• 대한설비공학회:학술대회논문집
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• 대한설비공학회 2007년도 동계학술발표대회 논문집
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• pp.652-657
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• 2007

This paper is an interim report on the investigation of thermodynamic properties of $CO_2$/oil mixture refrigerant. First, liquid density of POE (poly-ol ester) and PAG (poly alkylene glycol) were measured and expressed as a function of temperature. Then, a solubility equation was developed which enables us to calculate the weight fraction of $CO_2$ for the mixture in a liquid state. An experimental apparatus with a cell was constructed to measure P-$\upsilon$-T-$\chi$ data for $CO_2$/oil mixture. The volume of the cell was determined using a certain formula considering change in volume as a function of temperature and pressure. Then, experimental data were obtained over the temperatures $40^{\circ}C$, $50^{\circ}C$, $60^{\circ}C$, $70^{\circ}C$ and $80^{\circ}C$ with various mole fractions. Finally, assuming a primitive model of ideal gas, the volume of $CO_2$/oil mixture was predicted with a relatively larger error of 5.05% for $CO_2$/PAG and 8.81% for $CO_2$/POE. The volume of $CO_2$/oil mixtures would be better predicted using an appropriate equation of state, of which results will be reported soon.

• 대한설비공학회:학술대회논문집
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• 대한설비공학회 2008년도 동계학술발표대회 논문집
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• pp.131-136
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• 2008

The oil separation in an oil separator is one of the most important characteristics for proper compressor operation. In this study, a gravity type of oil separator is used. Oil separation characteristics has been investigated for $CO_2$/PAG mixture in the range of oil concentration 0 to 5 weight-percent and the mixture temperature range of $5^{\circ}C$ to $15^{\circ}C$ and $70^{\circ}C$ to $90^{\circ}C$. The results obtained indicate that the oil separation is increased with an increase in the oil concentration. It is also found that the oil separation in liquid state is increased with an increase in the mixture temperature while the oil separation in gas state is decreased.

• 설비공학논문집
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• 제19권12호
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• pp.842-849
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• 2007

For a $CO_2$ two-stage twin rotary compressor used for heat pump water heater system, changes of $CO_2$ solubility in PAG oil were investigated along the gas passages from the first stage suction to final discharge. Only slight changes in solubility took place in suction chambers for both of the first and second stages, but for compression chambers, solubility variation ranged from 0.115 to 0.136, and from 0.133 to 0.182, respectively for the first and second stages. Calculation of gas flashing in parts of leakage oil flows and of oil contained in control volumes due to solubility changes was conducted and included in gas pressure calculation. For the second stage, gas flashing amounts to around $5%\sim6%$ for most leakage flows. Cooling capacity, compressor input, and COP obtained by calculation were well compared to the experimental results. Effects of operation speed on the compressor performance was also studied: as the shaft speed increased, adiabatic efficiency decreased rapidly due to increased over-compression loss.

• 대한설비공학회:학술대회논문집
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• 대한설비공학회 2005년도 동계학술발표대회 논문집
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• pp.380-385
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• 2005

An experimental apparatus was constructed to obtain vapor-liquid equilibrium data for $CO_2$/oil mixtures using mass analysis method with sample cylinder. Lubricants employed were POE(Polyol Ester) oil and PAG(Poly Alkylene Glycol) oil. The phase equilibria of $CO_2$/oil mixtures formed in high pressure equilibrium cell are observed through sight glasses at the opposite ends. Data were measured over the temperature range from -10 to $10^{\circ}C$ with $5^{\circ}C$ intervals under pressures up to 14 MPa. Mole fractions were calculated for $CO_2$/oil and $CO_2$/PAAG, respectively and were compared with each other.

• 설비공학논문집
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• 제23권1호
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• pp.73-79
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• 2011

A portion of oil for lubrication of compressor flows together with refrigerant in the refrigeration system. If the oil discharge from a compressor is increased in the refrigeration system, not only pressure drop is increased in other components, such as evaporator and gas cooler, but also heat transfer coefficient in the heat exchangers is decreased. Oil discharge rate from a compressor may strongly depend on operating conditions of a compressor. In this study, one stage single rotary compressor is employed for measuring oil circulation ratio(OCR). Carbon dioxide and PAG oil are used as refrigerant and lubricant. Using a U-tube densimeter, mixture density is measured. Oil circulation ratio(OCR) can be estimated by measured mixture density. The results obtained indicate that the oil circulation ratio(OCR) is increased as the suction temperature or compressor operating frequency is increased. Oil circulation ratio(OCR) correlation of the compressor is also suggested.

• 대한설비공학회:학술대회논문집
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• 대한설비공학회 2007년도 하계학술발표대회 논문집
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• pp.9-9
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• 2007

• 설비공학논문집
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• 제20권2호
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• pp.106-112
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• 2008

In this paper, the experimental results on evaporation heat transfer characteristics were reported for a micro-fin tube using $CO_2$. An experimental refrigerant loop had been established to measure the evaporation heat transfer coefficient and pressure drop of $CO_2$. Experiments were conducted for mass fluxes, heat fluxes, saturation temperatures and PAG oil concentrations. With increasing the heat flux and the saturation temperature, the evaporation heat transfer coefficient increased. At the higher mass flux, however, the exit vapor quality of the micro-fin tube was to be lower. The peak of the heat transfer coefficient was shifted toward low quality region. The evaporation pressure drop increased as the mass flux increased and the saturation temperature decreased. As PAG oil concentration increased, the evaporation heat transfer coefficient decreased and the dryout was delayed by oil addition.

• International Journal of Air-Conditioning and Refrigeration
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• 제17권3호
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• pp.88-93
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• 2009

Lubricant oil is needed in air conditioning and refrigeration system because the compressor requires oil to prevent surface to surface contact between its moving parts, to remove heat, to provide sealing, to keep out contaminants, to prevent corrosion, and to dispose of debris created by wear. Thus, the oil separation in an oil separator is one of the most important characteristics for proper compressor operation. In this study, a gravity type of oil separator is used. Oil separation characteristics have been investigated for $CO_2$/PAG mixture in the range of oil concentration 0 to 5 weight-percent and the mixture temperature range of $0^{\circ}C$ to $15^{\circ}C$ at 50 bar and $70^{\circ}C$ to $90^{\circ}C$ at 80 bar. The results obtained indicate that the oil separation is increased with an increase in the oil concentration. It is also found that the oil separation in liquid state is increased with an increase in the mixture temperature while the oil separation in gas state is decreased.

• 설비공학논문집
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• 제21권1호
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• pp.16-22
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• 2009

In order to investigate $CO_2$ heat transfer coefficient and pressure drop by PAG oil concentration during $CO_2$ evaporation, the experiment on evaporation heat transfer characteristics in a mini-channels were performed. The experimental apparatus consisted of a test section, a DC power supply, a heater, a chiller, a mass flow meter, a pump and a measurement system. Experiment was conducted for various mass fluxes($300{\sim}800kg/m^{2}s$), heat fluxes($10{\sim}40kW/m^2$) saturation temperatures($-5{\sim}5^{\circ}C$), and PAG oil concentration(0, 3, 5wt%). The variation of the heat transfer coefficient was different according to the oil concentration. With the increase of the oil concentration, the evaporation heat transfer coefficient decreased and the delay of dryout by oil addition was found. Pressure drop increased with the increase of the oil concentration and heat flux, and the decrease of saturation temperature.

• Macromolecular Research
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• 제17권9호
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• pp.651-657
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• 2009

This study examined the optimum compositions of binder, photo-acid generator (PAG) and sensitizer for the cationic ring opening polymerization of 1,3-bis[2-(3-{7-oxabicyclo-[4.1.0]heptyl})]-tetramethyldisiloxane in the presence of polydimethylsiloxane with four epoxide moieties as a co-monomer. When diffractive efficiency (DE) values were compared quantitatively to analyze the effect of the binder on holographic photopolymerization, DE was affected by the viscosity of the binders and miscibility with the monomer mixture. Extremely low DE values were observed when the immiscible dimethyl silicone was used as a binder. Therefore, methylphenyl silicone, which is miscible with the monomer mixture, was used as the binder for further studies. The optimal conditions were a binder viscosity between 250 to 390 cP, and contents of the binder, PAG, and sensitizer were 75-125 wt%, > 6 wt% and 0.05 wt% to the total monomer mixture, respectively.