• 제목/요약/키워드: $CR_n$

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TiC, TiN, CrN, TiCrN, TiAlN 코팅의 산화특성 (Oxidation Characteristics of TiC, TiN, CrN, TiCrN and TiAlN Coatings)

  • ;황연상;원성빈;이동복
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2013년도 춘계학술대회 논문집
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    • pp.119-120
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    • 2013
  • 공구, 다이몰드 등에 널리 쓰이는 TiC, TiN, CrN, TiCrN, TiAlN 코팅의 산화특성을 비교하기 위하여 $600^{\circ}C-900^{\circ}C$에서 대기중 산화시험을 실시하였다. 내산화성은 (TiC, TiN), TiAlN, TiCrN, CrN 코팅의 순서로 증가하였다. 코팅원소중 Ti는 $TiO_2$로, Cr은 $Cr_2O_3$로, Al은 $Al_2O_3$로 산화되었다.

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이중층 주기가 CrZrN/CrZrSiN 다층 코팅의 기계적 특성에 미치는 영향 (Influence of Bilayer Periods on the Mechanical Properties of CrZrN/CrZrSiN Multilayer Coatings)

  • 김회근;라정현;배기태;이상율
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2015년도 추계학술대회 논문집
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    • pp.293-293
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    • 2015
  • 최근 다층 코팅의 합성을 통해 코팅의 경도, 내마모성 등의 기계적 물성을 향상시키는 연구가 활발히 진행되고 있다. 본 연구에서는 높은 경도, 낮은 마찰계수, 우수한 고온 특성을 함께 나타내기 위해 CrZrN/CrZrSiN 다층 코팅을 설계하였고, 이중층 주기를 조절하여 CrZrN/CrZrSiN 다층 코팅의 물성변화를 확인하였다.

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다양한 Cr-N 중간층을 증착한 CrZrN 코팅의 밀착력에 관한 연구 (The Study on Adhesion Strength of the CrZrN Coatings with Various Cr-N Interlayers)

  • 김회근;라정현;김규성;이상율;권오진
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2014년도 추계학술대회 논문집
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    • pp.225-225
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    • 2014
  • 텅스텐 카바이드(WC) 모재와 CrZrN 코팅 사이의 밀착력을 향상시키기 위해 다양한 Cr-N 중간층이 합성되었다. 질소 분압을 조절하여 Cr-N 중간층 내의 질소 함량을 변화시켰으며, 그 결과 다양한 조성을 갖는 Cr-N 중간층이 합성되었으며 중간층의 물성이 변화하여 밀착력에 영향을 주었다.

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Cr Interlayer 삽입에 따른 Cr-Al-Si-N 코팅과 SUS 304 기판의 밀착 특성 연구 (Effects of Cr Interlayer on Adhesion Properties between Cr-Al-Si-N Coatings and SUS 304 Substrate)

  • 최광수;홍영수;김광호
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2009년도 추계학술대회 초록집
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    • pp.165-166
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    • 2009
  • 이 연구에서는 SUS304 기판과 Cr-Al-Si-N 코팅사이의 밀착특성을 향상시키기 위하여 하이브리드 증착법으로 Cr Interlayer를 기판위에 증착시킨 후 Cr-Al-Si-N 코팅을 증착하였다. 그리고 Ball-on-disk 마모테스트와 스크래치 테스트를 통해 밀착력, 파괴기구, 그리고 마찰거동 등을 살펴보았다. Cr-Al-Si-N 코팅에 60nm 두께의 Cr Interlayer 삽입되었을 때는 기판에 Cr-Al-Si-N 코팅만 증착되었을 때의 밀착력(${\sim}30N$) 보다 더 우수한 ${\sim}50N$의 밀착력을 나타내었고 내마모성 또한 향상되었다. 밀착력 증가는 Cr Interlayer 삽입에 따른 SUS304 기판과 Cr-Al-Si-N 코팅사이의 전단응력 감소에 기인한 것으로 사료된다.

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아아크방전 유도형 이온플레이팅에 의한 Cr-N 피막의 특성 (Properties of Cr-N Films Prepared by the Arc-induced Ion Plating)

  • 정재인;문종호;홍재화;강정수;이영백
    • 한국표면공학회지
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    • 제24권1호
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    • pp.24-24
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    • 1991
  • Cr-N films were deposited on low-carbon steel sheets by the reactive arc-induced ion plating (AIIP). The influence of the deposition conditions (nitrogen pressure and substrate bias voltage) on the crystal orientation, morphology and microhardness of the Cr-N films has been investigated using x-ray diffractometer and scanning electron microscope. The impurities and contaminations on the surface and at the interface, and the layer-by-layer compositions of the film have been analyzed using scanning Auger multiprobe (SAM) and glow discharge spectroscope (GDS). The mixed state of Cr and Cr2N turned out to have a fine fibrous structure. The Cr2N films were deposited at a wide range of nitrogen flow rates. The orientations of Cr2N films were mainly (110) and (111), and the intensity of the (111) peak increased as the substrate bias voltage increased. The micorstructure of the Cr2N film was dense and no columnar structure was observed. The films in the mixed state of Cr2N and CrN were also dense without columnar structure. The maximum microhardness of the Cr-N films was 2400 kg/$\textrm{mm}^2$ at 10gf load.

Influence of N2 partial pressure on the characteristics of Cr-Zr-N coatings synthesized using a Cr-Zr segment target

  • 김광석;김영수;이상율
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2008년도 추계학술대회 초록집
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    • pp.1-1
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    • 2008
  • 본 연구에서는 비대칭 마그네트론 스퍼터링법을 이용하여 Cr-Zr-N 박막을 합성하였다. Cr-Zr-N 박막의 합성을 위해 사용된 타겟은 Cr 과 Zr의 segments(Cr:Zr= 50:50 vol.%)로 구성된 단일 타겟을 사용하였고, 공정조건 중 질소분압을 변화시켜 Cr-Zr-N 박막을 합성하였다. 또한 질소분압 변화에 따른 박막의 물리적, 기계적, 화학적 특성들의 변화를 분석하였으며, 기 발표된 Cr 타겟과 Zr 타겟을 이용하여 합성된 Cr-Zr-N 박막의 특성들과 비교하였다.

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아아크방전 유도형 이온플레이팅에 의한 Cr-N 피막의 특성 (Properties of Cr-N Films Prepared by the Arc-induced Ion Plating)

  • 정재인;문종호;홍재화;강정수;이영백
    • 한국표면공학회지
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    • 제25권1호
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    • pp.24-33
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    • 1992
  • Cr-N films were deposited on low-carbon steel sheets by the reactive arc-induced ion plating (AIIP). The influence of the deposition conditions (nitrogen pressure and substrate bias voltage) on the crystal orientation, morphology and microhardness of the Cr-N films has been investigated using x-ray diffractometer and scanning electron microscope. The impurities and contaminations on the surface and at the interface, and the layer-by-layer compositions of the film have been analyzed using scanning Auger multiprobe (SAM) and glow discharge spectroscope (GDS). The mixed state of Cr and Cr₂N turned out to have a fine fibrous structure. The Cr₂N films were deposited at a wide range of nitrogen flow rates. The orientations of Cr₂N films were mainly (110) and (111), and the intensity of the (111) peak increased as the substrate bias voltage increased. The microstructure of the Cr₂N film was dense and no columnar structure was observed. The films in the mixed state of Cr₂N and CrN were also dense without columnar structure. The maximum microhardness of the Cr-N films was 2400 kg/㎟ at 10 gf load.

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AIP법으로 증착된 TiN/CrN 다층박막의 특성 분석 (Analysis of Properties Multi-Layered TiN/CrN Thin Films Deposited by AIP Method)

  • 백민숙;윤동주;허기복;김병일
    • 한국재료학회지
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    • 제28권7호
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    • pp.405-410
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    • 2018
  • TiN and CrN thin films are among the most used coatings in machine and tool steels. TiN and CrN are deposited by arc ion plating(AIP) method. The AIP method inhibits the reaction by depositing a hard, protective coating on the material surface. In this study, the characteristics of multi-layer(TiN/CrN/TiN(TCT), CrN/TiN/CrN(CTC)) are investigated. For comparison, TiN with the same thickness as the multilayer is formed as a single layer and analyzed. Thin films formed as multilayers are well stacked. The characteristics of micro hardness and corrosion resistance are better than those of single layer TiN. The TiN/CrN peak is confirmed because both TCT and CTC are formed of the same component(TiN, CrN), and the phase is first grown in the (111) direction, which is the growth direction. However, the adhesion and abrasion resistance of the multilayer films are somewhat lower.

Wear Mechanism of CrN Coating on Aluminum Alloys Deposited by AIP Method

  • Kim, Seock-Sam;Suh, Chang-Min;Murakami, Ri-ichi
    • KSTLE International Journal
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    • 제3권1호
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    • pp.43-48
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    • 2002
  • Dry sliding wear and friction test of CrN coaling on two types of aluminum alloy substrates,6061 Al and 7075 Al deposited by arc ion plating, was peformed with a ball-on-disk tribometer. The effects of normal Bead and the mechanical properties of substrate on the friction coefficient and wear-resistance of CrN coating were investigated. The worn surfaces were observed by SEM. The results show that surface micro-hardness of CrN- coated 7075 Al is higher than that of CrN-coated 6061 Al. With an increase in normal lead, wear volume increases, while the friction coefficient decreases. The friction coefficient of CrN-coated 6061 Al is higher than that of CrN-coated 7075 Al, while the wear-resistance of CrN-coated 6061 Al is lower than the CrN-coated 7075 Al's, which indicates that the substrate mechanical properties have strong inf1uences on the friction coefficient and wear of CrN coating. The main wear mechanism was fragments of CrN coating, which were caused by apparent plastic deformation of substrate during wear test.

Machanical and electrochemical properties of CrZrN coatings as a function of $N_2$ partial pressure synthesized using a Cr-Zr segment target

  • 김영수;이하나;이상율
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2009년도 추계학술대회 초록집
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    • pp.138-138
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    • 2009
  • Cr과 Zr의 segments(Cr:Zr= 50:50 vol.%)로 구성되어진 단일타겟을 이용하여 CrZrN 박막을 합성하였다. CrZrN 박막은 비대칭 마그테트론 스퍼터링법을 이용하였으며, 공정조건 중 질소분압을 변화시켜 CrZrN 박막을 합성하였다. 질소분압 변화에 따른 CrZrN 박막의 기계적, 화학적 특성들의 변화를 분석하였다.

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