄생계수가 $150^{\circ}C$ 부근에서 서로 교차하였으며 이는 단결정 지르코늄의 $c_{44}$ 및 $c_{66}$의 교차 현상과 일치하였다.

• 제어로봇시스템학회:학술대회논문집
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• 제어로봇시스템학회 2005년도 ICCAS
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• pp.848-851
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• 2005

This paper proposes a design of IIR notch filter with modified pole placements. The pole angle is derived from quadratic programming to find the appropriate pole position on the unit circle in z-plane in order to achieve the symmetry of the amplitude response. The simulation results are shown when compared with the conventional design technique. Moreover, it uses the TMS320C31 DSP chip for hardware implementation. Finally, the hardware implementation can be applied to removal of ECG baseline wander and elimination of AC power line interference in ECG signal.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1998년도 추계학술대회 논문집 학회본부A
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• pp.40-42
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• 1998

Magnetization distribution in the ring magnet for BLDC motor is generally nonuniform because the structure of mutipole magnetizer is not symmetry and the air gap is not uniform. In this paper, the effect of the nonuniform magnetization on characteristics of the motor such as torque ripple, unbalanced force and current is examined. Time stepped finite element method is used for electromagnetic field analysis.